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Wyniki wyszukiwania dla: SELECTIVE SUBSTITUTION
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β2-Homo-Amino Acid Scan of µ-Selective Opioid Tetrapeptide TAPP
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State selective electron capture in the collision of S3+ ions in atomic hydrogen and helium.
PublikacjaZostało zaprezentowane teoretyczne podejście, uwzględniające obliczenia krytycznych adiabatycznych energii potencjalnych i dynamicznych sprzężeń pomiędzy nimi, do opisu procesu przechwytu elektronu przez jony siarki w zderzeniach z atomami wodoru i helu.
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A new strategy for PET depolymerization: Application of bimetallic MOF-74 as a selective catalyst
PublikacjaLarge-volume production of poly(ethylene terephthalate) (PET), especially in the form of bottles and food packaging containers, causes problems with polymer waste management. Waste PET could be recycled thermally, mechanically or chemically and the last method allows to obtain individual monomers, but most often it is carried out in the presence of homogeneous catalysts, that are difficult to separate and reuse. In view of this,...
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Synthesis and application of tetrazole di and triamide derivatives in ion-selective membrane electrodes
PublikacjaA number of tetrazole diamides and triamides have been synthesized and applied as ion carries in ion-selective membrane electrodes. Their selectivity and sensitivity were studied towards alkali, alkaline earth, transition and heavy metal cations. it was found that membranes doped with 3 and 2-nitrophenyl octyl ether exhibit an almost theoretial Nernstian response for NH+ over relatively wide concentration range. Elestrodes with...
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Potentiometric Solid-Contact Ion-Selective Electrode for Determination of Thiocyanate in Human Saliva
PublikacjaA new solid-contact potentiometric ion-selective electrode for the determination of SCN− (SCN-ISE) has been described. Synthesized phosphonium derivative of calix[4]arene was used as a charged ionophore. The research included selection of the ion-selective membrane composition, determination of the ISEs metrological parameters and SCN-ISE application for thiocyanate determination in human saliva. Preparation of the ISEs included...
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Antifungal Effect of Penicillamine Due to the Selective Targeting of L-Homoserine O-Acetyltransferase
PublikacjaDue to the apparent similarity of fungal and mammalian metabolic pathways, the number of established antifungal targets is low, and the identification of novel ones is highly desirable. The results of our studies, presented in this work, indicate that the fungal biosynthetic pathway of L-methionine, an amino acid essential for humans, seems to be an attractive perspective. The MET2 gene from Candida albicans encoding L-homoserine...
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Iron(III)-selective materials based on a catechol-bearing amide for optical sensing
PublikacjaThe synthesis and ion-binding properties of a new amide L derived from 3,4-dihydroxybenzoic acid are described. Due to the presence of a catechol unit, the compound interacts selectively with iron(III) in organic solvent (dimethyl sulfoxide, DMSO) to produce a color change from pale yellow to green. The incorporation of the ligand L into polymeric matrices or its encapsulation into surfactant-based spheres enables analyte detection...
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Multi-criteria selection of hydraulic gates
PublikacjaSelekcja doboru zamknięcia wodnego stanowi podstawowy element w jego projektowaniu. Projektowanie zamknięć można rozważać jako problem krótkoterminowy (zamknięcie natychmiastowe wysokiej wody) jak i problem długoterminowy uwzględniający problemy rolnicze, ekologiczne i zmiany klimatu. W doborze rodzaju zamknięć wodnych należy uwzględnić wiele kryteriów w tym ekonomicznych, wykonawczych, ekologicznych i innych. W pracy przedstawiono...
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Frequency bands selection of the Portevin-LeChatelier
PublikacjaEfekt Portevina-LeChateliera ujawnia się w postaci skokowych zmian naprężenia w trakcie procesu odkształcenia próbek pewnych stopów. Zjawisko PLC występuje w kilku odmianach charakteryzujących się istotnymi różnicami zarówno w przestrzennym rozkładzie pasm odkształcenia jak też przebiegu krzywej naprężeniowej. Przebiegi odpowiadające różnym odmianom serration charakteryzują się odmiennymi właściwościami rozkładu energetycznego...
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Clonal selection algorithm for vehicle routing
PublikacjaOver the years several successful computing techniques have been inspired by biological mechanisms. Studies of the mechanisms that allow the immune systems of vertebratesto adapt and learn have resulted in a class of algorithms called artificial immune systems. Clonal selection is a process that allows lymphocytes to launch a quick response to known pathogens and to adapt to new, previously unencountered ones. This paper presents...
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Prototype selection algorithms for distributed learning
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Combining Equity Country Selection Strategies
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Country selection strategies based on quality
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An Approach to RBF Initialization with Feature Selection
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Automated Reduced Model Order Selection
PublikacjaThis letter proposes to automate generation of reduced-order models used for accelerated -parameter computation by applying a posteriori model error estimators. So far,a posteriori error estimators were used in Reduced Basis Method (RBM) and Proper Orthogonal Decomposition (POD) to select frequency points at which basis vectors are generated. This letter shows how a posteriori error estimators can be applied to automatically select...
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Interoperability Constraints in Service Selection Algorithms
PublikacjaIn Service Oriented Architecture, composite applications are developed by integration of existing, atomic services that may be available in alternative versions realizing the same functionality but having different Quality of Service (QoS) attributes. The development process requires effective service selection algorithms that balance profits and constraints of QoS attributes. Additionally, services operate in a heterogeneous environment,...
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Selection of drive engines for dredge pumps
PublikacjaThis paper presents the principles of selecting drive engines for dredge pumps, formulated by this author. In order to formulate them influence of drive engines on dredge pump characteristics and dredger effectiveness, have been analyzed. Also, an analysis of results of the author's operational investigations concerning energy consumption and parameters of excavated soil transport on board dredgers has been performed.
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Selection of the tunnel thuster main parameters.
PublikacjaPrzedstawiono przegląd podstawowych odmian konstrukcyjnych sterów strumieniowych urządzeń zalecanych przez producentów. Z uwagi na znaczne różnice wartości otrzymywane z wymienionych metod, zamieszczono także wyniki analizy statystycznej sterów strumieniowych zastosowanych na statkach zbudowanych w Stoczni Gdynia w latach1995-2002. Porównanie wyników poszczególnych metod z parametrami sterów zastosowanych na wymienionych...
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EVALUATION OF THE SEMIVARIOGRAM SELECTION ON THE KRIGING INTERPOLATION
PublikacjaThe aim of the paper is to present the possibilities of geostatistical interpolation kriging method using in the process of generating digital terrain models (DTM). The source of data is a direct measurements realized with a precision GNSS positioning kinematic measurement technique RTN. Kriging algorithm was analysed, especially in the meaning of a semivariogram every step. Theoretical semivariogram selection influence on the...
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Comparison and Analysis of Service Selection Algorithms
PublikacjaIn Service Oriented Architecture, applications are developed by integration of existing services in order to reduce development cost and time. The approach, however, requires algorithms that select appropriate services out of available, alternative ones. The selection process may consider both optimalization requirements, such as maximalization of performance, and constraint requirements, such minimal security or maximum development...
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SELECTION OF DIAGNOSTIC FUNCTIONS IN A WHEELED TRACTOR
PublikacjaIn a classical approach to damage diagnosis, the technical condition of an analyzed machine is identified based on the measured symptoms, such as performance, thermal state or vibration parameters. In wheeled tractor the fundamental importance has monitoring and diagnostics during exploitation concerning technical inspection and fault element localizations. The main functions of a diagnostic system are: monitoring tractor components...
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Effect of the production method on the properties of RS3/RS4 type resistant starch. Part 2. Effect of a degree of substitution on the selected properties of acetylated retrograded starch
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Novel Potential Binding Sites for Selective Inhibitor Design of Human Soluble Epoxide Hydrolase
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Evaluation, Pitfalls and Recommendations for the “Water Layer Test” for Solid Contact Ion‐selective Electrodes
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Ion-selective electrodes based on p-tert-butyl-homooxacalixarene di(ethyl)amides
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Syntheses of N-Substituted Thymine Thioacetamides. A Novel Approach to Site Selective Acylation of Diaminoalkanes
PublikacjaA new series of N-substituted thiocarbamoyl derivs. contg. histamine, tryptamine, and other moieties having at least one amino group attached to an aliph. chain has been synthesized from (1-thyminyl)thioacetamide in good isolated yields (69-86%). N-[2-(4-Imidazolyl)ethyl](1-thyminyl)thioacetamide was hydrolyzed to its amide on prolonged heating in water. Ammonium sulfide (20-22% soln. in water) has found interesting new applications...
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A cortex-like model for animal recognition based on texture using feature-selective hashing
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Selective monoprotection of 1,4,7,10-tetraazacyclododecane via direct reactions with 4-nitrophenyl active esters
Publikacja1,4,7,10-tetraazacyklododekan jest cykliczną tetraaminą. Z chemicznego punktu widzenia wszystkie atomy azotu posiadają takie same właściwości fizykochemiczne. Jedyną różnicę stanowią ich właściwości kwasowo-zasadowe. Cyklen posiada dwa atomy azotu o obniżonej zasadowości. Właściwość ta z powodzeniem wykorzystywana jest w reakcjach jednoczesnej selektywnej substytucji dwóch atomów w pozycji 1 i 7. W przypadku bezpośredniej reakcji...
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Ion-selective electrodes based on p-tert-butyl-homooxacalixarene di(ethyl) amides
PublikacjaPochodne dietyloamidowe p-tert-butylodihomooksakaliks[4]arenu (1), p-tert-butyloheksahomotrioksakaliks[3]arenu (2) oraz p-tert-butylokaliks[4]arenu (3) były wykorzystane jako materiał aktywny w membranach elektrod jonoselektywnych w celu sprawdzenia detekcji kationów różnych rodzajów (Na+, K+, Cs+, Mg2+, Ca2+, Mn2+, Cu2+, Zn2+, Cd2+, Pb2+ oraz kation tetrametyloammoniowy). Wyznaczono charakterystyki elektrod oraz współczynniki...
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New sorbent materials for selective extraction of cocaine and benzoylecgonine from human urine samples
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Selective Synthesis of Magnetite Nanospheres with Controllable Morphologies on CNTs and Application to Lithium‐Ion Batteries
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Synthesis and Characterization of Size- and Charge-Tunable Silver Nanoparticles for Selective Anticancer and Antibacterial Treatment
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A rapid, selective, and ultrasensitive voltammetric and gravimetric protocol for MMP-1 active form detection
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New bis(azobenzocrown)s with dodecylmethylmalonyl linkers as ionophores for sodium selective potentiometric sensors
PublikacjaNovel biscrowns 1 and 2 were synthesized from 13-membered azobenzocrown ethers containing bromoalkylenoxy chains in para position relative to the azo group. The synthesized diester molecules are dodecylmethylmalonic acid derivatives differing by the linker length. The synthesized compounds have the potential of being used as sodium ionophores in ion-selective electrodes. They were characterized and used as ionophores in classic...
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Studies on 16-membered azothia-and azoxythiacrown ethers as ion carriers in ion selective membranes.
Publikacja16-członowe azo iazoksy korony zawierające w makropierścieniu atomy siarki były badane jako nośniki jonów w jonoselektywnych elektrodach membranowych. Związki te badane były pod kątem kompleksowania metali I i II grupy układu okresowego oraz metali ciężkich i przejściowych. Wyznaczone zostały stałe trwałości kompleksów azokoron z wybranymi kationami za pomocą metody sandwiczowej. W wyniku badań potwierdzono tworzenie się silnych...
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The selective salinity and hydrazine parameters for the start-up of non-anammox-specific biomass SBR
PublikacjaThe presence of ammonium (NH 4+ ) in wastewater above the permissible limits leads to undesirable ecological impact and public health concerns. In this study, the anaerobic ammonium oxidizing (anammox) bacteria-mediated nitrogen removal was investigated using a sequential batch reactor (SBR). Effects of different salinity levels were evaluated on the bacterial activity at: mild (below 0.2 g NaCl/L), elevated (18.2 g NaCl/L) and...
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The Substantial Improvement of Amphotericin B Selective Toxicity Upon Modification of Mycosamine with Bulky Substituents
PublikacjaAbstract: Background: It is assumed that the unfavorable selective toxicity of an antifungal drug Amphotericin B (AmB) can be improved upon chemical modification of the antibiotic molecule. Objective: The aim of this study was verification of the hypothesis that introduction of bulky substituents at the amino sugar moiety of the antibiotic may result in diminishment of mammalian vitro toxicity of thus prepared AmB derivatives. Methods:...
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Frequency Selective Surface Based MIMO Antenna Array for 5G Millimeter-Wave Applications
PublikacjaAbstract: In this paper a radiating element consisting of a modified circular patch is proposed for MIMO arrays for 5G millimeter-wave applications. The radiating elements in the proposed 2×2 MIMO antenna array are orthogonally configured relative to each other to mitigate mutual coupling that would otherwise degrade the performance of the MIMO system. The MIMO array was fabri-cated on Rogers RT/Duroid high frequency substrate...
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Cluster-based instance selection for machine classification
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A New Cluster-based Instance Selection Algorithm
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Cluster-Dependent Feature Selection for the RBF Networks
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Consensus-based cluster merging for the prototype selection
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Cluster Integration for the Cluster-Based Instance Selection
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Influence and selection of basic concepts on ontology design
PublikacjaOntologies as entities representing individual point of view on surrounding world introduce heterogeneity to knowledge representation. Common set of core concepts can introduce similarity big enough for further interoperability between ontologies. In this paper an experiment is presented proving that despite differences in detail ontologies stay similar in regard of core concepts. During the experiments NOIA methodology enhanced...
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Frequency bands selection of the Portevin–LeChatelier effect
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Selection Pressure in the Evolutionary Path Planning Problem
PublikacjaThis article compares an impact of using various post-selection methods on the selection pressure and the quality of the solution for the problem of planning the path for a moving object using the evolutionary method. The concept of selection pressure and different methods of post-selection are presented. Article analyses behaviour of post-selection for four options of evolutionary algorithms. Based on the results achieved, waveform...
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Wireless Network Selection: A Population Dynamics Approach
PublikacjaW artykule rozpatruje się środowisko wireless multihoming, gdzie terminal bezprzewodowy może w każdej chwili połączyć się z jedną z wielu dostępnych sieci bezprzewodowych. Zwrócono uwagę na rolę informacji zwrotnej z sieci powiadamiającej terminal o bieżącym stanie sieci. Zaproponowano trzy dynamiczne modele wyboru sieci, różniące się dostępem terminala do informacji zwrotnej dotyczących sieci, z którą nie jest aktualnie połączony.
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The flux compression generator load parameters selection
PublikacjaComputer simulation results of the flux compression generator (FCG) loaded with an inductor has been presented in this paper. Simulation research has been performed in order to select the parameters of FCG load coil properly. The influence of the load inductance and resistance on the current gain factor and the magnetic field energy accumulated in a load coil has been investigated.
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Selection of excitation signals for high-impedance spectroscopy
PublikacjaA method of fast impedance spectroscopy of technical objects with high impedance (|Zx| > 1 GOhm) is evaluated in this paper. An object is excited with a signal generated by a digital-to-analog converter (DAC) located on the U2531A DAQ module. Response signals proportional to current flowing through and voltage across the measured object are sampled by analog-to-digital converters (ADC) in the DAQ module. The object impedance spectrum...
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Extending Service Selection Algorithms with Interoperability Analysis
PublikacjaApplication development by integration of existing, atomic services reduces development cost and time by extensive reuse of service components. In Service Oriented Architecture, there exist alternative versions of services supplying the same functionality but differing in Quality of Service (QoS) attributes, which enables developers to select services with optimal QoS. Existing algorithms of service selection focus on the formal...