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Search results for: AUTOREDOX REACTION
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Reactions of methyl radicals with silica supported silver nanoparticles in aqueous solutions
PublicationSilica supported silver nanoparticles (Ag°–SiO2 –NCs, NCs=nanocomposites) suspended in aqueous solutions are efficient catalysts for the dimerization of methyl radicals to produce ethane, while bare silica is quite inert towards the interaction with methyl radicals. In the presence of small amounts of ethanol adsorbed on the SiO2 surface, the reaction path with methyl radicals is changed and methane is formed as the major product.
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Control of mass concentration of reagents by sound in a gas with nonequilibrium chemical reactions
PublicationThe weakly nonlinear dynamics of a chemically reacting gas is studied. Nonlinear interaction of acoustic and nonacoustic types of motion are considered. We decompose the base equations using the relationships of the gas-dynamic perturbations specific for every type of motion. The governing equation for the mass fraction of a reagent influenced by dominating sound is derived and discussed. The conclusions concern the equilibrium...
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Stock price reactions to an arrangement approval in restructuring proceedings – the case of Poland
PublicationThe study aims to empirically analyze the reaction of stock prices to the information about the conclusion and acceptance of a debtor–creditor arrangement under restructuring proceedings of companies listed on the stock exchange in Poland. The following main research hypothesis was verified: public disclosure of information about an arrangement conclusion and acceptance in restructuring proceedings...
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Insights Into Hydrodynamics of Spinning Fluids Reactor
PublicationSpinning fluids reactor (SFR) is one of the most efficient gas-liquid contacting system with high potential of application in many fields. The unique solution of SFR is the contacting of two spinning fluids which generated centrifugal force. The aim of this study was to investigate the pressure field distribution on the inner surface of reactors dispersing element. Obtained results confirm the high heterogeneity of the field pressure...
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Distorsional analysis of I-section beam
PublicationAn elastic stiffness matrix was derived in the case of distortion of a restrained thin-walled I-section beam using the minimum total stationary elastic energy condition. The function describing the angle of distortion was adopted form the solution of differential equation in the case of restrained distortion. The example presented in the paper helps to assess the correctness of the proposed solution. The proposed elastic stiffness...
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Influence of velocity description on dispersivity of reactor.
PublicationPrzy projektowaniu reaktorów z reguły stosuje się model przepływu tłokowego - prosty, lecz mało dokładny. W pracy pokazano wpływ dokładności stosowanej metody opisu pola prędkości na poziom projektu reaktora.
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Hydraulic and technological consequences of reactor asymmetry
PublicationKażdy reaktor, choć projektowany jako obiekt o regularnych kształtach, może utracić symetrię - bądź wskutek błędów wykonawczych, bądź wskutek odkształceń w trakcie eksploatacji. Fakt ten wpływa na pole prędkości przepływającej cieczy i może mieć znaczące skutki technologiczne. W pracy omówiono metodę określania tych konsekwencji i zilustrowano ją przykładami.
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The time dependence of pit creation impedance spectra
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Modelling and diagnostics of a traction transformer - a case study
PublicationW niniejszym artykule przedstawiono wyniki badań w dziedzinie diagnostyki kolei elektrycznych. Zostały one przeprowadzone przez międzynarodowe przemysłowo-akademickie konsorcjum w ramach projektu europejskiego (6-go programu ramowego). Skupiono się na modelowaniu transformatora trakcyjnego z myślą o rozwinięciu nieinwazyjnej metody diagnostycznej w czasie rzeczywistym. Model przeznaczony do badań finalnych został rozwinięty w oparciu...
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Model order reduction for subgridding in fdtd scheme
PublicationW artykule zaprezentowana została technika pozwalająca na uzyskanie wysokiej rozdzielczości w metodzie FDTD. Prezentowany algorytm jest połączeniem metod redukcji rzędu modelu i lokalnych zagęszczeń zaimplementowanych do FDTD. Pozwala to zmniejszyć liczbę użytych zmiennych stanu, a także skrócić krok czasowy, co skutkuje znacznie krótszym czasem symulacji, niż w przypadku klasycznej metody FDTD.
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Wow defect reduction based on interpolation techniques
PublicationW artykule przedstawiono wyniki badania różnych technik interpolacji wykorzystanych w redukcji kołysania dźwięku. W badaniach użyto: interpolację liniową, techniki interpolacji wielomianowej, i interpolację funkcją sink. Jakość rekonstrukcji zbadano wykorzystując sztucznie spreparowany sygnał foniczny, zrekonstruowany wymienionymi metodami interpolacji. Jakość rekonstrukcji oceniono wykorzystując standardowe deskryptory jakości...
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Unilateral Carotid Body Resection in Resistant Hypertension
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Injury characteristics in women in relation to their menopausal status
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Reduction of the end-effect in surface texture analysis
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Pulse pressure amplification in relation to body fatness
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Data reduction and stacking for imbalanced data classification
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Noise as a Factor of Green Areas Soundscape Creation
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Digital techniques for noise reduction in CCD detectors
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Application of optical fibres in oxidation-reduction titrations
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Prosociality in relation to developmental tasks of emerging adulthood
PublicationProsociality, understood as the capacity to act in a way that benefits others, is an important feature for emerging adults to fulfill their personal needs and fulfill developmental tasks. This life period is a time of exploration within various areas of life, enabling individuals to try out and choose own worldview, lifestyle, work and preferred patterns of interpersonal relationships. This review aims at bringing together the...
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Distributed Data Reduction through Agent Collaboration
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An Approach to Data Reduction and Integrated Machine Classification
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Optimization of Graphene Oxide Synthesis and Its Reduction
PublicationIn this article, we present the review of the chemical methods of synthesis of graphene oxide and its reduction in order to obtain the so-called reduced graphene oxide (rGO) whose properties are similar to those of pure graphene. We also present our experiments and the results in this field and the comparison of the efficiency of different methods of synthesis as well as the reduction of graphene oxide. To characterize the obtained...
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Reactive Energy Billing in Operator Tariffs in Poland
PublicationThe paper describes the current method of reactive energy billing in the tariffs of distribution grid operators in Poland. The current solutions are subject to critical assessment. Issues related to the motivation effect of the current solutions on consumers are analysed. Problems that occur in relation with connecting distributed generators to the distribution grid and challenges related to prosumer billing are indicated.
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Reduction of Derivative pipeline effort in water turbine
PublicationThe paper presents an approach to evaluate and reduce the effort of the derivative pipeline in a water turbine of a hydrostatic power station in its vulnerable spots. Potential places of the biggest effort of the structure, as well as the coefficient of displacement and safety factor related to them were identified using FEM numerical method. Pipeline reinforcement was designed and made based on FEM analysis. Original technology...
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Reduction of pressure forces in turbine labyrinth seals
PublicationPrzedstawiono nową metodę zmniejszani sił samowzbudnych typu aerodynamicznego. zastosowano ją do różnych typów nadbandażowych uszczelnień labiryntowych. Efektywność rdukcji sił samowzbudnych wynosiła nawet ponad 60%. Potwierdzone rezultay obliczeniami i eksperymentalnie.
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In-Situ Processing of Biocomposites via Reactive Extrusion
PublicationLaw regulations, economic and environmental factors are the main causes for the rapidly growing interests in biocomposites’ research, conducted currently in a number of academic and industrial scientific centers. However, weak polymer matrix/filler interactions, common in biocomposites, result in unsatisfactory mechanical properties, which limit their practical applications. From many attempts performed to solve this problem, in-situ...
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OSC - domain oriented ontology creation system
PublicationOntologies are, as part of semantic web, a basic component to enrich content available in the Internet with a meaning understandable for computers. In this publication an architecture and functionality of a domain oriented web portal for collaborative creation and storage of ontologies is presented. The system is being created by Gdańsk University of Technology Electronics, Telecommunications and Informatics faculty's Department...
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Technical diagnostics and monitoring of traction current collectors
PublicationNew evaluation methods of the technical condition of rolling stock current collectors are proposed in this paper. The method of automatic measurement of the pantograph static force characteristic, realized when the vehicle runs through the test section of the track with especially prepared overhead line height distribution, has been practically implemented by the Polish Railways. The method of testing the slipper spring suspension...
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Metal salts reduction during parylenes polymerization
PublicationPublikacja o wynikach obliczeń kwantowych o możliwości redukcji niektórych soli metali przy pomocy rodników parylenu w czasie jego polimeryzacji.
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The Large Customer Reactive Power Control Possibilities
Publicationn this paper the authors wish to draw attention to the rationale for, and the possibility of, the use of local reactive power sources by the Transmission Node Master Controller (TNMC). Large Customers (LC) are one of the possible reactive power sources. The paper presents the issues related to the need for coordination between the control systems installed in the LC network, and coordination between control systems of the LC as...
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Reduction of Inrush Current by Demagnetization of Magnetic Core
PublicationW artykule przedstawiono demagnetyzację rdzenia transformatora jako metodę ograniczania prądu załączeniowego. W zaproponowanej metodzie źródłem energii wykorzystywanej do rozmagnesowania jest kondensator. W przeprowadzonych obliczeniach symulacyjnych rozważono różne wartości pojemności kondensatora i wartości napięcia w celu określenia optymalnych wartości tych parametrów. Następnie obliczono strumienie szczątkowe, jakie ustalają...
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Thermohydraulic maldistribution reduction in mini heat exchangers
PublicationA detailed numerical investigation has been carried out to analyze the flow maldistribution in 50 parallel 1 mm × 1 mm rectangular minichannels and 1 mm depth minigap section with rectangular, trapezoidal, triangular or concave manifolds in Z-type flow configuration. The working medium was ethanol and the mass flow rate was 5 × 10−4 kg/s. Both sections were heated from the bottom side. Heat flux of 10 000 W/m2 and 5000 W/m2 was...
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Experiences and Challenges in Fatality Reduction on Polish Roads
PublicationAccording to the UN, road safety is the key to achieving sustainable development goals, yet the complexity of how road accidents happen makes this a difficult challenge leaving many countries struggling with the problem. For years, Poland has infamously been one of the EU’s top countries for road-accident fatality rates. Despite that, it has made significant progress in the last thirty years with a fatality reduction of more than...
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Reactive Processing and Functionalization of Ground Tire Rubber
PublicationThe dynamic development of the automotive industry resulted in a sig- nificant increase in rubber wastes, especially end-of-life tires, which are a serious threat to the natural environment and human health. This situation has enforced the industry and academic research groups to search new and cost-effective methods for recycling waste tires. In this field of research, reactive processing and functionaliza- tion seem to be a...
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Reduction of steel chimney vibrations with a pendlum damper.
PublicationKarman vortices observed around chimneys may induce dangerous structural vi-brations at certain wind velocities. The aim of this paper is to analyse theeffectiveness of pendulum damper in vibration reduction of a steel chimney. A two degree-of-freedom system is used to model the behaviour of the struc-ture equipped with a damper. The results of the study show that the use of pendulum with tuned frequency leads to significant...
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The time dependence of pit creation impedance spectra.
PublicationPrzeprowadzono pomiar impedancyjny w warunkach chronoamperometrycznych uzyskując zmiany impedancji układu w czasie. Na ich podstawie wyznaczono zmiany rezystancji przeniesienia ładunku i pojemności w czasie opisujące inicjację i rozwój korozji wżerowej. Potwierdzono użyteczność dynamicznej elektrochemicznej spektroskopii impedancyjnej w badaniu korozji wżerowej.
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Wow defect reduction based on interpolation techniques
PublicationW referacie przedstawiono wyniki badania różnych technik interpolacji wykorzystanych w redukcji kołysania dźwięku. W badaniach użyto: interpolację liniową, dwie techniki interpolacji wielomianowej (Hermite i spline), i technikę sumowania okienkowanych funkcji sink. Jakość rekonstrukcji wykonano wykorzystując sztucznie spreparowany sygnał audio, rekonstruowany wymienionymi metodami interpolacji. Jakość rekonstrukcji oceniono wykorzystując...
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The effect of a polyharmonic structure of the perturbation signal on the results of harmonic analysis of the current of a first-order electrode reaction
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The fixed state in impedance measurements of a two-step electrode reaction proceeding with accompanying adsorption of an intermediate product
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Proton transfer reaction from some C–H acids to N-bases in polar aprotic solvents
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Chemical-vapor generation of transition metals through the reaction with tetrahydroborate in recent achievements in analytical atomic spectrometry
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Toward an Understanding of the Chemiluminescence Accompanying the Reaction of 9-Carboxy-10-methylacridinium Phenyl Ester with Hydrogen Peroxide
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Phosphorus modified hollow, porous Nickel-Cobalt oxides nanocubes with heterostructure for oxygen evolution reaction in alkaline
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Effect of preparation conditions and promoters on the structure and activity of the ammonia decomposition reaction catalyst based on nanocrystalline cobalt
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The role of aluminium in metal–organic frameworks derived carbon doped with cobalt in electrocatalytic oxygen evolution reaction
PublicationWater electrolysis is one of the most crucial processes in the development of new energy sources, where ultra-clean fuel is produced - hydrogen. Oxygen evolution reaction (OER) is the sluggish process of overall water splitting. Therefore, this study presents the design, characterization and electrochemical study of cobalt-based electrocatalysts embedded into porous carbons derived from an Al-metal–organic...
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The effect of the iron oxidation degree on distribution of promotors in the fused catalyst precursors and their activity in the ammonia synthesis reaction
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Real-Time Monnitoring of Vegetable Oils' Thermal Degradation Using Proton Transfer Reaction Mass Spectrometry
PublicationThe volatile aldehydes, which are generated during frying, can be harmful to human health, therefore the concentration of these compounds in frying fumes should be monitored. In addition, aldehydes are markers of oils’ quality, and so it is possible to determine shelf-life or suitability for frying of these oils. Commonly, in order to determine aldehydes concentration gas chromatography is performed, however it does not allow for...
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Glutathione-mediated conjugation of anticancer drugs: an overview of reaction mechanisms and biological significance for drug detoxification and bioactivation.
PublicationThe effectiveness of many anticancer drugs depends on the creation of specific metabolites that may alter their therapeutic or toxic properties. One significant route of biotransformation is a conjugation of electrophilic compounds with reduced glutathione, which can be non-enzymatic and/or catalyzed by glutathione-dependent enzymes. Glutathione usually combines with anticancer drugs and/or their metabolites to form more polar...
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Tailoring a low-energy ball milled MnCo2O4 spinel catalyst to boost oxygen evolution reaction performance
PublicationThe development of cost-efficient oxygen evolution reaction (OER) catalysts is one of the most important tasks facing modern techniques for hydrogen production. In this work, for the first time, a low-energy ball milling process of MnCo2O4 (MCO) spinel powders, with a mechanical modification time exceeding 1 day was used. After 6 days of ball-milling, the obtained overpotential of the electrocatalyst reached the value of 375 mV...