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Experimental research of the stability of steel cylindricalshell subjected to circumferential compression
PublikacjaAt the Department of Metal Structures Gdańsk University of Technology, experiments have been performed on the stability of shell of steel cylindrical models. The experiments have been carried on a test bench built at the Department. The design based on other test benches which were created in the past by other scientists, where modernized by the courtesy of companies that offer modern solutions. The test bench enables to generate...
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Lower rim substituted p-tert-butylcalix[4]arene; Part 14. Synthesis, structures and binding studies of calix[4]arene thioamides
PublikacjaA number of p-tert-butylcalix[4]arene thioamides were synthesized and characterized by 1H-NMR and elemental analysis. Compounds 1-5 are O-substituted derivatives with -CH2-C(=S)-N-X groups, where NX = morpholidyl, NEt2, NHC2H4Ph, NHCH2Ph and NHEt,respectively. The X-ray structures of the ligands 1, 3, 5 and of the complex 3Pb(ClO4)2, (compound 6), are presented and their slightly distorted cone conformation is established. The...
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Determination of Sodium Ion Diffusion Coefficient in Tin Sulfide@Carbon Anode Material Using GITT and EIS Techniques
PublikacjaThe electroanalytical behavior of SnSx (x = 1, 2) encapsulated into a carbon phase was studied using the galvanostatic intermittent titration technique (GITT) and electrochemical impedance spectroscopy (EIS). These techniques are widely utilized in battery systems to investigate the diffusion of alkali metal cations in anode and cathode materials depending on the concentration of ions in the host material. Here, we report different...
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The role of organic and mineral constituents on kerogen transformation ratio
PublikacjaThe main aim of this dissertation is to determine the role of mineral and organic matter constituents in kerogen transformation ratio. Practical aspects of the work include application of the results in the assessment of hydrocarbon production potential; to make process of hydrocarbon recovery more predictable consistent and efficient. The work used shale from the Vaca Muerta formation from the Nequen basin in Argentina. The formation...
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Organic Supercritical Thermodynamic Cycles with Isothermal Turbine
PublikacjaOrganic Rankine cycles (ORC) are quite popular, but the overall efficiencies of these plants are rather very low. Numerous studies have been conducted in many scientific centers and research centers to improve the efficiency of such cycles. The research concerns both the modification of the cycle and the increase in the parameters of the medium at the inlet to the turbine. However, the efficiency of even these modified cycles rarely...
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A design framework and a digital toolset supporting the early-stage explorations of responsive kinetic building skin concepts
PublikacjaIn this paper we present the first phase of our research on the development of a framework for early-stage responsive kinetic building skin design. The aims of this study were: to formulate a methodological and instrumental basis for the construction of the framework, to conduct an initial pre-assessment of its features, and finally to provide the first example of how the framework could be applied in practice. Importantly, at...
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[NCh, ICh] Physical Chemistry of Organic Compounds in Natural Waters
Kursy Online{mlang pl} Dyscyplina: Nauki chemiczne Zajęcia obieralne dla doktorantów Prowadzący: prof. dr hab. Tadeusz Górecki Liczba godzin: 15 {mlang} {mlang en} Discipline: Chemical science Elective course for PhD students Academic teacher: prof. dr hab. inż. Tadeusz Górecki Total hours of training: 15 teaching hours {mlang}
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Sano-Tachiya-Noolandi-Hong, Onsager and Braun models vs Monte Carlo simulation of charge photogeneration in organic solids
PublikacjaThe Sano-Tachiya-Noolandi-Hong (STNH), Onsager, and Braun models as well as Monte Carlo (MC) simulations of charge recombination/separation have been applied for the first time to reproduce the results of the electromodulated photoluminescence measurements in vacuum-evaporated films of fluorescent materials commonly used in optoelectronic devices. The values of the electron-hole pair final recombination speed in the monomer emitters:...
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The influence of the carbon equivalent on the weldability of high-strength low-alloy steel in the water environment
PublikacjaFrom many years, the high strength low alloy steels are often used for offshore constructions. This constructions, due to the environment in which they work, require more frequent repairs than the constructions from the land. For economic reasons, repairs take place in the underwater conditions, however water significantly decreases the weldability of steel. The paper presents the results of the CTS weldability test for S460ML...
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Excited state properties of a series of molecular photocatalysts investigated by time dependent density functional theory.
PublikacjaTime dependent density functional theory calculations are applied on a series of molecular photocatalysts of the type [(tbbpy)2M1(tpphz)M2X2]2+ (M1 = Ru, Os; M2 = Pd, Pt; X = Cl, I) in order to provide information concerning the photochemistry occurring upon excitation of the compounds in the visible region. To this aim, the energies, oscillator strengths and orbital characters of the singlet and triplet excited states are investigated....
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Superconductivity on a Bi Square Net in LiBi
PublikacjaWe present the crystallographic analysis, superconducting characterization and theoretical modeling of LiBi, that contains the lightest and the heaviest nonradioactive metal. The compound crystallizes in a tetragonal (CuAu-type) crystal structure with Bi square nets separated by Li planes (parameters a = 3.3636(1)Å and c = 4.2459(2) Å, c/a = 1.26). Superconducting state was studied in detail by magnetic susceptibility and heat...
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MULTI-CRITERIA COMPARATIVE ANALYSIS OF THE USE OF SUBTRACTIVE AND ADDITIVE TECHNOLOGIES IN THE MANUFACTURING OF OFFSHORE MACHINERY COMPONENTS
PublikacjaThe dynamic development of additive manufacturing technologies, especially over the last few years, has increased the range of possible industrial applications of 3D printed elements. This is a consequence of the distinct advantages of additive techniques, which include the possibility of improving the mechanical strength of products and shortening lead times. Offshore industry is one of these promising areas for the application...
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Effect of heat treatment on the diffusion intermixing and structure of the Cu thin film on Si (111) substrate: a molecular dynamics simulation study
PublikacjaThis work is devoted to the study of the diffusion process at the interface between copper films with a thickness of 2, 3, 4, 7 and 10 atomic monolayers and silicon substrate by molecular dynamics simulation method. For this purpose, the variation of the concentration of copper and silicon along the perpendicular direction to the interface was investigated. An analysis of the density profile along this direction made it possible...
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Novel Diazocrowns with Pyrrole Residue as Lead(II) Colorimetric Probes
PublikacjaNovel 18- and 23-membered diazomacrocycles were obtained with satisfactory yields by diazocoupling of aromatic diamines with pyrrole in reactions carried under high dilution conditions. X-ray structure of macrocycle bearing five carbon atoms linkage was determined and described. Compounds were characterized as chromogenic heavy metal ions receptors. Selective color and spectral response for lead(II) was found in acetonitrile and...
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A simplified behavioral MOSFET model based on parameters extraction for circuit simulations.
PublikacjaThe paper presents results on behavior modeling of general purpose Metal-Oxide Semiconductor Field-Effect Transistor (MOSFET) for simulation of power electronics systems requiring accuracy both in steady-state and in switching conditions. Methods of parameters extraction including nonlinearity of parasitic capacitances and steady-state characteristics are based on manufacturer data sheet and externally measurable characteristics....
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Influence of Protonation State on the Excited State Dynamics of a Photobiologically Active Ru(II) Dyad
PublikacjaThe influence of ligand protonation on the photophysics of a ruthenium (Ru) dyad bearing the 2-(1-pyrenyl)-1H-imidazo[4,5-f][1,10]-phenanthroline (ippy) ligand was investigated by time-resolved transient absorption spectroscopy. It was found that changes in the protonation state of the imidazole group led to changes in the electronic configuration of the lowest lying excited state. Formation of the fully deprotonated imidazole...
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Development of dynamic method for evaluation of inhibition efficiency on the example of 8-hydroxyquinolin
PublikacjaSelection of a proper inhibitor should be based on the evaluation of its mechanism and effective concentrations. Mechanism of inhibition usually has dynamic character due to changing physicochemical conditions of the environment and corroding metal surface. Most of actually used methods are stationary or contain assumptions which highly influences obtained values. Development of new dynamic method, based on modified EIS, allows...
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RESIDUE ANALYSIS OF ETU AND PTU BY LC/MS
PublikacjaDithiocarbamates (DTCs) are important organosulfur compounds, which act as inhibitors of metal dependant and sulphydryl enzymes and have a serious consequence on biological systems. They possess variety of applications in agriculture as fungicides, as well as, in the rubber industry as vulcanization accelerators and antioxidants. In this way, DTCs are the main group of fungicides used to control approximately 400 pathogens of more...
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Correlations between organic pollution indicators in municipal wastewater
PublikacjaThe paper presents the results of a study of parameters used for determining the amount of organic pollutants in wastewater flowing into a collective wastewater treatment plant with a population equivalent of about 120 000 PE. The plant constituted part of a sewage system. Assays were performed for biochemical oxygen demand (BOD5), chemical oxygen demand (CODCr), permanganete index (CODMn) and total organic carbon (TOC). In addition,...
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Multi-Stage Video Analysis Framework
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Argument strategies and patterns of the Trust-IT framework
PublikacjaArtykuł dotyczy metodologicznego i narzędziowego środowiska Trust-IT wspierającego budowę dowodów zaufania (ang. trust case), a w szczególności strategii tworzenia dowodu zaufania. Strategia uzależniona jest od właściwości systemu (lub innego rozważanego obiektu), która podlega analizie w ramach dowodu zaufania. W artykule zaprezentowano dwie strategie: oparta na ryzyku i oparta na standardach oraz omówiono kilka często stosowanych...
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An agent-based framework for distributed learning
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A general framework of new subdivision regulations
PublikacjaOmówiono strukturę przepisów niezatapialności statków, opartą na podejściu probabilistycznym.
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A general framework of new subdivision regulations.
PublikacjaPodano prawidłową strukturę nowych przepisów niezatapialności, podkreślając, że wskaźniki niezatapialności są tym samym co uśredniony mnożnik s. Praca analizuje uśrednianie tego mnożnika. Wskazano na związek między wskaźnikami niezatapialności, a średnim stanem morza, które statek może przetrwać.
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Enhanced trap-assisted recombination in organic semiconductors
PublikacjaAn analytical model to describe the interaction of excitons and charge transfer states with deep traps is formulated for the case of molecular materials. Here, we have considered the influence of a trap-assisted recombination on this phenomenon. The final expression for the effective recombination rate has been derived from the Shockley–Read–Hall theory and kinetic equations which characterize different photophysical processes....
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Ion Chromatography in Environmental Analysis of Selected Organic Acids
PublikacjaLow molecular mass carboxylic acids (LCAs) occur in many environmental compartments dueto natural processes and human activity. When volatile and nonvolatile acids are to be monitored then liquidchromatography, including ion chromatography seems a method of choice. At high pH the acids are inionized form and can be separated as carboxylats by means of anion exchange chromatography. LCAs canalso be separated at low pH by ion exclusion...
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Activated Tungsten Inert Gas Weld Characteristics of P91 Joint for Advanced Ultra Supercritical Power Plant Applications
PublikacjaActivated Tungsten Inert Gas (A-TIG) welding, a variant of tungsten inert gas (TIG) welding, was used for welding P91. In Generation IV power plants, P91 welds are prone to premature failure due to the presence and formation of brittle phases and creep at high temperatures. When performing A-TIG welding, the flux composition plays a role in the reversal of the Marangoni flow in the weld pool, which ultimately determines the level...
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Underwater wet welding of S1300 ultra-high strength steel
PublikacjaMarine Structures Volume 81, January 2022, 103120 Underwater wet welding of S1300 ultra-high strength steel Author links open overlay panelJacekTomkówGrzegorzRogalski https://doi.org/10.1016/j.marstruc.2021.103120 Get rights and content Under a Creative Commons licenseopen access Highlights • Technological method of S1300 steel underwater weldability improving was proposed. • Number of cracks and hardness of welded joints was...
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Development of a vortex-assisted switchable-hydrophilicity solvent-based liquid phase microextraction for fast and reliable extraction of Zn (II), Fe (II), Pb (II), and Cd (II) from various baby food products
PublikacjaThis manuscript describes the development of a novel liquid phase microextraction (LPME) method for the extraction and determination of Zn (II), Fe (II), Pb (II), and Cd (II) in various infant/baby food and supplements products. The method is based on vortex-assisted extraction combined with a switchable-hydrophilicity solvent (SHS) sample preparation. The SHS, which undergoes reversible phase changes triggered by pH change, enables...
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The Use of Organic Coagulants in the Primary Precipitation Process at Wastewater Treatment Plants
PublikacjaMeasurements for determining the effect of chemically enhanced primary treatment (CEPT) on the efficiency of pollutant removal from wastewater were carried out using conventional inorganic coagulants PIX113 with polymer A110 (Kemipol, Police, Poland) and unconventional cationic organic coagulants Cofloc (Attana, Coalville, UK) C29510 (Kemipol, Police, Poland) and Sedifloc 575 (3F Chimica, Sandrigo, Italy). The average removal efficiency...
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Support Product Development Framework by Means of Set of Experience Knowledge Structure (SOEKS) and Decisional DNA
PublikacjaIn this paper, we propose a framework to support product development activi-ties by utilizing Set of Experience Knowledge Structure (SOEKS) and Decisional DNA (DDNA). This idea will provide a new direction to researchers working on product development, especially designers and manufacturers. They will be working on the same platform and this will be reducing their communication gap. Once the final idea is perceived about product...
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Mineral and Organic Matter Constituents in Weak Interfaces in Shales
PublikacjaThis paper identifies formation interfaces that would appear to be "weak interfaces", in the Jurassic, Early- Cretaceous Vaca Muerta formation, in the Neuquén Basin, Argentina. Significant distribution of the weak interfaces was observed including contacts between volcanic ash layers of varying thicknesses, calcite-filled veins, and contacts between lithology changes, such as between argillaceous mudstone and mottled carbonates....
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Dynamic fracture of brittle shells in a space-time adaptive isogeometric phase field framework
PublikacjaPhase field models for fracture prediction gained popularity as the formulation does not require the specification of ad-hoc criteria and no discontinuities are inserted in the body. This work focuses on dynamic crack evolution of brittle shell structures considering large deformations. The energy contributions from in-plane and out-of-plane deformations are separately split into tensile and compressive components and the resulting...
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Subcritical Thermodynamic Cycles with Organic Medium and Isothermal Expansion
PublikacjaThe efffciencies of the Organic Rankine Cycle (ORC) are not very high and only very seldom do they exceed 20%. The increase and optimization of initial parameters and certain modifications of the thermodynamic cycle make it possible to overcome these drawbacks. A new modified cycle has been described and analyzed in detail in the paper. Similarly to the Ericsson cycle for gas turbines, isothermal expansion in the turbine is suggested...
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Organic matter removal efficiency in treatment wetlands simulation by COD fractions
PublikacjaThe objective of this paper was to investigate the organic fraction (colloidal, particulate, and dissolved) in sewage treatment in treatment wetland. Performance of TWs was simulated well with a simple first order model k – C* based on monitoring data. In this investigation background or residual concentration (C*) was assumed to be equal concentration of input influent organic matter in particulate (CODp). Calculated reaction...
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Quenching effects in organic electroluminescence
PublikacjaWe examine various electronic processes that underlie the quenching of the emission from highly efficient phosphorescent and electrophosphorescent organic solid-state molecular systems. As an example, we study the luminescent efficiencies from the phosphorescent iridium (III) complex, fac tris (2-phenylpyridine) iridium [(Ir (ppy)3] doped into a diamine derivative doped polycarbonate hole-transporting matrix and in the form...
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Effect of environmental temperature variations on protective properties of organic coatings
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Local properties of organic coatings close to glass transition temperature
PublikacjaAcrylic coating applied on copper substrate has been investigated at different temperatures starting from the ambient one up to the level above the glass transition temperature. Its local topographic and electric properties have been examined with the atomic force microscopy (AFM) based approach including dc current mapping and local impedance spectroscopy. The local findings have been compared with the information from global...
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Effect of environmental temperature variations on protective properties of organic coatings
PublikacjaW oparciu o model rozwoju naprężeń oraz niszczenia kumulatywnego przedyskutowano wpływ zmiennych temperatur środowiska na mechaniczną spójność i własności ochronne systemów powłokowych. Badano wpływ cykli temperaturowych pomiędzy 20 i 55 st. C oraz między -20 i 20 st. C na trwałość różnych powłokowych systemów malarskich na stali. Stosując technikę spektroskopii impedancyjnej monitorowano zmiany parametrów powłok poddanych cyklom...
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Electrical and noise responses of Graphene-Silicon Schottky diodes decorated with Au nanoparticles for light-enhanced sensing of organic gases
Dane BadawczeGraphene-Silicon Schottky junctions decorated with Au nanoparticles were used for light-enhanced detection of organic tetrahydrofuran and chloroform. Au nanoparticles exhibited localized surface plasmon resonance (LSPR) in the range of yellow light; thus yellow LED (wavelength of 592 nm) was utilized to induce the plasmonic effect, that increased the...
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Miniaturized Dual-Band SIW-Based Bandpass Filters Using Open-Loop Ring Resonators
PublikacjaThis article presents two novel architectures of dual-band substrate integrated waveguide (SIW) bandpass filters (BPFs). Initially, two identical open-loop ring resonators (OLRRs) are coupled face-to-face on the top of the SIW cavity to realize a dual-band single-pole BPF. To obtain two-pole dual-band characteristics, two OLRRs resonant units are assembled horizontally within the top metal layer of the SIW, which is a technique...
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Chromogenic azomacrocycles with imidazole residue: Structure vs. properties
PublikacjaNew diazo macrocycles linked by hydrocarbon chain bearing imidazole or 4-methylimidazole residue have been synthetized with satisfactory yield (24–55%). The structure of macrocycles was confirmed by X-ray analysis and spectroscopic methods (1H NMR, MS, FTIR). Metal cation complexation studies were carried out in acetonitrile and acetonitrile-water system. It was found that azomacrocyles form triple-decker complexes with lead(II)....
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Microfluidic devices for photo-and spectroelectrochemical applications
PublikacjaThe review presents recent developments in electrochemical devices for photo- and spectroelectrochemical investigations, with the emphasis on miniaturization (i.e., nanointerdigitated complementary metal-oxide-semiconductor devices, micro- and nano-porous silicon membranes or microoptoelectromechanical systems), silica glass/microreactors (i.e., plasmonic, Raman spectroscopy or optical microcavities) or polymer-based devices (i.e.,...
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Shape Memory Materials from Rubbers
PublikacjaSmart materials are much discussed in the current research scenario. The shape memory effect is one of the most fascinating occurrences in smart materials, both in terms of the phenomenon and its applications. Many metal alloys and polymers exhibit the shape memory effect (SME). Shape memory properties of elastomers, such as rubbers, polyurethanes, and other elastomers, are discussed in depth in this paper. The theory, factors...
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Dirac fermions and possible weak antilocalization in LaCuSb2
PublikacjaLayered heavy-metal square-lattice compounds have recently emerged as potential Dirac fermion materials due to bonding within those sublattices. We report quantum transport and spectroscopic data on the layered Sb square-lattice material LaCuSb2. Linearly dispersing band crossings, necessary to generate Dirac fermions, are experimentally observed in the electronic band structure observed using angle-resolved photoemission spectroscopy,...
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Dynamic analysis of temporary steel grandstand equipped with different types of bracing system
PublikacjaIn the paper, behaviour of a temporary steel grandstand equipped with two different types of bracing system has been analysed through the numerical study. A typical solution concerning application of a diagonal tubular members has been compared with elements proposed by authors and called polymer dampers. A polymer element consists of two L-shape steel members bonded with polymer mass. The aim of the paper is to verify the effectiveness...
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Experimental research on marine oil-lubricated stern tube bearing
PublikacjaBearings of propeller shafts are very crucial elements of the propulsion system of each of the ships. The safety of shipping depends on their durability and reliability. The new legal restrictions mean that today we are looking for environmentally friendly solutions. That is why water-lubricated bearings are becoming more and more popular. So, will oil-lubricated shaft bearings belong to the past? The bearing with a white metal...
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Phytoremediation—From Environment Cleaning to Energy Generation—Current Status and Future Perspectives
Publikacja:Phytoremediationis a technology based on the use of green plants to remove, relocate, deactivate, or destroy harmful environmental pollutants such as heavy metals, radionuclides, hydrocarbons, and pharmaceuticals. Under the general term of phytoremediation, several processes with distinctively different mechanisms of action are hidden. In this paper, the most popular modes of phytoremediation are described and discussed. A broad...
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Electrolytic corrosion of water pipeline system in the remote distance from stray currents– case study
PublikacjaCase study of corrosion failure of urban water supply system caused by the harmful effects of stray currents was presented. The failure occurred at a site distant from the sources of these currents namely the tramway and railway traction systems. Diagnosis revealed the stray currents flow to pipeline over a remote distance of 800 ÷ 1,000 meters from the point of failure. At the point of failure stray currents flowed from the pipeline...
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3D Sound Intensity Measurement Around Organ Pipes Using Acoustic Vector Sensors
PublikacjaThe aim of the presented paper was to obtain and visualize sound intensity distribution of radiated acoustic energy around the organ pipes. The experimental setup consisted of the multichannel acoustic vector sensor and the specialized Cartesian robot. Measurements were performed in free field with spatial resolution of 0.1 [m]. Two organ pipes, i.e. wooden and metal were measured during the ex-periment. The organ pipes were activated...