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wyświetlamy 1000 najlepszych wyników Pomoc
Wyniki wyszukiwania dla: POCHODNA 4-METYLO-1-NITROAKRYDYNY C-1748
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Testing of DES toxicity towards Candida subhashii
Dane BadawczeDataset presents results of testing toxicity of selected DES solutions in mineral salt medium towards Candida subhashii.
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A note on an approximative scheme of finding almost homoclinic solutions for Newtonian systems
PublikacjaIn this work we will be concerned with the existence of an almost homoclinic solution for a perturbed Newtonian system in a finite dimensional space. It is assumed that a potential is C^1 smooth and its gradient is bounded with respect to a time variable. Moreover, a forcing term is continuous, bounded and squere integrable. We will show that the appproximative scheme due to J. Janczewska for a time periodic potential extends to...
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Halogen bonded polypseudorotaxanes based on a pillar[5]arene host
PublikacjaTwo crystalline supramolecular polypseudorotaxanes were obtained by combining permethylated pillar[5]arene as a macrocyclic wheel with 1,4-bis(1-imidazolyl)butane and 1,4-bis(iodoethynyl)benzene or 1,4-diiodo-1,3-butadiyne linked by C–I⋯N halogen bonds and creating a polyrotaxane axis. The resulting highly ordered supramolecular arrays were characterized by X-ray crystallography.
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Intercultural interactions at multinational corporations' workplace: Grounded theory.
Publikacjaenvironments is a new challenge for employees and managers. The aim of the paper is to analyze the social interactions in multicultural environments of multinational corporations (MNCs) as well as to propose a model of intercultural social interactions in MNCs’ specifi c context. Design/methodology/approach: The grounded theory approach was applied to create a model of intercultural interactions in MNCs. The data was obtained during...
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Synthesis, structural and spectroscopic properties of asymmetric schiff bases derived from 2,3-diaminopyridine
PublikacjaTwo Schiff base derivatives, 4-(2-amino-3-pyridyliminomethyl)phenol (I) and 3-(2-amino-3- pyridyliminomethyl)nitrobenzene (II ), were synthesised and characterised by spectroscopy. The structure of I was determined by single crystal X-ray diffraction studies. The asymmetric Schiff base derived from 2,3-diaminopyridine selectively recognise transition and heavy metal cations, and some anion. Ligands I and II form stable complexes...
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Elimination of excretion of ibuprofen and its metabolites in horses
PublikacjaAnalytical procedure based on application of gas chromatography-mass spectrometry (GC-MS) at the step of detection, identification and quantitation of ibuprofen (IBU) and detection of its metabolites – 1-hydroxyibuprofen (1-OH IBU) and carboxyibuprofen (CBX IBU) in horse urine by selected ion monitoring mode after sample preparation covering extraction at pH 3-4 and methylation has been used. The ions at m/z 161, 220 (methylated...
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Synthesis of highly crystalline photocatalysts based on TiO2 and ZnO for the degradation of organic impurities under visible-light irradiation
PublikacjaA TiO2–ZnO binary oxide system (with molar ratio TiO2:ZnO = 8:2) was synthesized by a hydrothermal method, assisted by calcination at temperatures of 500, 600 and 700 °C, using zinc citrate as the precursor of ZnO. The morphology (SEM, TEM), crystalline structure (XRD, Raman spectroscopy), diffuse reflectance spectra (DRS), chemical surface composition (EDXRF), porous structure parameters (low-temperature N2 sorption) and characteristic...
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Solvent influence on the crystal structures of new cadmium tri-tert -butoxysilanethiolate complexes with 1,4-bis(3-aminopropyl)piperazine: luminescence and antifungal activity
PublikacjaMonocrystals of dinuclear -1,4-bis(3-aminopropyl)piperazine-4N1,N10:N4,N40-bis[bis(tri-tert-butoxysilanethiolato-S)cadmium(II)], [Cd2(C12H27O3SSi)4(C10-H24N4)] or [Cd2{SSi(OtBu)3}4(-BAPP)], 1, and polynuclear catena-poly[[bis-(tri-tert-butoxysilanethiolato-S)cadmium(II)]--1,4-bis(3-aminopropyl)piperazine-2N10:N40], [Cd(C12H27O3SSi)2(C10H24N4)]n or [Cd{SSi(OtBu)3}2(-BAPP)]n,2, with 1,4-bis(3-aminopropyl)piperazine (BAPP)...
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Solvent influence on the crystal structures of new cadmium tri-tert -butoxysilanethiolate complexes with 1,4-bis(3-aminopropyl)piperazine: luminescence and antifungal activity
PublikacjaMonocrystals of dinuclear 1,4-bis(3-aminopropyl)piperazine-�4N1,N10:N4,N40-bis[bis(tri-tert-butoxysilanethiolato-�S)cadmium(II)], [Cd2(C12H27O3SSi)4(C10-H24N4)] or [Cd2{SSi(OtBu)3}4(�-BAPP)], 1, and polynuclear catena-poly[[bis- (tri-tert-butoxysilanethiolato-�S)cadmium(II)]-�-1,4-bis(3-aminopropyl)piperazine-�2N10:N40], [Cd(C12H27O3SSi)2(C10H24N4)]n or [Cd{SSi(OtBu)3}2(�-BAPP)]n, 2, with 1,4-bis(3-aminopropyl)piperazine (BAPP)...
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CTD Gdańsk Deep_2001_2005
Dane BadawczeDataset includes measurements of conductivity (mS cm-1), temperature (°C), sound speed (m s-1) and salinity (PSU) made with the probe Falmouth Scientific Inc. The research was carried out in 2001 (at the turn of May and June), 2003 (beginning of May), 2005 (end of April) and in 2002 and 2004 (at the turn of September and October). In 2002, only temperature...
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Kinetic characterization of hydrogen sulfide inhibition of suspended anammox biomass from a membrane bioreactor
PublikacjaThe inhibition effects of hydrogen sulfide (H2S) on anammox-enriched biomass from a laboratory membrane reactor were analyzed in a series of batch respirometric experiments. The determined half maximal inhibitory concentration (IC50) was 4.67 mg H2S-S L−1 at the constant pH = 7.0 and the total sulfide concentration varying between 1 and 15 mg TS-S L−1. In another test, the IC50 was found to be 4.25 mg H2S-S L−1 under a constant...
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Interplay between Aryl···Perfluoroaryl and Hydrogen Bonding Interactions in Cocrystals of Pentafluorophenol with Molecules of Trigonal Symmetry
PublikacjaCocrystals of seven star-shaped triaryl compounds with pentafluorophenol (pfp) were prepared and structurally characterized by the single-crystal X-ray diffraction method. Cocrystallization of pfp with planar (or almost planar) compounds gave six 3:1 molecular complexes with well-defined layered structures. The layers are composed of alternating pfp3 trimers, linked by hydrogen bonding, and triaryl molecules held together in planes...
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The influence of nanostructures size on V2O5 electrochemical properties as cathode materials for lithium ion battery
PublikacjaIn this paper, V2O5 nanostructures with a size depending on the annealing temperature are successfully synthesized by a sol-gel method. The crystal structure and morphology of samples are characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), selected area electron diffraction (SEAD) and scanning electron microscopy (SEM), respectively. Electrochemical testing such...
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XRD diffraction patterns for strontium ferrite molybdate-based compounds: as-prepared, reduced and reoxidized
Dane BadawczeThe dataset contains the XRD diffractograms collected at room temperature for SFM, LSFM and SFMNb in 3 different oxidation states, namely: as-prepared, reduced and reoxidized.
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Red Algae – An Alternative Source of Carbon Material for Energy Storage Application
PublikacjaNew electrode material obtained by pyrolysis of aquatic biomass macro (red algae) soaked with glucose solution has been characterized by SEM, EDX and Raman spectroscopy. Graphitized carbon was identified by Raman spectroscopy. Galvanostatic cyclic polarization of the materials in contact with 1M LiPF6 electrolyte in EC:DMC (1:1 v/v) and Li as a counter electrode was performed. Specific capacity of the novel material was enhanced...
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Investigation of the C-1311 glucuronidation: an electrochemical approach
Dane BadawczeThis study was undertaken to investigate the glucuronidation of the compound C-1311 (5-diethylaminoethylamino-8-hydroxyimidazoacridinone – the model anticancer acridine derivative) using electrochemistry/mass spectrometry (EC/MS) as a complementary technique to in vitro (liver microsomes) and in silico approaches.
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The complete list of two-dimensional rotation-symmetric number-conserving septenary cellular automata
Dane BadawczeThis dataset contains a complete list of all 30144 two-dimensional rotation-symmetric number-con-serving cellular automata with the state set {0,1,2,3,4,5,6} based on adjacent cells only, i.e. with the von Neumann neighborhood. The detailed definitions and the method of enumerating are given in the paper:
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Molecular basis of lipopolysaccharide heterogeneity in Escherichia coli: envelope stress-responsive regulators control the incorporation of glycoforms with a third 3-deoxy-α-D-manno-oct-2-ulosonic acid and rhamnose.
PublikacjaMass spectrometric analyses of lipopolysaccharide (LPS) from isogenic Escherichia coli strains with nonpolar mutations in the waa locus or overexpression of their cognate genes revealed that waaZ and waaS are the structural genes required for the incorporation of the third 3-deoxy-α-D-manno-oct-2-ulosonic acid (Kdo) linked to Kdo disaccharide and rhamnose, respectively. The incorporation of rhamnose requires prior sequential incorporation...
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MEASUREMENT OF TEMPERATURE-DEPENDENT VISCOSITY AND THERMAL CONDUCTIVITY OF ALUMINA AND TITANIA THERMAL OIL NANOFLUIDS
PublikacjaIn this study results of simultaneous measurements of dynamic viscosity, thermal conductivity, electrical conductivity and pH of two nanofluids, i.e. thermal oil/Al2O3 and thermal oil/TiO2 are presented. Thermal oil is selected as a base liquid because of possible application in ORC systems as an intermediate heating agent. Nanoparticles were tested at the concentration of 0.1%, 1% and 5% by weight within temperature range from...
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Chemically reduced graphene oxide based aerogels - Insight on the surface and textural functionalities dependent on handling the synthesis factors
PublikacjaEfficient adjusting of reduced graphene oxide aerogels properties requires information about experimental factor-aerogel property relationship. In this work, the reduced graphene oxide aerogels surface and textural functionalities in relation to precursor concentration, gelation time and hydrogel freezing temperature were studied in detail, with the use of dynamic adsorption method of gaseous organic probes and experimental design....
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Microstructure and mechanical properties of a dissimilar metal welded joint of Inconel 617 and P92 steel with Inconel 82 buttering layer for AUSC boiler application
PublikacjaThe application of the novel dissimilar metal welded (DMW) joint, utilizing Inconel 617 and P92 steel, was showcased in the advanced ultra-supercritical (AUSC) boiler. The work has been performed to investigate the effect of Inconel 82 (ERNiCr-3) buttering layer on microstructure and mechanical properties (high-temperature tensile strength, impact strength and microhardness) of gas tungsten arc welded (GTAW) dissimilar joint between...
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Solvent Impact on the Diversity of Products in the Reaction of Lithium Diphenylphosphide and a Ti(III) Complex Supported by a tBu2P–P(SiMe3) Ligand
PublikacjaWe present two important trends in the reactivity ofthe titanium complex [MeNacNacTi(Cl){η2-P(SiMe3)-PtBu2}](MeNacNac− = [Ar]NC(Me)CHC(Me)N[Ar]; Ar = 2,6-iPr2Ph)with nucleophilic reagents RLi (R = Ph2P,tBuO, (Me3Si)2N, andtBu2N) depending on the reaction medium. Reaction in nonpolarsolvent (toluene) leads to three main products: via an autoredoxprocess and nucleophilic substitution at the Ti-atom to afford theTi(IV) complex [MeNacNacTi(R){η2-P-PtBu2}]...
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Cooperativity of Halogen- and Chalcogen-Bonding Interactions in the Self-Assembly of 4‑Iodoethynyl- and 4,7-Bis(iodoethynyl)benzo-2,1,3-chalcogenadiazoles: Crystal Structures, Hirshfeld Surface Analyses, and Crystal Lattice Energy Calculations
PublikacjaSeveral new 4-iodoethynyl- and 4,7-bis- (iodoethynyl)benzo-2,1,3-chalcogenadiazoles were prepared, and a comprehensive analysis of the most prominent secondary bonding interactions responsible for the crystal self-assembly was performed using X-ray diffraction. The presence of both the iodoethynyl and chalcogenadiazole moieties allows an evaluation of the preference of these molecules to aggregate through either chalcogen- or halogen-bonding...
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Silicon oxycarbide-tin nanocomposite derived from a UV crosslinked single source preceramic precursor as high-performance anode materials for Li-ion batteries
PublikacjaIn this work, we report an innovative and facile UV light-assisted synthesis of a nanocomposite based on silicon oxycarbide (SiOC) and tin nanoparticles. SiOC ceramic matrix, containing a conductive free carbon phase, participates in lithium-ion storage, and buffers the volume changes of Li-alloying/de-alloying material. The reported synthesis procedure through a polymer-derived ceramic route involves the preparation of a single-source...
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Podstawy automatyki II [2020/21]
Kursy OnlineStudia stacjonarne, kierunek Automatyka, robotyka i systemy sterowania, stopień 1, semestr 4.
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Podstawy inżynierii sterowania II [2021/22]
Kursy OnlineStudia stacjonarne, kierunek Automatyka, robotyka i systemy sterowania, stopień 1, semestr 4.
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Podstawy inżynierii sterowania II [2022/23]
Kursy OnlineStudia stacjonarne, kierunek Automatyka, robotyka i systemy sterowania, stopień 1, semestr 4.
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An algorithmic approach to estimating the minimal number of periodic points for smooth self-maps of simply-connected manifolds
PublikacjaFor a given self-map f of M, a closed smooth connected and simply-connected manifold of dimension m 4, we provide an algorithm for estimating the values of the topological invariant D^m_r [f], which equals the minimal number of r-periodic points in the smooth homotopy class of f. Our results are based on the combinatorial scheme for computing D^m_r [f] introduced by G. Graff and J. Jezierski [J. Fixed Point Theory Appl. 13 (2013),...
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Fabrication, structural and electrical properties of Sr(V,Nb)O 3-δ perovskite materials
PublikacjaThe SrV1-xNbxO3-δ materials with different niobium content in perovskite B-sublattice were prepared by a solid-state reaction process. The microstructure and phase compositions of obtained samples were analyzed by the X-ray diffraction technique (XRD) and scanning electron microscopy (SEM). The electrical conductivity of samples was measured by a DC 4-wire method in range of 100–600 °C in different gas conditions. The oxidation...
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Numeryczna analiza wpływu kierunku rozchodzenia się fali wybuchu na krzywiznę asymetrycznie walcowanego pasma Al-Cu. Numerical analysis the influence of the direction of explosion wave at the curvature of asymmetrical rolling of bimetallic plate.
PublikacjaW artykule przedstawiono numeryczną analizę wpływu kierunku rozchodzenia się fali wybuchu na krzywiznę asymetrycznie walcowanego pasma Al-Cu. Przeprowadzono symulacje dla procesu walcowania w temperaturze 20 C. Proces walcowania prowadzono w walcarce duo D 150 mm, o prędkości obwodowej 18,5 obr/min. Badania przeprowadzono dla dwóch stosunków grubości warstw 2/10 i 4/8. Symulację procesu przeprowadzono dla trzech gniotów 10%, 20%,...
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A Convenient Way to Methylated 2-Imidazolines. Syntheses of Fluorene and Triazine Cyclic Diamidines
PublikacjaOne N-methyl- and 4-substituted 2-imidazolines are described. Fluorene bisimidazolines were obtained in good yield (64-92%), starting from 2,7-dicyanofluorene and ammonium sulfide. In a two-step procedure the crude bisthioamide was reacted with excess diaminoalkane-ethanol (1:1 mixt.) in an oil bath. This new procedure is superior over std. methods. For the sake of comparison, a new triazine bisimidazoline (I) was prepd. by...
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Inhibition of the granular anammox process by the high concentration of free ammonia.
PublikacjaHigh concentrations of ammonia and nitrite, typical for reject water treatment in the anammox process with the use of high temperatures and pH, may cause free ammonia (FA) inhibition. In this study, the inhibitory effect of FA on anammox process rate was investigated in a bench-scale sequencing batch reactor (SBR) with granular anammox biomass. Results of the study present that the anammox process could be successfully operated...
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Charge-assisted N(+)–H···(−)S hydrogen bonds in the crystal structure of selected diammonium thiophenolates.
PublikacjaNew salts of thiophenol with three flexible aliphatic diamines H2N(CH2)nNH2 (n = 2, 4 and 6) have been synthesized and characterized by elemental analyses, IR spectroscopy and X-ray crystallography in order to analyze their supramolecular architecture. Structural analyses indicate that in the crystals, proton transfer has occurred, with the –SH group giving (+)N–H···S(−) hydrogen bonding interaction. The structure of compound 1...
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Agnieszka Rek-Lipczyńska dr inż. arch.
Osobydr inż. arch. Agnieszka Rek-Lipczyńska 1. Edukacja i dane biograficzne: ur. 11.07.1975 r. w Radomiu 1998 – mgr inż. arch. – Politechnika Szczecińska, Wydział Budownictwa i Architektury 2. Stopnie i tytuły naukowe: 2011 dr– Wydział Architektury w Gliwicach, Politechnika Śląska 3. Stanowiska i funkcje: 2008 asystent, Katedra Rysunku Malarstwa i Rzeźby, WBiA 2012 adiunkt, ZTA,HiKZ, IAiPP,...
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SEM results of melamine sponges impregnated by DES
Dane BadawczeSEM results of melamine sponges impregnated by DES (3 um magnification). The set includes raw data from SEM analysis of pure melamine sponge and melamine sponges impregnated by:- Eucalyptol:Menthol (1:1)- Eucalyptol:Menthol (1:2)- Eucalyptol:Menthol (1:3)- Eucalyptol:Menthol (1:4)- Eucalyptol:Menthol (1:5)- Thymol:Menthol (1:1)
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Data on hydrogen migration in cation-induced dissociation of furan molecules
Dane BadawczeThe data include furan luminescence spectra obtained in collisions with H3+ and C+ cations and theoretical spectra of OH and CH radicals published in [1].
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Activated sodium percarbonate-ozone (SPC/O3) hybrid hydrodynamic cavitation system for advanced oxidation processes (AOPs) of 1,4-dioxane in water
PublikacjaHydrodynamic cavitation (HC) was employed to activate sodium percarbonate (SPC) and ozone (O3) to degrade recalcitrant 1,4-dioxane. The degradation efficiency > 99 % with a rate constant of 4.04 × 10−2 min−1 was achieved in 120 min under the optimal conditions of cavitation number (Cv) 0.27, pH 5, molar ratio of oxidant to pollutant (rox) 8, ozone dose of 0.86 g h−1 under 25 ± 2 °C with initial concentration of 1,4-dioxane 100...
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Kant i kantyzmy.O okresach i sposobach obecności Kanta w filozofii
PublikacjaArtykuł opisuje pięć okresów obecności Kanta:1. Wczesny kantyzm, ktory nie miał do czynienia z zamkniętym obrazem Kanta, 2.Idealizm niemiecki, gdzie Kant staje się częścią rozwoju idealizmu niemieckiego' 3.Neokantyzm redukujący filozofię do teorii poznania i wartości,4.Okres powrotu do realizmu i do ontologicznej oraz metafizycznej interpretacji Kanta,5.Okres współczesny.
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3D Buckling Analysis of a Truss with Horizontal Braces
PublikacjaThe present research is devoted to the study of out–of–plane buckling of a truss with horizontal braces. The truss is a model of real roof truss scaled by factor 1=4. A linear buckling and a non–linear analysis with geometric and material non–linearity were carried out. The truss buckling and limit load for different stiffnesses and number of braces are found. Numerical analysis are verified by experiment. Threshold bracing stiffness condition...
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Wpływ stoczni na środowisko naturalne
PublikacjaW referacie, w sposób przeglądowy, opisano podstawowe problemy związane z wpływem stoczni na środowisko naturalne. Podpunkty 1 i 2 odnoszą się do sytuacji przeszłej i obecnej. Podpunkty 3 i 4 odnoszą się do sytuacji nowej, która wynika ze wstąpienia Polski do UE. Pociąga to za sobą konieczność wprowadzenia zmian dostosowawczych przez każdą ze stoczni.
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Complex multiplier based on the polynomial residue number system
PublikacjaPrzedstawiono próbę zaprojektowania mnożnika zespolonego 4x4 opartego na algorytmie Skavantzosa i Stouraitisa. W algorytmie stosuje siękodowanie liczb n-bitowych jako wielomianów stopnia 7 w pierścieniu wielomianów modulo (x^8-1) z n/4-bitowymi współczynnikami. Mnożenie zespolone jest wykonywane jako 8-punktowy splot cykliczny. Podanoopóżnienie i złożoność sprzętową jak również porównanie ze standardowym.rozwiązaniem.
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Monolithic vs. Microservice Architecture: A Performance and Scalability Evaluation
PublikacjaContext. Since its proclamation in 2012, microservices-based architecture has gained widespread popularity due to its advantages, such as improved availability, fault tolerance, and horizontal scalability, as well as greater software development agility. Motivation. Yet, refactoring a monolith to microservices by smaller businesses and expecting that the migration will bring benefits similar to those reported by top global companies,...
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Green products from herbal medicine wastes by subcritical water treatment
PublikacjaHerbal medicine wastes (HMWs) are byproducts of medicine factories, which are mainly landfilled for their environmental problems. Only bearing in mind the contamination and concerns caused by the COVID-19 pandemic and environmental emissions, the worth of herbal medicine wastes management and conversion to green products can be understood. In this work, subcritical water treatment was carried out batch-wise in a stainless tube...
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Isothermal calorimetry data for cement pastes containing pristine and silica-coated bismuth oxide (Bi2O3) and gadolinium oxide (Gd2O3) structures
Dane BadawczeExcel file containing raw calorimetric data determined up to 168 h (Tam Air 3 8-channel isothermal calorimeter) of cement pastes containing variable amount of Bi2O3, Gd2O3, Bi2O3-SiO2 and Gd2O3-SiO2 structures. Sample designation in the Excel file is in line with sample designation in the manuscript associated with dataset.
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PRZEBIEG TEMPERATURY ZIM NA OBSZARZE POLSKI W LATACH 1720–2015
PublikacjaThe work discusses the air temperature course of winter periods (December–March) in Poland in the years 1720–2015. The analysis is carried out for area mean values calculated from 5 stations: Szczecin, Wrocław, Warsaw, Wilno and Lwów. The time series of the mean area winter temperature (hereinafter PLZ) consists of combined observational (140 years) and reconstructed (156 years) data. PLZ reconstruction is based on independent...
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Izolacja drożdży psychrotolerancyjnych oraz ocena ich zdolności do wykorzystania N-fosfonometyloglicyny jako źródła pierwiastków biogennych
PublikacjaN-fosfonometyloglicyna (PMG, glifosat) jest substancją aktywną herbicydu Roundup o szerokim spektrum aktywności biologicznej. Mechanizm jego działania opiera się na inhibicji aktywności syntazy 5-enolopirogroniano-szikimowo-3-fosforanowej (EPSP), przez co hamowana jest biosynteza aminokwasów aromatycznych u roślin. Glifosat jest związkiem fosforoorganicznym, w którego budowie wyróżnia się trwałe wiązanie C-P. Szybkość rozkładu...
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Growth, Crystal Structure and Magnetic Characterization of Zn-Stabilized CePtIn4
PublikacjaThe growth and characterization of CePtIn4, stabilized by 10% Zn substitution for In, is reported. The new material is orthorhombic, space group Cmcm (No. 63), with lattice parameters a = 4.51751(4) Å, b = 16.7570(2) Å, and c = 7.36682(8) Å, and the refined crystal composition has 10% of Zn substituted for In, i.e., the crystals are CePt(In0.9Zn0.1)4. Crystals were grown using a self-flux method: only growths containing Zn yielded...
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Electron-Induced Decomposition of 5-Bromo-4-thiouracil and 5-Bromo-4-thio-2′-deoxyuridine: The Effect of the Deoxyribose Moiety on Dissociative Electron Attachment
PublikacjaWhen modified uridine derivatives are incorporated into DNA, radical species may form that cause DNA damage. This category of molecules has been proposed as radiosensitizers and is currently being researched. Here, we study electron attachment to 5-bromo-4-thiouracil (BrSU), a uracil derivative, and 5-bromo-4-thio-20 -deoxyuridine (BrSdU), with an attached deoxyribose moiety via the N-glycosidic (N1-C) bond. Quadrupole mass spectrometry...
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The conversion of multinuclear μ-oxo titanium(IV) species in the reaction of Ti(OiBu)4 with branched organic acids; results of structural and spectroscopic studies
PublikacjaW reakcji tetraizobutoksylanu tytanu z rozgałęzionymi kwasami karboksylowymi otrzymano szereg wielordzeniowych związków kompleksowych tytanu(IV). Otrzymane produkty scharakteryzowano wykorzystując techniki spektroskopowe: FTIR, 1H i 13C NMR oraz rentgenowską analizę strukturalną. Zaproponowano ścieżki reakcji prowadzące do konwersji poszczególnych związków w coraz stabilniejsze formy.
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Improved Performance of 1-Ethyl-3-Methylimidazolium Tetrafluoroborate at Steel/HCl Interface by Iodide Ions
PublikacjaThe corrosion and corrosion inhibition of St37 steel in 0.1 M HCl solution by 1-ethyl-3-methylimidazolium tetrafluoroborate (EMITFB) and the effect of addition of KI on the inhibitive performance of EMITFB have been examined by electrochemical [electrochemical impedance spectroscopy, potentiodynamic polarization, and dynamic electrochemical impedance spectroscopy (DEIS)] and surface examination [scanning electron microscope (SEM)...