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Search results for: Organic–Inorganic Hybrid
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Separation of Volatile Oxygen-containing Organic Compounds by Gas Chromatography - selectivity comparison of different polarity stationary phases
PublicationThis paper present a results of the separation of 36 reference compounds belonging to the group of Volatile Oxygen-Containing Organic Compounds (OVOCs) using capillary gas chromatography with flame ionization detector (GC-FID) and three stationary phases of different polarity. A selectivity has been studied regarding to OVOCs and n -alkanes. The most useful for the separation of the group OVOCs is a polar ionic liquid stationary...
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Application of dispersive liquid-liquid microextraction and gas chromatography with mass spectrometry for the determination of oxygenated volatile organic compounds in effluents from the production of petroleum bitumen
PublicationWepresent a new procedure for the determination of oxygenated volatile organic compounds in samples of postoxidative effluents from the production of petroleum bitumens using dispersive liquid–liquid microextraction and gas chromatography with mass spectrometry. The eight extraction parameters were optimized for 43 oxygenated volatile organic compounds. The detection limits obtained ranged from 0.07 to 0.82 g/mL for most of the...
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The role of aluminium in metal–organic frameworks derived carbon doped with cobalt in electrocatalytic oxygen evolution reaction
PublicationWater electrolysis is one of the most crucial processes in the development of new energy sources, where ultra-clean fuel is produced - hydrogen. Oxygen evolution reaction (OER) is the sluggish process of overall water splitting. Therefore, this study presents the design, characterization and electrochemical study of cobalt-based electrocatalysts embedded into porous carbons derived from an Al-metal–organic...
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IDENTIFICATION OF ODOR OF VOLATILE ORGANIC COMPOUNDS USING CLASSICAL SENSORY ANALYSIS AND ELECTRONIC NOSE TECHNIQUE
PublicationThe paper compares two methods of analysis of odour of volatile organic compounds: classical sensory analysis and electronic nose technique. Eight volunteers participated in the classical sensory analysis investigations, which lasted two weeks. An instrumental odour analysis involved a prototype of 6-sensor electronic nose designed by the authors. The research performed with this device provided higher reproducibility and reliability...
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On the tendency of temperature and electric field dependences of interface recombination in P3HT:PCBM organic bulk heterojunction solar cells
PublicationWe demonstrate theoretical explanation of the temperature and electric field dependences of recombination coefficients in an organic P3HT:PCBM bulk heterojunction solar cell. Based onthe model of interface recombination, two analytical formulas describing the relative ratio of the interface (γI ) to the Langevin (γL) recombination coefficients have been derived. Our analysis indicates that the sign of parameters φT and φF determines...
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The estimation of total volatile organic compounds emissions generated from peroxide cured natural rubber/polycaprolactone blends
PublicationNatural rubber (NR)/polycaprolactone (PCL) blends at the ratio of 90/10% wt. (NR/PCL90/10) and 70/30% wt. (NR/PCL70/30), with a constant amount of dicumyl peroxide, were prepared by compounding in an internal mixer. Obtained NR/PCL bio-based blends were cured at three different temperatures (150 °C, 160 °C and 170 °C). The total content of volatile organic compounds (TVOC) as a function of the NR/PCL blends ratio, and their curing...
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Persistent organic pollutants (POPs) as an indicator of surface water quality in the vicinity of the Polish Polar Station, Horsund
PublicationSurface waters were collected in the vicinity of the Polish Polar Station in Hornsund (Svalbard) to determine their concentration of various persistent organic pollutants (POPs), such as polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs). In addition, parameters such as pH, SEC and TOC were measured. In total, 15 samples of lake water from and 15 samples of stream water were analysed. The sampling took...
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Metal-Organic Frameworks-Based Sensors for the Detection of Toxins in Food: A Critical Mini-Review on the Applications and Mechanisms
PublicationUsing scientific technologies to detect toxins in food is significant to prevent food safety problems and protect people’s health. Recently, the rise of sensors has made rapid, efficient, and safe detection of food toxins possible. One of the key factors impacting the sensor’s performance is the nanomaterials employed. Metal-organic frameworks (MOFs), with high specific surface area, tunable composition, porous structure, and flexible...
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Laser granulometer as an useful tool for selection of appropriate membranes used in the MIEX®DOC-UF/MF hybrid process
PublicationIn the study, particle size distribution of the MIEX® resin was presented. Such analyses enable to determinate whether presence of fine resin fraction may be the reason for unfavorable membrane blocking during water purification by the hybrid MIEX®DOC-microfiltration/ultrafiltration systems. Granulometric analysis of resin grains using the laser diffraction particle size analyzer (laser granulometer) was carried out as well as...
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Origin of bitumen fractions in the Jurassic-early Cretaceous Vaca Muerta Formation in Argentina: insights from organic petrography and geochemical techniques
PublicationThis paper investigates chemical functional groups of the two extracted bitumen fractions in shales of the Jurassic to early Cretaceous Vaca Muerta Formation of the Neuquén Basin in Argentina, South America. The results indicate that Bitumen I is strongly aliphatic and appears to be genetically related to fluorescent amorphous organic matter. In contrast, Bitumen II consists of highly condensed, aromatic hydrocarbons, and has some...
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Ionic Liquid Assisted Dissolution of Dissolved Organic Matter and PAHs from Soil Below the Critical Micelle Concentration
PublicationIncreased use and production of ionic liquids (ILs) may result in emissions into the environment. Particularly vulnerable are industrial areas and landfills where ILs are utilized and ultimately disposed of. This study investigates how IL contamination can affect soil properties and the sorption of pre-existing contaminants. The commonly used IL 1-methyl-3-octyl imidazolium chloride ([OMIM][Cl]) was added at various quantities...
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Interrelationship between total volatile organic compounds emissions, structure and properties of natural rubber/polycaprolactone bio-blends cross-linked with peroxides
PublicationNatural rubber/polycaprolactone (NR/PCL) bio-based blends with different organic peroxides were prepared using an internal batch mixer and subsequently cross-linked at 170°C. Two types of commonly used organic peroxides, dicumyl peroxide and di(tert-butylperoxyisopropyl)benzene peroxide, were applied as free-radical initiator. Cross-linking efficiency of NR/PCL blends were investigated using oscillating disc rheometer measurements,...
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Optimisation of the Energy Consumption of a Small Passenger Ferry with Hybrid Propulsion
PublicationThe main goal in the design phase is to create a safe ship with a very efficient (and preferably zero-emission) propulsion system. To obtain such ships, new concepts are being developed for both propulsion systems and individual components. The choice of a propulsion system is not straightforward. To optimise the selection of the propulsion system, it is valuable to optimise the energy demand of this unit, which can be done by...
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Voltage dips reducyion with a hybrid contactless short circuit limiter.
PublicationW artykule przedstawiono działanie bezstykowego ogranicznika prądów zwarciowych w oparciu o symulację komputerową. Szczególną uwagę zwrócono na możliwość poprawy jakości dostarczanej energii, poprzez ograniczenia trwania zapadów napięcia w sieci elektroenergetycznej, dzięki zastosowaniu wyłącznika hybrydowego. Modelowanie matematyczne wykonano w programie MATLAB i PSPICE.
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Raman system for on-line monitoring and optimisation of hybrid polymer gelation
PublicationW artykule przedstawiono system do monitorowania ramanowskiego reakcji żelowania w procesie zol-żel syntezy organiczno-nieorganicznych polimerów hybrydowych. System pomiarowy umożliwił wykonywanie pomiarów zdalnych, bez wkonieczności wprowadzania jego elementów do wnętrza komory reakcyjnej. Konstrukcja systemu zapewniła szeroki zakres pomiarowy od 200 do 3500 cm-1, przy odpowiednio wysokiej czułości i wyeliminowniu wpływu fluorescencji....
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Raman system for monitoring of dye doping to hybrid polymer network
PublicationZrealizowano i przedstawiono system ramanowski do zdalnego monitorowania procesu zol-żel, dedykowany do monitorowania procedury wprowadznia cząstek barwnika do sieci polimeru hybrydowego. System umożliwia wykonywanie pomiarów zdalnych, bez zakłócania i przerywania przebiegu procesu technologicznego. Zademonstrowano i skomentowano wyniki pomiarów dla przykładowego procesu.
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Effect of hybrid contactless short-cicruit limiters on power quality
PublicationPrzedstawiono działanie bezstykowego ogranicznika prądów zwarciowych w oparciu o symulację komputerową. Szczególną uwagę zwrócono na problem jakości dostarczanej energii elektrycznej poprzez ograniczanie zapadów napięcia za pomocą bezstykowego ogranicznika prądów zwarciowych. W modelowaniu elementów systemu elektroenergetycznego i zapadów napięcia, będących skutkiem zwarć wykorzystano program MATLAB z biblioteką Power System Blockset....
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Hybrid inductance-thyristor short-circuit current limiting devices
PublicationDla wartości prądu w gałęzi w której zainstalowane jest urządzenie jest mniejsza od prądu w dławiku urządzenia, dławik jest zwarty gałęzią z tyrystorem. Impedancja bieguna urządzenia hybrydowego jest praktycznie równa zero. W chwili wzrostu prądu w gałęzi z urządzeniem ograniczającym ponad tę wartość, do obwodu głównego wtrącona zostaje impedancja kolejno dwóch dławików, ograniczając bezzwłocznie dynamikę i amplitudę prądu zwarciowego....
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Power flow in typical series-parallel hybrid filters topologies
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Domain Reduction in Hybrid Technique for Electromagnetic Wave Scattering Problems
PublicationThis paper proposes a combination of the field matching technique, finite element method and generalized impedance matrix, the main idea of which is to reduce the computational domain by surrounding a scatterer with the smallest convex shape and applying the field matching technique. This approach can be applied for arbitrary shaped scatterers and types of materials and allows for the reduction of the computational domain. In order...
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The Investigation of Thermal and Optical Properties of Semiconducting Nanostructural Hybrid Films
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Hybrid nanolayers of star polymers and silver nanoparticles with antibacterial activity
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Hybrid Algorithm to Protect Java’s Code from Reverse Engineering
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Hybrid-Excited Permanent Magnet-Assisted Synchronous Reluctance Machine
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Performance Evaluation of an Axial Flux Machine with a Hybrid Excitation Design
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Hybrid Excited Synchronous Machine with Wireless Supply Control System
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The First Report on Hybrid NOTES Adjustable Gastric Banding in Human
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Numerical Simulations of Laser and Hybrid S700MC T-Joint Welding
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A hybrid speech codec employing parametric and perceptual coding techniques
PublicationW referacie przedstawiono hybrydowy kodek mowy dla zastosowan w komunikacji VoIP wykorzystujący kodowanie parametryczne i percetualne. Sygnał mowy jest dzielony na składowe dźwięczne, które podlegają kodowania perceptualnemu, składowe bezdźwięczne, które kodowane są metodą parametryczną oraz transjenty, które nie są kodowane żadną stratną metodą. Dodatkowo przedstawiono architekturę kodeka, w której perceptualnie kodowana i przesyłana...
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Hybrid Integrated Components For Optical Fiber Communication And Instrumentation Systems
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A Decision Support System for the Planning of Hybrid Renewable Energy Technologies
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Selected issues related to the research on a hybrid three-wheeler for the disabled
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Distributed Operation of CHP and Hybrid PV Using Consensus Protocol
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THERMAL ANALYSIS AND DESIGN OF HYBRID MICROCHANNEL-MICROJET TEST PROBE
PublicationThe paper presents the numerical investigation of a microjet- microchannel cooling module. In which microjets of water are impinging into the microchannels and forming a liquid film on the impingement surface. Applied technology takes benefits from two very attractive heat removal techniques. When lminar jets are impinging on the surface have a very high kinetic energy at the stagnation point, also in microchannels boundary layer...
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Hybrid quantum-classical approach for atomistic simulation of metallic systems
PublicationThe learn-on-the-fly (LOTF) method [G. Csanyi et al., Phys. Rev. Lett. 93, 175503 (2004)] serves to seamlessly embed quantum-mechanical computations within a molecular-dynamics framework by continual local retuning of the potential's parameters so that it reproduces the quantum-mechanical forces. In its current formulation, it is suitable for systems where the interaction is short-ranged, such as covalently bonded semiconductors....
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Raman investigation of sol-gel-derived hybrid polymers for optoelectronics
PublicationPrzedstawiono wykorzystanie spektroskopii ramanowskiej do kompleksowej diagnostyki polimerów hybrydowych stosowanych w optoelektronice. Zbadano efektywność kolejnych etapów procesu technologicznego: od monomerów do etapu produktu finalnego - cienkich warstw.
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Hybrid system of safe ship steering in a collision situation at sea
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Removal of persistant organic pollutants from landfill leachates treated in three constructed wetland systems
PublicationThe objective of the study was assessment of occurrence and removal of two groups of persistent organic pollutants: polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) in landfill leachate (LL) treated in three constructed wetland systems (CWs) of different construction and flow regime. Two subsurface flow systems (SSF) were analyzed: one with horizontal flow and the second one consisting of two vertical...
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Thermodynamic properties of inorganic salt in nonaqeous solvents. IV. Apparent molar volumes and compressibilities of divalent transition-metal bromides and chlorides in acetonitrile
PublicationWykonano pomiary gęstości roztworów chlorków i bromków w acetonitrylu w temperaturze 288.15, 293.15, 298.15, 303.15, 308.15, 313.15 K oraz pomiar szybkości rozchodzenia się dźwięku w badanych roztworach w temperaturze 298.15 K. Uzyskane wartości pozwoliły wyznaczyć pozorne objętości molowe oraz pozorne adiabatyczne ściśliwości, których wartości oraz zmiany ze stężeniem tłumaczone są obecnością złożonych układów komplesów w roztworze.
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International Journal of Recycling of Organic Waste in Agriculture
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Advancing sustainable hybrid bitumen systems: A compatibilization solution by functionalized polyolefins for enhanced crumb rubber content in bitumen
PublicationPolymer waste pollution has a profound effect on the environment and, consequently, on the lifestyle of hu- mankind. The massive production and disposal of cross-linked polymers clearly exemplify the challenges of recycling. Increasing efforts are being undertaken to introduce recycled polymers, especially crumb rubber (CR), into asphalt formulations. Due to the rather poor processability and phase separation associated with CR- modified...
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Hybrid geothermal-fossil power cycle analysis in a Polish setting with a focus on off-design performance and CO2 emissions reductions
PublicationGrowing demand for electricity due to economic development contributes to increased greenhouse gas production, especially CO2. However, emissions can be limited by enhancing the efficiency of primary energy conversion, such as integrating geothermal energy into coal-fired power plants. Therefore, this paper proposes replacing conventional feed-water heaters with geothermal preheaters to create a hybridized system. This study was...
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Real-time monitoring of the emission of volatile organic compounds from polylactide 3D printing filaments
PublicationEstablishing the emission profile of volatile organic compounds generated during fused deposition modeling 3D printing using polymer filaments is important in terms of both understanding the processes taking place during thermal degradation of thermoplastics, and assessing the user's exposure to potentially harmful volatiles. However, obtaining detailed, real-time qualitative and quantitative results poses a challenge. In this...
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Lanthanide-organic-frameworks modified ZnIn2S4 for boosting hydrogen generation under UV–Vis and visible light
PublicationNovel Ln-MOF with microrods shape were successfully combined with ZnIn2S4 (ZIS) microsphere and used for photocatalytic hydrogen generation under UV–Vis and visible light. The Ln-MOFs/ZIS system comprises lanthanide-carboxylate coordination networks (Tm and Gd as metal ions, and 1,3,5-benzenetricarboxylic acid (BTC) as the organic linker) deposited on ZnIn2S4 microspheres. Effect of the amount of ((Tm,Gd)-BTC) (1, 5, 10 wt%) on...
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Organic light-emitting diodes. Principles, characteristics and processes.
PublicationJest to pierwsze monograficzne opracowanie zjawiska elektroluminescencji w organicznych ciałach stałych. W sześciu rozdziałach książki opisano między innymi wytwarzanie stanów wzbudzonych w wyniku rekombinacji ładunku, sposoby zaniku stanów wzbudzonych i ich rozkład przestrzenny, elektryczne i optyczne własności organicznych diod elektroluminescencyjnych oraz procesy warunkujące wydajne świecenie takich diod.
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Electrochemical approach to evaluate the interlayer adhesion of organic coatings
PublicationZastosowano elektrochemiczną spektroskopię impedancyjną do wyznaczania międzywarstwowej adhezji w powłokach organicznych. Zbadano różne zestawy powłok do ochrony samochodów. Zastosowano dwie elektrody wykonane z prądoprzewodzącego tuszu umieszczone pomiędzy warstwami powłokowymi. Stwierdzono, że utrata adhezji międzywarstwowej następuje podobnie jak zmiany energii aktywacji przewodnictwa jonowego w obszarze międzywarstwowym. Uzyskane...
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Pathways and analytical tools in degradation studies of organic pollutants
PublicationWszystkie substancje chemiczne podlegają różnym procesom w wyniku wielu reakcji chemicznych, biochemicznych czy też fotochemicznych. W zależności od elementu środowiska w jakim znajduje się analit (np.: gleba, sedymenty, wody powierzchniowe i podziemne), może on ulegać powolnym przemianom w wyniku różnych procesów. W pracy przedstawiono niektóre drogi degradacji wybranych substancji w różnych warunkach. Omówiono problem identyfikacji...
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Space-charge-limited current fluctuations in organic semiconductors
PublicationBadania szumów elektrycznych w zakresie niskich częstotliwości, w regionie prĄdów ohmowych, zapełniania siĘ pułapek nośników ładunku i prądów ograniczonych ładunkiem przestrzennym w polikrystalicznych poliacenach, takich jak tetracen i pentacen.
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Currents and photocurrents in organic materials determined by the interface phenomena
PublicationW pracy analizowany jest wpływ złącza materiał-elektroda na prądy i fotoprądy. W szczególności dyskutowane są mechanizmy iniekcji, fotogeneracji oraz transportu nośników ładunku. Rozważania teoretyczne uzupełniają wyniki badań doświadczalnych zarówno własne jak i literaturowe.
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Accelerated ageing of organic coating systems by thermal treatment
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