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Hydrogen migration in formation of NH(A3Π) radicals via superexcited states in photodissociation of isoxazole molecules
PublikacjaFormation of the excited NH(A 3Π) free radicals in the photodissociation of isoxazole (C3H3NO) molecules has been studied over the 14-22 eV energy range using photon-induced fluorescence spectroscopy. The NH(A 3Π) is produced through excitation of the isoxazole molecules into higher-lying superexcited states. Observation of the NH radical, which is not a structural unit of the isoxazole molecule, corroborates the hydrogen atom...
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Chemical composition, antioxidant and anticancer effects of the seeds and leaves and indigo (polygonum tinctorium Ait.) Plant
PublikacjaSeeds and leaves of indigo (Polygonum tinctorium Ait.) plant were investigated and compared with another medicinal plant named prolipid for their properties such as chemical composition, antioxidant, and anticancer effects by Fourier transform infrared, three-dimensional fluorescence spectroscopy, and electrospray ionization-MS in negative mode. It was found that polyphenols, flavonoids, and flavanols were significantly higher...
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Photofragmentation of tetrahydrofuran molecules in the vacuum-ultraviolet region via superexcited states studied by fluorescence spectroscopy
PublikacjaPhotofragmentation of tetrahydrofuran molecules in the vacuum-ultraviolet region, producing excited atomic and molecular fragments, has been studied over the energy range 14-68 eV using photon-induced fluorescence spectroscopy. Excited hydrogen atoms H(n), n = 3-11, have been detected by observation of the Hα to Hı lines of the Balmer series. The diatomic CH(A2Δ), CH(B2Σ-) and C2(d3Πg) fragments, which are excited to low vibrational...
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Transcriptomic profiling of the salt stress response in excised leaves of the halophyte Beta vulgaris ssp. maritima
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Early stages of condensation from the gaseous phase in a H2O-N2 system: a molecular dynamics study.
PublikacjaW pracy przedstawiono wyniki symulacji wczesnych etapów kondensacji z fazy gazowej w układzie xH2O (1-x)N2. Przeanalizowano całkowitą liczbę klastrów, średni rozmiar klastra i rozmiar klastra maksymalnego w funkcji czasu.
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The nature of emitting states in electroluminescence of polymeric films do-ped with anthracene andanthracene-based supramolecules
PublikacjaZaobserwowano nową odmianę bi-molekularnych stanów wzbudzenia elektronowego w polimerowych jednowarstwowych diodach EL z molekułami antracenu wbudowanymi bezpośrednio w matrycę poliwęglanową, jak i pośrednio przez ich włączenie jako grup chromoforowych w dużych makromolekułach rotaxanowych. Stwierdzono, że obok typowej emisji ekscymerowej pojawia się długofalowe pasmo elektromerowe. Pasmo to związane jest z emisją kolumbowsko związanych...
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Fault diagnosis in electronic circuits based on bilinear transformation in 3-D and 4-D spaces
PublikacjaPrzedstawiono ideę nowych metod diagnostycznych 3-D i 4-D opartych na przek-ształceniu biliniowym. Metody te bazują na transformacjach operujących odpo-wiednio w trzy i czterowymiarowych przestrzeniach funkcji układowych. Dlatych metod omówiono algorytm lokalizacji i identyfikacji pojedynczych uszko-dzeń parametrycznych w liniowych układach elektronicznych oraz algorytm lo-kalizacji i identyfikacji pojedynczych uszkodzeń...
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Comparison of Renewable Energy Sources in ‘New’ EU Member States in the Context of National Energy Transformations
PublikacjaThe European Union strives to create sustainable, low-carbon economies; therefore, energy policies of all member states should move towards renewable energy sources (RES). That concerns also the so-called new EU member states. These countries, on the one hand, are characterized by significant historical similarities in terms of post-communist legacy and adopted development strategies linked with the EU membership, and on the other...
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A Novel Method for Intelligibility Assessment of Nonlinearly Processed Speech in Spaces Characterized by Long Reverberation Times
PublikacjaObjective assessment of speech intelligibility is a complex task that requires taking into account a number of factors such as different perception of each speech sub-bands by the human hearing sense or different physical properties of each frequency band of a speech signal. Currently, the state-of-the-art method used for assessing the quality of speech transmission is the speech transmission index (STI). It is a standardized way...
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Flooding Extent Mapping for Synthetic Aperture Radar Time Series Using River Gauge Observations
PublikacjaThe flooding extent area in a river valley is related to river gauge observations such as discharge and water elevations. The higher the water elevations, or discharge, the larger the flooding area. Flooding extent maps are often derived from synthetic aperture radar (SAR) images using thresholding methods. The thresholding methods vary in complexity and number of required parameters. We proposed a simple thresholding method that...
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The evolution of education spaces - from plan as generator to regenerative architecture, virtual rooms and green campuses
PublikacjaThe study programmes are often considered the main formative factors in the process of educating future architects. Another highly influential component is the architectural characteristics of learning spaces, and consequently the impact of the physical built environment on the quality of education has been widely discussed. However, not often do we realise that the characteristics of education spaces correlate with the organisational...
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Optimum shapes and dimensions of rubber bumpers in order to reduce structural pounding during seismic excitations
PublikacjaLarge displacement of structures observed during seismic excitations may lead to collisions between two adjacent, insufficiently-separated buildings and may result in major damages of both of them. In many building codes, appropriate equations or approximately recommended distances between structures in order to avoid pounding hazard have been introduced. Unfortunately, further, more detailed considerations show that safety situation...
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Highly Occupied Surface States at Deuterium-Grown Boron-Doped Diamond Interfaces for Efficient Photoelectrochemistry
PublikacjaPolycrystalline boron-doped diamond is a promising material for high-power aqueous electrochemical applications in bioanalytics, catalysis, and energy storage. The chemical vapor deposition (CVD) process of diamond forma-tion and doping is totally diversified by using high kinetic energies of deu-terium substituting habitually applied hydrogen. The high concentration of deuterium in plasma induces atomic arrangements and steric...
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Variational principles for bound states of Schrödinger and Dirac equations allowing the use of discontinuous trial functions
PublikacjaWe present systematic constructions of variational principles for energies of bound states of the Schroedinger and Dirac equations. The principles allow the use of discontinuous trial functions. The method employed is based on a generalized Lagrange procedure. Relationships between our variational principles and those available in the literature are established.
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Molecular Dynamics to Predict Cryo-EM: Capturing Transitions and Short-Lived Conformational States of Biomolecules
PublikacjaSingle-particle cryogenic electron microscopy (cryo-EM) has revolutionized the field of the structural biology, providing an access to the atomic resolution structures of large biomolecular complexes in their near-native environment. Today’s cryo-EM maps can frequently reach the atomic-level resolution, while often containing a range of resolutions, with conformationally variable regions obtained at 6 Å or worse. Low resolution...
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Equivalence of equicontinuity concepts for Markov operators derived from a Schur-like property for spaces of measures
PublikacjaVarious equicontinuity properties for families of Markov operators have been – and still are – used in the study of existence and uniqueness of invariant probability for these operators, and of asymptotic stability. We prove a general result on equivalence of equicontinuity concepts. It allows comparing results in the literature and switching from one view on equicontinuity to another, which is technically convenient in proofs....
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Time-series analysis of road safety trends aggregated at national level in Europe for 2000-2010
PublikacjaThe reader will find in this study road safety modelling theory and time-series analysis techniques, applications to long period data of injury accidents and casualities, aggregared at national level
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Excited state properties of a series of molecular photocatalysts investigated by time dependent density functional theory.
PublikacjaTime dependent density functional theory calculations are applied on a series of molecular photocatalysts of the type [(tbbpy)2M1(tpphz)M2X2]2+ (M1 = Ru, Os; M2 = Pd, Pt; X = Cl, I) in order to provide information concerning the photochemistry occurring upon excitation of the compounds in the visible region. To this aim, the energies, oscillator strengths and orbital characters of the singlet and triplet excited states are investigated....
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Energy Demand of Short-Range Inland Ferry with Series Hybrid Propulsion Depending on the Navigation Strategy
PublikacjaInterest in hybrid propulsion systems that can be used on small vessels has increased significantly in recent years. They can replace inefficient and environmentally burdensome conventional systems based on diesel engines. Hybrid propulsion has many advantages such as high energy efficiency and virtually noiseless operation, and therefore it fits well with the current trends of “green shipping” and “zero emission”. The aim of the...
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Synthesis, Molecular Structure, Metabolic Stability and QSAR Studies of a Novel Series of Anticancer N-Acylbenzenesulfonamides
PublikacjaA series of novel N-acyl-4-chloro-5-methyl-2-(R1-methylthio)benzenesulfonamides 18–47 have been synthesized by the reaction of N-[4-chloro-5-methyl-2-(R1-methylthio) benzenesulfonyl]cyanamide potassium salts with appropriate carboxylic acids. Some of them showed anticancer activity toward the human cancer cell lines MCF-7, HCT-116 and HeLa, with the growth percentages (GPs) in the range from 7% to 46%. Quantitative structure-activity relationship...
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Reliable Multi-Stage Optimization of Antennas for Multiple Performance Figures in Highly-Dimensional Parameter Spaces
PublikacjaDesign of modern antenna structures needs to account for multiple performance figures and geometrical constraints. Fulfillment of these calls for the development of complex topologies described by a large number of parameters. EM-driven tuning of such designs is mandatory yet immensely challenging. In this letter, a new framework for multi-stage design optimization of multi-dimensional antennas with respect to several performance...
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Analysis of compressive forces in CFGFT cylindrical pillars and their coatings using laboratory tests and metric spaces
PublikacjaThe article discusses compressive forces tests in composite-concrete pillars with the use of laboratory active experiment including the factors and properties of materials which have a significant impact on the test results and their repeatability. A polymer composite based on glass fiber reinforced resin with different fiber beam angles (20, 55 and 85) was used as a buffer/coat of the pole. Due to the problems with direct comparison...
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Experimental test results of the 150kVA 18-pulse diode rectifier with series active power filter
PublikacjaThe paper presents the control system and selected results of experimental tests of the ac/dc power converter consisting of 18-pulse diode rectifier on the basis of coupled reactors and a serial active power filter. Three configurations of the 150kVA converter were tested experimentally and compared: 18-pulse diode rectifier with and without additional grid reactor and the rectifier integrated with the active power filter. The...
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COMPOSITION OF BIOACTIVE SECONDARY METABOLITES AND MUTAGENICITY OF SAMBUCUS NIGRA L. FRUIT AT DIFFERENT STAGES OF RIPENESS
PublikacjaThe relationship between the content of bioactive compounds and mutagenic activity of elderberry fruit at different stages of ripeness was investigated. Signifi cant differences in the antioxidant profi les (TLC, HPLC with post-column derivatization) and antioxidant activity (ABTS, DPPH, and FC tests) were observed for studied elderberry extracts. The more ripen the fruit at the time of harvest were, the higher the content of...
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Silica In Silico: A Molecular Dynamics Characterization of the Early Stages of Protein Embedding for Atom Probe Tomography
PublikacjaA novel procedure for the application of atom probe tomography (APT) to the structural analysis of biological systems, has been recently proposed, whereby the specimen is embedded by a silica matrix and ablated by a pulsed laser source. Such a technique, requires that the silica primer be properly inert and bio-compatible, keeping the native structural features of the system at hand, while condensing into an amorphous, glass-like...
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COVID-19-Associated Mucormycosis (CAM): Case-Series and Global Analysis of Mortality Risk Factors
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Tropospheric parameters derived from the selected IGS stations in the global tropics for the years 2001-2018
Dane BadawczeThis dataset contains daily GNSS-derived zenith tropospheric delay (ZTD), a posteriori corrected zenith wet delay (ZWD), and precipitable water vapour (PWV) time series. These troposphere-related data were estimated for the period between January 2001 and December 2018, for the 43 International GNSS Service (IGS) stations, located in the global tropics....
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Artists - researchers of postindustrial city area. SEAS In Gdańsk / Artyści-badacze przestrzeni poprzemysłowego miasta, SEAS w Gdańsku
PublikacjaArtykuł przedstawia gdańską odsłonę interdyscyplinarnego projektu SEAS, w ramach którego artyści na różne sposoby odkrywali urbanistyczny potencjał poprzemysłowych terenów w miastach portowych nad Bałtykiem i Adriatykiem.
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Experimental research on effectiveness of the magnetic fluid seals for rotary shafts working in water
PublikacjaUszczelnianie wałów obrotowych, łożysk i innych zespołów mechanicznych, za pomocą cieczy magnetycznej, tworzącej przegrodę uszczelniającą utrzymywaną siłami pola magnetycznego jest techniką uszczelniania, stosowaną z powodzeniem w urządzeniach pracujących w środowisku gazowym przy ciśnieniu do około 1,0 MPa. Uszczelnienia te umożliwiają również skuteczne rozwiązywanie problemu szczelności przepustów stałych i ruchowych w urządzeniach...
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Influence of the steam within seals and glands of the turbine on its rotor motion stability.
PublikacjaPrzedstawiono metodę obliczania charakterystyk dynamicznych wpływu parowych uszczelnień turbin na ich dynamikę i stateczność ruchu wirników. Zarysowano model ''masowy'' uszczelnienia. Podano przykłady zastosowań.
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Influence of the Shear Cap Size and Stiffness on the Distribution of Shear Forces in Flat Slabs
PublikacjaThe scope of this paper is to investigate analytically and numerically the influence of shear cap size and stiffness on the distribution of shear forces in flat slabs in a slab–column-connections-reinforced concrete structure. The effect of support (shear cap) stiffness on the calculation of the length of the shear control perimeter according to the available methods is presented. Based on the analysis, the authors indicate in...
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NEW DESIGNS OF CENTRIFUGAL MAGNETIC FLUID SEALS FOR ROTATING SHAFTS IN MARINE TECHNOLOGY
PublikacjaThe centrifugal magnetic fluid seals have important advantage over the conventional centrifugal seals. They maintain very good sealing capacity at static, medium and high speeds of shaft rotation, with the increased seal lifetime, and minimum torque and static friction. These seals are particularly useful in cases when the angular shaft velocity varies and sometimes decreases to nearly or exactly zero, such as in flywheel applications,...
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Stanisław Maciej Kot prof. dr hab.
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Effect of nanosilver (nAg) on disinfection, growth, and chemical composition of young barley leaves under in vitro conditions
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The electronic excited states of dichloromethane in the 5.8-10.8 eV energy range investigated by experimental and theoretical methods
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Impurity trapped exciton states related to rare earth ions in crystals under high hydrostatic pressure
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Molecular Characterisation of Uterine Endometrial Proteins during Early Stages of Pregnancy in Pigs by MALDI TOF/TOF
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Remote learning among students with and without reading difficulties during the initial stages of the COVID-19 pandemic
PublikacjaThis article presents the results of a survey on yet under-researched aspects of remote learning and learning difficulties in higher education during the initial stage (March – June 2020) of the COVID-19 pandemic. A total of 2182 students from University of Warsaw in Poland completed a two-part questionnaire regarding academic achievements in the academic year 2019/2020, living conditions and stress related to learning and pandemic,...
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Stress coping strategies and their clinical correlates in patients with psychosis at various stages of illness: A case‐control study
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Supine blood pressure normalised by daytime series values is independently associated with ischaemic wake-up stroke
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Sizes and Shapes of Sea Ice Floes Broken by Waves–A Case Study From the East Antarctic Coast
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Facile and cost-effective technique to control europium oxidation states in glassy fluorophosphate matrices with tunable photoluminescence
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Repeated Intra-Articular Administration of Platelet-Rich Plasma (PRP) in Temporomandibular Disorders: A Clinical Case Series
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Electron Binding Capabilities of Some Silylenes Having Small Singlet−Triplet Splittings or Triplet Ground States
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A la recherche d’une coherence perdue – Possible Arguments for the Non-application of EU Law in Member States
PublikacjaThe European Union (EU) is an international organization which has a broad scope of competences that have been transferred to it by its Member States in the founding Treaties. The object of the article is to identify arguments raised, or that potentially might be raised, by national Constitutional Courts (and in the future possibly by other actors as well) to exclude in certain instances the application of EU law or EU jurisprudence...
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Acoustical Standards Used in Design of School Spaces = Standardy akustyczne używane w projektowaniu przestrzeni szkoły
PublikacjaArtykuł prezentuje wytyczne projektowania akustyki wnętrz w pomieszczeniach szkolnych zawarte w europejskich i amerykańskich standardach technicznych. Opisane są także aktualne polskie przepisy odnoszące się do akustyki wnętrza. We wnioskach zaprezentowano wytyczne dla poprawy komfortu akustycznego w szkołach. // Design guidelines for interior acoustics in learning spaces included in European and American technical standards and...
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Electronic States of Tris(bipyridine) Ruthenium(II) Complexes in Neat Solid Films Investigated by Electroabsorption Spectroscopy
PublikacjaWe present the electric field-induced absorption (electroabsorption, EA) spectra of the solid neat films of tris(bipyridine) Ru(II) complexes, which were recently functionalized in our group as photosensitizers in dye-sensitized solar cells, and we compare them with the results obtained for an archetypal [Ru(bpy)3]2+ ion (RBY). We argue that it is difficult to establish a unique set of molecular parameter values by discrete parametrization...
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Examination of advanced isotropic constitutive laws under complex stress states in plain and reinforced concrete specimens
PublikacjaThe performance of advanced isotropic constitutive laws under complex stress states in plain and reinforced concrete specimens is investigated. Three different formulations are chosen: original Mazars model, Mazars mi model and model proposed by Pereira and coworkers. The degradation of the material in all formulations is described via a single variable, but a strain/stress state is taken into account via quite sophisticated relationships....
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Can unequal distributions of wealth influence vote choice? A comparative study of Germany, Sweden and the United States.
PublikacjaIt is widely accepted that income influences voting behavior. Does wealth? Is the effect similar across countries? Studies of wealth and voting behavior have not existed until recently, in part because of the absence of data on wealth holdings. The findings in this chapter indicate that wealth is related to voting behavior in some countries but not in others. The chapter models the effects of wealth on one form of voting behavior,...
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The electronic excited states of dichloromethane in the 5.8-10.8 eV energy range investigated by experimental and theoretical methods
PublikacjaWe present a comprehensive experimental high-resolution vacuum ultraviolet (VUV) photoabsorption spectrum of dichloromethane, CH 2 Cl 2 , with absolute cross sections determined for the full 5.8–10.8 eV energy-range. The calculations on the vertical excitation energies and oscillator strengths were performed using the equation-of-motion coupled cluster method, restricted to the single and double excitations level (EOM-CCSD), and...