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Targ Węglowy as the keystone of two ring road complexes of Gdańsk city centre
PublikacjaThe urban structure of Gdansk city centre is determined by two ring road complexes. The first of them, the Gdansk Ring, has been created as a result of a city defortification at the turn of the 19th and 20th centuries and has been destroyed in the end of World War Two with the rest of Gdansk. The second, the Main Town Green Belt, has been formed in place of the medieval fortification system of the city’s most important historical...
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Occurrence and Determination of Volatile Fatty Acids in Landfill Leachate and Gas
PublikacjaIn landfills containing biological matter volatile fatty acids (VFAs) are generated at high rate at the early stage of waste disposal and their content in leachate is high as compared to the leachate from old parts of landfill since they are converted to methane gas. Monitoring of the leachate for the content of VFAs can help determine the processes occurring in waste and possible effect of the leachate on the environment in the...
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Occurrence and Determination of Volatile Fatty Acids in Landfill Leachate and Gas
PublikacjaIn landfills containing biological matter volatile fatty acids (VFAs) are generated at high rate at the early stage of waste disposal and their content in leachate is high as compared to the leachate from old parts of landfill since they are converted to methane gas. Monitoring of the leachate for the content of VFAs can help determine the processes occurring in waste and possible effect of the leachate on the environment in the...
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Multivariate Statistical Analysis for Mutual Dependence Assessment of Selected Polyphenols, Organic Acids and Metals in Cool-Climate Wines
PublikacjaPolyphenols, organic acids and metal ions are an important group of compounds that affect the human health and quality of food and beverage products, including wines. It is known that a specific correlation between these groups exist. While wines coming from the New World and the Old World countries are extensively studied, wines coming from cool-climate countries are rarely discussed in the literature. One of the goals of this...
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SENSITIVITY ANALYSIS IN THE REHABILITATION OF HISTORIC TIMBER STRUCTURES ON THE EXAMPLES OF GREEK CATHOLIC CHURCHES IN POLISH SUBCARPATHIA
PublikacjaThis work concerns structural and sensitivity analysis of carpentry joints used in historic wooden buildings in south-eastern Poland and western Ukraine. These are primarily sacred buildings and the types of joints characteristic for this region are saddle notch and dovetail joints. Thus, in the study the authors focus on these types of corner log joints. Numerical models of the joints are defined and finite element simulations...
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Difference in Perceived Speech Signal Quality Assessment Among Monolingual and Bilingual Teenage Students
PublikacjaThe user perceived quality is a mixture of factors, including the background of an individual. The process of auditory perception is discussed in a wide variety of fields, ranging from engineering to medicine. Many studies examine the difference between musicians and non-musicians. Since musical training develops musical hearing and other various auditory capabilities, similar enhancements should be observable in case of bilingual...
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MgPdSb─An Electron-Deficient Half-Heusler Phase
PublikacjaThe half-Heusler family consists of many semiconducting intermetallic compounds, virtually all of them having a valence electron count (VEC) of 18. We have studied an electron-deficient (VEC = 17) phase MgPdSb and its Pd-stuffed variant MgPd1.25Sb. The cubic F4̅3m crystal structure was confirmed by the Rietveld refinement of powder X-ray diffraction (XRD) data. The lattice parameter is a = 6.284 and 6.335 Å for MgPdSb and MgPd1.25Sb,...
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The hydration properties of protein stabilizer, trimethylamine-N-oxide in aqueous solutions of N-methylacetamide – The volumetric and compressibility studies between 288.15 and 308.15 K
PublikacjaApparent molar volumes and apparent molar isentropic compressions of the protein stabilizer, trimethylamine-N-oxide (TMAO) were determined from the densities and speed of sound measured at T = (288.15, 298.15 and 308.15) K in aqueous solutions of N-methylacetamide (NMA) at four different concentrations (2, 4, 6 and 8 mol/kg). The concentration dependencies of the calculated quantities extrapolated to the infinite dilution lead...
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Explainable AI for Inspecting Adversarial Attacks on Deep Neural Networks
PublikacjaDeep Neural Networks (DNN) are state of the art algorithms for image classification. Although significant achievements and perspectives, deep neural networks and accompanying learning algorithms have some important challenges to tackle. However, it appears that it is relatively easy to attack and fool with well-designed input samples called adversarial examples. Adversarial perturba-tions are unnoticeable for humans. Such attacks...
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Comparison of Absorbed and Intercepted Fractions of PAR for Individual Trees Based on Radiative Transfer Model Simulations
PublikacjaThe fraction of absorbed photosynthetically active radiation (fAPAR) is a key parameter for estimating the gross primary production (GPP) of trees. For continuous, dense forest canopies, fAPAR, is often equated with the intercepted fraction, fIPAR. This assumption is not valid for individual trees in urban environments or parkland settings where the canopy is sparse and there are well-defined tree crown boundaries. Here, the distinction...
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L'economia mondiale dopo la guerra fredda
PublikacjaChe cosa è successo negli equilibri economici mondiali a partire dal 1989 e dalla dissoluzione del vecchio ordine sovietico? Dopo aver esaminato gli Usa e i suoi competitori asiatici, Giappone e Cina, il libro si concentra sull’Europa e sulle grandi trasformazioni portate dalla riunificazione tedesca, da Maastricht e dalla nascita dell’euro. Infine analizza, nell’ambito della globalizzazione, il ruolo dei BRICS, lo sviluppo economico...
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Detekcja osoby w wannie
PublikacjaStarzenie się społeczeństwa powoduje narastanie problemów chorób wieku starczego. Częstym problemem są zasłabnięcia w wannie podczas kąpieli. Celem publikacji jest przedstawienie metody identyfikacji tkanki ożywionej w wodzie z wykorzystaniem technik elektromagnetycznych. Obserwując zmiany amplitudy i częstotliwości pracy generatorów, pracujących w pętli sprzężenia zwrotnego z cewką, istnieje możliwość scharakteryzowania i określenia...
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Gdańsk oczami Irlandzkich i Polskich Artystów Plastyków. Krenz J.: Cykl 7 akwarel i pasteli. Zimowy Gdańsk
PublikacjaMiędzynarodowa wystawa zbiorowa, poplenerowa: Gdańsk oczami Irlandzkich i Polskich Artystów Plastyków. Galeria Sztuki Domu Aktora w Gdańsku. Przez kilka grudniowych dni artyści plastycy z Irlandii i Polski malowali zimowy Gdańsk. Stronę irlandzką reprezentowali: Jonathan Brennan, Katherine St.Angelo, Esther O’Kelly, Joanna Mules, Marcus Patton. Polscy uczestnicy: Magdalena Nowacka-Kolano, Anna Schumacher, Krzysztof Ludwin i Komisarz...
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Synthesis, molecular structure, and metabolic stability of new series of N' -(2-alkylthio-4-chloro-5-methylbenzenesulfonyl)-1-(5-phenyl-1 H -pyrazol-1-yl)amidine as potential anti-cancer agents
PublikacjaA series of new N'-(2-alkylthio-4-chloro-5-methylbenzenesulfonyl)-1-(5-phenyl-1H-pyrazol-1-yl)amidine derivatives have been synthesized and evaluated in vitro by MTT assays for their antiproliferative activity against cell lines of colon cancer HCT-116, cervical cancer HeLa and breast cancer MCF-7. The studied compounds display selective activity mainly against HCT-116 and HeLa cells. Thus, five compounds show selective cytotoxic...
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Advantages of the Application of the Temper Bead Welding Technique During Wet Welding
PublikacjaThermo-mechanically rolled S460ML steel was chosen for welding in underwater wet welding conditions by covered electrodes. The main aim of this study was to check the weldability for fillet welds in a water environment by controlled thermal severity (CTS) tests and to check the influence of temper bead welding (TBW) on the weldability of the investigated steel. Non-destructive and destructive tests showed that S460ML steel has...
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Experimental Research on the Energy Efficiency of a Parallel Hybrid Drive for an Inland Ship
PublikacjaThe growing requirements for limiting the negative impact of all modes of transport on the natural environment mean that clean technologies are becoming more and more important. The global trend of e-mobility also applies to sea and inland water transport. This article presents the results of experimental tests carried out on a life-size, parallel diesel-electric hybrid propulsion system. The eciency of the propulsion system was...
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CONTEMPORARY APPROACH TOWARDS RESPONSIVE ARCHITECTURE
PublikacjaConstantly changing environment pressures every living for a change, and response becomes a basic reaction of any living form. Change is a natural reaction that enables survivor of all the species. However, in architecture, the responsive structure did not take important role until the twentieth century. During that time many concepts and building introduced kinematics into the discipline. In the late 50 and 60 of XX century, visionary...
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PCR and real-time PCR assays to detect fungi of Alternaria alternata species
PublikacjaFungi of the Alternaria genus are mostly associated with allergic diseases. However, with a growing number of immunocompromised patients, these fungi, with A. alternata being the most prevalent one, are increasingly recognized as etiological agents of infections (phaeohyphomycoses) in humans. Nowadays, identification of Alternaria spp. requires their pure culture and is solely based on morphological criteria. Clinically, Alternaria...
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Stabilization of N-, N,N-, N,N'-Methylated and Unsubstituted Simple Amidine Salts by Multifurcated Hydrogen Bonds
PublikacjaIn the light of the usefulness of amidines in medicinal chem., this paper considers the effects on biol. properties and chem. reactivities of org. mols. affected by intramol. interactions. The study of chem. shifts has been an important source of information on the electronic structure of amidine salts and their ability to form non-covalent bonds with nucleic acids. The NMR and IR results demonstrate that hydrogen bonds are...
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Selective Cytostatic and Cytotoxic Anticancer Effects of Bisfunctional Agents: A Strategy for the Design of DNA Binding Agents
PublikacjaVarious agents have been synthesized and proved useful for the National Cancer Institute's anticancer testing as potential new drugs, but most agents suffer side effects from their limited selectivity against cancer cells over healthy ones. Therefore, this paper attempts to describe drugs in terms of the level of tumor cell selectivity which they possess to define the features of mols. that are essential for useful cytotoxicity....
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Zastosowanie superkondensatorów w autonomicznych systemach fotowoltaicznych
PublikacjaSuperkondensatory (ang. supercapacitors, ultracapacitors, double-layer capacitors, gold capacitors and power capacitors) stanowią istotną nowość w energetyce prądu stałego, zwłaszcza w dziedzinie magazynowania i oddawania energii.Przy ogólnych cechach zbliżonych do cech akumulatorów superkondensatory wyróżniają się nieosiągalną dla akumulatorów zdolnością do szybkiego ładowania prądem o dużym natężeniu oraz do chwilowego, jeszcze...
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Silver-modified titania with enhanced photocatalytic and antimicrobial properties under UV and visible light irradiation
PublikacjaCommercial titania photocatalysts were modified with 2 wt% of silver by photodeposition. The properties of the samples were characterized by DRS, XPS, XRD, FE-SEM and STEM. The modified samples exhibited activity under visible light and enhanced activity under UV irradiation for 2-propanol and acetic acid oxidation, respectively. The time-resolved microwave conductivity (TRMC) analysis indicated that enhanced activity (2.5–8-fold...
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Mercury concentrations in marine biota with special focus on grey and ringed seals
PublikacjaMarine organisms are exposed and sensitive to effects of environmental contamination by heavy metals including different forms of mercury. Baltic seals as the top predators of the marine ecosystem are even more endangered due to (considerable) longevity as well as a long biological half-time of toxin elimination. The concentrations of mercury in seals from the Baltic is poorly known, thus the aim of this work is to determine and...
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Investing in wine, precious metals and G-7 stock markets – A co-occurrence analysis for price bubbles
PublikacjaThis paper used the GSADF test to determine the periods defined in this paper as price bubbles in the three markets studied, i.e. the investment wine market, precious metal market and national stock market indices of G-7 countries. The results obtained enabled the calculation of the values of the phi correlation coefficients, which served the research objective of assessing the co-occurrence of price bubbles in the markets analysed....
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BP-EVD: Forward Block-Output Propagation for Efficient Video Denoising
PublikacjaDenoising videos in real-time is critical in many applications, including robotics and medicine, where varying light conditions, miniaturized sensors, and optics can substantially compromise image quality. This work proposes the first video denoising method based on a deep neural network that achieves state-of-the-art performance on dynamic scenes while running in real-time on VGA video resolution with no frame latency. The backbone...
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Lead-free bismuth-based perovskites coupled with g–C3N4: A machine learning based novel approach for visible light induced degradation of pollutants
PublikacjaThe use of metal halide perovskites in photocatalytic processes has been attempted because of their unique optical properties. In this work, for the first time, Pb-free Bi-based perovskites of the Cs3Bi2X9 type (X = Cl, Br, I, Cl/Br, Cl/I, Br/I) were synthesized and subjected to comprehensive morphological, structural, and surface analyses, and photocatalytic properties in the phenol degradation reaction were examined. Furthermore,...
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Bacterial presence in polar regions associated with environment modification by chemical compounds including contaminants
PublikacjaMicrobes are omnipresent and diverse members of all biological communities. In marine and freshwater ecosystems, microorganisms form the base of the food chain supporting higher trophic levels. Even though, microbes generally are thought to live in warm regions of Earth, many of them develop in cold climates. Polar regions remain relatively protected from widespread anthropogenic disturbances, which is a consequence of its remoteness...
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Biomass Production and Removal of Nitrogen and Phosphorus from Processed Municipal Wastewater by Salix schwerinii: A Field Trial
PublikacjaIn many Baltic regions, short-rotation willow (Salix spp.) is used as a vegetation filter for wastewater treatment and recycling of valuable nutrients to upsurge bioeconomy development. In this context, a four-year field trial (2016–2019) was carried out near a wastewater treatment plant in eastern Finland (Outokumpu) to investigate the effect of the processed wastewater (WW) on biomass production as well as the nutrients uptake...
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Creating a Remote Choir Performance Recording Based on an Ambisonic Approach
PublikacjaThe aim of this paper is three-fold. First, the basics of binaural and ambisonic techniques are briefly presented. Then, details related to audio-visual recordings of a remote performance of the Academic Choir of the Gdańsk University of Technology are shown. Due to the COVID-19 pandemic, artists had a choice, namely, to stay at home and not perform or stay at home and perform. In fact, staying at home brought in the possibility...
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Landscape of Automated Log Analysis: A Systematic Literature Review and Mapping Study
PublikacjaLogging is a common practice in software engineering to provide insights into working systems. The main uses of log files have always been failure identification and root cause analysis. In recent years, novel applications of logging have emerged that benefit from automated analysis of log files, for example, real-time monitoring of system health, understanding users’ behavior, and extracting domain knowledge. Although nearly every...
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Analytical chemistry in technical approaches: immobilization of biosorbent waste containing heavy metals in cemented materials
PublikacjaAn ecologically safe and economically justified method of stabilization of the used biosorbents was developed. Sorbent contaminated with heavy metals has been successfully solidified/stabilized using a hydraulic binder. The test results indicated that up to 1% of the biosorbent residue used could be added without compromising the compressive strength of the mortar. The compressive strength of the modified mortars did not change...
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Wear Resistance Enhancement of Al6061 Alloy Surface Layer by Laser Dispersed Carbide Powders
PublikacjaIn this paper, results of the experimental study on improving wear resistance in sliding friction of Al-based alloy are presented. The technique used involves the formation of a metal matrix composite (MMC) in the alloy surface layer by laser dispersion of carbide powders such as WC, TiC and SiC. For WC and TiC MMC surface coatings fabricated under conditions typical for most of the technologically relevant solid-state lasers (wavelength...
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Data governance: Organizing data for trustworthy Artificial Intelligence
PublikacjaThe rise of Big, Open and Linked Data (BOLD) enables Big Data Algorithmic Systems (BDAS) which are often based on machine learning, neural networks and other forms of Artificial Intelligence (AI). As such systems are increasingly requested to make decisions that are consequential to individuals, communities and society at large, their failures cannot be tolerated, and they are subject to stringent regulatory and ethical requirements....
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Śladami prof. Stanisława Hueckla
PublikacjaGromadzone, przechowywane i opracowywane w Sekcji Historycznej spuścizny pozwalają zachować pamięć o osobach, których wkład w rozwój nauki, uczelni oraz regionu Pomorza jest bezdyskusyjny. Zgromadzone w nich materiały stanowią ważne uzupełnienie do oficjalnej dokumentacji archiwalnej, ukazując często interesujące, czasem mniej znane fakty obejmujące twórczość i działalność zasłużonych postaci, wykraczające poza życie zawodowe....
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Deep eutectic solvents based highly efficient extractive desulfurization of fuels – Eco-friendly approach
PublikacjaThe developed process is based on alternative, green and cheap solvents for efficient desulfurization of fuels. Several deep eutectic solvents (DESs) were successfully synthesized and studied as extraction solvents for desulfurization of model fuel containing thiophene (T), benzothiophene (BT) and dibenzothiophene (DBT). The most important extraction parameters (i.e. kind of DES, DES: fuel volume ratio, hydrogen bond acceptor:...
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Design principles for creating digital transparency in government
PublikacjaUnder pressure to fight corruption, hold public officials accountable, and build trust with citizens, many governments pursue the quest for greater transparency. They publish data about their internal operations, externalize decision-making processes, establish digital inquiry lines to public officials, and employ other forms of transparency using digital means. Despite the presence of many transparency-enhancing digital tools,...
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Application of safirinium N-hydroxysuccinimide esters to derivatization of peptides for high-resolution mass spectrometry, tandem mass spectrometry, and fluorescent labeling of bacterial cells
PublikacjaMass spectrometry methods are commonly used in the identification of peptides and biomarkers. Due to a relatively low abundance of proteins in biological samples, there is a need for the development of novel derivatization methods that would improve MS detection limits. Hence, novel fluorescent N-hydroxysuccinimide esters of dihydro-[1,2,4]triazolo[4,3-a]pyridin-2-ium carboxylates (Safirinium P dyes) have been synthesized. The...
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Chemical investigation on the mechanism and kinetics of the atmospheric degradation reaction of Trichlorofluoroethene by OH⋅ and Its subsequent fate in the presence of O2/NOx
PublikacjaThe M06-2X/6-311++G(d,p) level of theory was used to examine the degradation of Trichlorofluoroethene (TCFE) initiated by OH⋅ radicals. Additionally, the coupled-cluster single-double with triple perturbative [CCSD(T)] method was employed to refine the single-point energies using the complete basis set extrapolation approach. The results indicated that OH-addition is the dominant pathway. OH⋅ adds to both the C1 and C2 carbons,...
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Principles of target DNA cleavage and the role of Mg2+ in the catalysis of CRISPR–Cas9
PublikacjaAt the core of the CRISPR–Cas9 genome-editing technology, the endonuclease Cas9 introduces site-specific breaks in DNA. However, precise mechanistic information to ameliorate Cas9 function is still missing. Here, multimicrosecond molecular dynamics, free energy and multiscale simulations are combined with solution NMR and DNA cleavage experiments to resolve the catalytic mechanism of target DNA cleavage. We show that the conformation...
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China and the Chinese in the modern world. An interdisciplinary study
PublikacjaThis monograph is a collection of chapters devoted to modern China on various approaches. There is no future without a past and a modern China is a country that skillfully combines the new with the old and the authors have attempted to present this phenomenon in this book. It brings to light issues such as a honorificativity in Chinese administrative and legal documents, a comparison of Chinese and...
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Structure and electrical properties of Y, Fe-based perovskite mixed conducting composites fabricated by a modified polymer precursor method
PublikacjaIn this work, samples of Y0.07Sr0.93Ti1-xFexO3-d with 20, 40, 60 and 80 mol% of iron amount were prepared by a low-temperature polymer precursor method. The SEM-EDS analysis proved that analyzed Y0.07Sr0.93Ti1-xFexO3-d samples were composites of two Ti- and Fe-rich perovskite samples. This kind of composite consists of two phases in which one has a good ionic and the other electronic conductivity, which makes such a composite a...
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Study of nanomechanical properties of (1-y)BST-yMgO thin films
PublikacjaIn the present study thin films of MgO – modified Ba0.6Sr0.4TiO3 (BST60/40) solid solution were prepared by the sol-gel-type chemical solution deposition method on stainless steel substrates. A multilayer spin-coating approach was utilized for the Ba0.6Sr0.4TiO3-MgO thin film deposition with subsequent thermal annealing at T=650-750C. Dried BST60/40-MgO gel powders were studied with thermogravimetric and differential thermal analysis...
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Kinetics of photochromic reactions in a 10-membered dibenzoazo crown ether
PublikacjaPrzedstawiono rezultaty pomiarów kinetyki fotochromowych reakcji dla jednego z serii eterów koronowych zawierających fragment azobenzenowy. Badano 10-członową dibenzoazokoronę, która ulega odwracalnej foto i termicznej izomeryzacji, podobnie jak macierzysty azobenzen. Eksperymenty były prowadzone w matrycy pMMA. Reakcja izomeryzacji monitorowana była spektrofotometrycznie. Czynnik przedwykładniczy dla termicznej izomeryzacji cis-trans...
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Core-Shell Nanoparticles with Hyperbranched Poly(arylene-oxindole) Interiors
PublikacjaCore-shell type star polymers composed of poly(tert-butyl acrylate) (poly(t-BuA)) arms and 100% hyperbranched poly(arylene-oxindole) interiors were synthesized via the "core-first" method. Atom transfer radical polymerization of t-BuA initiated by 2-bromopropionyl terminal groups of the hyperbranched core was applied for the synthesis of the stars. The resultant star structures were characterized by gel permeation chromatography...
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Metrological parameters of sulphur dioxide amperometric sensor containing addition of aprotic solvents
PublikacjaW publikacji zaprezentowano wyniki badań nad dodatku rozpuszczalnika aprotycznego do roztworu elektrolitu wewnętrznego czujnika na parametry metrologiczne prototypowego czujnika ditlenku siarki z membraną nafionową. Porównywano właściwości pięciu czujników różniących się składem elektrolitu. W każdym przypadku elektroda pracująca wykonana była ze złota, próżniowo napylonego na powierzchnię membrany. Roztwory elektrolitów zawierały...
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Estimation of platinum in environmental water samples with solid phase extraction technique using inductively coupled plasma mass spectrometry
PublikacjaZoptymalizowano metodykę oznaczania śladowych poziomów stężeń platyny (IV) w oparciu o technikę ekstrakcji do fazy stałej w połączeniu ze spektrometrią mas z plazmą wzbudzoną indukcyjnie. Na etapie wzbogacania platyny wykorzystano żel krzemionkowy modyfikowany grupami aminopropylowymi. Ilościowy odzysk platyny uzyskano poprzez wykorzystanie 1.0 mol L-1 roztworu tiomocznika jako eluenta. Odchylenie standardowe wyników (RSD) było...
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Improvements and new functionalities of UNRES server for coarse-grained modeling of protein structure, dynamics, and interactions
PublikacjaIn this paper we report the improvements and extensions of the UNRES server (https://unres-server.chem.ug.edu.pl) for physics-based simulations with the coarse-grained UNRES model of polypeptide chains. The improvements include the replacement of the old code with the recently optimized one and adding the recent scale-consistent variant of the UNRES force field, which performs better in the modeling of proteins with the β and the...
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Structural and luminescence properties of B2O3-Bi2O3-AlF3 glass doped with Eu3+, Tb3+ and Tm3+ ions
PublikacjaThe B2O3-Bi2O3-AlF3 glass system doped with Eu3+, Tb3+, Tm3+ and triply doped with Eu3+/Tm3+/Tb3+ ions in different molar ratios were successfully synthesized. Glass transition and crystallization temperatures were examined by Differential Scanning Calorimetry (DSC) measurements. X-ray Diffraction (XRD) confirmed the amorphous character of the samples. Fourier Transform Infrared Spectroscopy (FTIR) revealed that the glass matrix...
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THE PANTOGRAPH AND ITS GEOMETRIC TRANSFORMATIONS - A FORMER POPULAR TOOL FOR COPYING AND SCALING
PublikacjaDevelopment of digital technology has resulted in significant transformations of designer workshops. Computer applications replaced the previously existing tools and methods for drawing up of projects. Professional, sophisticated drawing instruments and tools for manual plotting, as well as basic drawing aids, have gradually fallen into oblivion and become relicts of a bygone era - the objects of collectors' interest. Gdansk University...
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Thermoplastic polyurethanes derived from petrochemical or renewable resources: A comprehensive review
PublikacjaThermoplastic polyurethanes (TPUs) materials are obtained by the reaction of polyol (ether-, ester-, and carbonate-based diols with average molecular weight in the range from 1,000 to 3,000 g/mol) with aliphatic or aromatic diisocyanates. Synthesized materials consist of the hard and soft segments which are separated in different level. All mechanical and thermal properties of TPUs depend on the chemical structure of used monomers,...