Wyniki wyszukiwania dla: polyurethane%20foams
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The porosity and morphology of PU foams prepared by solvent casting/salt leaching method with different solvents
PublikacjaIn this study, the polyurethane (PU) system based on poly(ethylene-butylene) adipate diol, 1,6-hexamethylene diisocyanate, 1,4-butanediol and ascorbic acid is used to prepare a foamed material. Polymer foams were created using solvent casting/salt-particle leaching (SC/PL) method. The influence of the PU concentration in different solutions [either in a DMF or in DMF with THF as a co-solvent] on the morphology and porosity of the...
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Application of sublation and two phase titration methods for analytical of surfactants in AFFF fire-fighting foams
PublikacjaCelem badań była próba opracowania odpowiedniej metody izolacji ze ścieków fluorowanych związków powierzchniowo czynnych FZPC do celów analitycznych, a także metody ich ilościowego oznaczania. W badaniach polegających na oznaczaniu stężenia FZPC w oparciu o miareczkowanie w układzie dwufazowym: woda/chloroform użyto Hyaminy 1622, jako titranta oraz błękitu metylenowego, jako wskaźnika. Kolejnym etapem badań była izolacja ZPC z...
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Michał Strankowski dr hab. inż.
OsobyJest zatrudniony w Katedrze Technologii Polimerów na Wydziale Chemicznym od 2006 roku. W tym samym roku uzyskał stopień doktora nauk technicznych w zakresie technologii chemicznej. Stopień doktora habilitowanego w dziedzinie nauk ścisłych i przyrodniczych uzyskał w 2019 roku. W okresie 2013-2015 pełnił funkcję kierownika projektu „PUR-GRAF” pt. „Nanokompozyty poliuretanowe zawierające zredukowany tlenek grafenu”. Za opracowane...
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Physico‐Mechanical Properties and Flammability of PUR/PIR Foams Containing Expandable Graphite Core‐Shell Composite Particles
PublikacjaIn this work, polyurethane/polyisocyanurate (PUR/PIR) foams were modified by two types of expandable graphite (EG) core-shell composite particles. The pulverized EG core-shell composite particles were prepared during emulsion polymerization using methyl methacrylate or glycidyl methacrylate for the synthesis of the polymeric shells (poly(methyl methacrylate) (PMMA) and poly (glycidyl methacrylate) (PGMA)), and then the obtained EG_PMMA...
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Study on the Structure-Property Dependences of Rigid PUR-PIR Foams Obtained from Marine Biomass-Based Biopolyol
PublikacjaThe paper describes the preparation and characterization of rigid polyurethane-polyisocyanurate (PUR-PIR) foams obtained with biopolyol synthesized in the process of liquefaction of biomass from the Baltic Sea. The obtained foams differed in the content of biopolyol in polyol mixture (0–30 wt%) and the isocyanate index (IISO = 200, 250, and 300). The prepared foams were characterized in terms of processing parameters (processing...
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Poliuretany do zastosowań w medycynie na bazie poli(ε-aprolaktonodiolu) oraz poliglikolu etylenowego. Poly(ε-caprolactonediol) and polyethylene glycol-based polyurethanes for medical applications
PublikacjaOmówiono sposoby otrzymywania poliuretanów do zastosowań medycznych. W wyniku modyfikacji znanej metody prepolimerowej syntezy otrzymano dwie serii nowych poliuretanów różniących się składem chemicznym, dlaktórych przygotowano pełne charakterystyki właściwości. Wykazano, że wprowadzenie poliglikolu etylenowego do struktury poliestouretanówotrzymanych na bazie polikaprolaktonu znacząco poprawia powinowactwo materiałów do wody, zwiększa...
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Study on the Structure-Property Dependences of Rigid PUR-PIR Foams Obtained from Marine Biomass-Based Biopolyol
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Structure, Mechanical, Thermal and Fire Behavior Assessments of Environmentally Friendly Crude Glycerol-Based Rigid Polyisocyanurate Foams
PublikacjaIn this work, rigid polyisocyanurate foams were prepared at partial substitution (0–70 wt%) of commercially available petrochemical polyol, with previously synthesized biopolyol based on crude glycerol and castor oil. Influence of the biopolyol content on morphology, chemical structure, static and dynamic mechanical properties, thermal insulation properties, thermal stability and flammability was investigated. Incorporation of...
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Obtaining and Characterization of the PLA/Chitosan Foams with Antimicrobial Properties Achieved by the Emulsification Combined with the Dissolution of Chitosan by CO2 Saturation
PublikacjaA new method of obtaining functional foam material has been proposed. The materials were created by mixing the poly lactic acid (PLA) solution in chloroform, chitosan (CS) dissolved in water saturated with CO2 and polyethylene glycol (PEG), and freeze-dried for removal of the solvents. The composite foams were characterized for their structural (SEM, FT-IR, density, porosity), thermal (DSC), functional (hardness, elasticity, swelling...
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Obtaining and Characterization of the PLA/Chitosan Foams with Antimicrobial Properties Achieved by the Emulsification Combined with the Dissolution of Chitosan by CO2 Saturation
PublikacjaA new method of obtaining functional foam material has been proposed. The materials were created by mixing the poly lactic acid (PLA) solution in chloroform, chitosan (CS) dissolved in water saturated with CO2 and polyethylene glycol (PEG), and freeze-dried for removal of the solvents. The composite foams were characterized for their structural (SEM, FT-IR, density, porosity), thermal (DSC), functional (hardness, elasticity, swelling...
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Józef Haponiuk prof. dr hab. inż.
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Rheological properties, oxidative and thermal stability, and potential application of biopolyols prepared via two-step process from crude glycerol
PublikacjaIn this work, previously synthesized biopolyols were analyzed in terms of their rheological and thermal properties, very important from the technological point of view. For better evaluation of performed synthesis, the influence of its time and temperature on the properties of biopolyols was determined. In the end, obtained materials were used to prepare rigid polyurethane-polyisocyanurate (PUR-PIR) foams, to evaluate their potential...
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Polymers doped by Ca or P. Chemical composition investigations
Dane BadawczeThe calcium and phosphorus doped polyurethane polymers (PU) were analyzed by XPS method. A series of samples with various content of Ca and P dopand - from 0% up to 21%) were selected for measutements. The chemical composition and valence state of elements were measurements using OmicronNatechnology UHV system wih Argus hemispherical photoelectron...
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Influence of bio-polyols with different molecular weight on properites of PUR-PIR foams
Dane BadawczeThis work attempts to validate the possibility of replacing petrochemical polyols with previously synthesized bio-polyols and their impact on the structure and properties of rigid polyurethane-polyisocyanurate (PUR-PIR). The influence of bio-polyols addition on foam properties was investigated by mechanical testing, Fourier transform infrared spectroscopy...
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Challenges and recent advances in bio-based isocyanate production.
PublikacjaPolyurethanes (PUs) are key players in the plastics industry. According to the Global Polyurethane Market (2019–2023), their value in the global market reached $95.13 billion in 2019 and is expected to grow at a compound annual growth rate of 12%. This is in line with the increase in the number of research papers and patents on the synthesis and application of petroleum-based PUs (P-PUs) and biomass or green PUs (G-PUs) (from 67 657...
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Synthesis, structure and properties of novel poly(hydroxyurethane)s obtained by non-isocyanate route
PublikacjaNon-isocyanate polyurethanes (NIPUs) can be synthesized by polyaddition of five-membered bis(cyclic carbonate)s and primary diamines. NIPUs are an alternative for the commonly used (in the form of foams, elastomers, coatings or fibers) in the industry polyurethanes obtained using toxic and moisture sensitive diisocyanates, polyols and low-molecular weight chain extenders. The main aim of this work was to synthesize non-isocyanate...
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Characterization of volatile compounds, structural, thermal and physico-mechanical properties of cross-linked polyethylene foams degraded thermo-mechanically at variable times
PublikacjaWaste cross-linked polyethylene foam (wXLPE) was thermo-mechanically degraded at variable time using internal batch mixer. The progress of wXLPE degradation has been investigated by using a simultaneous thermogravimetric/differential scanning calorimetry analyzer coupled with Fourier transform infrared spectroscopy, swelling measurements, tensile tests and scanning electron microscopy. Volatile organic compounds generated during...
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Recent Advances in Development of Waste-Based Polymer Materials: A Review
PublikacjaLimited petroleum sources, suitable law regulations, and higher awareness within society has caused sustainable development of manufacturing and recycling of polymer blends and composites to be gaining increasing attention. This work aims to report recent advances in the manufacturing of environmentally friendly and low-cost polymer materials based on post-production and postconsumer wastes. Sustainable development of three groups...
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Bio‐polyols synthesized by liquefaction of cellulose: Influence of liquefaction solvent molecular weight
PublikacjaCurrently, the plastics industry including polyurethanes is based on the use of petrochemicals. For this reason, scientists are looking for new types of renewable resources for the substitution of petrochemical substances. This work aims to evaluate the effect of polyethylene glycols (PEG) with different molecular mass impact on properties of bio-based polyols synthesized via biomass liquefaction of cellulose. To date, research...
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Experimental Study on Dynamics of Wooden House Wall Panels with Different Thermal Isolation
PublikacjaWood frame buildings are very popular in regions that are exposed to different dynamic excitations including earthquakes. Therefore, their seismic resistance is really important in order to prevent structural damages and human losses. The aim of the present paper is to show the results of experimental tests focused on the dynamic response of wall panels of a wooden frame building with thermal isolation made of mineral wool and...
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Development of conductive porous media as packing materials for biotrickling filter – microbial fuel cell system (BTF-MFC system)
Dane BadawczeDataset presents values of electrical resistance measured for three developed conductive packimg materials for the application in a BTF-MFC system.
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MODAL ANALYSIS OF REAL TIMBER FRAME HOUSES WITH DIFFERENT INSULATION MATERIALS
PublikacjaThe aim of this article is to present the results of a numerical modal analysis of two actual structures of timber frame buildings and the different behaviour due to the used insulation material. One model of the timber structure was filled with mineral wool, while the other with polyurethane foam. During the modal analysis, eigenvalues for both models have been determined. The results of the analysis clearly show the increase...
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Experimentation, material modelling and simulation of bonded joints with a flexible adhesive
PublikacjaThe paper deals with material parameters identification of a flexible adhesive and the numerical simulation of its behaviour in a single lap bonded joint. The material modelling was based on the simple shear and tensile-shear laboratory tests of the bonded joints made of thin aluminium and polyurethane plates with the flexible adhesive Terostat MS 9360 manufactured by Henkel AG & Co. The adhesive was considered as a hyperelastic...
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Prediction of the fatigue lifetime of PUR structural elements using a combined experimental-numerical approach
PublikacjaThis paper presents a method for estimating the fatigue life of polyurethane elastomeric components. A rubber replacement - polyurethane of hardness 80ShA commonly used in vibration damping systems, for example, in motor vehicle suspensions, was used for the study. A metal-rubber bushing component was selected for analysis, and numerical analysis was carried out along with a fatigue model proposal based on a modification of the...
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Structure and properties comparison of poly(ether-urethane)s based on nonpetrochemical and petrochemical polyols obtained by solvent free two-step method
PublikacjaThe application of thermoplastic polyurethanes (TPU) is becoming more and more extensive, and the decreasing of used petrochemical monomers and reduction of energy for the polymerization and processing processes is getting increasingly important. In this paper, we confirmed the positive influence of high bio-based monomers contents (by replacing petrochemical polyol and glycol by bio-based counterparts) on processing and properties...
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Kinetics of hexane and cyclohexane biodegradation using Candida subhashii in mineral salt medium in the presence of DES solution
Dane BadawczeDataset presents results of investigations on kinetics of biodegradation of hexane and cyclohexane in Candida subhashii.
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Novel bio-based thermoplastic poly(ether-urethane)s. Correlations between the structure, processing and properties
PublikacjaThe main purpose of this work was to analyze the effect of the number of unreacted isocyanate groups and the [NCO]/[OH] molar ratio during the chain extension of a prepolymer during the polymerization process on the structure, processing and selected properties of thermoplastic poly(ether-urethane)s. Three series of novel thermoplastic polyurethanes were obtained via a prepolymer route. Three prepolymers were synthesized from diisocyanate...
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Preparation, characterization, and manufacturing of new polymeric materials for 3D printing for medical applications
PublikacjaThis work concerns the synthesis, formation, and characteristics of new filaments for 3D printing in FDM™/FFF technology for medical purposes. Two types of filaments were developed, i.e. degradable polyurethane and biodegradable polylactide-starch. The influence of the 3D printing process on selected filament properties was investigated. A detailed analysis of the filament formation process by the extrusion method was carried out,...
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Timber frame houses resistant to dynamic loads - seismic analysis
PublikacjaThe aim of the article is to present results of seismic analysis results of two real-sized timber frame buildings subjected to seismic excitations. The first model was insulated with mineral wool, the second one with polyurethane foam. Technology and specifications involved in both models construction is based on the previously conducted experimental research on timber frame houses, including wall panels tests, wall numerical models...
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Risks related to car fire on innovative Poroelastic Road Surfaces-PERS
PublikacjaTo reduce tyre/road noise, the concept of poroelastic road surfaces (PERS) was invented. PERS is a road surface material that is porous, and at the same time, it is flexible because of the substantial amount of rubber granulate content (from 20% to 85%). The rubber and stone particles are bound by polyurethane resin instead of bitumen. It was feared that in case of fire, because of the high content of rubber and polyurethane, there...
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Kinetics of cyclohexane removal by Candida subhashii and Fusarium solani
Dane BadawczeDataset presents cyclohexane biodegradation in gas phase using two species of microorganisms: Candida Subhashii and Fusarium solani. Biodegradation was carried out in sealed chambers with a capacity of 1000 ml. In each of them there are two discs inhabited with microorganisms, made of polyurethane foam, 80 mm in diameter and 20 mm thick.
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Assessment of the impact of bacteria Pseudomonas denitrificans, Pseudomonas fluorescens, Bacillus subtilis and yeast Yarrowia lipolytica on commercial poly(ether urethanes)
PublikacjaThe assessment of the impact of the bacteria Pseudomonas denitrificans, Pseudomonas fluorescens, Bacillus subtilis and yeast Yarrowia lipolytica on commercial poly(ether urethanes) Tecoflex® and Tecothane® is presented. The polyurethane samples were incubated with pure cultures of the microorganisms at 30 °C for five months. The changes in the chemical structure of the polymers were evaluated using loss of weight and contact angle...
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New-fangled sources of cellulose extraction: comparative study of the effectiveness of Cissus latifolia and Ficus benghalensis cellulose as a filler
PublikacjaRecycled polymers and biopolymers are receiving a great deal of attention these days. If these two can be combined, it will lead to an environment-friendly green material with a great deal of applications. Here the present work is about incorporating bio-based fillers in a recycled polyurethane matrix. Two unusual and extremely novel sources of cellulose have been proposed. The celluloses obtained from Cissus latifolia and Ficus...
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Low Noise Poroelastic Road Pavements Based On Bituminous Binder
PublikacjaTire/road noise is the dominant source of traffic noise. It depends both on the tire design and on the characteristics of road pavements as well as on the vehicles’ operating conditions. Due to the fact that conventional (pneumatic) car tires have almost reached the limits of their ability to further reduce their noisiness, it is widely believed that the additional reduction of tire noise will be possible mainly through modifications...
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Synteza, struktura chemiczna i właściwości bezizocyjanianowych poliuretanów otrzymywanych z wykorzystaniem CO2 oraz surowców pochodzenia naturalnego.
PublikacjaZ uwagi na wciąż rosnącą świadomość proekologiczną, politykę zrównoważonego rozwoju, a także nurt zielonej chemii wiodącym trendem w przemyśle tworzyw sztucznych jest poszukiwanie alternatywnych metod otrzymywania materiałów polimerowych. Komercyjnie poliuretany otrzymywane są w wyniku reakcji poliaddycji di- lub poliizocyjanianów z poliolami i małocząsteczkowymi przedłużaczami łańcucha. Z uwagi na niekorzystne właściwości diizocyjanianów,...
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Developing Materials for Biodegradable Otolaryngological Stents
PublikacjaMaterials for otolaryngological stents have to be characterized by good tensile strength, wear resistance, biocompatibility, and specific degradation time. This work aimed to synthesize polyurethanes based on various biodegradable polyol blends. Their biodegradability and mechanical properties were tested and compared to commercial BIOFLEX material.
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Comparison of the Efficiency of Hetero- and Homogeneous Catalysts in Cellulose Liquefaction
PublikacjaBiomass liquefaction is a well-known and extensively described process. Hydrothermal processes are well understood and can be used in the fuel industry. The use of organic solvents can result in full-fledged products for use in the synthesis of polyurethanes. The plastics industry, including polyurethanes, is targeting new, more environmentally friendly solutions. One of these is the replacement of petrochemical polyols with compounds...
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Modeling of wood frame structures with different insulation materials under damaging dynamic loading
PublikacjaWood frame buildings are very popular in regions that are exposed to different dynamic excitations, such as damaging earthquakes. Their seismic resistance is really important in order to prevent structural damages and human losses. This paper presents the results of advanced numerical investigation carried out using the FEM. Based on the models of wall panels, the numerical model of real structure of the wood frame building has...
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Synthesis, structure and properties of poly(ester-urethane)s obtained using bio-based and petrochemical1,3-propanediol and 1,4-butanediol
PublikacjaIn this paper, the poly(ester-urethane)s obtained using petrochemical and bio-based chain extenders were prepared and characterized. The influence of glycols’ origin on the chemical structure, mechanical and thermal properties of the prepared polyurethanes was studied. The materials were synthesised by prepolymer method. The first step involved the reaction of α,ω-dihydroxy(ethylene-butylene adipate (POLIOS 55/20) with 4,4’-diphenylmethane...
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Polyester-urethanes modified with gelatine for tissue scaffolds
PublikacjaNovel aliphatic PU foams, modified with gelatine, were obtained in a one-step polymerization process. Hard segments were obtained from 1,6-hexamethylene diisocyanate (HDI) and chain extenders 1,4-butanediol (BDO) or 2-(2-(2-hydroxyethoxy)ethoxy)ethanol (TG), soft segments were obtained from poly(ethylene-buthylene adipate) (EBO) polyol. We examined the PU foams for their sorption capability in canola oil, saline (0.9% NaCl water...
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GOOD HEALTH PRODUCTS AND POLYMER COMPOSITES OBTAINED WITH THE USE OF NATURAL ORIGIN MICRO- AND NANOFIBERS
PublikacjaThe aim of this work was focused on good health products and polymer composites obtained with the use of natural origin micro- and nanofibers. Many different type of the natural plants are used in the production of good health products and polymer processing like curcuma, cellulose, microalgae and others. Often are used as a antioxidants and fillers. In this work the effect of algae and cellulose as a microfillers on the chosen...
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Novel Biomass-Based Polymers: Synthesis, Characterization, and Application
PublikacjaA wide range of polymers were prepared from biomass-derivatives, using different polymerization mechanisms. Well-defined, fully hydroxy-functional polyesters based on aliphatic diols were synthesized, using either conventional metal-based catalysts or the organic superbase 1,5,7-triazabicyclododecene (TBD). Unsaturated polyesters were also made, offering additional functionality to these biobased resins. Metal-catalyzed or enzymatic...
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Processing of Polyester-Urethane Filament and Characterization of FFF 3D Printed Elastic Porous Structures with Potential in Cancellous Bone Tissue Engineering
PublikacjaThis paper addresses the potential of self-made polyester-urethane filament as a candidate for Fused Filament Fabrication (FFF)-based 3D printing (3DP) in medical applications. Since the industry does not provide many ready-made solutions of medical-grade polyurethane filaments, we undertook research aimed at presenting the process of thermoplastic polyurethane (TPU) filament formation, detailed characteristics, and 3DP of specially...
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Effects of liquid phase modification on the performance of biotrickling filters
Dane BadawczeDataset presents the effects of liquid phase modification on the biotrickling filtration (BTF) performance of air polluted with toluene, ethylbenzene, xylene and styrene.
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Podatność na degradację poliuretanów z syntetycznym polihydroksymaślanem w środowisku utleniającym i hydrolitycznym
PublikacjaPoliuretany (PURs), zawierające w segmencie giętkim ataktyczny, telecheliczny poli([R,S]-3-hydroksymaślan) (a-PHB) oraz polikaprolaktonodiol (PCL) lub polioksytetrametylenodiol (PTMG), poddano degradacji hydrolitycznej i oksydacyjnej. Poliuretany poddano degradacji hydrolitycznej w buforze fosforanowym z dodatkiem NaN3 w czasie 36 tygodni oraz oksydacyjnej w roztworze CoCl2/H2O2 w czasie 16 tygodni inkubacji. Próbki inkubowano...
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Polyisocyanates from Sustainable Resources
PublikacjaIsocyanates, next to polyols, constitute the major components essential for polyurethane (PU) production. They have a significant impact on physicochemical, mechanical, and thermal properties of PU materials. They also have an impact on those materials’ purposes, forms, textures, and other features. The available and used isocyanates are of a petrochemical origin. With the development of a trend toward green chemistry in the science...
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Biotrickling filtration of air polluted with hexane and cyclohexane: effects of trickling liquid modification with DES solutions
Dane BadawczeDataset presents selected parameters monitored during processes of biotrickling filtration of air polluted with hexane and cyclohexane.
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Two-step Conversion of Crude Glycerol Generated by Biodiesel Production into Biopolyols: Synthesis, Structural and Physical Chemical Characterization
PublikacjaIn this work biopolyols were synthesized via two-step process from crude glycerol and castor oil. For better evaluation of analyzed process, the impact of its time and temperature on the structure and properties of biopolyols was determined. Obtained results fully justified conducting of synthesis in two steps. Prepared materials were characterized by hydroxyl value and water content comparable to polyols industrially applied in...
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A Simple Replica Method as the Way to Obtain a Morphologically and Mechanically Bone-like Iron-Based Biodegradable Material
PublikacjaPorous iron-based scaffolds were prepared by the simple replica method using polyurethane foam as a template and applying the sintering process in a tube furnace. Their surface morphology was characterized using scanning electron microscopy (SEM) and phase homogeneity was confirmed using X-ray diffraction (XRD). Corrosion behavior was determined using immersion and potentiodynamic polarization methods in phosphate buffered saline...
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Mathematical Modelling of a Seismic Isolation System to Protect Structures During Damaging Earthquakes
PublikacjaThe present study aims to determine the effectiveness of a nonlinear mathematical model in simulating complex mechanical behaviour of a seismic isolation system to protect structures during strong and damaging earthquakes. In order to construct the Polymeric Bearings considered in this research, a specially prepared flexible polyurethane elastomer with increased damping properties has been used. The usefulness of the proposed mathematical...