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Search results for: POLYPYRIDINE COMPLEXES
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Synthesis, structure, DNA binding and anticancer activity of mixed ligand ruthenium(II) complex
PublicationIn order to obtain a potential chemotherapeutic which is not affected on the normal BALB/3T3 cell line, a new arene ruthenium(II) complex {[RuCl(L1)(η6-p-cymene)]PF6}2 · H2O has been synthesized by a direct reaction of precursor, [{(η6-p-cymene)Ru(μ-Cl)}2Cl2], with N,N-chelating ligand (L1 - 2,2′-bis(4,5-dimethylimidazole). The compound has been fully characterized by elemental analysis, X-ray diffraction, IR, UV–Vis and 1H, 13C...
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Simplified Map-based Selection of Optimal Spindle Speeds When Milling Complex Structures
PublicationIn the paper a method for selecting optimal spindle speeds for complex structures during milling operations is presented. It is based on the selection of the spindle speed in accordance with a simple equation resulting from the minimisation of vibration energy, which leads to the minimisation of the work of cut-ting forces presented in previous elaborations by the authors [1]. Optimal spindle speeds are obtained for many points...
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Advances in Architectures, Big Data, and Machine Learning Techniques for Complex Internet of Things Systems
PublicationTe feld of Big Data is rapidly developing with a lot of ongoing research, which will likely continue to expand in the future. A crucial part of this is Knowledge Discovery from Data (KDD), also known as the Knowledge Discovery Process (KDP). Tis process is a very complex procedure, and for that reason it is essential to divide it into several steps (Figure 1). Some authors use fve steps to describe this procedure, whereas others...
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Multi-Criteria Knowledge-Based Recommender System for Decision Support in Complex Business Processes
PublicationIn this paper, we present a concept of a multi-criteria knowledge-based Recommender System (RS) designed to provide decision support in complex business process (BP) scenarios. The developed approach is based on the knowledge aspects of Stylistic Patterns, Business Sentiment and Decision-Making Logic extracted from the BP unstructured texts. This knowledge serves as an input for a multi-criteria RS algorithm. The output is prediction...
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Transcriptome sequencing of Brassica napus highlights the complex issues with soil supplementation with sewage sludge
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ARUZ — Large-scale, massively parallel FPGA-based analyzer of real complex systems
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Post-Activation Performance Enhancement: Save Time With Active Intra-Complex Recovery Intervals
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A new pitch shifter based on complex instantaneous frequency rescaling and direct digital synthesis
PublicationZaproponowano nową metodę zmiany wysokości dźwięku za pośrednictwem skalowania zespolonej częstotliwości chwilowej i na podstawie cyfrowej syntezy bezpośredniej. Zaprezentowano schematy blokowe opracowanych algorytmów. Pracę zilustrowano przykładem syntezy sygnału wywoławczego (''dzwonka'' telefonicznego), gdzie dźwięki poszczególnych nut generowanej melodii uzyskano na podstawie naturalnego sygnału - pojedynczego świergotu o widmie...
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Determination of Complex Permeability of Silicon Steel for Use in High-Frequency Modeling of Power Transformers
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Influence of hydrophobic nanosilica and hydrophobic medium on water bound in hydrophilic components of complex systems
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Road traffic can be predicted by machine learning equally effectively as by complex microscopic model
PublicationSince high-quality real data acquired from selected road sections are not always available, a traffic control solution can use data from software traffic simulators working offline. The results show that in contrast to microscopic traffic simulation, the algorithms employing neural networks can work in real-time, so they can be used, among others, to determine the speed displayed on variable message road signs. This paper describes...
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Greening procedures and analytical parameters. The polychlorinated naphthalenes analysis in complex matrices as proof of concept
PublicationDue to the complexity of analytical procedures employed for the determination of wide spectrum of persistent organic pollutants (POPs), it is important to consider the green character of the applied protocols and propose the greenest solutions. In this review, the green aspects of several analytical procedures used for the determination of polychlorinated naphthalenes (PCNs) (as a representatives of POPs) in different types of...
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Comprehensive two-dimensional gas chromatography - promising technique for analysis of complex food matrices
PublicationThe present paper is focused on brief description of operational principle of comprehensive two-dimensional gas chromatography (GC×GC) technique, instrumentation and data processing. Furthermore, the examples of application in the field of food analysis, performed also in the author's laboratory, are given. The detailed discussion of GC×GC characterization and comparison of the volatile composition of berries of different blue...
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Networked Object Monitor - A distributed system for monitoring, diagnostics and control of complex industrial facilities
PublicationRozwój mobilności i technologii internetowych, a także globalizacji gospodarki światowej, uwzględniający kluczowe aspekty zarządzania przepływem informacji, otworzył zupełnie nowe możliwości opracowywania i konstruowania innowacyjnych rozwiązań technicznych. Z taką myślą powstał prototyp Sieciowego Monitora Obiektu, aplikacji umożliwiającej nie tylko ciągłą kontrolę parametrów obiektów przemysłowych i biznesowych, ale również zarządzanie...
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The partial-order tree: a new structure for indexing on complex attributes in object-oriented databases
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Large electric field effects on photoluminescence of organic Eu3+ complex-based electroluminescent emitters
PublicationW pracy zaobserwowano silne wygaszenie fotoluminescencji pod wpływem zewnętrznego pola elektrycznego w organicznym kompleksie europu Eu(III). Wygaszenie fotoluminescencji przypisano elektrycznopolowej dysocjacji ekscytonów oraz anihilacji ekscytonów na wstrzykniętym do próbki ładunku elektrycznym.
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Nested Space Mapping Technique for Design and Optimization of Complex Microwave Structures with Enhanced Functionality
PublicationIn this work, we discuss a robust simulation-driven methodology for rapid and reliable design of complex microwave/RF circuits with enhanced functionality. Our approach exploits nested space mapping (NSM) technology, which is dedicated to expedite simulation-driven design optimization of computationally demanding microwave structures with complex topologies. The enhanced func-tionality of the developed circuits is achieved by means...
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Rheological Characteristics of Novel Meloxicam-Loaded Complex Organogels Based on Fumed Silica and Poloxamer
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Improved magnitude estimation of complex numbers using alpha max and beta min algorithm
PublicationThe paper presents an improved algorithm for calculating the magnitude of complex numbers. This problem, which is a special case of square rooting, occurs for example, in FFT processors and complex FIR filters. The proposed method of magnitude calculation makes use of the modified alpha max and beta min algorithm. The improved version of the algorithm allows to control the maximum magnitude approximation error by using an adequate...
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Evaluation of propagation parameters of open guiding structures with the use of complex root finding algorithms
PublicationAn efficient complex root tracing algorithm is utilized for the investigation of electromagnetic wave propagation in open guiding structures. The dispersion characteristics of propagated and leaky waves are calculated for a couple of chosen waveguides. The efficiency of the root tracing algorithm is discuses and compared to a global root finding algorithm.
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Modeling of Electrified Transportation Systems Featuring Multiple Vehicles and Complex Power Supply Layout
PublicationThe paper proposes a novel approach to modeling electrified transportation systems. The proposed solution reflects the mechanical dynamics of vehicles as well as the distribution and losses of electric supply. Moreover, energy conversion losses between the mechanical and electrical subsystems and their bilateral influences are included. Such a complete model makes it possible to replicate, e.g., the impact of voltage drops on vehicle...
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Study on Polymer Elements for Mitigation of Earthquake-Induced Pounding Between Buildings in Complex Arrangements
PublicationPounding between neighboring structures during seismic events has been revealed as one of the most commonly observed reasons for severe damage or even total collapse of the adjacent buildings. Therefore, pounding effects have recently become an issue of great interest of many numerical and experimental investigations in many earthquake-prone regions of the world. It has also been observed that the differences in dynamic characteristics...
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Multimodal Particle Swarm Optimization with Phase Analysis to Solve Complex Equations of Electromagnetic Analysis
PublicationIn this paper, a new meta-heuristic method of finding roots and poles of a complex function of a complex variable is presented. The algorithm combines an efficient space exploration provided by the particle swarm optimization (PSO) and the classification of root and pole occurrences based on the phase analysis of the complex function. The method initially generates two uniformly distributed populations of particles on the complex...
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New “one‐pot” Pd(II) and Zn(II) complexes of Schiff bases, derivatives of 1‐amino‐1‐deoxy‐d‐sorbitol: Spectroscopic studies and biological and catalytic activities
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Two isomorphic ZnII/CoII complexes with tri-tert-butoxysilanethiol and histamine, and (4-hydroxymethyl-1H-imidazole-κN)bis(tri-tert-butoxysilanethiolato-κ2O,S)zinc(II)
PublicationOtrzymano dwa izomorficzne kompleksy cynku(II) i kobaltu(II) z tri-tert-butoksysilanotiolem i histaminą oraz kompleks cynku(II) z tri-tert-butoksysilanotiolem i 4(5)-hydroksymetyloimidazolem. Scharakteryzowano strukturę otrzymanych kompleksów w ciele stałym.
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The first manganese trialkoxysilanethiolates: formation, properties and structure of solvent ligated complexes - [Mn{SSi(OBut)3}2(MeCN)] and [Mn{SSi(OBut)3}2(MeOH)4]
PublicationW pracy przedstawiono otrzymywanie i strukturę pierwszych trialkoksysilanotiolanowych kompleksów manganu(II). Syntezy prowadzone były reakcji 2≡SiSH+ MnCl2 + 2Et3N = (≡SiS)2Mn + 2Et3N.HCl doprowadziły do otrzymania nowych kompleksów: [Mn{SSi(OBut)3}2(MeOH)4] (gdy jako rozpuszczalnik zastosowano MeOH) oraz [Mn{SSi(OBut)3}2(NCCH3)], gdy w badaniach posłużono się acetonitrylem.
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Predictors of complete remission of type 2 diabetes in patients over 65 years of age – a multicenter study
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Incorporation of the complete ammonia oxidation (comammox) process for modeling nitrification in suspended growth wastewater treatment systems
PublicationThe newly discovered process complete ammonia oxidation (comammox) has changed the traditional under-standing of nitrification. In this study, three possible concepts of comammox were developed and incorporated as part of an extended two-step nitrification model. For model calibration and validation, two series of long-term biomass washout experiments were carried out at 12 ◦C and 20 ◦C in a laboratory sequencing batch reactor....
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Main complications connected with detection, identification and determination of trace organic constituents in complex matrix samples
PublicationIt is well known that some problems with the determination of organic analytes at trace level can occur. This issue is connected with contamination during each stage of the analytical procedure from sampling to sample preparation up to chromatographic analysis, which often leads to false-positive or overestimated results. Another problem associated with determination of analytes occurs at trace- and ultra-trace level is a background...
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Uncertainty of antioxidant profiling in complex mixtures using liquid chromatography involving post-column derivatisation
PublicationThe main goal of this paper is to discuss the problems associated with antioxidant profiling in complex samples using a high-throughput HPLC system coupled with post-column derivatisation reactor. Based on the experimental data reported in the literature, we demonstrated that improper optimisation of temperature and/or pH assay conditions performed using an on-line derivatisation reactor may substantially change the antioxidant...
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Global Complex Roots and Poles Finding Algorithm Based on Phase Analysis for Propagation and Radiation Problems
PublicationA flexible and effective algorithm for complex roots and poles finding is presented. A wide class of analytic functions can be analyzed, and any arbitrarily shaped search region can be considered. The method is very simple and intuitive. It is based on sampling a function at the nodes of a regular mesh, and on the analysis of the function phase. As a result, a set of candidate regions is created and then the roots/poles are verified...
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New achievements in the field of extraction of trace analytes from samples characterized by complex composition of the matrix
PublicationWithout any doubt, the monitoring of compounds present in samples at trace or ultra-trace level usually requires a preliminary step of isolation and/or enrichment of analytes due to the fact that majority of analytical techniques are not sensitive enough for direct determination of trace compounds. On the other hand, sample preparation is considered as crucial part of whole analytical procedures, in particular in samples characterized...
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Isostructural zinc and cadmium silanethiolates with bridging biimidazole co-ligands – Enhanced luminescence of zinc complex
PublicationTwo dinuclear complexes of zinc and cadmium with silanethiolate and bridging biimidazole ligands are characterized by X-ray diffraction, FT-IR, UV–Vis and emission spectroscopies. The complexes 1 (Zn) and 2 (Cd) are isostructural but exhibit different electronic structures and different character of frontier HOMO orbitals as indicated by DFT calculations. Lluminescence studies prove strong emission properties of zinc complex.
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An investigation on the chemistry of the R2P=P ligand: reactions of a phosphanylphosphinidene complex of tungsten(VI) with electrophilic reagents
PublicationThe nucleophilic properties of the title compound [(2,6-i-Pr2C6H3N)2(Cl)W(η2-t-Bu2PvP)]Li·3DME (1) were investigated in reactions with selected electrophilic reagents such as MeI, M(CO)5THF (M = Cr, Mo, W), AlCl3, and GaCl3. Methylation of 1 by MeI yields phosphanylphosphido complexes [(2,6-i-Pr2C6H3N)2W(X)(1,2-η-t-Bu2PvP–CH3)] (X = Cl, I) (2-Cl/2-I) with the formation of a new P–C bond. Moreover, 1 reacts with electrophilic compounds...
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Green Therapy w projektowaniu ośrodków medycznych Green Therapy in complex design of health centres
PublicationKoncepcja przestrzenna ogrodu terapeutycznego podporządkowana jest generalnej idei otwierania się projektantów na poszukiwanie nowych możliwości poprawy samopoczucia odbiorcy - poprzez zapewnienie użytkownikom poczucia bezpieczeństwa, komfortu i odprężenia, harmonii. Dotyczy to nie tylko grupy osób chorych, które dręczone są przez niepokoje i napięcia wywołane przez niepełnosprawność czy chorobę, ale także pacjentów w różnym wieku...
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Evaluation of the possibility of identifying a complex polygonal tram track layout using multiple satellite measurements
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Poly(amidoamine) Dendrimer/Camptothecin Complex: From Synthesis to In Vitro Cancer Cell Line Studies
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Molecular dynamics simulation and MM-PBSA analysis of Oxytricha nova TEBP ternary complex with ssDNA
PublicationPraca dotyczy badań metodami chemii obliczeniowej właściwości elektrostatycznych i termodynamicznych kompleksu telomerowego białka TEBP pochodzącego z organizmu Oxytricha z jednoniciowym telomerowym DNA (ssDNA).
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Adsorption of a metalorganic complex at a metal surface: A density functional theory study vs. model description
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A total scoring system and software for complex modified GAPI (ComplexMoGAPI) application in the assessment of method greenness
PublicationEvaluating analytical methods with innovative metrics is essential to ensure the effectiveness of analytical procedures. Various approaches have been proposed to assess the performance of an analytical method and its environmental consequences, as sustainable environment and green chemistry ideology are of high importance nowadays. Considering greenness evaluation of developed analytical procedures, Green Analytical Procedure Index...
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SERRATE interacts with the nuclear exosome targeting (NEXT) complex to degrade primary miRNA precursors in Arabidopsis
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Visualizing the macroscale spatial distributions of biofilms in complex flow channels using industrial computed tomography
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<title>Multi-cavity complex controller with vector simulator for TESLA technology linear accelerator</title>
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Evaluation of the Possibility of Identifying a Complex Polygonal Tram Track Layout Using Multiple Satellite Measurements
PublicationWe present the main assumptions about the algorithmization of the analysis of measurement data recorded in mobile satellite measurements. The research team from the Gda´nsk University of Technology and the Maritime University in Gdynia, as part of a research project conducted in cooperation with PKP PLK (Polish Railway Infrastructure Manager), developed algorithms supporting the identification and assessment of track axis layout....
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Evaluation of the Possibility of Identifying a Complex Polygonal Tram Track Layout Using Multiple Satellite Measurements
PublicationWe present the main assumptions about the algorithmization of the analysis of measurement data recorded in mobile satellite measurements. The research team from the Gda´nsk University of Technology and the Maritime University in Gdynia, as part of a research project conducted in cooperation with PKP PLK (Polish Railway Infrastructure Manager), developed algorithms supporting the identification and assessment of track axis layout....
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Port Cities within Port Regions: Shaping Complex Urban Environments in Gdańsk Bay, Poland
PublicationPort cities located within various metropolitan or functional regions face very different development scenarios. This applies not only to entire municipalities but also to particular areas that play important roles in urban development—including ports as well as their specialized parts. This refers also to the various types of maritime industries, including the processing of goods, logistics operations, shipbuilding, or ship repairing,...
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Behavior Based Complete Coverage Task of Unknown Area by an Autonomous Mobile Robot SCORPION with Static Obstacles in Environment
PublicationIn the paper the behavior based control system of an autonomous mobile robot SCORPION is presented to execute the one of the most difficult navigation task, which is the complete coverage task of unknown area with static obstacles in the environment. The main principle assumed to design control system was that the robot should cover all area only once, if it possible, to optimize the length of path and energy consumption. All commercial...
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Long-Term Follow-Up after Laparoscopic Uterovestibular Anastomosis in Patients with Cervical Atresia and Complete Absence of the Vagina
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Complete Mesogastric Excisions Involving Anatomically Based Concepts and Embryological-Based Surgeries: Current Knowledge and Future Challenges
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Body fat, energy balance and estradiol levels: a study based on hormonal profiles from complete menstrual cycles
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