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Search results for: SOLID STATE POST-CONDENSATION
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Crystallographic study of self-organization in the solid state including quasi-aromatic pseudo-ring stacking interactions in 1-benzoyl-3-(3,4-dimethoxyphenyl)thiourea and 1-benzoyl-3-(2-hydroxypropyl)thiourea
Publication1-Benzoylthioureas contain both carbonyl and thiocarbonyl functional groups and are of interest for their biological activity, metal coordination ability and involvement in hydrogen-bond formation. Two novel 1-benzoylthiourea derivatives, namely 1-benzoyl-3-(3,4-dimethoxyphenyl)thiourea, C₁₆H₁₆N₂O₃S, (I), and 1-benzoyl-3-(2-hydroxypropyl)thiourea, C₁₁H₁₄N₂O₂S, (II), have been synthesized and characterized. Compound (I) crystallizes...
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Mixed-ligand complexes of zinc(II), cobalt(II) and cadmium(II) with sulfur, nitrogen and oxygen ligands. Analysis of the solid state structure and solution behavior. Implications for metal ion substitution in alcohol dehydrogenase
PublicationScharakteryzowano strukturę heteroleptycznych kompleksów cynku(II), kobaltu(II) i kadmu(II) z 2-(2'-hydroksyetylopirydyną), tri-tert-butoksysilanotiolem i metanolem. Przy pomocy widm UV-Vis i NMR stwierdzono szybką wymianę N-liganda w roztworach tych kompleksów. Wyznaczono przesunięcia 15N NMR 2-(2'-hydroksyetylopirydyny) w kompleksach cynku(II) i kadmu(II). Na podstawie widm w podczerwieni i obliczeń DFT oszacowano względną moc...
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Mixed-ligand complexes of zinc(II), cobalt(II) and cadmium(II) with sulfur, nitrogen and oxygen ligands. Analysis of the solid state structure and solution behavior. Implications for metal ion substitution in alcohol dehydrogenase
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CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE
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Ceramic composites for single-layer fuel cells
PublicationComposite materials consisting of acceptor doped lanthanum orthoniobate electrolyte phase (La0.98Ca0.02NbO4) and Li2O:NiO:ZnO semiconducting phase were synthesized. The precursor powder of La0.98Ca0.02NbO4 was prepared in nanocrystalline (mechanosynthesis) and microcrystalline (solid-state synthesis) form. The composite can be applied in a single-layer fuel cell, because of the presence of two phases acting as an anode and a cathode...
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Properties of LiMnBO3 glasses and nanostructured glass-ceramics
PublicationPolycrystalline LiMnBO3 is a promising cathode material for Li-ion batteries. In this work, we investigated the thermal, structural and electrical properties of glassy and nanocrystallized materials having the same chemical composition. The original glass was obtained via a standard melt-quenching method. SEM and 7Li solid-state NMR indicate that it contains a mixture of two distinct glassy phases. The results suggest that the...
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Ryszard Jan Barczyński dr hab. inż.
PeopleRyszard Jan Barczyński (b. 24 June 1957 in Gdańsk), Polish scientist, engineer, a specialist in solid state physics and electronic measurement techniques. In 1976, he obtained a high school diploma in the IV High School Tadeusz Kosciuszko in Torun. Higher education he graduated in 1981 at the Institute of Physics, Technical University of Gdansk in specialty of solid state physics, obtaining master's degree in engineering. Since...
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Stabilization of the pyrochlore phase of Mn2Sb2O7 by double substitution
PublicationPolycrystalline samples of (Ce4+Mn2+3)(Ga3+Sb5+3)O14 were synthesized by a high-temperature solid-state reaction. In contrast with the parent Mn2Sb2O7 compound that adopts a rhombohedral or monoclinic structure at T > 600 °C, the pyrochlore structure of CeMn3GaSb3O14 is retained up to at least T = 1070°C. High-resolution synchrotron x-ray diffraction measurements show no sign of a superstructure or distortion from cubic symmetry...
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Wojciech Sadowski prof. dr hab. inż.
PeopleWojciech Sadowski (born 2 February 1954 in Ostaszewo, Poland), scientist, engineer, professor at Gdansk University of Technology, specialist in solid state body physics, nanotechnology, optoelectronics. In 1973 he completed his high school education at High School Nicolaus Copernicus in Chelmno. In 1979 he graduate from Leningrad Electrotechnical Institute in Russia (former Soviet Union) with specialism in dielectrics and semiconductors....
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Effect of isovalent substitution on microstructure and phase transition of LaNb1−xMxO4 (M=Sb, V or Ta; x=0.05–0.3)
PublicationLaNb1−xMxO4 oxides with pentavalent elements of different ionic sizes (M=Sb, Ta and V, x=0.05–0.3) were synthesized by the solid state reaction method. Special interest was devoted to the antimony substituted lanthanum niobate which is a new material in this group. Rietveld analysis of the X-ray diffraction patterns was used to determine the influence of the material composition on unit cell parameters. On the basis of dilatometric...
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Novel luminescent calixarene-based lanthanide materials: From synthesis and characterization to the selective detection of Fe3+
PublicationCalix[n]arene-based coordination networks are an emerging class of materials with intriguing properties resulted from the presence of the cavity-like structure of the macrocycle and metallic nodes. In this work, four novel luminescent materials based on calix[4]arene-carboxylate and lanthanides (Eu3þ and Tb3þ) were prepared by two synthetic approaches, solvothermal (CDA-Eu-ST) and slow diffusion (CDA-Eu-RT, CDA-Tb-RT, CTA-Tb-complex)...
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Structural and spectroscopic investigation of new luminescent hybrid materials based on calix[4]arene-tetracarboxylate and Ln 3+ ions (Ln = Gd, Tb or Eu)
PublicationLanthanide-calixarene hybrid materials are of particular interest due to the combination of the interesting properties of the ligand cavity-like structure and the luminescent features of lanthanides. The aim of this study was to synthesize and investigate the photophysical properties of Eu3+, Tb3+ and Gd3+ hybrids based on calix[4]arene-tetracarboxylate. The preparation of two structurally different...
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Lead(II) coordination polymers with imidazole-4- and pyrazole-3-carboxylate isomeric linkers: Structural diversity and luminescence properties
PublicationUsing 1H-imidazole-4-carboxylic acid (4imCOOH) and 1H-pyrazole-3-carboxylic acid (3pyrCOOH) coordination polymers [Pb(4imCOO)2(H2O)]n (1) and [Pb2(3pyrCOO)4]n (2) were constructed. Obtained polymers were characterized via FT-IR, X-ray, PL and TG methods. The coordination polyhedron around Pb(II) in 1 is described as distorted pentagonal pyramid with hemidirected coordination sphere (based on DFT calculations). Compound 2 consists...
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The computational methods in the development of a novel multianalyte calibration technique for potentiometric integrated sensors systems
PublicationIn recent years, integration and miniaturization of ion-selective electrodes (ISEs) have brought many benefits resulting in the possibility of simultaneous determination of the ions concentration in small volume samples. One of the key problems related to the preparation of potentiometric integrated sensors systems (PISSs) is a calibration procedure due to the necessity to calibrate each particular sensor separately. The main aim...
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Piotr Konieczka prof. dr hab. inż.
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Physica Status Solidi (C) Current Topics in Solid State Physics
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COMPARISON OF TWO MODELS OF CONDENSATION
PublicationIn the low-pressure part of steam turbine, the state path usually crosses the saturation line in penultimate stages. At least last two stages of this part of turbines operate in two –phase region. The liquid phase in this region in mainly created in the process of homogeneous and heterogeneous condensation. Several observations confirm however, that condensation often occurs earlier than it is predicted by theory i.e. before the...
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Maciej Łuszczek dr hab. inż.
PeopleMaciej Łuszczek born in 1967 in Gdynia. He received the M.Sc. degree in Applied Physics in 1991, the Ph.D. degree in 1999, and the D.Sc. (‘habilitation’) degree in 2015, all from the Gdańsk University of Technology. Since 1991 he has been with the above university, initially at the Faculty of Applied Physics and Mathematics, Department of Solid State Physics, and currently (since 2015) at the Faculty of Electrical and Control Engineering,...
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STRUCTURE AND MAGNETIC PROPERTIES OF Bi5Ti3FeO15 CERAMICS PREPARED BY SINTERING, MECHANICAL ACTIVATION AND EDAMM PROCESS. A COMPARATIVE STUDY
PublicationThree different methods were used to obtain Bi5Ti3FeO15 ceramics, i.e. solid-state sintering, mechanical activation (MA) with subsequent thermal treatment, and electrical discharge assisted mechanical milling (EDAMM). The structure and magnetic properties of produced Bi5Ti3FeO15 samples were characterized using X-ray diffraction and Mössbauer spectroscopy. The purest Bi5Ti3FeO15 ceramics was obtained by standard solid-state sintering...
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Powder x-ray diffraction pattern of polycrystalline synthetic leningradite, PbCu3V2O8Cl2
Open Research DataPolycrystalline sample of Cu2+ (S=1/2) antiferromagnetic PbCu3V2O8Cl2 (synthetic analogue of the mineral leningradite) was prepared by solid state reaction of PbCl2, CuO, and V2O5.
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X-Ray photoemission spectroscopy measurements of the Nb-V-Sr-O ceramics
Open Research DataNiobium doped strontium vanadate based perovskite SrV1-xNbxO3-δ materials were prepared via conventional solid state reaction (SSR) method. For comparison, different samples with a various amount of niobium dopant in the structure were synthesized; x = 0; 0,2; 0,5; 0,8 and 1. Samples were sintered by two-steps: first under a pure hydrogen (purity >99.999%)...
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Giant Nernst effect in the incommensurate charge density wave state of P4W12O44
PublicationWe report the study of Nernst effect in quasi-low-dimensional tungsten bronze P4W12O44 showing a sequence of Peierls instabilities. We demonstrate that both condensation of the electronic carriers in the charge density wave state and the existence of high-mobility electrons and holes originating from the small pockets remaining in the incompletely nested Fermi surface give rise to a Nernst effect of a magnitude similar to that...
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Phosphorus concentration and availability in raw organic waste and post fermentation products
PublicationThe aim of the study was to determine the mobility of phosphorus forms in raw organic waste and from the solid and liquid fractions of digestate. To achieve the purpose of this study, the components (including livestock manure, agricultural waste, food waste, sewage sludge) and their post fermentation products were considered. Subsequently, the effect of the fermentation process on the mobility of phosphorus forms in post-fermentation fractions...
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iMAGS IoT Minaturized Ammonia Gas Sensor System
ProjectsProject realized in Department of Microwave and Antenna Engineering according to WPN/4/66/i-MAGS/2022 agreement from 2022-12-08
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Molecular geometry and optical activity of helically chiral N-nitrosamines derived from 1,2,3,4-tetrahydro- and 1,2,3,4,7,8,9,10-octahydro-1,10-phenanthroline
PublicationX-ray crystallographic analysis of the title N-nitrosamines revealed that they assume helical conformations in the solid state. Nitrosamines 1b and 2b were resolved by inclusion crystallization with optically active diols (TADDOLs). The absolute configuration of the guest molecules in the complexes 1b·3b and 2b·3b was assigned as M. The optical activity of the resolved compounds is manifested by their solid state CD spectra, which...
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Cation sensing by diphenyl-azobenzocrowns
PublicationMetal cations complexation and proton binding by 13- and 16-membered diphenyl-azobenzocrowns and diphenyl-hydroxyazobenzocrowns were studied in acetonitrile using spectroscopic methods: UV–vis spectroscopy, spectrofluorimetry, and 1H NMR spectroscopy. Phenyl moieties in benzene rings were found to affect binding strength alkali and alkaline earth metal cations and hydrogen ion, and affect tautomeric equilibrium of hydroxyazobenzocrowns....
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Mössbauer Spectroscopy and Magnetoelectric Effect Studies of Multiferroic Ceramics Based on BiFeO<sub>3</sub>
PublicationIn this work the results of investigations for (BiFeO3)x(BaTiO3)1-x and Bi1-xNdxFeO3 solid solutions are described. Samples were prepared by the conventional solid-state sintering method. X-ray diffraction, 57Fe Mössbauer spectroscopy, and magnetoelectric effect measurements were applied as complementary methods to determine the structure and magnetic properties of materials. For (BiFeO3)x(BaTiO3)1-x solid solutions Mössbauer...
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Joanna Rymaszewska prof. dr hab. n. med.
PeopleCV Joanna Rymaszewska Wroclaw University of Science and Technology, Wroclaw, Poland +48 601 98 26 24, joanna.rymaszewska@pwr.edu.pl orcid.org/0000-0001-8985-3592 2023 → Professor of Wroclaw University of Science and Technology (WUST), Poland 2011 → 2023 Professor of Wroclaw Medical University (WMU), PL 2016 → 2022 Head of the Department of Psychiatry, Wroclaw Medical University 2016 → 2022 Head of the Clinic of Psychiatry,...
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Reactions of Lithiated Diphosphanes R2P−P(SiMe3)Li (R = tBu and iPr) with [MeNacnacTiCl2·THF] and [MeNacnacTiCl3]. Formation and Structure of TitaniumIII and TitaniumIV β‑Diketiminato Complexes Bearing the Side-on Phosphanylphosphido and Phosphanylphosphinidene Functionalities
Publicationβ-Diketiminate complexes of TiIII-containing phosphanylphosphido ligands [MeNacnacTi(Cl){η2-P(SiMe3)- PR2}] (MeNacnac− = [Ar]NC(Me)CHC(Me)N[Ar]; Ar = 2,6- iPr2C6H3) were prepared by reactions of [MeNacnacTiCl2· THF] with lithium derivatives of diphosphanes R2P−P(SiMe3) Li (R = tBu, iPr) in toluene solutions. Surprisingly, reactions of [MeNacnacTiCl2·THF] with R2P−P(SiMe3)Li in THF solutions led to TiIV complexes containing phosphanylphosphinidene ligands...
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Electronic conductivity in the SiO2–PbO–Fe2O3 glass containing magnetic nanostructures
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Electrical properties and structure of lead-borate glass containing iron ions
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Influence of phonon-phonon coupling on superconducting state in honeycomb-type crystal lattice
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Multigap superconducting state in molecular metallic hydrogen
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Superconducting state in the atomic metallic hydrogen just above the pressure of the molecular dissociation
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The superconducting state in the B2H6 compound at 360GPa
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Description of the thermodynamic properties of BiH 5 and BiH 6 superconductors beyond the mean-field approximation
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Identification of the Inertia of Masses Flowing Water through the Pipes in Water Power Plants
PublicationW artykule przedstawiono sposób identyfikacji stałej czasowej reprezentującej bezwładność mas przepływającej wody w systemie rurociągów, w elektrowni wodnej. Przedstawiono strukturę modelu układu regulacji prędkości kątowej wykorzystywanego w procesie identyfikacji oraz przeprowadzono badania skuteczności działania metody w środowisku Matlab-Simulink. Opisano najistotniejsze wnioski wynikające z przeprowadzonych badań symulacyjnych.
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Selected problems of navigation of educational mobile robot
PublicationW artykule przedstawiono ideę sterowania układem autonomicznego robota mobilnego skonstruowanego do celów edukacyjnych. Opisano strukturę mechaniczną układu, układy sensorów oraz zakres możliwości wynikających z działania oprogramowania robota.
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The Behaviour Based Area Coverage of Unknown Environment by Autonomous Mobile Robot Using Modified ''The Way of the Ox'' Algorithm
PublicationPrzedstawiono propozycję rozwiązania zagadnienie całkowitego pokrycia terenu w układzie autonomicznego robota mobilnego. W tym celu zmodyfikowano algorytm "siewcy" oraz opracowano odpowiedni model układu, w środowisku Matlab-Simulink. Wykonano serię badań symulacyjnych, których najistotniejsze wyniki opisano w artykule.
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Localization of Mobile Robot Using Radio Waves
PublicationOpisano systemy lokalizacji robotów mobilnych wykorzystujące metody triangulacji i trilateracji, w przestrzeniach dwuwymiarowych. Zaproponowano metodę pomiaru odległości drogą radiową oraz przedstawiono uzyskane wyniki badań.
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Comparison the Accuracy of the Extrapolation Methods of the Time Phase Coincidence in Synchronization of Power Generating Units
PublicationW artykule opisano metody ekstrapolacji chwili zgodności fazowej napięć łączonych obiektów elektroenergetycznych. Przeprowadzono analizę porównawczą wybranych metod ekstrapolacji w równych warunkach pracy oraz przedstawiono najistotniejsze wyniki badań.
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Assessment of FSW Welds Made of Aluminum Alloy AW7075-T651.
PublicationThis paper summarizes the results of experimental studies in which the aluminum alloy AW7075-T651 was friction stir welded (FSW) using various combinations of process parameters (rotational - R and travel speed - T). Mechanical properties of the test welds were assessed by using static tensile test and Vickers hardness measurement. The temperature of the welded plates was monitored during welding by means of thermocouples placed...
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The Characteristic of Surface Layers on Austenitic Stainless SteelAfter Glow-discharge Nitriding Process.
PublicationThis paper presents investigation of surface layers. The diffusion layers were produced by using different parameters of reactive atmosphere (N2:H2). The research of the surface layers was performed using scanning electron microscope (SEM). The results of energy dispersive X-ray (EDX) analysis and X-ray diffraction (XRD) analysis are presented. Research reveals the influence of chemical constitution of reactive atmosphere on the...
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The Effect Fabrication Method of Cobalt Base Clad Layer On Air Oxidation
PublicationNapawane warstwy ze stopu kobaltu zostały wykonane za pomocą napawania plazmowego (PTA) oraz laserowego. Zostały one poddane utlenia niu w temperarurze 1100 stopni celsiusza prze 200 godzin. Przeprowadzono badania mikrostruktury i składu chemicznego warstwy tlenkowej oraz głębszych warstw napoiny. Nie stwierdzono wpływu metody wytwarzania na skutki procesu utleniania.
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Simulation and Experiments of High Speed Machining Vibration Monitoring with Variable Spindle Velocity
PublicationArtykuł poświęcony jest nadzorowaniu drgań wirujących narzędzi podczas obróbki szybkościowej na nowoczesnych centrach frezarskich. Przeprowadzono analizę dynamiki procesu skrawania smukłym frezem kulistym. W celu zredukowania drgań zastosowano, z powodzeniem, zmienną prędkość obrotową narzędzia. Badania symulacyjne dotyczące efektywności proponowanej metody zostały potwierdzone wynikami badań eksperymentlanych na frezarce Alcera...
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Cobalt Base Clad Layer Resistance On The Corrosion Under Low Sulfur Preassure
PublicationNapawane laserowo warstwy ze stopu kobaltu, zostały poddane siarkowaniu przy niskich ciśnieniach cząstkowych w temperaturze 800 stopni celsiusza prze 24 godziny. Uzyskano warstwę zgorzeliny zróżnicowaną w zależności od zastosowanego ciśnienia. W obu jednak przypadkach podobne były zmiany zachodzące w warstwie po zgorzeliną - degradacja węglików i intensywna korozja wzdłuż granic dendrytów.
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Influence of cavitation intensity on the relative cavitation resistance of laser processed C45 carbon steel
PublicationPraca przedstawia badania względnej odporności kawitacyjnej we wstępnym okresie niszczenia laserowo przetopionej 6 kW laserem CO2 stali C45. Badania odporności kawitacyjnej wykonano na stanowisku z wirującą tarczą. Na erodowanej przetopionej warstwie powierzchniowej określono trzy obszary o różnej intensywności oddziaływania obciążeń kawitacyjnych. Określano wielkość odkształceń plastycznych w analizowanych obszarach, spowodowanych...
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Cavitation Erosion Resistance of Austenitic Microstructure Created byLaser Beam
PublicationPraca przedstawia własności kawitacyjne różnych mikfrostruktur austenitycznych tworzonych za pomocą wiązki lasera na stalach X5CrNi18-10 oraz C45. Stal X5CrNi18-10 była laserowo stopowana węglikiem TiC oraz stopowana Ni, Mn, Cr i Nb. Jako żródło mocy stosowany był laser CO2. Własności kawitacyjne oceniane były na stanowisku z wirującą tarczą. Badania ujawniły różną podatność struktury austenicycznej do odkształceń plastycznych...
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Limb/Ground Impacts and Unexpected Impacts Control Strategy for a Model of a Limb of a Walking Robot
PublicationPraca prezentuje wyniki analizy numerycznej dynamiki robota kroczącego. Uwaga skoncentrowana jest na zagadnieniu kontaktu odnóża z podłożem. W kierunku normalnym kontakt opisano więzami jednostronnymi. W kierunku stycznym, założono obecność poślizgu i tarcia. Z uwagi na jednostronność kontaktu, może się on rozpocząć z niezerową prędkością względną. Z chwila rozpoczęcia kontaktu, prędkości zmieniają się gwałtownie. Towarzysza temu...
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Application of Syntactic Pattern Recognition Approach in Design and Optimisation of Group Machining Systems
PublicationRozwinięto koncepcję budowy zoptymalizowanych struktur systemów wytwarzania grupowego spektrum części z wykorzystaniem modelu analizy syntaktycznej sekwencji operacji ich procesów technologicznych. Określono formułę metryki odległościowej opisu stopnia zróżnicowania marszrut indywidualnych procesów oraz testowano jej skuteczność w aspekcie eksploracji wielowymiarowych danych i klasteryzacji obiektów wg cech wymagań technologicznych....