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Search results for: STEARIC ACID
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Targeting mTORs by omega-3 fatty acids: A possible novel therapeutic strategy for neurodegeneration?
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Interactions of telomeric proteins with nucleic acids: sequence recognition on intact and oxidatively damaged telomeres
PublicationTelomeres are complex nucleoprotein assemblies that play a vital role in the maintenance of functional ends of linear chromosomes. Telomeric DNA, composed of tandem repeats of the 5'-TTAGGG-3' motif, solves the so-called end replication problem: as chromosomes shorten with each cell division, no information is lost, and the telomere can be re-extended. In the cell, many protein factors regulate telomere length, nuclear positioning...
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Optical activity of the guest azobenzene molecule generated by inclusion complexation with steroidal bile acids.
PublicationZsyntetyzowano krystaliczne kompleksy inkluzyjne azobenzenu z kwasami cholowym i deoksycholowym. Otrzymane związki inkluzyjne poddano badaniom przy wykorzystaniu spektroskopii dichroizmu kołowego w fazie stałej (KBr). Dodatni efekt Cottona, odpowiadający niskoenergetycznemu przejściu elektronowemu n-pi*, skorelowano z helikalnością M,M skręconej cząsteczki azobenzenu. Ponadto w celach porównawczych zmierzono dichroizm kołowy w...
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Biorefinery Approach for H2 and Acids Production Based on Uncontrolled pH Fermentation of an Industrial Effluent
PublicationIn this work, the feasibility of uncontrolled pH acidogenic fermentation of industrial organic effluent from corn-bioethanol production was studied and modelled by using a Monod-based mathematical model. In order to do that, several tests were carried out at different initial pH values, ranging from 4 to 6. The experimental data showed a pH reduction during the fermentation process due to the generation of short-chain acids. When...
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Microscopic Imaging to Visualize the Distribution of Dietary Nucleic Acids in Food Products of Various Origins
PublicationDietary nucleic acids (dietNAs) are being increasingly recognized as important food components with nutritional value. However, the precise dietary recommendations for dietNAs are limited, because established methods for determining the quantity and nutritional role of dietNAs are still lacking. One of the tools to narrow this gap could be microscopic imaging, as a convenient approach to visualize the abundance and distribution...
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An improved preparation of N2-tert-butoxycarbonyl- and N2-benzyloxycarbonyl-(S)-2,4-diaminobutanoic acids.
PublicationN-Benzyloksykarbonylo i N-tert-butoksykarbonylo-(S)-asparaginę przekształcono do odpowiednio chronionego kwasu (S)-2,4-diaminobutanowego z dobrą wydajnością, w reakcji z octanem jodobenzenu w temp. 0 st.C w mieszaninie tetrahydrofuranu i wody.
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State aid for entrepreneurs at special economic zones
Open Research DataThe dataset encompasses a choice of important legal acts, a list of selected Polish bibliography and a list of important individual sentences issued on the topic of state aid for entreprenuers investing at special economic zones. Thanks to that the reader gets the possibility do acquire basic knowledge on the above mentioned topic.
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A concept of using static gps masurements for determination of vertical and horizontal land deformations in the main and old city of Gdańsk
PublicationArtykuł opisuje koncepcję wykorzystania statycznych pomiarów GPS (stacje GPS) przy analizie przemieszczeń gruntu na terenie Głównego i Starego Miasta w Gdańsku.
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Behavior Based Complete Coverage Task of Unknown Area by an Autonomous Mobile Robot SCORPION with Static Obstacles in Environment
PublicationIn the paper the behavior based control system of an autonomous mobile robot SCORPION is presented to execute the one of the most difficult navigation task, which is the complete coverage task of unknown area with static obstacles in the environment. The main principle assumed to design control system was that the robot should cover all area only once, if it possible, to optimize the length of path and energy consumption. All commercial...
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Effect of Compounding Conditions on Static and Dynamic Mechanical Properties of High Density Polyethylene/Ground Tire Rubber Blends
PublicationSearching for new and cost-effective methods of waste rubber recycling is a subject of research in many scientific centers in the world. In this paper there are presented results of the research of the extrusion process of cheap and environmentally friendly thermoplastic compositions containing 50 % wt. of masses of ground tire rubber (GTR). The aim of this study was to determine the relationship between the mixing conditions and...
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Reactive oxygen species (ROS) production in human peripheral blood neutrophils exposedin vitroto static magnetic field
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Distributed System for Monitoring of the Large Scale Infrastructure Structures Based on Analysis of Changes of its Static and Dynamic Properties
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A non-quasi-static-signal MOSFET model for radio and microware frequencies including spreading gate resistances and capacitaces.
PublicationZaprezentowano nowy, spójny fizycznie nie-quasi-statyczny model małosygnałowy tranzystora MOS słuszny od 0 Hz aż do częstotliwości mikrofalowych. Scharakteryzowano właściwości nowego czterokońcówkowego modelu. Model został zweryfikowany eksperymentalnie aż do częstotliwości 27 GHz.
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Simulation of static response of thin walled bars with changed design parameters by means of second order sensitivity analysis.
PublicationZa pomocą analizy wrażliwości drugiego rzędu wyznaczono przybliżone wartości sił wewnętrznych i przemieszczeń pręta cienkościennego dla zmieniających się parametrów projektowych. W przykładzie numerycznym wyznaczono pierwszą i drugą wariację bimomentu w funkcji grubości półek skręcanego dwuteownika. Zbadano dokładność rozwiązania uzyskanego za pomocą analizy wrażliwości z rozwiązaniem ścisłym.
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Modelling of shear zones during quasi-static granular silo flow using material point method (MPM)
PublicationThe paper focuses on confined silo flow of cohesionless sand. The problem considered is a quasi-static flow in a plane strain model silo with parallel walls simulated with the material point method (MPM). The simulation used a non-local hypoplastic constitutive model. Initially, the paper validated the implemented numerical approach with basic element tests and a plane strain compression test. The subsequent MPM calculations for...
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Study of the influence of medium composition on motility and aggregation of recombinant Escherichia coli strain BL21(DE3)/pCC90 Dra D-mut-M9 + 0.5% cassaminic acids, M9 + 0.5% cassaminic acids + 0.2% glucose, M9 + 0.5% cassaminic acids + 0.5% glucose
Open Research DataMicrobial motility is a fundamental aspect of many microbial life cycles and is a key survival mechanism that enables microorganisms to navigate diverse and dynamic environmental conditions. This phenomenon becomes particularly important in response to changes in stimuli in time and space. The following experiment aimed to investigate how the composition...
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Introduction of non-natural amino acid residues into the substrate-specific P1 position of trypsin inhibitor SFTI-1 yields potent chymotrypsin and cathepsin G inhibitors
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New chromogenic substrates of human neutrophil cathepsin G containing non-natural aromatic amino acid residues in position P1 selected by combinatorial chemistry methods
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Density, sound velocity, viscosity, and refractive index of new morpholinium ionic liquids with amino acid-based anions: Effect of temperature, alkyl chain length, and anion
PublicationIn this work, room temperature synthesis of twenty new ionic liquids (ILs) based on the N-alkyl-N-methylmorpholinium ([Mor1,R], R = 2, 3, 4, 6, 8) cation and N-acetyl-L-amino acid anions (L-alaninate, L-valinate, L-leucinate, L-isoleucinate) was described. The synthesized ILs were characterized by various spectroscopic techniques and high-resolution mass spectrometry. Furthermore, density (ρ), sound velocity (v), viscosity (η)...
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The synthesis and biological activity of lipophilic derivatives of bicine conjugated with n3-(4-methoxyfumaroyl)-l-2,3-diaminopropanoic acid(fmdp) - an inhibitor of glucosamine-6-phosphate synthase
PublicationOtrzymano serię pochodnych bicyny połączonych z inhibitorem syntazy glukozamino-6-fosforanu (fmdp)oraz zbadano ich właściwości lipofilowe i aktywność przeciwgrzybową. otrzymane związki charakteryzowały się wyższą llipofilowością niż fmdp. wszystkie otrzymane związki wykazywały także wyższą aktywność przeciwgrzybową niż fmdp.
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Simple Physics-Based Analytical Formulas for the Potentials of Mean Force for the Interaction of Amino Acid Side Chains in Water. IV. Pairs of Different Hydrophobic Side Chains
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Modification of Rapana thomasiana hemocyanin with choline amino acid salts significantly enhances its antiproliferative activity against MCF-7 human breast cancer cells
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Optimization of submerged fermentation conditions for immunosuppressant mycophenolic acid production by Penicillium roqueforti isolated from blue-molded cheeses: enhanced production by ultraviolet and gamma irradiation
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Sensitive method for determination of benzoic acid in beverages and food samples using air–assisted hydrophobic deep eutectic solvent-based dispersive liquid-liquid microextraction
PublicationA simple, reliable and rapid air–assisted hydrophobic deep eutectic solvent-based dispersive liquid–liquid microextraction (AA-HDES-DLLME) was developed for analysis of benzoic acid in various beverages and food samples. The final determination stage was performed via UV–visible spectrophotometry. The key parameters (extraction time, HDES type and volume, dispersant volume, pH and sample volume) of the AA-HDES-DLLME method were...
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Stability investigation of the PCM nanocomposites
PublicationIn present study was showed the results of research the stability of nanoPCMs in terms of types and concentrations of surfactant used. For stearic acid has been added PVP or oleic acid in concentrations of 0%, 5% and 10%. Nanoparticles TiO2 and Al-2O3 in concentration of 1% were chosen to be researched in this test. The mixing of nanocomposites has been done in an ultrasonic scrubber in which the samples were placed for 45 mins....
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Peptide modification with thiomalonoamide moiety
PublicationAbstract: Meldrum acid derivatives under the thermal decomposition are well known source of ketenes. Recently we investigated chemical properties of thiocarbamolyl meldrum acids. We found that 5-(α-alkylamino- α'-sulfhydryl)methylene Meldrum's acids hated in the presence of amines produce thiomalonamides. We used this reaction to the one pot synthesis of series of short peptides containing thiomalonoamide motif.
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MSIS Image Postioning in Port Areas with the Aid of Comparative Navigation Methods
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Concept of Multicriteria Aid of Choice of Threshold Value IN Biometrical Authentication System
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Immersive Technologies that Aid Additive Manufacturing Processes in CBRN Defence Industry
PublicationTesting unique devices or their counterparts for CBRN (C-chemical, B-biological, R-radiological, N-nuclear) defense relies on additive manufacturing processes. Immersive technologies aid additive manufacturing. Their use not only helps understand the manufacturing processes, but also improves the design and quality of the products. This article aims to propose an approach to testing CBRN reconnaissance hand-held products developed...
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Studies on development of headspace - gas chromatographic determination of volatile fatty acids in troublesome environmental samples
PublicationBadania nad opracowaniem procedur oznaczania LKT w silnie zanieczyszczonych próbkach środowiskowych za pomocą techniki analizy fazy nadpowierzchniowej w połączeniu z chromatografią gazową z wykorzystaniem detektora płomieniowo-jonizacyjnego na etapie oznaczeń końcowych. Dobrano warunki ekstrakcji LKT do fazy nadpowierzchniowej oraz warunki chromatograficzne. Metodyka pozwala oznaczać LKT w bardzo skomplikowanych próbkach ciekłych...
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Determination of PAHs, PCBs, minerals, trace elements and fatty acids in Rapana thomasiana as an indication of pollution
PublicationW trakcie badań wykorzystano różne metodyki analityczne do oznaczania zawartości szerokiego spektrum składników (anality z grupy WWA i PCB), metali ciężkich i innych pierwiastków oraz kwasów tłuszczowych w próbkach tkanek miękkich mięczaków morskich pochodzących z miejsc o różnym poziomie antropopresji (obszary zanieczyszczone i niezanieczyszczone w bułgarskiej strefie przybrzeżnej Morza Czarnego).Analiza statystyczna uzyskanych...
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Fatty Acids Composition of Mustard Oil from Two Cultivars and Physico-chemical Characteristics of the Seeds
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On the origin of surface imposed anisotropic growth of salicylic and acetylsalicylic acids crystals during droplet evaporation
PublicationIn this paper droplet evaporative crystallization of salicylic acid (SA) and acetylsalicylic acid (ASA) crystals on different surfaces, such as glass, polyvinyl alcohol (PVA), and paraffin was studied. The obtained crystals were analyzed using powder X-ray diffraction (PXRD) technique. In order to better understand the effect of the surface on evaporative crystallization, crystals deposited on glass were scraped off. Moreover,...
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The influence of different acids and pepsin on the extractability of collagen from the skin of Baltic cod (Gadus morhua)
PublicationZastosowano 5,0 M roztwory kwasu cytrynowego, mlekowego, octowego oraz 0,115 M roztwór kwasu solnego. Kolagen z całych skór ekstrahowano w 4 st.C odpowiednimi kwasami (1 : 6, w/v) w czasie 24, 48 i 72 h. Stwierdzono, że kwas solny jest najmniej efektywnym rozpuszczalnikiem kolagenu spośród użytych kwasów. W zastosowanych warunkach doświadczeń maksymalnie można wyekstrahować kwasem cytrynowym 60 % kolagenu, kwasem octowym i mlekowym...
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The Physicochemical, Antioxidant, and Color Properties of Thin Films Based on Chitosan Modified by Different Phenolic Acids
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Diversity of Students’ Unethical Behaviors in Online Learning Amid COVID-19 Pandemic: An Exploratory Analysis
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Biofortification of Hens Eggs with Polyunsaturated Fatty Acids by New Dietary Formulation: Supercritical Microalgal Extract
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Spectral Characteristic and Preliminary Anticancer Activity in vitro of Selected Rhodanine‐3‐carboxylic Acids Derivatives
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The stereoselective formation of β-lactams with acyl ketenes generated from 5-acyl-Meldrum's acids
PublicationAcyl ketenes formed during thermal decompositions of 5-acyl-2,2-dimethyl-1,3-dioxa-4,6-diones undergo stereoselective [2+2] cycloaddition to chiral aldimines. We report the first example of optically active 3-acyl-β-lactams formation from Meldrum’s acid derivatives.
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The Toolbox of Methods for Multidirectional Characterization of Dietary Nucleic Acids; Verification for Raw and Processed Food Products
PublicationCurrently, the nutritional value of food is associated mainly with components such as proteins, carbohydrates, and lipids. However, another important macromolecules present in many foods are dietary nucleic acids (dietNA), i.e., DNA as well as both coding and non-coding RNAs. In the context of food chemistry and nutrition, dietNA are nowadays vastly neglected. In consequence, there are no dedicated methodologies to characterize...
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Esterification kinetics of glycerol with fatty acids in the presence of zinc carboxylates: Preparation of modified acylglycerol emulsifiers.
PublicationZbadano zależności kinetyczne estryfikacji glicerolu kwasami tłuszczowymi (C12:0 - C18:0), prowadzonych w obecności soli cynku tych kwasów tłuszczowych. Przeanalizowano wpływ temperatury, stężenia karboksylanu oraz budowy części hydrofobowej kwasu tłuszczowego i karboksylanu, na postęp reakcji estryfikacji. Wyznaczono wartości odpowiednich stałych szybkości reakcji, energii aktywacji oraz maksymalnej zawartości monoestru glicerolu,...
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Substituent effects on ^15N NMR chemical shifts in selected N-alkylthiohydroxamic acids. A comparative study
PublicationNa podstawie widm 15N NMR przeanalizowano wpływy podstawników wybranych kwasów tiohydroksamowych na przesunięcia chemiczne N-15. Analiza porównawcza z przesunięciami chemicznymi strukturalnie podobnych amidów, tioamidów i kwasów hydroksamowych pozwoliła na stwierdzenie, że nie zatłoczenie steryczne a grupa N-OH jest odpowiedzialna za osłabienie efektów odsłaniających zarówno podstawników bezpośrednio związanych z atomem azotu jak...
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Brewery spent grain valorization through fermentation: Targeting biohydrogen, carboxylic acids and methane production
PublicationThis study investigated three different fermentation approaches to explore the potential for producing biohydrogen, carboxylic acids, and methane from hydrolysates of thermally dilute acid pretreated brewer's spent grains (BSG). Initially, the research focused on maximizing the volumetric hydrogen production rate (HPR) in the continuous dark fermentation (DF) of BSG hydrolysates by varying the hydraulic retention time (HRT). The...
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The Physicochemical and Antibacterial Properties of Chitosan-Based Materials Modified with Phenolic Acids Irradiated by UVC Light
PublicationThis paper concerns the physicochemical properties of chitosan/phenolic acid thin films irradiated by ultraviolet radiation with wavelengths between 200 and 290 nm (UVC) light. We investigated the preparation and characterization of thin films based on chitosan (CTS) with tannic (TA), caffeic (CA) and ferulic acid (FA) addition as potential food‐packaging materials. Such materials were then exposed to the UVC light (254 nm) for...
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New reaction of dithiophosphoric acids with O-thioacylhydroxylamines. Nucleophilic substitution or single electron transfer process?
PublicationUdowodniono, że dipodstawione lub sterycznie przeszkodzone hydroksyloaminy reagują z przestrzennie rozbudowanymi S-tioacyloditiofosforanami dając odpowiednie O-tioacylohydroksyloaminy. Dalsza reakcja O-tioacylohydroksyloaminy z kwasem ditiofosforowym prowadzi do powstania disiarczku acylowo tiofosfo-rylowego oraz soli amoniowej kwasu ditiofosforowego. Wpływ pułapek rodnikowych na wydajność tej reakcji świadczy dobitnie, że w procesie...
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Correlation between in vitro and in vivo data on food digestion. What can we predict with static in vitro digestion models?
PublicationDuring the last decade, there has been a growing interest in understanding food's digestive fate in order to strengthen the possible effects of food on human health. Ideally, food digestion should be studied in vivo on humans but this is not always ethically and financially possible. Therefore, simple in vitro digestion models mimicking the gastrointestinal tract have been proposed as alternatives to in vivo experiments. Thus,...
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Screw displacement pile shaft deformations measured by vibrating wire and fiber optic systems during a static load test
PublicationThis paper describes a full scale static load test performed on a 400 mm diameter screw displacement pile equipped with four different strain measuring systems. Three types of vibrating wire strain gauges (VWSG) were used: global - retrievable, local attached to steel pipe and local concrete embedded. The fourth system was distributed fiber optic sensors based on Rayleigh back scattering (DFOS) - three in the pile cross section....
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Experimental study of the impact of notches and holes made in the front edge of adherends on the properties of static and fatigue strength of adhesive joints
PublicationThe paper presents the results of experimental studies aimed at determining the effect of holes and notches at the front edge of adherends on the strength of adhesive joints. Single-lap joints made of S235JR steel sheets joined with Araldite 2014-2 epoxy adhesive were tested. Comparative tests of static strength in the shear test as well as high-cycle fatigue strength tests were carried out. Joints with three holes with a diameter...
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INVESTIGATIONS OF QUASI-STATIC VORTEX-STRUCTURES IN 3D SAND SPECIMENS BASED ON DEM AND HELMHOLTZ-HODGE VECTOR FIELD DECOMPOSITION.
PublicationArtykuł omawia wyniki numeryczne dotyczące struktur wirowych w materiałach granulowanych w warunkach 3D. Obliczenia wykonano dla ściskania dwuosiowego. W symulacjach wykorzystano metodę elementów dyskretnych i dekompozycję pola wektorowego wg Helmholtza-Hodge’a Struktury wirowe okazały się znakomitym prekursorem lokalizacji odkształceń stycznych w materiałach granulowanych podczas obciążenia.
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Effect of free water on the quasi‑static compression behavior of partially‑saturated concrete with a fully coupled DEM/CFD approach.
PublicationThe work aims to numerically investigate the quasi-static response of partially fluid-saturated concrete under two-dimensional uniaxial compression at the mesoscale. We investigated how the impact of free pore fluid content (water and gas) affected the quasi-static strength of concrete. The totally and partially fluid-saturated concrete behavior was simulated using an improved pore-scale hydro-mechanical model based on DEM/CFD....