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Wyniki wyszukiwania dla: GREEN BIOMATERIALS
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In vivo degradation of short-term implants
PublikacjaStan powierzchni wywiera istotny wpływ na właściwości użytkowe implantu. Stawiane wymagania, zależą od funkcji jakie ma spełniać wszczep oraz rodzaju implantowanego materiału. W przypadku implantów krótkotrwałych wymagana jest przede wszystkim odpowiednia odporność korozyjna, nie powinno tworzyć się trwałe połączenie pomiędzy wszczepem a tkanką kostną.Wszystkie biomateriały ulegają degradacji. Ważne jest to, aby produkty tej degradacji...
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Expert System as a classification method for optimal Legg-Calve-Perthes Disease treatment
PublikacjaZaproponowano utworzenie systemu eksperckiego jako metody klasyfikacji w prognozowaniu dowolnej formy leczenia dzieci z chorobą Legg-Calve-Perthesa. Obecnie nie ma jednego optymalnego sposobu leczenia choroby Perhtes'a i proponowana metoda jest próbą utworzenia wymiernego i uniwersalnego narzędzia, które będzie stanowiło podstawę przy podejmowaniu decyzji o najlepszym sposobie leczenia chorego stawu biodrowego. System ekspercki,...
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The possibility of an use of laser treatment to improve the behaviour of the Ti-6Al-4V alloy
PublikacjaPrezentowana praca miała na celu stworzenie warunków ultraszybkiego chłodzenia przetopionej warstwy w obecności azotu tak, aby otrzymać twardą i gruba warstwę wierzchnią na stopie Ti-6Al-4V , najczęściej używanm stopie Ti, zawierającą struktury martenzytu i azotku tytanu.
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Estimation of the expected effects of different surface modifications on mechanical, chemical and biological behaviour of endoprostheses
PublikacjaPrzedstawiono koncepcję nowej endoprotezy o szczególnie wysokiej odporności na zużycie i pękanie. Koncepcja zakada wytwarzanie wieloetapową obróbkę powierzchniową kompozytu metalowo-ceramicznego.
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The phase composition of the surface layer of laser melted Ti-6Al-4V bioalloy
PublikacjaZastosowanie metody obróbki laserowej stopów Ti zwiekszyły twardość i odporność stopu na korozję. Jednakże uzyskane warstwy były stosunkowo cieńkie. W pracy zastosowano laser o dużej mocy dla stopu schłodzonego w ciekłym azocie, aby uzyskać grubszą warstwę, która w strefie zewnętrznej złożona będzie z tlenku i azotku tytanu, ważnych faz w biostopach.
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Maximum contact stress estimation on acetabular surface in total hip replacement using fuzzy reasoning system
PublikacjaArtykuł przedstawia rozmyty system wnioskowania dla oszacowania maksymalnego naprężenia kontaktowego na powierzchni panewki endoprotezy stawu biodrowego. Maksymalne naprężenie kontaktowe zostało określone na podstawie kąta Wiberga oraz masy ciała pacjenta.
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Badania obszarów zagrożonych zniszczeniem w biomateriałach koron stomatologicznych
PublikacjaDo analizy obszarów zagrożonych zniszczeniem w biomateriałach koron stomatologicznych zastosowano analizę strukturalną elementów skończonych MES. Opracowano dwu wymiarowy model korony stomatologicznej zamocowanej na kikucie zęba, w którym określono obszary występowania poszczególnych materiałów. Przyjęte do obliczeń numerycznych wartości modułu Younga i współczynniki Poissona odniesiono do rzeczywistych biomateriałów korony stomatologicznej....
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Optimalization of TiO2 nanotube geometry using fuzzy reasoning approach
PublikacjaThe geometry of TiO2 nanotube layer on titanium, obtained by electrochemical anodization, has been determined by using fuzzy reasoning approach. A proposed method showed the possibility of nanotube array architecture optimization by choosing an appropriate anodization condition. A fuzzy logic controller (FLC) was utilized using Matlab Software.
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The reactions occuring on the implant as a result of contact with human tissue
PublikacjaObecnosc implantu w ciele czlowieka powoduje liczne, czesto nieprzewidywalne skutki. Powodem takiej sytuacji jest duza roznorodnosc interakcji materialu medycznego z kontaktujaca sie z nim tkanka. Stwierdzenie to dotyczy glownie oddzialywan i skutkow zachodzacych na poziomie molekularnym w poszczegolnych komorkach kontaktujacej sie tkanki.
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Optimalization of titanium acaffold design using fuzzy reasoning approach
PublikacjaOpracowano metodę wnioskowania rozmytego do oszacowania geometrii scaffoldu Ti6Al4V, otrzymanego przy użyciu metody metalurgii proszków. Zaproponowana metoda umożliwia oszacowanie i optymalizację architektury scaffoldu poprzez dobór odpowiednich parametrów procesu. Zaprojektowano i przeprowadzono symulację działania sterownika rozmytego (FLC) za pomocą oprogramowania Matlab.
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Degradation of metal implants covered with silver
PublikacjaSilver was known for its antibacterial properties as long ago as in antiquity. The silver ions have ability to join the bacteria surface. Low density of silver ions Ag+ influence the protons through the bacteria surface, which results in total destruction of the cell. Antibacterial activity of silver remains in proportion with the density of silver ions Ag+ in the environment.
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Powłoka hydroksyapatytowa na nanorurkowej warstwie tlenkowej na stopie tytanu
PublikacjaPrzedstawiono sposób nakładania powłok hydroksyapatytowych na porowaty stop tytanu Ti13Nb13Zr za pomocą osadzania biomimetycznego poprzez zanurzenie materiału w przesyconym symulowanym płynie fizjologicznym. Powłoka hydroksyapatytowa została osadzona na nanorurkową warstwę tlenkową, otrzymaną w wyniku utleniania elektrochemicznego w roztworze zawierającym jony fluorkowe.
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Metal implants in ostheosynthesis - construction solutions, materials and applications
PublikacjaThe aim of the article is to present two case studies on intramedullary nails. The research included the evaluation of the type of fracture and the analysis of microstructure, chemical composition and hardness of the implant material.
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Simvastatin Coadministration Modulates the Electrostatically Driven Incorporation of Doxorubicin into Model Lipid and Cell Membranes
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The biological reactions on the implant-organism border
PublikacjaMateriał przeznaczony do implantacji w tkanki żywego organizmu powinien być biozgodny i biofunkcjonalny. Jeśli tak nie jest, ciało reaguje stanem zapalnym. Reakcje zapalne mogą się objawiać np. odrywaniem się cząstek materiału z powierzchni implantu na skutek tarcia lub nacisku, lub wytworzeniem biofilmu na jego powierzchni.
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Fuzzy reasoning approach to properties' determination of calcium phosphate coatings processed using ion beam assisted deposition on heated substrates
PublikacjaPraca przedstawia rozmyty system wnioskowania dla zamodelowania związków pomiędzy temperaturą podłoża oraz stosunkiem molowym Ca/P w gradientowej powłoce hydroxyapatytowej na podłożu tytanowym. Przeprowadzono symulację działania sterownika rozmytego na pomocą oprogramowania Matlab.
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Finite element method (FEM) implementation in some chosen areas in dental tytanium-ceramic crown design
PublikacjaAnaliza rozkładu naprężeń wykazała, że szczególnie duże spiętrzenia naprężeń powstają w częściach przyszyjkowych tytanowo-ceramicznej korony stomatologicznej. W przyszyjkowej części modelu występują największe naprężenia rozciągające, szczególnie niebezpieczne dla ceramiki nieodpornej na tego typu obciążenia. Mogą one stanowić przyczynę spękania i odprysków w części przyszyjkowej korony. Wyniki symulacji komputerowej metodą MES...
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Wstępne badania biokompatybilności poliuretanów otrzymanych z udziałem syntetycznego polihydroksymaślanu
PublikacjaCelem pracy było oznaczenie sorpcji oleju oraz pozostałości po ekstrakcji wodą i heksanem poliuretanów otrzymanych z udziałem poli{[R,S]-3-hydroksymaślanu. Oceniono także jego wpływu na parametry krwi. Wysoka sorpcja oleju roślinnego przez badane próbki oraz przebieg widm FTIR przed i po ekstrakcji heksanem a także analiza parametrów krwi po kontakcie z próbkami PU wskazują na potencjalną przydatność tych polimerów jako biomateriałów...
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Preparation of nano-tubular oxide layers on titanium alloy Ti13Nb13Zr
PublikacjaThe article presents results of oxidation tests and corrosion investigations of titanium alloy Ti13Nb13Zr preformed at different conditions. The oxide layers have been formed using electrochemical method in 2M H3PO4 + 0,3% HF solution for 30 min. and 1h at 20V constant voltage. The corrosion tests heve been made with poteniodynamic method in Ringer's solution at pH ranged 3 and 7. It has been shown that the nano-oxide films, which...
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Badania bioaktywności z wykorzystaniem komórek kościotwórczych na tytanie pokrytym chitozanem = Bioactivity studies using osteogenic cells on titanium coated with chitosan
PublikacjaChitosan is a natural polymer from the group of polysaccharides, which has found wide application in biomedical applications to induce bioactivity of implant. The studies described were carried out test imposition of chitosan membranes with varying degrees of deacetylation on the surface of titanium, and then check the bioactivity of the material in vitro, using osteogenic cells MC3T3-E1. Titanium surface before imposition of...
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Wpływ poliuretanów z syntetycznym polihydroksymaślanem na wzrost mikroorganizmów
PublikacjaW pracy przedstawiono wyniki badań oddziaływania nowych alifatycznych poliuretanów, otrzymanych z udziałem polihydroksymaślanu na wzrost Staphylococcus aureus, Escherichia coli i Candida albicans wokół próbek poliuretanowych. Najbardziej wrażliwym na działanie materiału poliuretanowego w warunkach prowadzenia doświadczenia był szczep Staphylococcus aureus.
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Influence of Ultrasound on the Characteristics of CaP Coatings Generated Via the Micro-arc Oxidation Process in Relation to Biomedical Engineering
PublikacjaOver the past decade, bone tissue engineering has been at the core of attention because of an increasing number of implant surgeries. The purpose of this study was to obtain coatings on titanium (Ti) implants with improved properties in terms of biomedical applications and to investigate the effect of ultrasound (US) on these properties during the micro-arc oxidation (MAO) process. The influence of various process parameters, such...
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Smartphone-Assisted and Optical Quantification of Copper and Glucose Using Palm Wine-Tailored Carbon Dots and Their Multiple Logic Gate Application
PublikacjaIn this work, potassium, sulfur, nitrogen, and chlorine self-doped carbon dots (CDs) were hydrothermally synthesized using palm wine as a carbon source. The palm wine-derived CDs (PW-CDs) are amorphous in nature and displayed an average particle size of 4.19 ± 0.89 nm. The as-synthesized CDs are used to fabricate a photoluminescent sensing probe to simultaneously detect Cu2+ and glucose via the “Turn ON−OFF−ON” mechanism. The PL...
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COMPOSITE MATERIAL SELECTION FOR A PATIENT TRANSFER ASSIST DEVICE
PublikacjaLaminates - layered composites containing at least two elements (matrix and reinforcement) widely used in industry have also found their usage in medicine. Their main feature is the ability to modify the material in order to obtain the required properties. Depending on the needs, we can modify reinforcement, type of resin or the method of bonding substrates. Commonly used fibers are: carbon fiber, glass and aramid fibers; resins...
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SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF NIOBIUM-DOPED HYDROXYAPATITE CERAMICS
PublikacjaHydroxyapatite (HAp) ceramic materials are considered as one of the most promising implant materials in bone surgery and in dentistry. They exhibit unique biocompatibility, bioactivity, and osteoconductivity, which are the most desirable biomaterial features. However, HAp itself is brittle, has low strength, high degree of crystallinity and low solubility at physiological pH. Doping synthetic HAp with metal ions plays an important...
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Elctrochemical oxidation and corrosion resistance of the Ti13Nb13Zr alloy
PublikacjaThis paper presents the results of oxidation and corrosion tests carried out on titanium alloy Ti13Nb13Zr. The oxide film was prepared by electrochemical environment 2M H3PO4 for 30 min and 1 h, at a constant voltage 40V. The tests of corrosion resistance were performed by potentiostatic method in Ringer's solution at different pH values: 7, 5 and 3. The change in an appearance of surface and the increase in corrosion resistance...
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The research of glass-ceramics implants used for bone pitches to examine bacteria adhesion occuring in human body
PublikacjaThe paper deals with the research concerning the bacteria adhesion on bioactive glass - ceramics materials
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Effects of the preheating laser treatment on microstructure and corrosion resistance of Ti6Al4V bioalloy
PublikacjaThe laser remelting of the Ti6Al4V alloy was made on specimens pre-heated at elevated temperatures. The laser treatment effected in change of microstructures of surface layers and an appearance of blisters and numerous cracks. The corrosion tests demonstrated the decrease in corrosion resistance for each preheating temperature. The observed effects were attributed to negative influence of excessive compressive stresses with no...
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Cu-HKUST-1 and Hydroxyapatite–The Interface of Two Worlds toward the Design of Functional Materials Dedicated to Bone Tissue Regeneration
PublikacjaA novel composite based on biocompatible hydroxyapatite (HA) nanoparticles and Cu-HKUST-1 (Cu-HKUST-1@HA) has been prepared following a layer-by-layer strategy. Cu-HKUST-1 was carefully selected from a group of four Cu-based metal−organic frameworks as the material with the most promising antimicrobial activity. The formation of a colloidal Cu- HKUST-1 layer on HA nanoparticles was confirmed by various techniques, e.g., infrared...
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Vascular stents - materials and manufacturing technologies
PublikacjaThe objective of this article is to present materials and technology for the manufacture of vascular stents with appropriate design requirements. The use of the right material is very important in implantology. A biomaterial introduced into the circulatory system must be biocompatible and hemocompatible. At the same time, it should not initiate toxic, mutagenic, or immunological reactions. Currently, 316L stainless steel (316L...
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Biological and mechanical research of titanium implants covered with bactericidal coating
PublikacjaThe paper concerns the biological and mechanical properties of titanium implants with an antibacterial coating. The Ti13Zr13Nb alloy samples were coated with hydroxyapatite (HAp) coatings using the electrophoretic deposition technique (EPD). Subsequently, the surface of the samples was modified with silver, copper, and nickel nanoparticles by the immersion method. Different titanium sample types (i.e. HAp-only and nanometals-enriched...
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Green's function for the wavized Maxwell fish-eye problem
PublikacjaRozpatrzono niezależne od czasu skalarne równanie falowe dla ośrodka typu ''rybie oko'' Maxwella w przestrzeni R^N (N >=2). Pokazano, że równanie to posiada unikalne własności transformacyjne względem inwersji w pewnej klasie hipersfer. Wykorzystano ten fakt do znalezienia zamkniętej postaci funkcji Greena, oraz uogólnionej funkcji Greena, dla wyjściowego równania.
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Collagen Type II—Chitosan Interactions as Dependent on Hydroxylation and Acetylation Inferred from Molecular Dynamics Simulations
PublikacjaChitosan–collagen blends have been widely applied in tissue engineering, joints diseases treatment, and many other biomedical fields. Understanding the affinity between chitosan and collagen type II is particularly relevant in the context of mechanical properties modulation, which is closely associated with designing biomaterials suitable for cartilage and synovial fluid regeneration. However, many structural features influence...
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Preparation and characterization of porous scaffolds from chitosan-collagen-gelatin composite
PublikacjaNovel porous scaffolds composed of chitosan, collagen and gelatin were prepared and characterized. For preparing scaffolds gelatin and collagen isolated from fish skins with various physicochemical properties were used. In order to reduce preparation solubility glutaraldehyde in the amount of 1%, w/w relative to the total biopolymers weight in solution was used. All obtained biomaterials showed a homogeneous porosity. Protein polymer...
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Gelatin-Modified Polyurethanes for Soft Tissue Scaffold
PublikacjaRecently, in the field of biomaterials, which are being designed for soft tissue scaffolding, is growing the interest of their modification with natural polymers. Synthetic polymers are often hard, not easy to process and they do not possess fine biodegradable profile. From the other hand natural polymers are biocompatible, but weak when used alone. The combination of natural and synthetic polymers gives the suitable properties...
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Electrodeposited Biocoatings, Their Properties and Fabrication Technologies: A Review
PublikacjaCoatings deposited under an electric field are applied for the surface modification of biomaterials. This review is aimed to characterize the state-of-art in this area with an emphasis on the advantages and disadvantages of used methods, process determinants, and properties of coatings. Over 170 articles, published mainly during the last ten years, were chosen, and reviewed as the most representative. The most recent developments...
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Comparative Greenness Evaluation
PublikacjaGreenness of analytical procedure is multivariable aspect as many greenness criteria should be taken into consideration. On the other hand, modern analytical chemistry offers dozens of analytical procedures, based on different sample preparation and final determination techniques that are used for the determination of a given analyte in a given matrix. For such complex decision-making processes, multi-criteria decision analysis...
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REVIEW OF CURRENT RESEARCH ON CHITOSAN AS A RAW MATERIAL IN THREE-DIMENSIONAL PRINTING TECHNOLOGY IN BIOMEDICAL APPLICATIONS
PublikacjaThree-dimensional (3D) biomaterial manufacturing strategies show an extraordinary driving force for the development of innovative solutions in the biomedical sector, including drug delivery systems, disease modelling and tissue and organ engineering. Due to its remarkable and promising biological and structural properties, chitosan has been widely studied for decades in several potential applications in the biomedical field. However,...
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Exploring avian exposure to parent polycyclic aromatic hydrocarbons (PAHs): Using the common eider Somateria mollissima in a global context
PublikacjaCompared to other organic contaminants, birds are rarely studied for their exposure to polycyclic aromatic hydrocarbons (PAHs), mainly due to their effective metabolization of parent PAHs. However, as some studies suggest, exposure to PAHs may result in adverse health effects including decreased survival, especially following oil spills. In the present study, we analyzed samples from a sea duck, the common eider Somateria mollissima...
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Public Participation practice versus economic pressure: transformation of the Gdansk Coastal Strip
PublikacjaThe paper focuses on the issue of public participation in the areas that are particularly sensitive to the transformation processes based on the case study of Gdańsk Coastal Strip. Moreover the article presents the outcome of an innovative attempt at promotion of public participation introduced in university education that was built on the experiences gathered during elaboration of the pro publico bono project of the Coastal Strip...
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Assessment and design of greener deep eutectic solvents – A multicriteria decision analysis
PublikacjaDeep eutectic solvents (DES) are often considered as green solvents because of their properties, such as negligible vapor pressure, biodegradability, low toxicity or natural origin of their components. Due to the fact that DES are cheaper than ionic liquids, they have gained many applications in a short period of time. However, claims about their greenness sometimes seem to be exaggerated. Especially, bearing in mind lots of data...
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Nanostructure of the laser-modified transition metal nanocomposites for water splitting
PublikacjaAlthough hydrogen is considered by many to be the green fuel of the future, nowadays it is primarily produced through steam reforming, which is a process far from ecological. Therefore, emphasis is being put on the development of electrodes capable of the efficient production of hydrogen and oxygen from water. To make the green alternative possible, the solution should be cost-efficient and well processable, generating less waste...
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Analytical procedures for short chain chlorinated paraffins determination - How to make them greener?
PublikacjaThe aim of the following paper was to gather current scientific information about the analytical protocols dedicated to measuring the content level of short-chain chlorinated paraffins (SCCPs) in various types of environmental samples. Moreover, the data about the basic validation parameters of applied procedures for SCCPs determination are listed. The main issue which is highlighted in the paper is the possibility of the application...
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Cognitive network model dedicated to transport system telematics
PublikacjaThe paper defines the concept of cognitive radio, in the context of transport systems, with particular emphasis on modern ecological concept of “green cognitive radio”. In addition, in the paper a modified cognitive network model dedicated to transport system telematics is proposed and presented. Algorithms to support the functioning of the cognitive radio are discussed. Sensors necessary to use the network to support cognitive...
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Lithuania inland waterways and its prospects
PublikacjaInland waterways have some traditions in Lithuania and in neighbor Countries, but during last 50 years other modes of transport move out inland waterway transport from real economical activity. In the same time inland waterways is the main green and sustainable transport system. In this article are presented analysis situation, methodology for the ships optimal using in inland waterways, forecasting of the possible cargo and passenger...
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Chitosan-based electrospun nanofibers for encapsulating food bioactive ingredients: A review
PublikacjaToday, society has been more aware of healthy food products and related items containing bioactive compounds, which potentially contribute to human health. Unfortunately, the long-term stability and bioactivity of biologically active compounds against environmental factors compromise their target and effective action. In this way, lab-designed vehicles, such as nanoparticles and nanofibers, provide enough properties for their preservation...
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Gelatin and gelatin/starch-based films modified with sorbitol for wound healing
PublikacjaGelatin-based films modified with sorbitol were produced from gelatin solution or gelatin/starch blends using a simple and low-cost solvent casting method, and subsequently, their physicochemical, mechanical, and biocompatibility properties were characterized. This work focused on developing and optimizing a biopolymeric blend to improve the pure biopolymers’ properties for potential biomedical applications such as wound dressing....
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A general theory for anisotropic Kirchhoff–Love shells with in-plane bending of embedded fibers
PublikacjaThis work presents a generalized Kirchhoff–Love shell theory that can explicitly capture fiber-induced anisotropy not only in stretching and out-of-plane bending, but also in in-plane bending. This setup is particularly suitable for heterogeneous and fibrous materials such as textiles, biomaterials, composites and pantographic structures. The presented theory is a direct extension of classical Kirchhoff–Love shell theory to incorporate...
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Microextraction Techniques Used in the Procedures for Determining Organomercury and Organotin Compounds in Environmental Samples
PublikacjaDue to human activities, the concentrations of organometallic compounds in all parts of the environment have increased in recent decades. The toxicity and some biochemical properties of mercury and tin present in the environment depend on the concentration and chemical form of these two elements. The ever-increasing demand for determining compounds at very low concentration levels in samples with complex matrices requires...
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Lead(II) coordination polymers with imidazole-4- and pyrazole-3-carboxylate isomeric linkers: Structural diversity and luminescence properties
PublikacjaUsing 1H-imidazole-4-carboxylic acid (4imCOOH) and 1H-pyrazole-3-carboxylic acid (3pyrCOOH) coordination polymers [Pb(4imCOO)2(H2O)]n (1) and [Pb2(3pyrCOO)4]n (2) were constructed. Obtained polymers were characterized via FT-IR, X-ray, PL and TG methods. The coordination polyhedron around Pb(II) in 1 is described as distorted pentagonal pyramid with hemidirected coordination sphere (based on DFT calculations). Compound 2 consists...