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Search results for: WARYSTORY ZNO
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Badania modelowe stateczności warstw uszczelniających skarpy i dno składowiska odpadów.
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SEI Growth and Depth Profiling on ZFO Electrodes by Soft X-Ray Absorption Spectroscopy
PublicationZnFe2O4 (ZFO) Li-ion batteries (LIBs) represent a reliable, affordable, and safe energy storage technology for use in portable application. However, current LIB active materials (graphite, lithium/transition metal spinel or layered oxides, olivine structures) can store only limited energy since they rely on insertion storage based on solid-state host-guest interactions. Moreover, performances and durability of the cells are strongly...
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Role of MnO in manganese–borate binary glass systems: a study on structure and thermal properties
PublicationStructural and thermal properties of x MnO−(100−x)B2O3 (where x=40, 50 and 60 mol%) glass samples have been investigated with the employment of various techniques. Fourier transform infrared spectroscopy results revealed the influence of MnO on glass matrix. Decrease of B–O bond-related band intensities has been observed. MnO addition was found to introduce broken [BO2O−]n chains. Differential scanning calorimetry (DSC) measurements...
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Current commutation process in a ultra-fast fuse-IGBT hybrid circuit breaker.
PublicationUkład hybrydowy bezpiecznika topikowego i tranzystora IGBT umożliwia bardzo szybkie włączenie do obwodu zwarciowego impedancji ograniczającej wartość prądu. Po eksplozji krótkiego topika bezpiecznika wywołanej narastającym prądem zwarciowym wywołuje w czasie poniżej 2 ms wzrost napięcia na topiku do wartości ok.20 - 25V, po czym prąd jest komutowany do gałęzi z przyrządem półprzewodnikowym typu GTO lub IGBT. Ostateczne wyłączenie...
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Stress corrosion cracking of Al-Zn-Mg weldments.Korozja naprężeniowa złączy spawanych stopów Al-Zn-Mg.
PublicationPraca zawiera wyniki badań odporności korozyjnej złączy spawanych Al-Zn-Mg. Zbadano wpływ składu chemicznego stopu oraz spoiwa na odporność na korozje naprężeniową w warunkach statycznych naprężeń rozciągających.
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Effect of diet on the capacity to remove mercury from the body of a penguin (Spheniscus demersus) living in the ZOO
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The Effect of Marginal Zn2+ Excess Released from Titanium Coating on Differentiation of Human Osteoblastic Cells
PublicationComposite coatings based on chitosan and zinc nanoparticles (ZnNPs) were successfully produced on Ti13Zr13Nb substrates by cathodic electrophoretic deposition (EPD). The unfavorable phenomenon of water electrolysis-induced nonuniformity was reduced by applying a low voltage (20 V) and a short deposition time (1 min). Surface analysis (roughness and hydrophilicity) reveals the potential of these coatings for enhancing cell attachment...
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Local Structure and Stability of SEI in Graphite and ZFO Electrodes Probed by As K-edge Absorption Spectroscopy
PublicationThe evolution of the solid electrolyte interphase (SEI) during the first Li uptake in advanced Li-ion electrodes is studied by X-ray absorption spectroscopy (XAS). The As atoms present in the electrolyte solution were used as a local probe for monitoring the SEI growth on different electrodes. High-quality As K-edge spectra were collected in fluorescence mode for a set of graphite and carbon-coated ZnFe2O4 electrodes. XAS measurements...
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Benzene-induced hydro(solvo)thermal synthesis of Cu2+ and Zn2+ coordination polymers based on 1,3-benzenedicarboxylate
PublicationHydro(solvo)thermal reactions of Cu(NO3)2·2.5H2O or Zn(NO3)2·6H2O with 1,3-H2bdc provided two structurally different coordination polymers; a 2D network “metallacalixarene” based on the paddlewheel-type cluster with the formula [Cu(1,3-bdc)·H2O]·H2O (1) and a 3D framework [Zn(1,3-bdc)] (2), respectively. The use of a base was unnecessary in this synthesis; however, the presence of benzene played a crucial role in the crystallization...
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Synthesis of 5-Substituted 1H-Tetrazoles from Nitriles in the Presence of Heterogeneous Catalyst
PublicationTetrazoles are five-membered heterocyclic compounds containing in their rings four nitrogen atoms. They have wide applications as corrosion inhibitors, analytical reagents, high-energy materials and gas generating compositions. Tetrazoles also play important role in coordination chemistry as ligands and in medicinal chemistry as metabolically stable surrogates for carboxylic acids. In recent years, investigation of new method of...
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Synthesis, characteristics, and photocatalytic activity of zinc oxide nanoparticles stabilized on the stone surface for degradation of metronidazole from aqueous solution
PublicationAbstract Background: The presence of antibiotics such as metronidazole in wastewater even at low concentrations requires searching for a suitable process such as advanced oxidation process (AOP) to reduce the level of pollutants to a standard level in water. Methods: In this study, zinc oxide (ZnO) nanoparticles were synthesized by thermal method using zinc sulfate (ZnSO4) as a precursor, then, stabilized on stone and was used...
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New heterometallic Co/Zn, Ag/Co, and Ag/Zn imidazolates: structural characterization and catalytic activity in the oxidation of organic compounds
PublicationNanocrystalline powders of monometallic and bimetallic imidazolates of Co, Zn, and Ag were produced by a reaction carried out in water. The powders were characterized by powder X-ray diffraction and the crystal structures of new compounds Ag2ZnIm4 and Ag2CoIm4 (Im = imidazolate) were solved. Heterometallic Co/Zn imidazolates showed the standard ZIF-8 crystal structure while Ag/Zn and Ag/Co systems were isostructural with the copper...
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Effect of Indium on the Properties of Mg-Zn-Based Alloys
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Tb3+ ions in presence of ZnS:Mn2+ nanocrystals immobilized on silica: Energy transfer ZnS→Tb3+ and coordination state of Mn2+ ions
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Critical minima in elastic scattering of electrons from Ar and Zn.
PublicationDokonano obliczeń różniczkowych przekrojów czynnych na sprężyste rozpraszanie elektronów na atomach argonu i cynku. Otrzymane minimum krytyczne z tych przekrojów porównano z niedawno otrzymanymi danymi doświadczalnymi.
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THE POTENTIAL OF DIFFERENT VARIETIES OF WHITE CABBAGE IN PHYTOREMEDIATION OF ZN AND CD
PublicationThe species belong to the botanical family Brassi- caceae are considered to be useful for phytoremediation of soil contaminated with heavy metals. Problems with use the plants recognized as hyperacumulators is that, the plants need to be harvested shortly after the plants become mature, which causes problems of disposal of obtained biomass. When these plants are dried, they easily crumble and flake off, greatly reducing the yield obtained,...
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Growth, Crystal Structure and Magnetic Characterization of Zn-Stabilized CePtIn4
PublicationThe growth and characterization of CePtIn4, stabilized by 10% Zn substitution for In, is reported. The new material is orthorhombic, space group Cmcm (No. 63), with lattice parameters a = 4.51751(4) Å, b = 16.7570(2) Å, and c = 7.36682(8) Å, and the refined crystal composition has 10% of Zn substituted for In, i.e., the crystals are CePt(In0.9Zn0.1)4. Crystals were grown using a self-flux method: only growths containing Zn yielded...
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Mercury and Chlorinated Pesticides on the Highest Level of the Food Web as Exemplified by Herring from the Southern Baltic and African Penguins from the Zoo
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Development of headspace-gas chromatography-flame ionization detection procedure to determine volatile fatty acids in zoo organic waste leachate
PublicationNadrzędnym celem pracy było opracowanie metodyki oznaczania lotnych kwasów tłuszczowych z fazy nadpowierzchniowej opartej na chromatografii gazowej z detektorem płomieniowo-jonizacyjnym oraz sprawdzenie jej przydatności w analizie próbek odcieku ze składowiska odpadów ogrodu zoologicznego. Na podstawie przeprowadzonych badań określono warunki, w jakich przebiegać powinna izolacja lotnych kwasów tłuszczowych, a także określono najlepsze...
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Phage-Directed Synthesis of Photoluminescent Zinc Oxide Nanoparticles under Benign Conditions
PublicationBiological systems, especially bacteriophages and peptides, are an attractive green alternative to other known methods of nanoparticle synthesis. In this work, for the first time, bacteriophages were employed to synthesize a specific peptide, capable of producing nanoparticles (NPs). Derivatives of M13 bacteriophage exposing a ZnO-binding peptide (TMGA-LGLKWPV) on either pIII or pVIII phage coat protein were constructed and used...
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Problemy pomiaru prądów upływowych w diagnostyce ograniczników przepięć
PublicationW monografii opisano wybrane zagadnienia związane z diagnostyką warystorowych ograniczników przepięć wykonanych z tlenku cynku ZnO. Spośród wielu metod diagnostycznych skupiono się głównie na problemach pomiaru prądów upływowych, których znajomość między innymi umożliwia bezinwazyjną diagnostykę ogranicznika w czasie jego eksploatacji. W celu prawidłowej oceny stanu ogranicznika tą metodą analizowano wyznaczanie składowej czynnej...
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Tuning the photocatalytic performance through magnetization in Co-Zn ferrite nanoparticles
PublicationIn this work, the link between the photocatalytic performance of Co-Zn ferrite nanoparticles and the net magnetic moment is analyzed. CoxZn1-xFe2O4 nanoparticles (0 ≤ x ≤ 1) were synthesized by co-precipitation method and different physicochemical techniques were employed to characterize the samples (X-ray diffraction, Transmission Electron Microscopy (TEM), BET surface area, Diffuse Reflectance Spectroscopy (DRS), Photoluminescence spectroscopy,...
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Curing epoxy with electrochemically synthesized Zn Fe3-O4 magnetic nanoparticles
PublicationCathodic electrodeposition (CED) was applied in synthesis of undoped and zinc (Zn) doped Fe3O4 nanoparticles. Changes in the lattice structure of nanoparticles were monitored using X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM) supported by dispersive X-ray spectrometry (EDS), and vibrating sample magnetometry (VSM). Detailed analyses explored the formation of ZnxFe3–xO4 nanoparticles with x ≈ 0.1,...
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The Biocompatibility and Self-Healing Effect of a Biopolymer’s Coating on Zn Alloy for Biomedical Applications
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Long-term researches of stress corrosion cracking of Al-Zn-Mg alloys
PublicationPraca przedstawia wyniki odporności na korozję naprężeniową stopów Al-Zn-Mg uzyskane w warunkach stacjonarnych. Dodatkowo określono wpływ składu chemicznego oraz obróbki cieplnej na odporność korozyjną tych stopów. Badania prowadzono w 3% NaCl w warunkach stałego obciążenia σ = 0.8R0.2 przez 1500 godzin. Stwierdzono, iż zawartość Zn i Mg oraz szybkość chłodzenia to główne czynniki wpływające na podatność tych stopów na korozje...
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Structural, physicochemical and anticancer study of Zn complexes with pyridyl-based thiazolyl-hydrazones
PublicationThiazolyl-hydrazones (THs) exhibit a wide spectrum of biological activity that can be enhanced by complexation with various metal ions. Zn(II) complexes with α-pyridine-1,3-TH ligands may represent an alternative to the standard platinum-based chemotherapeutics. In addition, they show photoluminescence properties and thus can be regarded as multifunctional materials. In this study, we synthesized and characterized three neutral...
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Influence of synthesis conditions on zinc oxide nanorode layer morphology
PublicationIn recent years one dimensional (1D) nanostructures (nanotubes, nanowires, nanoribbons and nanorods) have been widely studied. Among studied nano-materials, the greatest interest can be seen for zinc oxide (ZnO). However, there is still a need for simple, inexpensive and reproducible fabrication method. In the literature different fabrication methods can be found, most of them requires expensive equipment and involve complex...
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Solvent Exchange around Aqueous Zn(II) from Ab Initio Molecular Dynamics Simulations
PublicationHydrated zinc(II) cations, due to their importance in biological systems, are the subject of ongoing research concerning their hydration shell structure and dynamics. Here, ab initio molecular dynamics (AIMD) simulations are used to study solvent exchange events around aqueous Zn2+, for which observation in detail is possible owing to the considerable length of the generated trajectory. While the hexacoordinated Zn(H2O)62+ is the...
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Bioaccessibility of Ca, Cu, Fe, Mg, Mn and Zn from commercial bee honeys
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Epigenetic modifications and NF-κB pathway activity in Cu,Zn-SOD-deficient mice
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Land development and forms of heavy metals occurrence (zn, cd, pb) in polish rivers
PublicationEkosystemy rzeczne podlegają intensywnej antropopresji. Metale ciężkie występujące w glebie i osadach dennych w różnych formach specjacyjnych mają istotny wpływ na wtórne zanieczyszczenie wody ze względu na takie procesy jak migracja, akumulacja i biowzbogacanie.Przedmiotem badań były próbki gleby, osadów dennych oraz wody pobrane z różnych rzek z południowej części województwa świętokrzyskiego. W trakcie badań próbek wykorzystano...
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Photoelectrochemical properties of BIMEVOX (ME=Cu, Zn, Mn) electrodes in contact with aqueous electrolyte
PublicationLayered oxide Bi4O2O11 and mixed oxides of bismuth, vanadium and a third metal (ME = Cu, Zn, Mn) were synthesized and characterized using XRD, Raman and SEM. The energy band gap (Eg) of samples determined using UV–VIS reflectance spectra equals to 2.46, 2.34, 2.27 and 2.18 eV for Bi4V2O11, BICUVOX (Bi2V1 − xCuxO5.5 − 3x/2), BIZNVOX (Bi2V1 − xZnxO5.5 − 3x/2) and BIMNVOX (Bi2V1 − xMnxO5.5 − x/2) (x = 0.1), respectively. Open circuit...
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Thermostability and photophysical properties of mixed-ligand carboxylate/benzimidazole Zn(II)-coordination polymers
PublicationThe reaction between Zn(NO3)2*6H2O or Zn(CH3COO)2*2H2O and isophthalic acid (1,3-H2bdc) in the presence of benzimidazole (Hbzim) in dimethylformamide (DMF)/ethanol (EtOH)/H2O solvent mixture at room temperature yielded two structurally different coordination polymers: [Zn2(1,3-bdc)2(Hbzim)2] (1) and [Zn2(1,3-bdc)(bzim)2] (2). (1) is a 2D-layered framework with a molecule of benzimidazole coordinated to the Zn center, whereas (2)...
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Stone cutting industry waste-supported zinc oxide nanostructures for ultrasonic assisted decomposition of an anti-inflammatory non-steroidal pharmaceutical compound
PublicationPowdered stone waste (PSW) obtained from a stone cutting industrial unit was applied as support for the immobilization of nano-sized ZnO to be utilized as an effective catalyst for the catalytic conversion of acetaminophen (ACE) under ultrasonication. The incorporation of ZnO nanostructures into PSW structure enhanced the specific surface area and pore volume of the as-prepared nanocompound. The change in the value of zero point...
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Wwpływ temperatury suszenia osadów ściekowych na specjację metali ciężkich (Zn, Cu, Cd, Pb) = Influence of thermal drying temperature on heavy metal (Zn, Cu, Cd, Pb) speciation in sewage sludge
PublicationPrzedstawiono wpływ temperatury suszenia osadów ściekowych na zmiany specjacji metali ciężkich oraz określono stopień mobilności metali ciężkich w aspekcie ich późniejszego zagospodarowania. Ekstrakcja sekwencyjna metali ciężkich została wykonana wg schematu Tessier'a.
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Photocatalytic activity of zinc oxide nanorods incorporated graphitic carbon nitride catalyst
PublicationBackground Photocatalysts are user-friendly and serve as compatible materials for degrading industrial dye pollutants. This study utilizes zinc oxide/graphitic carbon nitride (ZnO/g-C3N4) nanocomposites against degrading methylene blue (MB). Methods The hydrothermal method assisted sonication technique was used to fabricate the ZnO/g-C3N4 composite with varying ratios of ZnO/g-C3N4 (1:0.25, 1:0.50, 1:1). The synthesized materials...
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Sonocatalytic degradation of tetracycline antibiotic using zinc oxide nanostructures loaded on nano-cellulose from waste straw as nanosonocatalyst
PublicationThe aim of the present investigation was the combination of ZnO nanostructures with nano-cellulose (NC) for the efficient degradation of tetracycline (TC) antibiotic under ultrasonic irradiation. The removal efficiency of 12.8% was obtained by the sole use of ultrasound (US), while the removal efficiency increased up to 70% by the US/ZnO treatment process. Due to the integration of ZnO nanostructures with NC, the removal efficiency...
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Zastosowanie metody polaryzacyjnej Hebba-Wagnera do badania przewodnictwa elektrycznego w mieszanych przewodnikach jonowo-elektronowych
PublicationMieszane przewodniki jonowo-elektronowe (MIECs) znajdują obecnie powszechne zastosowanie m.in. jako elektrody w ogniwach paliwowych, czujnikach gazów lub jako warystory. Jednak wciąż niepoznane do końca mechanizmy występowania zjawiska mieszanego przewodnictwa sprawiają, że prace nad tymi materiałami wciąż trwają. Badanie przewodnictwa jonowego tego typu materiałów wymaga zastosowania stałoprądowych, elektrochemicznych metod...
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The accumulation of metal (Co, Cr, Cu, Mn and Zn) in freshwater Ulva (Chlorophyta) and its habitat
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Micro Arc Oxidation of Mechanically Alloyed Binary Zn-1X (X = Mg or Sr) Alloys
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Tetrahedrally modified MnMe0.1Co1.9O4 (Me = Zn, Mg, Li) spinels for non-enzymatic glucose sensing
PublicationIn this work, tetrahedrally modified MnMe0.1Co1.9O4 (Me = Zn, Mg, Li) spinels were prepared via the sol–gel synthesis method with subsequent ball-milling fragmentation. The prepared samples were evaluated as glucose–sensing catalyst. The reference MnCo2O4 spinel exhibited a sensitivity of 49 µA mM−1 cm−2 and a nonlinearity error of 5.2% in the response range from 0.02 to 1 mM. The partial substitution of cobalt in the reference...
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Effect of contactless hybrid current limiter on voltage dips in power system
PublicationW referacie przedstawiono działanie hybrydowego niskonapięciowego ogranicznika prądu zwarciowego, składającego się z ultraszybkiego bezpiecznika, tranzystora mocy i warystora. W szczególności omówiono możliwości polepszenia jakości dostarczanej do odbiorców energii elektrycznej. Zastosowanie hybrydowego ogranicznika prądu znacznie ogranicza czasy trwania zapadów napięcia w systemie elektroenergetycznym. Obliczenia wykonano przy...
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Effect of contactless hybrid current limiter on voltage dips in power system.
PublicationW referacie przedstawiono działanie hybrydowego niskonapięciowego ogranicznika prądu zwarciowego, składającego się z ultraszybkiego bezpiecznika, tranzystora mocy i warystora. W szczególności omówiono możliwości polepszenia jakości dostarczanej do odbiorców energii elektrycznej. Zastosowanie hybrydowego ogranicznika prądu znacznie ogranicza czasy trwania zapadów napięcia w systemie elektroenergetycznym. Obliczenia wykonano przy...
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Zinc tri-tert-butoxysilanethiolates. Syntheses, properties and crystal and molecular structures of [Zn{μ-SSi(OBut)3}(acac)]2 and [{(ButO)3SiS}(H2O)2Zn{μ-SSi(OBut)3}Zn(acac){SSi(OBut)3}]
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Wpływ geometrii i szorstkości ścian na wielkość naporu materiału sypkiego na dno silosu = Influence of geometry and wall roughness of silo wall on bottom vertical pressure
PublicationW pracy przedstwiono analizę wpływu wysokości i szorstkości ścian silosu cylindrycznego na rozkład naporu na ściany i dno. Badania przeprowadzono dla piasku bezkohezyjnego.
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Sorption of Cu(II), Zn(II) and Pb(II) Ions in an Aqueous Solution on the PVC-Acetylacetone Composites
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Novel composite of Zn/Ti-layered double hydroxide coupled with MXene for the efficient photocatalytic degradation of pharmaceuticals
PublicationIn the present study, a hybrid photocatalyst of Zn/Ti layered double hydroxide (LDH) coupled with MXene – Ti3C2 was synthesized for the first time and applied in photocatalytic degradation of acetaminophen and ibuprofen, two commonly present in the natural environment and prone to accumulate in the aquatic ecosystem pharmaceuticals. The effect of MXene content (0.5 wt%, 2.5 wt%, and 5 wt%) on the photocatalytic activity of LDH/MXene...
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Stable nanoconjugates of transferrin with alloyed quaternary nanocrystals Ag–In–Zn–S as a biological entity for tumor recognition
PublicationOne way to limit the negative effects of anti-tumor drugs on healthy cells is targeted therapy employing functionalized drug carriers. Here we present a biocompatible and stable nanoconjugate of transferrin anchored to Ag-In-Zn-S quantum dots modified with 11-mercaptoundecanoic acid (Tf-QD) as a drug carrier versus typical anticancer drug, doxorubicin. Detailed investigations of Tf-QD nanoconjugates without and with doxorubicin...
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Unconditionally blue: Curing epoxy with polyethylene glycol (PEG) surface-functionalized Zn Fe3-O4 magnetic nanoparticles
PublicationNanoparticles govern early (chemical-controlled) and late (diffusion-controlled) stages of epoxy crosslinking, respectively. Surface functionalization of nanoparticles with macromolecules was recognized as an effective route to compensate for inadequate diffusion-controlled crosslinking. However, the effect of bulk composition amended with cations having catalytic effect towards epoxy ring opening has remained hitherto undescribed....
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Giant increase of optical transparency for Zn-rich CaxZn1−xO on Al2O3 (0001) grown by pulsed laser deposition
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