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Search results for: ORGANIC MATERIALS ORGANIC PHOTOVOLTAIC CELLS POWER CONVERSION EFFICIENCY ENERGY LOSSES IN ORGANIC PHOTOVOLTAICS INDOOR PHOTOVOLTAICS
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Electrochemical approach to evaluate the interlayer adhesion of organic coatings
PublicationZastosowano elektrochemiczną spektroskopię impedancyjną do wyznaczania międzywarstwowej adhezji w powłokach organicznych. Zbadano różne zestawy powłok do ochrony samochodów. Zastosowano dwie elektrody wykonane z prądoprzewodzącego tuszu umieszczone pomiędzy warstwami powłokowymi. Stwierdzono, że utrata adhezji międzywarstwowej następuje podobnie jak zmiany energii aktywacji przewodnictwa jonowego w obszarze międzywarstwowym. Uzyskane...
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Pathways and analytical tools in degradation studies of organic pollutants
PublicationWszystkie substancje chemiczne podlegają różnym procesom w wyniku wielu reakcji chemicznych, biochemicznych czy też fotochemicznych. W zależności od elementu środowiska w jakim znajduje się analit (np.: gleba, sedymenty, wody powierzchniowe i podziemne), może on ulegać powolnym przemianom w wyniku różnych procesów. W pracy przedstawiono niektóre drogi degradacji wybranych substancji w różnych warunkach. Omówiono problem identyfikacji...
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Space-charge-limited current fluctuations in organic semiconductors
PublicationBadania szumów elektrycznych w zakresie niskich częstotliwości, w regionie prĄdów ohmowych, zapełniania siĘ pułapek nośników ładunku i prądów ograniczonych ładunkiem przestrzennym w polikrystalicznych poliacenach, takich jak tetracen i pentacen.
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Organic light-emitting diodes. Principles, characteristics and processes.
PublicationJest to pierwsze monograficzne opracowanie zjawiska elektroluminescencji w organicznych ciałach stałych. W sześciu rozdziałach książki opisano między innymi wytwarzanie stanów wzbudzonych w wyniku rekombinacji ładunku, sposoby zaniku stanów wzbudzonych i ich rozkład przestrzenny, elektryczne i optyczne własności organicznych diod elektroluminescencyjnych oraz procesy warunkujące wydajne świecenie takich diod.
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Zr‐Based Metal‐Organic Framework UiO‐66/Ultem® 1000 Membranes for Effective CO2/H2 Separation
PublicationMixed-matrix membranes (MMMs) using UiO-66 nanofillers as dispersing inorganic phase and polyetherimide (PEI) as continuous polymeric matrix were synthesized. Different UiO-66 loadings of 10, 20, and 30 wt % were applied. The morphology and UiO-66 dispersion over the prepared MMMs were examined. Gas separation measurements were performed for H2/CO2 gas mixture to evaluate the influence of UiO-66 on the separation yield of resulting...
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Single-dopant organic white electrophosphorescent diodes with very high efficiency and its reduced current density roll-off
PublicationW pracy opisano konstrukcję wysokowydajnej diody elektrofosforescencyjnej zawierającej domieszkę organicznego kompleksu platyny PtL2Cl (L oznacza organiczny ligand). Dioda emituje światło białe które pochodzi od ekscymerów świecących w czerwieni i wzbudzonych monomerów świecących w części niebieskiej widma. Kwantowa wydajność świecenia diody wynosi ok. 15% i słabo maleje ze wzrostem gęstości płynącego prądu elektrycznego.
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Highly efficient organic electrophosphorescent light-emitting diodes with a reduced quantum efficiency roll off at large current densities.
PublicationW pracy opisano diody elektrofosforescencyjne zbudowane na bazie organicznych komplesów platyny PtOEP oraz Pt(thpy)2. Pokazano, ze mechanizmem ograniczjącym wydajność świecenia tych diod w zakresiedużych prądów elektycznych jest elektrycznopolowa dysocjacja ekscytonutrypletowego z transferem dziury na molekułę TPD.
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Fabrication and photoactivity of organic-inorganic systems based on titania nanotubes and PEDOT containing redox centres formed by different Prussian Blue analogues
PublicationHerein, the heterojunction composed of an inorganic substrate: ordered hydrogenated titania nanotubes (H-TiO2NTs) and a deposited organic film: poly(3,4-ethylenedioxythiophene) (PEDOT) is reported. The conducting polymer is modified with different transition metal haxacyanoferrates (Mehcf), wherein as metal: copper, iron, cobalt and nickel are introduced. The presence of various metal centres provides characteristic redox activity...
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Exergy Losses in the Szewalski Binary Vapor Cycle
PublicationIn this publication, we present an energy and exergy analysis of the Szewalski binary vapor cycle based on a model of a supercritical steam power plant. We used energy analysis to conduct a preliminary optimization of the cycle. Exergy loss analysis was employed to perform a comparison of heat-transfer processes, which are essential for hierarchical cycles. The Szewalski binary vapor cycle consists of a steam cycle bottomed with...
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Analytical Estimation of Power Losses in a Dual Active Bridge Converter Controlled with a Single-Phase Shift Switching Scheme
PublicationMicro-grid solutions around the world rely on the operation of DC/DC power conver- sion systems. The most commonly used solution for these topologies is the use of a dual active bridge (DAB) converter. Increasing the efficiency and reliability of this system contributes to the improvement in the stability of the entire microgrid. This paper discussed an analytical method of energy efficiency and power loss estimation in a single...
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Prospects of Decreasing Power Losses in a Hydrostatic Thrust Bearing
PublicationIn numerous machines, axial load is carried by tilting pad thrust bearings known since the beginning of 20th century. These bearings are commonly bath lubricated, which is simple, does not require any additional pumps, and, due to this, such systems are highly reliable. In a contemporary technology, however, minimization of friction losses became an important goal of machinery improvement. Calculations based on elementary rules...
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Photovoltaic Maximum Power Point Technique based on Incremental Conductance (INCON) control algorithm
PublicationMaximum output power status can significantly improve the deployment rate of solar energy system. In order to get the maximum power output, issue of tracking maximum power point (MPP), reduced harmonics around MPP and improve efficiency of the solar power energy system, this paper presents the improved maximum power point tracking (MPPT) control...
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Efficiency analysis of an energy conversion system for a variable speed small hydropower plant
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Pendant Proton-Relays Systematically Tune the Rate and Selectivity of Electrocatalytic Ammonia Generation in a Fe-Porphyrin Based Metal-Organic Framework
PublicationElectrocatalytic nitrite reduction (eNO2RR) is a promising alternative route to produce ammonia (NH3). Until now, several molecular catalysts have shown capability to homogeneously reduce nitrite to NH3, while taking advantage of added secondary-sphere functionalities to direct catalytic performance. Yet, realizing such control over heterogeneous electrocatalytic surfaces remains a challenge. Herein, we demonstrate that heterogenization...
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Phase Change Thermal Energy Storage – The Experience of the Materials Preparation for the Specific Applications.
PublicationThermal energy storage and temperature stabilization is very important in many engineering applications. There are three kinds of thermal energy storage: sensible heat storage, latent heat storage and reversible chemical reaction heat storage. Phase change materials (PCM) absorb, store and release large amounts of energy in the form of latent heat, at constant temperature, called the transition temperature. The amount of heat...
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Effect of electrode resistance on admittance spectra of planar organic device carrying SCLC and on charge carrier mobility extracted from susceptance
PublicationThe work presents small signal admittance spectra of a sandwich system with thin organic layer carrying a space charge limited current. The effect of series resistance of electrodes on the spectra is discussed. Spectra of small signal capacitance are added to get more detailed insight. The analysis performed shows that the series resistance can affect both parts of small signal response within a whole range of frequency. Moreover,...
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Analysis of energy and economic efficiency of water heating system powered by photovoltaic module
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Ground Tire Rubber Modified by Elastomers via Low-Temperature Extrusion Process: Physico-Mechanical Properties and Volatile Organic Emission Assessment
PublicationIn this paper, low-temperature extrusion of ground tire rubber was performed as a proecological waste tires recycling method. During this process, ground tire rubber was modified with constant content of dicumyl peroxide and a variable amount of elastomer (in the range: 2.5–15 phr). During the studies, three types of elastomers were used: styrene-butadiene rubber, styreneethylene/butylene-styrene grafted with maleic anhydride and...
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Application of dynamic headspace and gas chromatography coupled to mass spectrometry (DHS-GC-MS) for the determination of oxygenated volatile organic compounds in refinery effluents
PublicationThe paper presents a new procedure for the determination of oxygenated volatile organic compounds (O-VOCs) in postoxidative effluents from the production of petroleum asphalt using dynamic headspace coupled to gas chromatography-mass spectrometry in the selected ion monitoring (SIM) mode (DHSGC-MS). Among the GC capillary columns tested, a polar SLB-IL111 column with the ionic liquid stationary phase was found to be superior due...
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IEEE Workshop on Organic Computing
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Application of cyanated asphaltenes in gas-phase adsorption processes for removal of volatile organic compounds
PublicationThe paper presents an innovative, chemically modified (methylcyanated) asphaltene-based adsorbent that can be an inter-esting low-cost alternative for traditional adsorbents. Adsorption properties of adsorbents were examined by inverse gas chromatography technique, adsorption isotherms, and breakthrough curves. A significant increase in retention volume for pyridine, 2-pentanone, nitropropane, toluene, and 1-butanol was observed....
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AC-DC-DC Converter for Small Power Energy Storage Systems
PublicationThe energy transformation driven by the development of renewable energy sources has become a reality for all power grid users. Prosumer energy, primarily utilizing photovoltaic installations, is one of the fastest-growing market segments. The advancement of technology, a decrease in electrochemical energy storage prices, and changes in the legal framework governing energy billing for grid-fed power have led to a growing interest...
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Direct measurements of odorous volatile organic compounds present in biosolids cakes by Proton Transfer Reaction – Mass Spectrometry Technique
PublicationThis paper show the results of investigation of concentration of odorous chemical compounds emitted upon ageing of anaerobically stabilised biosolids that could contribute to the overall odour character of nuisance emissions. Biosolids samples from wastewater treatment plant were collected in spring time. Concentrations of volatile organic compounds using a US EPA flux hood and Proton Transfer Reaction-Time of Flight-Mass Spectrometry...
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Analysis of Induced Voltages and Power Losses in High Voltage Power Cables for Selected Methods of Cables Sheaths Bonding
PublicationPower is increasingly supplied to city centres with 110 kV cable lines. This is a convenient way to supply power, and practically the only one possible in areas of dense urban development. A high-voltage cable contains a coaxial metallic sheath, in which in normal operation and in fault conditions (during short-circuits) significant line-to-earth voltages can be induced, which threatens electric shock and/or damage to the cable’s...
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Comparative study of a bottoming SRC and ORC for Joule–Brayton cycle cooling modular HTR exergy losses, fluid-flow machinery main dimensions, and partial loads
PublicationEnergy conversion efficiency increase in power plants with high-temperature gas-cooled reactors via implementation of the bottoming cycle was investigated under nominal and minimal thermal load of a high-temperature reactor (HTR). Heat transfer surface area and turbine outlet volumetric flow rate in bottoming cycles was also investigated. Water and two low-boiling point working fluids (ammonia and ethanol) were analyzed. Analyzed...
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Modification of cellulosic filler with diisocyanates – volatile organic compounds emission assessment and stability of chemical structure over time
PublicationThis paper investigated the impact of type and content of diisocyanate on the structure of modified cellulose fillers. Four the most popular isocyanates were applied – isophorone, hexamethylene, toluene and methylene diphenyl diisocyanate – at loadings of 1–15 wt%. Chemical structure, and its short-term storage stability, were investigated for eight weeks. Moreover, the main volatile organic compounds detected during modification,...
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The chemistry of river–lake systems in the context of permafrost occurrence (Mongolia, Valley of the Lakes) Part II. Spatial trends and possible sources of organic composition
PublicationThe chemistry of river–lake systems located in Central Mongolia near the southern border of permafrost occurrence has not been well studied. The main aim of this paper is to summarize patterns in water chemistry in supply springs, rivers and lakes in relation to permafrost occurrence, as well as other natural and anthropogenic impacts. The analyses involved water samples taken from two river–lake systems: the Baydrag River–Böön...
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Anticorrosive and antimicrobial efficiency of photopolymerizable phosphorus (meth)acrylate oligomers-based coating materials
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Air-cooled photovoltaic roof tile as an example of the BIPVT system – An experimental study on the energy and exergy performance
PublicationThe air-cooled photovoltaic tile is a subject of presented investigations, which focused on improving the overall system efficiency of PV tiles with heat recovery. The operational efficiency of a PV roof tile, together with the construction optimising the air cooling efficiency, were the main points of plans realized at this research stage. The article describes the experimental research consisting of the assessment of electrical,...
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Innovative system for energy collection and management integrated within a photovoltaic module
PublicationThe dynamic development of battery technology and design based on the flow of lithium ions, mainly driven by the needs of the automotive industry, leads to the conclusion that these batteries are becoming a more viable alternative to traditional lead-acid batteries. Their use is driven by the ability to quickly charge and discharge, a higher durability, maintenance-free operation, much smaller dimensions and lighter weight. The...
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Pretreatment of Lignocellulosic Materials as Substrates for Fermentation Processes
PublicationLignocellulosic biomass is an abundant and renewable resource that potentially contains large amounts of energy. It is an interesting alternative for fossil fuels, allowing the production of biofuels and other organic compounds. In this paper, a review devoted to the processing of lignocellulosic materials as substrates for fermentation processes is presented. The review focuses on physical, chemical, physicochemical, enzymatic,...
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The importance of anchoring ligands of binuclear sensitizers on electron transfer processes and photovoltaic action in dye-sensitized solar cells
PublicationThe relatively low photon-to-current conversion efficiency of dye-sensitized solar cells is their major drawback limiting widespread application. Light harvesting, followed by a series of electron transfer processes, is the critical step in photocurrent generation. An in-depth understanding and fine optimization of those processes are crucial to enhance cell performance. In this work, we synthesize two new bi-ruthenium sensitizers...
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Marek Adamowicz dr hab. inż.
PeopleStopień naukowy doktora uzyskał w 2008 r. na Wydziale Elektrotechniki i Automatyki Politechniki Gdańskiej. W latach 2005 – 2011 pracował na Akademii Morskiej w Gdyni. W 2010 r. jako laureat programu NCBR LIDER wybrał Wydział Elektrotechniki i Automatyki Politechniki Gdańskiej jako jednostkę realizującą swój projekt z zakresu szerokopasmowych przyrządów półprzewodnikowych i ich zastosowań w elektrowniach wiatrowych. Od 2011 roku...
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GaN Nanowire Array for Charge Transfer in Hybrid GaN/P3HT:PC71BM Photovoltaic Heterostructure Fabricated on Silicon
PublicationAbstract: We demonstrate that a GaN nanowire array can be used for efficient charge transfer between the organic photovoltaic layer and silicon in a Si/GaN/P3HT:PC71BM inverted hybrid heterostructure. The band alignment of such a material combination is favorable to facilitate exciton dissociation, carrier separation and electron transport into Si. The ordered nature of the GaN array helps to mitigate the intrinsic performance...
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Średnio - i trudnolotne związki organiczne w powietrzu wewnętrznym. Analityka i monitoring = Semivolatile organic compounds in indoor air. Analytics and monitoring
PublicationZwiązki organiczne występujące w powietrzu wewnętrznym na różnych poziomach stężeń mogą stanowić poważną przyczynę problemów zdrowotnych mieszkańców i użytkowników pomieszczeń. Bardzo ważnym staje się zagadnienie monitoringu obecności związków organicznych, należących do grupy trwałych zanieczyszczeń organicznych (POP).
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Asian Journal of Organic Chemistry
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Insights into modification of lignocellulosic fillers with isophorone diisocyanate: structure, thermal stability and volatile organic compounds emission assessment
PublicationThis study presents an analysis of the structure and properties of different types of lignocellulosic fillers modified by isophorone diisocyanate (IPDI) to provide insights into the possibility of their application to the manufacturing of wood polymer composites (WPCs). Moreover, it deals with the environmental aspects of modified fillers, by assessment of volatile organic compounds (VOCs) emitted during modification, as well as...
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Study of the influence of the presence of Dr fimbriae on the hydrophobicity of cells of recombinant Escherichia coli strains: AAEC191A and BL21(DE3)
Open Research DataThe ability of a cell surface to repel or adhere to surfaces is crucial, and it was assessed through a microbiological adhesion test involving hexadecane and xylene. In this method, microorganisms in an aqueous layer are mixed with an organic layer, and after completion, the absorbance of each sample is measured at a 570 nm wavelength. The results obtained...
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Assessment of ecotoxicity and total volatile organic compound (TVOC) emissions from food and children's toy products
PublicationThe development of new methods for identifying a broad spectrum of analytes, as well as highly selective tools to provide the most accurate information regarding the processes and relationships in the world, has been an area of interest for researchers for many years. The information obtained with these tools provides valuable data to complement existing knowledge but, above all, to identify and determine previously unknown hazards. Recently,...
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Determination of polycyclic aromatic hydrocarbons (PAHs) and other organic pollutants in freshwaters on the western shore of Admiralty Bay (King George Island, Maritime Antarctica).
PublicationOrganic contamination in freshwater samples has never been investigated at the western shore of Admiralty Bay. Therefore, the presence of polycyclic aromatic hydrocarbons (PAHs) in five different sites distributed along a shore running from the Arctowski Station to the Baranowski Glacier was studied. Moreover, organic compounds such as n-alkanes, toluene and ethylbenzene were also noted. Increased ΣPAHs in late Austral summer 2016...
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The conversion of multinuclear μ-oxo titanium(IV) species in the reaction of Ti(OiBu)4 with branched organic acids; results of structural and spectroscopic studies
PublicationW reakcji tetraizobutoksylanu tytanu z rozgałęzionymi kwasami karboksylowymi otrzymano szereg wielordzeniowych związków kompleksowych tytanu(IV). Otrzymane produkty scharakteryzowano wykorzystując techniki spektroskopowe: FTIR, 1H i 13C NMR oraz rentgenowską analizę strukturalną. Zaproponowano ścieżki reakcji prowadzące do konwersji poszczególnych związków w coraz stabilniejsze formy.
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Lanthanide metal–organic frameworks: Structural, thermal and sorption properties
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Total, methyl and organic mercury in sediments of the Southern Baltic Sea
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Small-signal admittance for Schottky-Richardson emission into an organic layer
PublicationPraca przedstawia małosygnalową admitancję emisji Schottky'ego-Richardsona do warstwy organicznej. Analiza obejmuje obie składowe zespolonej odpowiedzi.
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Potentiometric detection of organic ionics in separation methods: a critical evaluation
PublicationCzujniki potencjometryczne są w tej chwili stosowane głównie w połączeniu ze wstrzykową analizą przepływową. Badano membranowe czujniki potencjometryczne pod względem zastosowania w połączeniu z wysokosprawną chromatografią cieczową i elektroforezą kapilarną. Stosowano anality takie jak środki powierzchniowo czynne i proste leki. Zauważono, że czujniki potencjometryczne dają dobre odpowiedzi na małe i duże jony z ładunkiem wielokrotnym...
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Organic light sources look forward to optimize the photosynthesis process
PublicationW pracy opisano własności organicznej diody EL, zbudowanej na bazie organicznego kompleksu platyny, emitującej światło czerwone i niebieskie, które może być wykorzystane w procesie fotosyntezy.
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Magnetic Covalent Organic Frameworks—Fundamentals and Applications in Analytical Chemistry
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Screening for Antagonistic Yeasts to Manage Alternaria spp. in Organic Farming
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Dynamics of Organic Cations in Switchable Quinuclidinium Metal Chloride Dielectrics
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Prussian Blue Analogues Cubes in the Organic Polymer Electrospun Fibres
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