Wyniki wyszukiwania dla: COBALT-CERIA OXIDES
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Impedance spectroscopy studies on hybrid materials consisting of poly(3,4-ethylenedioxythiophene) and iron, cobalt and nickel hexacyanoferrate
PublikacjaBadania warstw polimeru pEDOT modyfikowanego heksacyjanożelazianami żelaza, kobaltu i niklu przeprowadzono za pomocą spektroskopii impedancyjnej (SI). Wykazano, że materiały hybrydowe charakteryzują się dobrą stabilnością. Warstwy testowano w zakresie temperatur od 283 do 313K. w kontakcie z wodnym roztworem KCl. Wysokie współczynniki dyfuzji wskazują na możliwości wykorzystania układów jako przewodników jonowych.
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Polyrhodanine cobalt ferrite (PRHD@CoFe2O4) hybrid nanomaterials - Synthesis, structural, magnetic, cytotoxic and antibacterial properties
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Cobalt(II) tri-tert-butoxysilanethiolates: in search of models for catalytic metal site of liver alcohol dehydrogenase
PublikacjaPrzeprowadzono syntezę trzech kompleksów: [Co{SSi(OBut)3}2(NH3)(L-pic)],[Co{SSi(OBut)3}2(NH3)2]xMeCN i [Co{SSi(OBut)3}3(H2O)][NHEt3]. Kompleksy są monomeryczne, dla nich wyznaczono strukturę krystalograficzną. Kompleks [Co{SSi(OBut)3(NH3)(L-pic)] o rdzeniu CoN2OS2 posiada dwa różne ligandy azotowe, zaś [Co{SSi(OBut)3(L-pic)] stanowi substrat do syntezy związku modelującego centrum katalityczne LADH.
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Morfologia warstw napawanych plazmowo na bazie kobaltu. (Morfology of cobalt base PTA cladding layers)
PublikacjaPrzedmiotem badań była struktura napawanych plazmowo warstw na bazie kobaltu, które spełniają funkcję powłok naprawczych na grzybkach zaworów silników okrętowych. Określono mikrostrukturę, mikrotwardość na przekroju warstwy oraz rozkład pierwiastków w różnych obszarach napoiny.
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Functionalization of the transition metal oxides FeO, CoO, and NiO with alkali metal atoms decreases their ionization potentials by 3–5 eV
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Study on the flammability, thermal stability and diffusivity of polyethylene nanocomposites containing few layered tungsten disulfide (WS2) functionalized with metal oxides
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Cu-Content La1−XSrxNi1−YCuyO3−Δ Perovskites As Cobalt-Free Cathode Materials for High-Performance It-SOFCs
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Broad-Range Spectral Analysis for Chiral Metal Coordination Compounds: (Chiro)optical Superspectrum of Cobalt(II) Complexes
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Robust effectiveness behavior of synthesized cobalt doped Prussian blue graphene oxide ferrite against EMI shielding
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Biomimetic zinc(II) and cobalt(II) complexes with tri-tert-butoxysilanethiolate and imidazole ligands - structural and spectroscopic studies.
PublikacjaNowe heteroleptyczne kompleksy tri-tert-butoksysilanotiolanowe Zn(II) i Co(II) z dodatkowymi ligandami imidazolowymi zostały scharakteryzowane strukturalnie i spektralnie. Otrzymano kompleksy o różnych centrach koordynacji w zależności od ligandów imidazolowych. Dla jonów Co(II)otrzymano kompleksy o rdzeniach: NOS2 (z cząsteczką metanolu jako O-donorowy ligand) w związku 2', NO2S2 w 2'', N2S2 w 1, zaś w przypadku jonów Zn(II):...
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Solvation of cobalt(II) ion in N,N-dimethylformamide-methanol mixed solvent: calorimetry and VIS spectroscopy studies
PublikacjaZmierzono entalpie rozpuszczania trifluorometanosulfonianów Co(II) i Na(I) w mieszaninie N,N-dimetyloformamid(DMF)-metanol(MeOH) w całym zakresie jej składu. Z danych tych wyznaczono entalpie przeniesienia jonu Co(II) i jonu trifluorometanosulfonowego. Wyniki zanalizowano za pomocą teorii solwatacji preferencyjnej. Zmierzono również widma w zakresie widzialnym roztworów jonu Co(II) w mieszaninie DMF-MeOH i zanalizowano je, stosując...
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Enhancing the Fresh and Early Age Performances of Portland Cement Pastes via Sol-Gel Silica Coating of Metal Oxides (Bi2O3 and Gd2O3)
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Thermal properties of strontium–borate glasses and glass-ceramics containing bismuth and vanadium oxides measured with DSC method
Dane BadawczeThermal properties of strontium–borate glasses and glass-ceramics containing bismuth and vanadium oxides was measured by DSC.
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The topography of strontium–borate glasses and glass-ceramics containing bismuth and vanadium oxides measured with SEM method
Dane BadawczeThe topography of strontium–borate glasses and glass-ceramics containing bismuth and vanadium oxides was measured by SEM.
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Morphology and dispersion of nanostructured manganese–cobalt spinel on various carbon supports: the effect on the oxygen reduction reaction in alkaline media
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Extracellular biosynthesis of cobalt ferrite nanoparticles by Monascus purpureus and their antioxidant, anticancer and antimicrobial activities: Yield enhancement by gamma irradiation
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The structure of strontium–borate glasses and glass-ceramics containing bismuth and vanadium oxides measured with X-ray diffraction method
Dane BadawczeThe structure of strontium–borate glasses and glass-ceramics containing bismuth and vanadium oxides was measured by XRD.
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Fe-Al based composite reinforced with ultra-fine Al<sub>2</sub>O<sub>3</sub> oxides for high temperature applications
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Simultaneous determination of thermodynamic and kinetic parameters of aminopolycarbonate complexes of cobalt(II) and nickel(II) based on isothermal titration calorimetry data
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Solvation of cobalt(II) and trifluoromethanesulfonate ions in N,N-dimethylformamide-methanol mixed solvent studied by means of FT-IR spectroscopy
PublikacjaWidma FT-IR roztworów Co(CF3SO3)2-N,N-dimetyloformamid-metanol były analizowane w zakresie pasm CO i OH za pomocą metody widm różnicowych. Wyznaczono liczbę cząsteczek DMF i MeOH w pierwszej sferze solwatacji jonu Co(II) w zależności od składu rozpuszczalnika. Stwierdzono także obecność drugiej sfery solwatacji jonu Co(II) i scharakteryzowano ją ilościowo. Zbadano również solwatację jonu tifluorometanosulfonowego oraz asocjację...
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Wpływ podwyższonych temperatur na napawane warstwy na bazie kobaltu = The elevated temperatures influence on the cobalt base cladding layer
Publikacjaw pracy przeanalizowano wpływ temperatur utleniania (850, 950 i 110 stopni C) na mikrostrukturę i twardośc napawanych plazmowo warstw zykonanych z proszku na bazie kobaltu zdodatkiem 28,8% chromu, 4,9% wolframu, 2,2% niklu, 2,09% żelaza, 1,2% krzemu i 1,2% węgla. W wyniku utleniania na powierzchni napoiny powstaje warstwa tlenku chromu stanowiaca dobrą ochronę w niższych temperaturach, jednak w temperaturach wyższych ulega ona...
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Effect of Nitrogen Ion Implantation on the Cavitation Erosion Resistance and Cobalt-Based Solid Solution Phase Transformations of HIPed Stellite 6
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Effect of Nitrogen Ion Implantation on the Cavitation Erosion Resistance and Cobalt-Based Solid Solution Phase Transformations of HIPed Stellite 6
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The structure of lead-silicate glasses containing nanocrystallites of iron oxides
Dane BadawczeThe structure of iron-doped glasses and glass-ceramics were studied. Samples has the composition of (50 − 0.5x)SiO2–(50 − 0.5x)PbO–xFe2O3, where x = 2, 5, 10, 15, 20 and 25 (in mol%). All samples were prepared by the conventional melt quenching technique; the melting was conducted in air at 1623 K in alumina crucibles. The melts were poured on a brass...
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The structure of lead-borate glasses containing nanocrystallites of iron oxides
Dane BadawczeThe structure of iron-doped glasses and glass-ceramics were studied. Glass samples of composition of xFe2O3–(100 − x)(B2O3–2PbO) (2.5 b x b 37, in mol%) were prepared by the conventional melt quenching technique. The melting was conducted in alumina crucibles at the temperature of 1523 K. The melts were poured on a preheated (573 K) brass plate and...
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The morphology of lead-silicate glasses containing nanocrystallites of iron oxides
Dane BadawczeThe topography of iron-doped glasses and glass-ceramics were studied. Samples has the composition of (50 − 0.5x)SiO2–(50 − 0.5x)PbO–xFe2O3, where x = 2, 5, 10, 15, 20 and 25 (in mol%). All sampleswere prepared by the conventional melt quenching technique; the melting was conducted in air at 1623 K in alumina crucibles. The melts were poured on a brass...
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XPS investigations of tge tin/tin oxides - CNT composites
Dane BadawczeThe composite of tin/tin oxide nanoparticles with graphene oxide and CMC based on laser ablation technique as an electrode material for energy storage devices were manufactured. The material exhibited a three-dimensional conducting graphene oxide network decorated with tin or tin oxide nanoparticles. The presence of tin/tin oxide in composites was...
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A Novel Microstructural Evolution Model for Growth of Ultra-Fine Al2O3 Oxides from SiO2 Silica Ceramic Decomposition during Self-Propagated High-Temperature Synthesis
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Selectivity of Mixed Iron-Cobalt Spinels Deposited on a N,S-Doped Mesoporous Carbon Support in the Oxygen Reduction Reaction in Alkaline Media
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Structural Variety of Cobalt(II), Nickel(II), Zinc(II), and Cadmium(II) Complexes with 4,4′-Azopyridine: Synthesis, Structure and Luminescence Properties
PublikacjaSelf-assembled bi- and polymetallic complexes of CoII, NiII, ZnII, and CdII were obtained by the reaction of 4,4′-azopyridine (azpy) with metal tri-tert-butoxysilanethiolates (Co, 1; Cd, 2), acetylacetonates (Ni, 3; Zn, 4), and acetates (Cd, 5). All compounds were characterized by single-crystal X-ray structure analysis, elemental analysis, FTIR spectroscopy, and thermogravimetry. Complexes 1, 2 and 4, 5 exhibit diverse structural...
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La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3-δ oxygen electrodes for solid oxide cells prepared by polymer precursor and nitrates solution infiltration into gadolinium doped ceria backbone
PublikacjaInfiltration is a method, which can be applied for the electrode preparation. In this paper oxygen electrode is prepared solely by the infiltration of La0.6Sr0.4Co0.2Fe0.8O3‐δ (LSCF) into Ce0.8Gd0.2O2-δ (CGO) backbone. The use a polymer precursor as an infiltrating medium, instead of an aqueous nitrate salts solution is presented. It is shown that the polymer forms the single-phase perovskite at 600 °C, contrary to the nitrates...
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Tuning Cu-Content La1−xSrxNi1−yCuyO3−δ with Strontium Doping as Cobalt-Free Cathode Materials for High-Performance Anode-Supported IT-SOFCs
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Iminodiacetate complex of cobalt(II) – Structure, physicochemical characteristics, biological properties and catalytic activity for 2-chloro-2-propen-1-ol oligomerization
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Wpływ procesów utleniania na budowę warstwy napawanej ze stopu kobaltu = Oxidation process influence on the morphology the cobalt alloy clad layer
PublikacjaWarstwę napawaną laserowo ze stopu kobaltu poddano utlenianiu w różnych warunkach. Na powierzchni otrzymano różniące się warstwy tlenków o zróżnicowanej morfologii. Brak było widocznych zmian w mikrostrukturze napoiny. Zbadano także wpływ utleniania na twardość warstwy.
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The AFM micrographs of vanadium oxides thin films obtained at 800°C
Dane BadawczeThe DataSet contains the atomic force microscope images of the surface of vanadium oxide thin films. The thin films were obtained by the sol-gel method. The information about sol synthesis is described in the Journal of Nanomaterials. The sol was deposited on a silicon substrate and vanadium thin films were obtained by annealing as-prepared films at...
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The AFM micrographs of vanadium oxides thin films obtained at 1200°C
Dane BadawczeThe DataSet contains the atomic force microscope images of the surface of vanadium oxide thin films. The thin films were obtained by the sol-gel method. The information about sol synthesis is described in the Journal of Nanomaterials. The sol was deposited on quartz glass and silicon substrate and vanadium thin films were obtained by annealing as-prepared...
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The AFM micrographs of vanadium oxides thin films obtained at 400°C
Dane BadawczeThe DataSet contains the atomic force microscope images of the surface of vanadium oxide thin films. The thin films were obtained by the sol-gel method. The information about sol synthesis is described in the Journal of Nanomaterials. The sol was deposited on quartz glass and silicon substrate and vanadium thin films were obtained by annealing as-prepared...
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The AFM micrographs of vanadium oxides thin films obtained at 600°C
Dane BadawczeThe DataSet contains the atomic force microscope images of the surface of vanadium oxide thin films. The thin films were obtained by the sol-gel method. The information about sol synthesis is described in the Journal of Nanomaterials. The sol was deposited on quartz glass and silicon substrate and vanadium thin films were obtained by annealing as-prepared...
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The AFM micrographs of of vanadium oxides thin films obtained at 300°C
Dane BadawczeThe DataSet contains the atomic force microscope images of the surface of vanadium oxide thin films. The thin films were obtained by the sol-gel method. The information about sol synthesis is described in the Journal of Nanomaterials. The sol was deposited on quartz glass and silicon substrate and vanadium thin films were obtained by annealing as-prepared...
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Electrical properties of silicate-lead glasses containing nanostructures of iron oxides.
Dane BadawczeElectrical properties of silicate-lead glasses doped with different content of iron oxide was studied. The set of glass samples were prepared with the composition of (50 − 0.5x)SiO2–(50 − 0.5x)PbO–xFe2O3, where x = 2, 5, 10, 15, 20 and 25 (in mol%). All sampleswere prepared by the conventional melt quenching technique; the melting was conducted in...
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The AFM micrographs of vanadium oxides thin films obtained at 150°C
Dane BadawczeThe DataSet contains the atomic force microscope images of the surface of vanadium oxide thin films. The thin films were obtained by the sol-gel method. The information about sol synthesis is described in the Journal of Nanomaterials. The sol was deposited on quartz glass and silicon substrate and vanadium thin films were obtained by annealing as-prepared...
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The AFM micrographs of vanadium oxides thin films obtained at 200°C
Dane BadawczeThe DataSet contains the atomic force microscope images of the surface of vanadium oxide thin films. The thin films were obtained by the sol-gel method. The information about sol synthesis is described in the Journal of Nanomaterials. The sol was deposited on quartz glass and silicon substrate and vanadium thin films were obtained by annealing as-prepared...
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The AFM micrographs of vanadium oxides thin films obtained at 450°C
Dane BadawczeThe DataSet contains the atomic force microscope images of the surface of vanadium oxide thin films. The thin films were obtained by the sol-gel method. The information about sol synthesis is described in the Journal of Nanomaterials. The sol was deposited on quartz glass and silicon substrate and vanadium thin films were obtained by annealing as-prepared...
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Fast determination of bisphenol A in spiked juice and drinking water samples by pipette tip solid phase extraction using cobalt metal organic framework as sorbent
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Investigation of cationic distribution, Y–K angles, and optical and dielectric properties of as-synthesized cerium-doped cobalt nano-ferrites prepared by co-precipitation method
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Wpływ zawartości wolframu na własności warstw na bazie kobaltu napawanych plazmowo.The influence of tungsten amount on the PTA cobalt base layers property.
PublikacjaW pracy przeanalizowano podobieństwa i różnice między warstwami napawanymi plazmowo z wykorzystaniem proszków na bazie kobaltu o różnych zawartościach wolframu. Morfologia warstw i rozkład pierwiastków dla obydwu warstw jest analogiczna. Stwierdzono wyższą twardość warstw wykonanych z proszku o wyższej zawartości wolframu.
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Chemical composition of tellurium oxides thin films deposited by magnetron sputtering method
Dane BadawczeThin films were prepared by radio frequency reactive magnetron sputtering technique. Metallic Te target was sputtered for about 45 min in argon-oxygen atmosphere what resulted in 300 nm film thickness deposition. The pressure in the chamber was below 0.2 Pa and substrate was heated at 200 °C. The distance between sputtered target and the Corning 1737...
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Correction to: Investigation of cationic distribution, Y–K angles, and optical and dielectric properties of as-synthesized cerium-doped cobalt nano-ferrites prepared by co-precipitation method
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Manganese–Cobalt Based Spinel Coatings Processed by Electrophoretic Deposition Method: The Influence of Sintering on Degradation Issues of Solid Oxide Cell Oxygen Electrodes at 750 °C
PublikacjaThis paper seeks to examine how the Mn–Co spinel interconnect coating microstructure can influence Cr contamination in an oxygen electrode of intermediate temperature solid oxide cells, at an operating temperature of 750 °C. A Mn–Co spinel coating is processed on Crofer 22 APU substrates by electrophoretic deposition, and subsequently sintered, following both the one-step and two-step sintering, in order to obtain significantly...
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Luminescent properties of Tb and Eu activated AxB1-xAlO3 (A = Y, Lu, Gd; B = Lu; x = 0, 0.5, 1) mixed oxides crystals prepared by micro-pulling-down method
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