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Wyniki wyszukiwania dla: CORROSION RATE
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Applying of Doped Graphene Oxide Coatings for Corrosion Prevention
PublikacjaINTRODUCTION Graphene is a carbonaceous material characterized by extraordinary properties (high electron mobility, high surface area, high mechanical strength of 1100 GPa, very dense network hindering the passage of even the smallest helium atoms) [1]. Therefore, it found many applications, also as an anti-corrosive layer [2]. Electrophoretic Deposition (EPD) is one of the methods to deposit coatings. However, due to slight solubility...
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The Application of Dynamic Electrochemical Impedance Spectroscopy (DEIS) Technique in Corrosion and Corrosion Inhibition Studies
Publikacjaorrosion studies have attracted considerable interest in the areas of materials chemistry and industrial chemistry, as it affects the direct and indirect costs of industry, leading to huge economic setbacks due to the need for repair, maintenance, and even shutdowns due corrosion damage. This new volume is a comprehensive resource that presents new and up-to-date, theoretical, and experimental corrosion inhibition studies.
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Surface and Corrosion Properties of AA6063-T5 Aluminium Alloy in Molybdate-containing Sodium Chloride Solutions
PublikacjaCorrosion properties of aluminium alloy AA6063-T5 were investigated in molybdate-containing NaCl solutions. Electrochemical, microscopic, and spectroscopic experiments were utilized to examine the mechanism of corrosion inhibition by molybdates. SEM-EDX, magnetic force, and intermodulation electrostatic force microscopy data suggested that the inhibition initiation preferentially occurred over Fe-rich cathodic IMPs. Spectroscopic...
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The Impact of Crushed Rock Spoil on Pitting Corrosion of Selected Stainless Steel
PublikacjaThe paper presents the results of the pitting resistance investigations of selected stainless steels in the chloride environment and the simultaneous impact of erosive factors using the cyclic polarization technique. Additionally, using electrochemical techniques, ie: electrochemical impedance spectroscopy (EIS) and measurement of corrosion potential, the behavior of the passive layer of selected stainless steels in the environment...
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Corrosion resistance examinations of Ti6Al4V alloy with the use of potentiodynamic method in Ringer`s and artificial saliva solutions
PublikacjaThe research results of corrosion resistance of the Ti6Al4V alloy in the simulated body fluids (SBF) are presented. The polished specimens have shown better corrosion resistance than grinded surfaces in both liquids. The artificial saliva has revealed more aggressive test solution than Ringer`s solution. The pitting tendency has been observed in Ringer`s solution for grinded specimens.
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Special Issue: Recent Advances in Corrosion Science
PublikacjaThe dynamic development of the global industry and growing demand for new material technologies generates constantly increasing problems regarding premature material degradation and the requirement to determine corrosion mechanisms and to develop new protection/evaluation approaches. This Special Issue, “Recent Advances in Corrosion Science”, brings together fourteen articles and one review, providing a snapshot of the recent activity...
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Nanotubular Oxide Layer Formed on Helix Surfaces of Dental Screw Implants
PublikacjaSurface modification is used to extend the life of implants. To increase the corrosion resistance and improve the biocompatibility of metal implant materials, oxidation of the Ti-13Nb- 13Zr titanium alloy was used. The samples used for the research had the shape of a helix with a metric thread, with their geometry imitating a dental implant. The oxide layer was produced by a standard electrochemical method in an environment of...
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Corrosion Properties of Dissimilar AA6082/AA6060 Friction Stir Welded Butt Joints in Different NaCl Concentrations
PublikacjaA solid-state friction stir welding method which is increasingly used in the marine and shipbuilding industry, has been developed to produce welds with high mechanical properties. In seawater, the oxide layer of aluminium is attacked by Cl− ions resulting in its disruption and formation of pitting corrosion. It is particularly important to determine the electrochemical properties of the produced welds and to evaluate the efect...
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Case Study of Stray Current Corrosion of Tall Ship Mast
PublikacjaNowadays, in the present technical civilization there are numerous complex technical systems that may generate various hazards. Large transport units like ships can be considered as the most dangerous systems. Therefore, it is important to eliminate all possible hazards, especially for ship crewmembers. Destruction of ship structural components caused by vast corrosion is one of these hazards. Usually, its activity leads to a decrease...
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Effects of the preheating laser treatment on microstructure and corrosion resistance of Ti6Al4V bioalloy
PublikacjaThe laser remelting of the Ti6Al4V alloy was made on specimens pre-heated at elevated temperatures. The laser treatment effected in change of microstructures of surface layers and an appearance of blisters and numerous cracks. The corrosion tests demonstrated the decrease in corrosion resistance for each preheating temperature. The observed effects were attributed to negative influence of excessive compressive stresses with no...
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Tensile test of part of CuNiFeR pipeline
Dane BadawczeCopper and nickel alloys called cunifers (Cu, Ni, Fe and R – rest of alloy elements) have found wide application in the production of ship pipeline components in contact with sea water, such as, for example, the main engine cooling system. These alloys are characterized by a very high corrosion resistance, which is ensured by appropriately carried out...
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Images of topography and mechanical properties (phase imaging) of cast iron samples from water installations
Dane BadawczeMeasurements in contact and semi-contact mode. NTEGRA Prima (NT-MDT) device. CSG 10.
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The electrochemical impedance spectroscopy studies of cataphoretic-grown epoxy-based coatings
Dane BadawczeThe dataset contains electrochemical impedance spectroscopy spectra collected for epoxy-based cataphoretic coatings in order to determine the offered anti-corrosion protection. Particular spectra pertain to the coatings applied for the different magnitude of polarization potential imposed, namely 10V, 20V and 30V. The results were obtained within the...
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Influence of pitting corrosion on fatigue and corrosion fatigue of ship structures. Part I: pitting corrosion of ship structures.
PublikacjaThe paper is a literature survey focused on pitting corrosion and its influence on fatigue of ship and offshore steels. Mechanisms of short- and long-term pitting corrosion in marine environment have been described including pit nucleation and growth phases. Some models of pit growth versus time of exposure have been presented. Some factors which influence the pit growth have been discussed briefly.
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High temperature corrosion of evaporator tubes with thermal sprayed coatings
PublikacjaDegradation examinations of outer surface of low-emission steam boiler evaporator tubes are presented in the paper. Metallographic evaluation of scale morphology, its micro sites chemical composition analysis and distribution of elements on cross sections have been performed. Water-wall tubes were exposed in steam boiler for up to two years period. Common tubes made of 16Mo3 steel suffered sulphide and molten salts corrosions....
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Electrolytic corrosion of water pipeline system in the remote distance from stray currents– case study
PublikacjaCase study of corrosion failure of urban water supply system caused by the harmful effects of stray currents was presented. The failure occurred at a site distant from the sources of these currents namely the tramway and railway traction systems. Diagnosis revealed the stray currents flow to pipeline over a remote distance of 800 ÷ 1,000 meters from the point of failure. At the point of failure stray currents flowed from the pipeline...
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Influence of electropolymerization temperature on corrosion, morphological and electrical properties of PPy doped with salicylate on iron
PublikacjaIn this work, the influence of the electropolymerization temperature on corrosion, morphological and electrical properties of polypyrrole (PPy) film is studied. Polypyrrole is electrochemically synthesized on iron in the presence of sodium salicylate. The X-ray diffraction and scanning electron microscopy are performed in order to study the structure and morphology of electrodeposited PPy. The electroactive surface area, corrosion...
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Fabrication of anti-corrosion nitrogen doped graphene oxide coatings by electrophoretic deposition
PublikacjaThis work assesses anti-corrosion properties of graphene and N-doped graphene coatings deposited on copper by an electrophoretic method. Graphene oxide (GO) precursor was synthesized by an improved Hummers' method, whereas N-doping was performed hydrothermally in the presence of ammonia. After nitrogenation, doped graphene oxide samples (NGO) contained a reduced amount of oxygen and about 9% w/w nitrogen as pyridinic, pyrrole,...
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Determination of Local Corrosion Current from Individual Harmonic Components
PublikacjaHarmonic analysis has been used in corrosion measurements for several decades. During this period the method has been refined and developed. Nevertheless, the technique has not been applied to properties determination in local scale yet. This paper is focused on local corrosion current measurements based on harmonic analysis. For this purpose, a non-linear nature of electrode processes is used and measured in local scale applying...
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Guided wave propagation signals measured on corroded stiffened panels
Dane BadawczeThe fundamental antisymmetric Lamb mode was excited by piezoelectric transducers attached at the pre-selected points on stiffened panels, representing typical structural ship components. The specimens were exposed to accelerated marine corrosion degradation, so the signals were collected to analyze the influence of the degree of degradation on the wave...
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Tensile test of 1.4307 / X2CrNi18-9 / AISI 304L grade austenitic steel
Dane BadawczeShip structures and their components are build mainly of steel. Hull steel is used to build the hull structure. Some structural elements, such as RSW (Refrigerated See Water) tanks, or LNG (Liquid Natural Gas) tanks - gas transported at temperatures below -162° C, are build from austenitic steels. Austenitic steels have a different microstructure and...
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AFM visualization of Mg alloy surface modification
Dane BadawczeMagnesium alloys with additives improving their mechanical properties are valued as materials with low density and elasticity coefficient. Additionally, their biocompatibility and biodegradability make them interesting in prosthetic applications. However, the last of these features, valuable in medicine, contradicts the industrial needs for the described...
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Tensile test of 1.4541 / X6CrNi18-10 / AISI 321 grade austenitic steel
Dane BadawczeShip structures and their components are build mainly of steel. Hull steel is used to build the hull structure. Some structural elements, such as RSW (Refrigerated See Water) tanks, or LNG (Liquid Natural Gas) tanks - gas transported at temperatures below -162° C, are build from austenitic steels. Austenitic steels have a different microstructure and...
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Corrosion process monitoring by AFM higher harmonic imaging
PublikacjaThe atomic force microscope (AFM) was invented in 1986 as an alternative to the scanning tunnelling microscope, which cannot be used in studies of non-conductive materials. Today the AFM is a powerful, versatile and fundamental tool for visualizing and studying the morphology of material surfaces. Moreover, additional information for some materials can be recovered by analysing the AFM's higher cantilever modes when the cantilever...
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Improved Performance of 1-Ethyl-3-Methylimidazolium Tetrafluoroborate at Steel/HCl Interface by Iodide Ions
PublikacjaThe corrosion and corrosion inhibition of St37 steel in 0.1 M HCl solution by 1-ethyl-3-methylimidazolium tetrafluoroborate (EMITFB) and the effect of addition of KI on the inhibitive performance of EMITFB have been examined by electrochemical [electrochemical impedance spectroscopy, potentiodynamic polarization, and dynamic electrochemical impedance spectroscopy (DEIS)] and surface examination [scanning electron microscope (SEM)...
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Analysis of the chemical composition of sediments
PublikacjaAnalysis of sediments and corrosion products was carried out, including microscoping and spectroscopic measurements with SEM/EDX
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Design of experiments approach for ultimate strength assessment of corroded stiffened plates
PublikacjaThe impact of corrosion degradation on the ultimate strength of stiffened plates subjected to compressive loading is investigated. The DoE technique is used considering different plate and column slenderness ratios and corrosion severity. The FE method, considering geometrical and material nonlinearities, is employed. A two-stage corrosion degradation model is adopted. Firstly, a uniform thickness loss is adopted to reflect the...
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Effects of Surface Pretreatment of Titanium Substrates on Properties of Electrophoretically Deposited Biopolymer Chitosan/Eudragit E 100 Coatings
PublikacjaThe preparation of the metal surface before coating application is fundamental in determining the properties of the coatings, particularly the roughness, adhesion, and corrosion resistance. In this work, chitosan/Eudragit E 100 (chit/EE100) were fabricated by electrophoretic deposition (EPD) and both their microstructure and properties were investigated. The present research is aimed at characterizing the effects of the surface...
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The Influence of Gas Mixture in the Glow-Discharge Nitriding Process of Austenitic Stainless Steel on Characteristic of Nitrided Cases
PublikacjaAustenitic stainless steels characterize with excellent corrosion resistance, although low mechanical properties. In many cases that limits their exploitation in industrial applications. Moreover, austenitic stainless steel is susceptible to local corrosion in the presence of halide ions. In present works, it was emphasized that the nitriding of austenitic stainless steels gives some potential abilities to obtain beneficial effect...
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Diaryl Sulfide Derivatives as Potential Iron Corrosion Inhibitors: A Computational Study
PublikacjaThe present work aimed to assess six diaryl sulfide derivatives as potential corrosion inhibitors. These derivatives were compared with dapsone (4,4′-diaminodiphenyl sulfone), a common leprosy antibiotic that has been shown to resist the corrosion of mild steel in acidic media with a corrosion efficiency exceeding 90%. Since all the studied compounds possess a common molecular backbone (diphenyl sulfide), dapsone was taken as the...
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Ni/cerium Molybdenum Oxide Hydrate Microflakes Composite Coatings Electrodeposited from Choline Chloride: Ethylene Glycol Deep Eutectic Solvent
PublikacjaCerium molybdenum oxide hydrate microflakes are codeposited with nickel from a deep eutectic solvent-based bath. During seven days of exposure in 0.05 M NaCl solution, the corrosion resistance of composite coating (Ni/CeMoOxide) is slightly reduced, due to the existence of some microcracks caused by large microflakes. Multielemental analysis of the solution, in which coatings are exposed and the qualitative changes in the surface...
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Tensile test of 1.4571 / X6CrNiMoTi17-12-2 / AISI 316Ti grade austenitic steel
Dane BadawczeShip structures and their components are build mainly of steel. Hull steel is used to build the hull structure. Some structural elements, such as RSW (Refrigerated See Water) tanks, or LNG (Liquid Natural Gas) tanks - gas transported at temperatures below -162° C, are build from austenitic steels. Austenitic steels have a different microstructure and...
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Austenitic stainless steel sensitization
Dane BadawczeHigh-alloy steels, thanks to their composition and content of appropriate alloying additives, are characterized by increased resistance to many corrosive environments. However, this is due to the increased sensitivity of the described construction materials to specific environmental conditions during their use. An example may be the increased susceptibility...
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Thermographic images during testing measuring instrument boards
Dane BadawczeThe dataset presents thermografic images acquired during testing the prototype of measuring instrument for resistiometric corrosion monitoring. The testing was performed in the room temperature. VIGOcam v50 thermal imaging camera (VIGO System S.A., Ozarow Mazowiecki, Poland) was used for taking the pictures. These pictures were used as preliminary tests...
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Advances in Modelling and Analysis of Strength of Corroded Ship Structures
PublikacjaThe present study reviews the recent advances in modelling and analyses the strength of corroded ship structures. Firstly, the time-variant methodologies that consider only the mean structural element thickness loss due to corrosion degradation are identified. Corrosion degradation is regarded as the phenomenon that causes uneven thinning of specimens. This has been captured by various researchers as the loss of mechanical properties...
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PROBLEMS WITH CORROSION PROTECTION STEEL STACKS IN FGD SYSTEMS
PublikacjaThis paper presents problems associated with corrosion of steel stacks and changes in philosophy of corrosion protection when implemented into flue gas desulphurization systems. In-situ tests were taken by means of electrochemical impedance spectroscopy at a stack which discharges flue gas before wet lime/limestone desulphurization. A very rapid soaking of spherical infill vinylester coating with electrolyte has been observed....
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Measurement system for nonlinear surface spectroscopy by atomic force microscopy for corrosion processes monitoring
PublikacjaIn addition to traditional imaging the surface, atomic force microscopy (AFM) enables wide variety of additional measurements. One of them is higher harmonic imaging. In tapping mode the nonlinear contact between tip and specimen results in higher frequency vibrations. More information available from the higher harmonics analysis proves to be helpful for more detailed imaging. Such visualization is especially useful for heterogeneous...
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Exploring Mechanism of Corrosion Inhibition of WE43 and AZ31 Alloys by Aqueous Molybdate in Hank’s Solution by Multisine Impedimetric Monitoring
PublikacjaThe concept of utilizing multisine dynamic electrochemical impedance spectroscopy to monitor effectiveness of a model molybdate inhibitor for AZ31 and WE43 Mg alloys is proposed. The corrosion kinetics and instantaneous values of inhibition efficiency (IE) of molybdate at concentrations up to 150 mM were examined. The inhibitor provides inhibition in Hank’s solution at concentrations starting from ca. 25 mM, with the IE of about...
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High Temperature Corrosion Evaluation of Porous Hastelloy X Alloy in Air and Humidified Hydrogen Atmospheres
PublikacjaIn this work a commercially available porous Hastelloy X alloy is characterized in terms of high temperature corrosion resistance. The alloy was oxidized in the temperature range from 500C to 900C in air and humidified hydrogen for 100 hours. Corrosion rates and porosity changes were measured. Microstructural characterization was performed using X-ray diffractometry and scanning electron microscopy. Results show that porous alloys...
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A measurement system for nonlinear surface spectroscopy with an atomic force microscope during corrosion process monitoring
PublikacjaIn addition to traditional imaging the surface, atomic force microscopy (AFM) enables wide variety of additional measurements. One of them is higher harmonic imaging. In tapping mode the nonlinear contact between tip and specimen results in higher frequency vibrations. More information available from the higher harmonics analysis proves to be helpful for more detailed imaging. Such visualization is espe-cially useful for heterogeneous...
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Imaging of morphological and physicochemical changes occuring in the structure of austenitic steel due to the thermal sensitization
Dane BadawczeIn polycrystalline materials, grain boundaries are always where phenomena such as surface diffusion, sedimentation and corrosion occur. They have a significant impact on the macroscopic properties of the construction material [1]. In addition to inhomogeneities such as manganese sulphide inclusions formed during the metallurgical process, interfacial...
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Metal-Organic Framework (MOF)/Epoxy Coatings: A Review
PublikacjaEpoxy coatings are developing fast in order to meet the requirements of advanced materials and systems. Progress in nanomaterial science and technology has opened a new era of engineering for tailoring the bulk and surface properties of organic coatings, e.g., adhesion to the substrate, anti-corrosion, mechanical, flame-retardant, and self-healing characteristics. Metal-organic frameworks (MOFs), a subclass of coordinative polymers...
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A probabilistic-driven framework for enhanced corrosion estimation of ship structural components
PublikacjaThe work proposes a probabilistic-driven framework for enhanced corrosion estimation of ship structural components using Bayesian inference and limited measurement data. The new approach for modelling measurement uncertainty is proposed based on the results of previous corrosion tests that incorporate the non-uniform character of the corroded surface of structural components. The proposed framework's basic features are outlined,...
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Nondestructive corrosion degradation assessment based on asymmetry of guided wave propagation field
PublikacjaThe article presents the results of numerical and experimental investigation of guided wave propagation in steel plates subjected to corrosion degradation. The development of novel procedures allowing for the assessment of the corrosion degradation level is crucial in the effective diagnostics of offshore and ship structures that are especially subjected to aggressive environments. The study’s main aim is to investigate the influence...
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Effect of Processing Parameters on Strength and Corrosion Resistance of Friction Stir-Welded AA6082
PublikacjaThe friction stir welding method is increasingly attracting interest in the railway sector due to its environmental friendliness, low cost, and ease of producing high-quality joints. Using aluminum alloys reduces the weight of structures, increasing their payload and reducing fuel consumption and running costs. The following paper presents studies on the microstructure, strength, and corrosion resistance of AA6082 aluminum alloy...
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RESEARCH ON ORGANIC COATINGS DESIGNED FOR UNDERWATER APPLICATIONS
PublikacjaUnderwater steel structures require periodic maintenance. In the case of vessels, anti-corrosion works are carried out in the shipyard, where very good conditions for applying organic protective coatings can be provided. Very good surface preparation can be obtained by the use of abrasive blasting. The well-prepared metal surface is free from impurities (particularly inorganic salts). Suitable conditions for the application and...
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Examination of the epoxy coating system's resistance to Corrobill
PublikacjaThe tests of the influence of the surface cleaning agent on the epoxy coating were carried out. Electrochemical and corrosion tests were carried out. The effect of the preparation on the adhesion and hardness of the tested coating was tested.
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The protective properties of graphene oxide coatings functionalized with phosphorus atoms.
PublikacjaRecently, electrophoretically deposited graphene oxide coatings are commonly applied as an anti-corrosion layer. However, improper adjustment of electrophoretic deposition (EPD) parameters as well as the hydrophilic nature of graphene oxide contribute to the formation of defects in the coatings and the increase in the wetting properties, respectively, and thus lead to a reduction of protective properties. The growth of wetting...
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Ultimate compressive strength assessment of uncleaned and cleaned corroded plates with locked crack
PublikacjaThe work presented here investigates the structural response of cleaned corroded plates, subjected to compressive load in the presence of a locked crack, where the change of mechanical properties as a result of corrosion development and the cleaning process is also accounted for. A Finite Element model for assessing the compressive strength, considering geometric and material nonlinearities, is developed, and the analysed plates...
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Experimental and Quantum Chemical Evaluation of 8-Hydroxyquinoline as a Corrosion Inhibitor for Copper in 0.1 M HCl
PublikacjaThe corrosion inhibition properties of 8-hydroxyquinoline (8-HQ) in 0.1 M HCl for copper have been investigated by using experimental (electrochemical impedance spectroscopy (EIS), dynamic electrochemical impedance spectroscopy (DEIS), and potentiodynamic polarization) and theoretical methods complemented by surface morphological examination with the aid of scanning electron microscopy (SEM) and electron dispersive X-ray spectroscopy...