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Silicon Oxycarbide (SiOC) Ceramic Materials as Anodes for Lithium Ion Batteries
PublikacjaPolymer derived ceramics (PDCs) have attracted attention as alternative anode material for Li-ion batteries. It has been found that ternary SiOC and SiCN ceramics obtained through pyrolysis of various preceramic polymers display high reversible capacities of 500 – 650 mAh/g. In this work we try to correlate the electrochemical performance of polymer derived silicon oxycarbide with its chemical composition and microstructural features....
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Comparison of Properties of the Hybrid and Bilayer MWCNTs—Hydroxyapatite Coatings on Ti Alloy
PublikacjaCarbon nanotubes are proposed for reinforcement of the hydroxyapatite coatings to improve their adhesion, resistance to mechanical loads, biocompatibility, bioactivity, corrosion resistance, and antibacterial protection. So far, research has shown that all these properties are highly susceptible to the composition and microstructure of coatings. The present research is aimed at studies of multi-wall carbon nanotubes in three different...
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The possibility to use multi-walled carbon nanotubes as a sorbent for dispersive solid phase extraction of selected pharmaceuticals and their metabolites: Effect of extraction condition
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Poly(vinylidene fluoride) and Carbon Derivative Structures from Eco-Friendly MOF-5 for Supercapacitor Electrode Preparation with Improved Electrochemical Performance
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Adsorption of anionic dye Direct Red 23 onto magnetic multi-walled carbon nanotubes-Fe3C nanocomposite: Kinetics, equilibrium and thermodynamics
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One-Step Synergistic Effect to Produce Two-Dimensional N-Doped Hierarchical Porous Carbon Nanosheets for High-Performance Flexible Supercapacitors
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Striking influence of Fe2O3 on the “catalytic carbonization” of chlorinated poly(vinyl chloride) into carbon microspheres with high performance in the photo-degradation of Congo red
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Selectivity of Mixed Iron-Cobalt Spinels Deposited on a N,S-Doped Mesoporous Carbon Support in the Oxygen Reduction Reaction in Alkaline Media
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Mechanisms of carbon monoxide hydrogenation yielding formaldehyde catalyzed by the representative strong mineral acid, H2SO4, and Lewis–Brønsted superacid, HF/AlF3
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Simultaneous impedance and volumetric studies and additionally potentiodynamic polarization measurements of molasses as a carbon steel corrosion inhibitor in 1M hydrochloric acid solution
PublikacjaThe inhibition effect of molasses on the corrosion of low carbon steel in 1M hydrochloric acid solution was investigated by volumetric and electrochemical measurements. Potentiodynamic polarization and dynamic electrochemical impedance spectroscopy (DEIS) results were obtained and compared with to those, obtained with the hydrogen evolution technique. All results indicate that molasses functioned as a good inhibitor in 1M hydrochloric...
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Direct determination of paraquat herbicide by square-wave voltammetry by two-step transfer mechanism at heterogeneous boron-doped carbon nanowall electrodes
PublikacjaBoron-doped carbon nanowalls (B:CNW) versus boron-doped diamond (BDD) materials were investigated for the effective electrochemical detection of highly toxic herbicide paraquat (PQ). Depending on the surface morphology and functional groups of BDD and B:CNWs, the electrochemical absorption and detection of the target analyte PQ revealed different detection mechanisms. The surface absorption mechanism was mainly observed for BDD,...
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Boron-doped carbon nanowalls for fast and direct detection of cytochrome C and ricin by matrix-free laser desorption/ionization mass spectrometry
PublikacjaDetecting proteins via surface assisted laser desorption/ionization mass spectrometry (SALDI-MS) method is still highly challenging, and only few examples of nanomaterials have been demonstrated to perform such detection so far. In this study, carbon nanowalls (CNWs), vertically aligned graphene sheet-based materials, presenting specific morphology, dimensions, and boron doping levels have shown improved performances for both qualitative...
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Super tough interpenetrating polymeric network of styrene butadiene rubber‐poly (methyl methacrylate) incorporated with general purpose carbon black ( N660 )
PublikacjaA classic set of polymeric interpenetrating polymeric network (IPN) microcomposites has been fabricated using an elastomer—styrene butadiene rubber [SBR], a thermoplastic poly(methyl methacrylate)-PMMA and with carbon black (CB)-N660 as a filler and reinforcing agent. This synthesized IPN composite can be promisingly employed as a toughened plastic and vibrational damper in a wide service range with excellent thermal stability,...
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Modeling the Effect of External Carbon Source Addition under Different Electron Acceptor Conditions in Biological Nutrient Removal Activated Sludge Systems
Publikacjahe aim of this study was to expand the International Water Association Activated Sludge Model No. 2d (ASM2d) to predict the aerobic/anoxic behavior of polyphosphate accumulating organisms (PAOs) and “ordinary” heterotrophs in the presence of different external carbon sources and electron acceptors. The following new aspects were considered: (1) a new type of the readily biodegradable substrate, not available for the anaerobic activity...
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Stable Field Electron Emission and Plasma Illumination from Boron and Nitrogen Co‐Doped Edge‐Rich Diamond‐Enhanced Carbon Nanowalls
PublikacjaSuperior field electron emission (FEE) characteristics are achieved in edge-rich diamond-enhanced carbon nanowalls (D-ECNWs) grown in a single-step chemical vapor deposition process co-doped with boron and nitrogen. The structure consists of sharp, highly conductive graphene edges supplied by a solid, diamond-rich bottom. The Raman and transmission electron microscopy studies reveal a hybrid nature of sp3-diamond and sp2-graphene...
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Strategies for mitigating nitrous oxide production and decreasing the carbon footprint of a full-scale combined nitrogen and phosphorus removal activated sludge system
PublikacjaNitrous oxide (N2O) emitted from biological nutrient removal activated sludge systems contributes significantly to the total carbon footprint of modern wastewater treatment plants. In the present study, N2O production and emissions were experimentally determined in a large-scale plant (220,000 PE) employing combined nitrogen (N) and phosphorus (P) removal. As a modelling tool, the Activated Sludge Model 2d (ASM2d) was extended...
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Electrode materials for electrochemical capacitors based on poly(3,4-ethylenedioxythiophene) and functionalized multi-walled carbon nanotubes characterized in aqueous and aprotic electrolytes
PublikacjaWithin this work, we report a facile one-stage synthesis of nanocomposites based on functionalized carbon nanotubes (CNTs) and electroactive polymer poly(3,4-ethylenedioxythiophene). Three different composites are investigated as potential electrode materials for the electrochemical capacitors. Two of the composites contain carbon nanotubes (ox-CNTs), functionalized by acid oxidation process (65% HNO3, 120 °C). The third composite...
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Modeling nitrous oxide production by a denitrifying-enhancedbiologically phosphorus removing (EBPR) activated sludge in thepresence of different carbon sources and electron acceptors
PublikacjaIn this study, the IWA Activated Sludge Model No. 2d (ASM2d) was expanded to identify the most important mechanisms leading to the anoxic nitrous oxide (N2O) production in the combined nitrogen (N) and phosphorus (P) removal activated sludge systems. The new model adopted a three-stage denitrification concept and was evaluated against the measured data from one/two-phase batch experiments carried out with activated sludge withdrawn...
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Microstructure and corrosion behaviour of carbon steel and ferritic and austenitic stainless steels in NaCl solutions and the effect of p-nitrophenyl phosphate disodium salt
PublikacjaThe microstructure and corrosion behavior of carbon steel (CSA516) and ferritic (SS410) and austenitic (SS304L) stainless steels were studied and compared. Corrosion tests were carried out in 0.5 M NaCl solutions. Rates of corrosion were monitored based on weight loss, Tafel extrapolation and linear polarization resistance (LPR) methods. Rates of corrosion were ranked following the order: CSA516 >> SS410 > SS304L. The impact of...
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Carbon nanowalls: A new versatile graphene based interface for laser desorption/ionization-mass spectrometry detection of small compounds in real samples.
PublikacjaCarbon nanowalls, vertically aligned graphene nanosheets, attract attention owing to their tunable band-gap, high conductivity, high mechanical robustness, high optical absorbance and other remarkable properties. In this paper, we report for the first time, the use of hydrophobic boron-doped carbon nanowalls (CNWs) for laser desorption/ionization of small compounds and their subsequent detection by mass spectrometry (LDI-MS). The...
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Dziewica z Orleanu i Don Carlos w twórczości Mickiewicza i operach Wagnera (w interpretacji Zdziechowskiego) ["The Maid of Orleans and Don Carlos" in the works by Mickiewicz and the operas by Wagner (in Zdziechowski's interpretation)]
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Application of single drop extraxtion (SDE) gas chromatography method for the determination of carbonyl compounds in spirits and vodkas
PublikacjaW pracy przedstawiono metodę oznaczania związków karbonylowych w spirytusach i wódkach, wykorzystującą do izolacji i wzbogacania technikę mikroekstrakcji do pojedynczej kropli (SDE)po derywatyzacji analitów O-(2,3,4,5,6-pentafluorobenzylo)hydroksylaminą. Określono optymalne parametry izolacji i wzbogacania aldehydów z roztworów alkoholowych (objętość próbki, objętość kropli, zawartość alkoholu, temperaturę i czas ekstrakcji)....
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Molecular dynamics simulations of the affinity of chitin and chitosan for collagen: the effect of pH and the presence of sodium and calcium cations
PublikacjaChitosan and chitin are promising biopolymers used in many areas including biomedical applications, such as tissue engineering and viscosupplementation. Chitosan shares similar properties with hyaluronan, a natural component of synovial fluid, making it a good candidate for joint disease treatment. The structural and energetic consequences of intermolecular interactions are crucial for understanding the biolubrication phenomenon...
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Toward an Understanding of the Chemiluminescence Accompanying the Reaction of 9-Carboxy-10-methylacridinium Phenyl Ester with Hydrogen Peroxide
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Apparent Molar Volumes and Expansivities of Ionic Liquids Based on N-Alkyl-N-methylmorpholinium Cations in Acetonitrile
PublikacjaDensities of some acetonitrile solutions of ionic liquids based on N-alkyl-N-methyl-morpholinium cations, N-ethyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide, N-butyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide, N-methyl-N-octylmorpholinium bis(trifluoromethanesulfonyl)imide and N-decyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide were measured at T = (298.15− 318.15) K and at atmospheric pressure....
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Solvation and partial molar volumes of some transition metal cations in N,N-dimethylacetamide, triethylphosphate and acetonitrile.
PublikacjaW oparciu o precyzyjne pomiary gęstości roztworów nadchloranów metali przejściowych szeregu Mn(II)-Zn(II) w DMA, TEP i AN wyznaczono pozorne molowe oraz graniczne wartości cząstkowych molowych objętości sole w temperaturach 293, 298 i 303,15 K. Wyznaczone wartości rozdzielono na udziały jonowe. Przeanalizowano czynniki decydujące o wielkości cząstkowych molowych objętości solwatowanych kationów.
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PHOTON LUMINESCENCE STUDIES OF TETRAHYDROFURAN FOLLOWING TRIHYDROGEN CATIONS IMPACT IN THE 20–1000 EV ENERGY RANGE
PublikacjaPhoton emission arising during tetrahydrofuran (C4H8O, THF) fragmentation initiated by H3 + ion impact has been studied experimentally. Luminescence fragmentation spectra and the relative emission cross-sections of the excited fragments have been measured using collision-induced emission spectroscopy in the 20–1000 eV energy range. The main features in the spectra are the H Balmer series lines, whose intensities decrease with increasing...
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Replicating DNA by cell factories: roles of central carbon metabolism and transcription in the control of DNA replication in microbes, and implications for understanding this process in human cells
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Co-Existence of Iron Oxide Nanoparticles and Manganese Oxide Nanorods as Decoration of Hollow Carbon Spheres for Boosting Electrochemical Performance of Li-Ion Battery
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Branched Poly(l-lysine)-Derived Nitrogen-Containing Porous Carbon Flake as the Metal-Free Electrocatalyst toward Efficient Oxygen Reduction Reaction
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Characterization and properties of low-friction, multilayered Cr-doped diamond-like carbon coatings prepared by pulse biased filtered cathodic arc deposition
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A Comparison of Carbon Dioxide Exhaust Emissions and Fuel Consumption for Vehicles Tested over the NEDC, FTP-75 and WLTC Chassis Dynamometer Test Cycles
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Experimental and analytical thermal study of PTFE composite sliding against high carbon steel as a function of the surface roughness, sliding velocity and applied load
PublikacjaThis study investigates the contact temperatures caused by frictional heating of sliding parallel pairs. In this case the materials studied are a PTFE composite in contact with a high carbon steel plate. These materials are commonly used for industrial applications, in particular as the main contacting components within a scroll expander system. The expected contact temperature values are important to be quantified in order to...
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Low energy inelastic electron scattering from carbon monoxide: II. Excitation of the b3Σ+, j3Σ+, B1Σ+, C1Σ+ and E1Π Rydberg electronic states
PublikacjaIn this second part of a two part paper (first part: Zawadzki et al (2020 J. Phys. B: At. Mol. Opt. Phys. 53 165201)) we present differential scattering cross sections for excitation of several Rydberg electronic states of carbon monoxide by electron impact. The first part concerned the low-lying valence states of CO. In the present study cross sections are obtained experimentally using low-energy electron energy-loss spectroscopy...
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Highly sensitive large strain cellulose/multiwalled carbon nanotubes (MWCNTs)/thermoplastic polyurethane (TPU) nanocomposite foams: From design to performance evaluation
PublikacjaAerogel-based polymer composite foams are promising for large strain piezoresistive sensors, but their aerogel skeleton is partially destroyed during the foaming process, limiting their sensitivity. Herein, the thermoplastic polyurethane was synthesized on the aerogel skeleton to obtain cellulose/multiwalled carbon nanotubes (MWCNTs)/thermoplastic polyurethane (TPU) nanocomposite materials foamed with the aid of supercritical carbon...
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HYGRO-MAGNETIC VIBRATION OF THE SINGLE-WALLED CARBON NANOTUBE WITH NONLINEAR TEMPERATURE DISTRIBUTION BASED ON A MODIFIED BEAM THEORY AND NONLOCAL STRAIN GRADIENT MODEL
PublikacjaIn this study, vibration analysis of single-walled carbon nanotube (SWCNT) has been carried out by using a refined beam theory, namely one variable shear deformation beam theory. This approach has one variable lesser than a contractual shear deformation theory such as first-order shear deformation theory (FSDT) and acts like classical beam approach but with considering shear deformations. The SWCNT has been placed in an axial or...
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Damped forced vibration analysis of single-walled carbon nanotubes resting on viscoelastic foundation in thermal environment using nonlocal strain gradient theory
PublikacjaIn this paper, the damped forced vibration of single-walled carbon nanotubes (SWCNTs) is analyzed using a new shear deformation beam theory. The SWCNTs are modeled as a flexible beam on the viscoelastic foundation embedded in the thermal environment and subjected to a transverse dynamic load. The equilibrium equations are formulated by the new shear deformation beam theory which is accompanied with higher-order nonlocal strain...
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Post-critical buckling of truncated conical carbon nanotubes considering surface effects embedding in a nonlinear Winkler substrate using the Rayleigh-Ritz method
PublikacjaThis research predicts theoretically post-critical axial buckling behavior of truncated conical carbon nanotubes (CCNTs) with several boundary conditions by assuming a nonlinear Winkler matrix. The post-buckling of CCNTs has been studied based on the Euler-Bernoulli beam model, Hamilton’s principle, Lagrangian strains, and nonlocal strain gradient theory. Both stiffness-hardening and stiffness-softening properties of the nanostructure...
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Adsorptive Removal of Aqueous Phase Crystal Violet Dye by Low-Cost Activated Carbon Obtained from Date Palm (L.) Dead Leaflets
PublikacjaUp to now, water pollution is still one of the important issues and challenges worldwide, due to its environmental, economic and human life impacts. It is also remains a challenge to environment scientists and technologists. Nowadays, the textile dyeing industry is considered one of the largest water consuming industries and produces large volumes of colored wastewater in its dyeing and finishing process. In this study, date palm...
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Screening of protozoan and microsporidian parasites in feces of great cormorant (Phalacrocorax carbo)
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Facile and continuous synthesis of graphene nanoflakes in RF thermal plasma
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Three dimensional graphene/carbonized metal-organic frameworks based high-performance supercapacitor
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Bulk quantity and physical properties of boron nitride nanocapsules with a narrow size distribution
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Post-plasma oxidation in water of graphene paper surface
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Preparation of exfoliated graphite by microwave irradiation
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Influence of chemically prepared H2SO4-graphite intercalation compound (GIC) precursor on parameters of exfoliated graphite (EG) for oil sorption from water
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Unraveling the role of boron dimers in the electrical anisotropy and superconductivity in boron-doped diamond
PublikacjaWe use quantum mechanics (QM) to determine the states formed by B dopants in diamond. We find that isolated B sites prefer to form BB dimers and that the dimers pair up to form tetramers (BBCBB) that prefer to aggregate parallel to the (111) surface in the <110> direction, one double layer below the H-terminated surface double layer. These tetramers lead to metallic character (Mott metal Insulator Transition) with holes in the...
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Volumetric incorporation of NV diamond emitters in nanostructured F2 glass magneto-optical fiber probes
PublikacjaIntegration of optically-active diamond particles with glass fibers is a powerful method of scaling diamond's magnetic sensing functionality. We propose a novel approach for the integration of diamond particles containing nitrogen-vacancy centers directly into the fiber core. The core is fabricated by stacking the preform from 790 soft glass canes, drawn from a single rod dip-coated with submicron diamond particles suspended in...
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Nonlinearity shaping in nanostructured glass-diamond hybrid materials for optical fiber preforms
PublikacjaNanodiamond integration with optical fibers has proved a compelling methodology for magneto-optics. We reveal that the applicability of nanodiamonds in nonlinear optics goes beyond the previous demonstrations of frequency converters. Instead, we exploit the recently reported volumetric integration of nanodiamonds along the optical fiber core and show that the nonlinear response of glasses can be manipulated by nanodiamonds. By...
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Low-strain sensor based on the flexible boron-doped diamond-polymer structures
PublikacjaA free-standing high boron-doped diamond nanosheet (BDDNS) has been fabricated for the development of a flexible BDDNS strain senor. High boron-doped diamond was initially grown on a tantalum substrate in a microwave plasma-assisted chemical vapor deposition method, and was then transferred to a Kapton polymer substrate to fabricate the flexible BDDNS/Kapton device. Before performing the transfer process, the thin BDDNS’s morphology...