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Search results for: IDF FORMULAS
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Liquefaction of macroalgae Enteromorpha biomass for the preparation of biopolyols by using crude glycerol
PublicationThis article describes the liquefaction process of macroalgae Enteromorpha with the use of crude glycerol as a solvent and a reagent, aimed at obtaining of new bio-polyols, which are characterized with respect to their chemical structure, physical and thermal properties. Six different biopolyols were prepared. In order to optimize the liquefaction of algal biomass for the best bio-polyol properties, two catalysts (sulfuric or orthophosphoric...
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Performance properties of rigid polyurethane-polyisocyanurate/brewers’ spent grain foamed composites as function of isocyanate index
PublicationIn the presented work, rigid polyurethane-polyisocyanurate (PUR-PIR) foams filled with brewers’ spent grain (BSG) were prepared. The influence of the isocyanate index (II) on its performance was investigated. Foams obtained with higher isocyanate index required a higher amount of hydrofluorocarbon physical blowing agent to provide the same apparent density of material. An increase of isocyanate index resulted in a slight decrease...
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Morfologia, właściwości mechaniczne oraz palność spienionych materiałów poliuretanowo-poliglicerynowych modyfikowanych grafitem ekspandowanym
PublicationSpienione kompozyty poliuretanowo-glicerynowe modyfikowane grafitem ekspandowanymotrzymano metodą jednostopniową z układu dwukomponentowego, gdzie jako składnik poliolowyzastosowano odpadową poliglicerynę. Scharakteryzowano morfologię, właściwościmechaniczne oraz klasę palności otrzymanych materiałów. Uzyskane wyniki wskazują, żewprowadzenie poligliceryny do matrycy poliuretanowej umożliwia otrzymanie materiałówcharakteryzujących...
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Potential applications of crude glycerol in polymer technology–Current state and perspectives
PublicationThe increasing use of bio-based fuels and fuel additives, among them biodiesel, causes significant surplus of crude glycerol on the market which creates new challenges in terms of its sustainable utilization. A lot of ways for the incorporation of this by-product into different branches of industry requires purification by expensive and complicated processes. Therefore, researchers are seeking for applications of untreated crude...
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Processing and structure–property relationships of natural rubber/wheat bran biocomposites
PublicationIn this work, wheat bran was used as cellulosic filler in biocomposites based on natural rubber. The impact of wheat bran content [ranging from 10 to 50 parts per hundred rubber (phr)] on processing, structure, dynamic mechanical properties, thermal properties, physico-mechanical properties and morphology of resulting biocomposites was investigated. For better characterization of interfacial interactions between natural rubber...
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Biopolyols obtained via crude glycerol-based liquefaction of cellulose: their structural, rheological and thermal characterization
PublicationIn this work lignocellulose biomass liquefaction was used to produce biopolyols suitable for the manufacturing of rigid polyurethane foams. In order to better evaluate the mechanism of the process, pure cellulose was applied as a raw material. The effect of time and temperature on the effectiveness of liquefaction and the parameters of resulting biopolyols were characterized. The prepared materials were analyzed in terms of their...
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Injectable poloxamer/graphene oxide hydrogels with well‐controlled mechanical and rheological properties
PublicationAlthough significant progress has been made in the design and application of injectable hydrogels for biomedical applications, concurrent control of rheological and mechanical properties of injectable hydrogels has remained as an open challenge to the researchers. In this work, we introduce and put into practice a photo‐curable poloxamer (also known as Pluronic)/graphene oxide (Plu/GO) injectable hydrogel with well‐controlled rheological...
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Microwave treatment in waste rubber recycling – recent advances and limitations
PublicationEnvironmentally-friendly microwave heating is increasingly used in polymer chemistry and technology. The selectivity and highly efficiency in the heat transfer present a huge advantage in systems based on recycling, improving their productivity and economic competitiveness. In case of the industrial recycling of waste rubbers, especially end-of-life tires, microwave-induced devulcanization and pyrolysis are nowadays considered...
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Assessment of microstructure, physical and thermal properties of bitumen modified with LDPE/GTR/elastomer ternary blends
PublicationLDPE/GTR/elastomer ternary blends with variable LDPE/GTR ratio and constant elastomer content were prepared via melt-compounding. Obtained LDPE/GTR/elastomer blends were applied as thermoplastic modifiers into bitumen. Microstructure, physical and thermal properties of the modified bitumen were determined. It was observed that chemical composition of LDPE/GTR/elastomer blends has significant influence on their density and rheological...
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The study on application of biopolyols obtained by cellulose biomass liquefaction performed with crude glycerol for the synthesis of rigid polyurethane foams
PublicationIn this work rigid polyurethane foams (PUR) were obtained by replacement of 0–70 wt% of petrochemical polyol with bio-polyol obtained via cellulose liquefaction in presence of crude glycerol. The foams with different content of a bio-polyol were prepared by single step method for NCO/OH ratio equals 1.5. The prepared materials were analyzed in terms of their morphology, chemical structure, thermal stability and basic physical and...
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Reinforcing and plasticizing effects of reclaimed rubber on the vulcanization and properties of natural rubber
PublicationThe production of high-added value reclaimed rubber (RR) is of great signifi-cance for the sustainability of rubber industries. To green recycle waste rub-bers and broaden the application of RR, a RR material with potentialreinforcing and plasticizing effects on nature rubber (NR) composites are pre-pared by a thermo-oxidative reclamation process. The reclamation degree ofRR is controlled by adjusting the content of soybean oil....
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Assessment of the devulcanization process of EPDM waste from roofing systems by combined thermomechanical/microwave procedures
PublicationEthylene-propylene-diene rubber (EPDM) is a elastomer widely used in common industrial applications. EPDM can be shaped into sheets and employed as isolating material for roofing systems. In this study, scraps of EPDM from commercial, industrial and residential roofing systems were treated by combined thermo-mechanical and microwave devulcanization processes including peroxide of benzoyl (BPO). The devulcanized EPDM (Dev-EPDM)...
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THE IMPACT OF GROUND TIRE RUBBER TREATMENT ON THE THERMAL CONDUCTIVITY OF FLEXIBLE POLYURETHANE/GROUND TIRE RUBBER COMPOSITES
PublicationWaste car tires are burdensome waste, and their utilization is crucial for the natural environment. In many countries, the primary method of their recycling is energy recovery, performed by simple combustion. However, material recycling is much more effective and significantly more beneficial for the natural environment. It results in the generation of ground tire rubber, which can be used to produce polymerrubber composites. It...
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OIL-ASSISTED THERMO-MECHANICAL RECLAMATION OF GROUND TIRE RUBBER
PublicationNowadays, it is crucial to seek for the methods of by-products and waste utilization, considering both environmental and economic factors. The example of waste material generated in the massive amounts, which requires the attention is ground tire rubber generated during recycling of post-consumer car tires. It can be applied as a filler into different polymer matrices, but to enhance its effectivity proper modifications should...
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The Impact of Ground Tire Rubber Oxidation with H2O2 and KMnO4 on the Structure and Performance of Flexible Polyurethane/Ground Tire Rubber Composite Foams
PublicationThe use of waste tires is a very critical issue, considering their environmental and economic implications. One of the simplest and the least harmful methods is conversion of tires into ground tire rubber (GTR), which can be introduced into different polymer matrices as a filler. However, these applications often require proper modifications to provide compatibility with the polymer matrix. In this study, we examined the impact...
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DETERMINATION OF THE HYDROXYL NUMBER OF GROUND TIRE RUBBER PARTICLES VIA MODIFIED TEST METHOD FOR ISOCYANATE GROUPS
PublicationNowadays, considering the environmental trends and law regulations associated with the circular economy, it is very important to seek for the methods of by-products and waste utilization. The example of such material, which requires the attention and recycling method is ground tire rubber generated during recycling of post-consumer car tires. It can be introduced into various polymer matrices as a filler, but to enhance its effectivity...
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THERMOMECHANICAL PERFORMANCE OF FLEXIBLE POLYURETHANE FOAMS AS A FUNCTION OF THE ISOCYANATE INDEX
PublicationPolyurethane foams are very versatile materials applied in different branches of industry. Their popularity is attributed, among others, to the flexibility in engineering their mechanical performance by the adjustment of their formulations. One of the most crucial factors is the isocyanate index, determining the ratio between the free hydroxyl and isocyanate groups present in the polyurethane system. By the change of this ratio,...
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Mechanical Properties, Microstructure and Surface Quality of Polypropylene Green Composites as a Function of Sunflower Husk Waste Filler Particle Size and Content
PublicationAgricultural waste is a still untapped source of materials that can, in case of proper utilization, significantly improve the sustainability of polymers and their composites. In this work, polymer composites based on isotactic polypropylene were produced incorporating ground sunflower husk in the amount of 10 wt% and 20 wt%. The work’s main objective is to evaluate how preliminary fractioning of this agricultural waste filler affects...
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Recycling of Waste Rubber by the Manufacturing of Foamed Polyurethane-Based Composites—Current State and Perspectives
PublicationWorn car tires are disruptive waste, and the issue of their management is crucial for the natural environment. In many countries, the primary method of end-of-life tires utilization is energy recovery. However, more effective and beneficial for the environment is material recycling. Using them for the production of polymer-rubber composites seems to be an auspicious direction of research. Incorporation of ground tire rubber into...
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Enhanced aging resistance of poly(ε-caprolactone)/brewers’ spent grain composites
PublicationThe presented paper investigated the influence of brewers’ spent grain (BSG) extrusion pa-rameters on the photo-oxidative resistance of poly(ε-caprolactone)-based wood polymer composites. Filler samples characterized by the higher melanoidin content were more efficient in hindering of poly-mer degradation, inhibiting the decomposition of the polymer amorphous phase. As aresult, deteriora-tion of mechanical performance was limited,...
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Impact and stretching standardized tests as useful tools for assessment of viscoelastic behavior for highly rubberized asphalt binder
PublicationAsphalt binder is generally identified as a brittle material at low service temperature or under high-speed load, and the brittleness becomes serious after weathering aging. Improving the toughness of asphalt binder through adding high-content of crumb tire rubber is an efficient method to solve this problem. Devulcanized rubber modified asphalt binder (DRMA) with different contents (15–40%) of devulcanized rubber (DR) were prepared...
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Flame-Retardant Polymer Materials Developed by Reactive Extrusion: Present Status and Future Perspectives
PublicationThe development of flame retardant polymer materials has two roots, one in materials design, and the other in materials processing. Over recent decades, different types and classes of flame retardant polymer materials have been commercialized to meet safety requirements in the construction, automotive, and coatings industries. In the vast majority of cases, the design and fabrication of new materials presenting low fire hazards...
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Modified linear viscoelastic model of earthquake-induced structural pounding
PublicationIn recent times, earthquake-induced structural pounding has been intensively studied through the use of different impact force models. The numerical results obtained from the previous studies indicate that the linear viscoelastic model is relatively simple and accurate in modeling pounding-involved behavior of structures during earthquakes. The only shortcoming of the model is a negative value of the pounding force occurring just...
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Can Inflation Forecast and Monetary Policy Path be Really Useful? The Case of the Czech Republic
PublicationProducing and revealing inflation forecast is belie ved to be the best way of implementing a forward-looking monetary policy. The article focuses on inflation forecast targeting (IFT) at the Czech National Bank (CNB) in terms of its efficiency in shaping consumers’ inflation expectations. The goal of the study is to verify the accuracy of the inflation forecasts, and their influence on inflation...
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Seagrass vegetation and meiofauna enhance the bacterial abundance in the Baltic Sea sediments (Puck Bay)
PublicationThis study presents the first report on bacterial communities in the sediments of eelgrass (Zostera marina) meadows in the shallow southern Baltic Sea (Puck Bay). Total bacterial cell numbers (TBNs) and bacteria biomass (BBM) assessed with the use of epifluorescence microscope and Norland’s formula were compared between bare and vegetated sediments at two localities and in two sampling summer months. Significantly higher TBNs and...
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Exploring novel Cd(ii) complexes with 5-methyl-4-imidazolecarboxaldehyde: synthesis, structure, computational insights, and affinity to DNA through switchSense methodology
PublicationA series of four Cd(II) complexes with 5-methyl-4-imidazolecarboxaldehyde (L) with different inorganic anions within or outside the coordination sphere of general formula: [CdCl2 L2 ] (1), [CdBr2 L 2] (2), [CdI2L 2] (3), and [CdL4 ](PF6 )2 ·3H2 O (4) was synthesized through one-step and two-step reactions, respectively. All complexes were obtained as colorless crystals without the need for recrystallization and exhibited solubi- lity...
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Rapid Characterization of the Human Breast Milk Lipidome Using a Solid-Phase Microextraction and Liquid Chromatography-Mass Spectrometry-Based Approach.
PublicationHuman breast milk (HBM) is a biofluid consisting of various biomolecules such as proteins, lipids, carbohydrates, minerals and bioactive substances. Due to its unique and complex composition, HBM provides not only nutritional components required for the growth of the infant, but also additional protection against infections. Global insight into the composition of HBM is crucial to understanding the health benefits infants receive...
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Fe-modified Mn2CuO4 spinel oxides: coatings based on abundant elements for solid oxide cell interconnects
PublicationThe current state of the art steel interconnect coating materials are based on critical raw material - Co-oxide spinels. Replacing Co-oxide spinels with alternative, abundant materials can reduce the dependence on the critical raw materials. Cobalt-free coatings with the general formula Mn2-xCuFexO4, where x = 0, 0.1, 0.3, were electrophoretically deposited on a ferritic stainless-steel support and evaluated. Prior to deposition,...
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Multilayer coatings based on cerium oxide and manganese cobaltite spinel for Crofer22APU SOC interconnects
PublicationThe current state of the art steel interconnect coating materials are based on critical raw material - Co-oxide spinels. Replacing Co-oxide spinels with alternative, abundant materials can reduce the dependence on the critical raw materials. Cobalt-free coatings with the general formula Mn2-xCuFexO4, where x = 0, 0.1, 0.3, were electrophoretically deposited on a ferritic stainless-steel support and evaluated. Prior to deposition,...
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Grafika Inżynierska I, P, ZiIP sem 01, zimowy 2021/2022 (PG_ 00055730)
e-Learning CoursesZakres tematyczny projektów z przedmiotu Grafika Inżynierska I dla studentów kierunku Zarządzanie i Inżynieria Produkcji, I stopień, semestr 01
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Wstęp do technologii polimerów - 2021/2022
e-Learning CoursesKurs dla semestru IV kierunku Technologia Chemiczna Zarys technologii otrzymywania i przetwórstwa podstawowych tworzyw sztucznych
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Wstęp do technologii polimerów
e-Learning CoursesKurs dla semestru IV kierunku Technologia Chemiczna Zarys technologii otrzymywania i przetwórstwa podstawowych tworzyw sztucznych
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Recovery and re-use of photovoltaic solar cells from crystalline silicon
PublicationCrystalline silicon-type PV modules consist, in order of mass, of glass, an aluminium frame, an EVA coating, solar cells, a terminal box, back film and tapping screws. From the economic point of view, pure silicon, recoverable from spent cells, is the most important material owing to its cost and shortage. For crystalline, silicon-based PV cells, the following chemical treatments were performed: removal of the metal coating, followed...
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Extending loophole-free nonlocal correlations to arbitrarily large distances
PublicationQuantum theory allows spatially separated observers to share nonlocal correlations, which enable them to accomplish classically inconceivable information processing and cryptographic feats. However, the distances over which nonlocal correlations can be realized remain severely limited due to their high fragility to noise and high threshold detection efficiencies. To enable loophole- free nonlocality across large distances, we introduce...
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THE ESSENCE OF THE TRANSFORMATION OF SOCIO-ECONOMIC RELATIONS IN THE NATIONAL ECONOMY: THEORETICAL AND METHODOLOGICAL ASPECT
PublicationThe article is devoted to a thorough study of the theoretical and methodological foundations of the essence of the transformation of socio-economic relations of the national economy. Based on the study of scientific sources, a proper definition of the concept of "transformation of socio-economic relations" was formed. It is proposed to consider transformational processes from the point of view of their direct or indirect impact...
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Application of Diffusion Models in the Analysis of Financial Markets: Evidence on Exchange Traded Funds in Europe
PublicationExchange traded funds (ETFs) are financial innovations that may be considered as a part of the index financial instruments category, together with stock index derivatives. The aim of this paper is to explore the trajectories and formulates predictions regarding the spread of ETFs on the financial markets in six European countries. It demonstrates ETFs’ development trajectories with regard to stock index futures and options that...
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Tomasz Wąsowicz dr hab.
PeopleTomasz Wąsowicz's research was first related to high-resolution atomic spectroscopy and focused on measurements and analysis of the transition probabilities of the forbidden lines, the hyperfine and isotopic structure of spectral lines of heavy elements, Stark effect in the helium atom. Tomasz Wąsowicz currently studies physicochemical processes occurring during interactions of various forms of radiation with atoms and molecules...
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Structure elucidation of carbamoylo-β-lactam diastereoisomers by ROESY and NOESY experiments
PublicationRecently we have focused in the problem of preparation of carbamoylo-β-lactams as a result of oxidative cyclization of malonyl enamides. In our experiments we obtain mixture of two main β-lactam products: as a result of subsequent elimination and a second as a product of substitution. All of the produced β-lactams have trans configuration what was confirmed by 1H coupling constants. However id should be stressed that in the case...
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Uogólniona metoda agregacji w sensie AHP w analizie ryzyka systemów technicznych.
PublicationPrzedstawiono problematykę badawczą związaną z uwzględnieniem czynników wpływu w ocenie bezpieczeństwa oraz jakościowej i ilościowej analizie ryzyka systemów technicznych. Podkreśla się znaczenie oceny czynników środowiskowych, ludzkich i organizacyjnych w procesie analizy ryzyka i podejmowania decyzji. Proponowana metoda stosowania HID (hierarchical influence diagrams)wspomagająca analizę i szeregowanie opcji sterowania...
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Tradycyjne i nowoczesne kanały dystrybucji wykorzystywane w procesie świadczenia usług ubezpieczeniowych dojrzałym konsumentom
PublicationPrzedmiotem artykułu są usługi ubezpieczeniowe świadczone z wykorzystaniem tradycyjnych i nowoczesnych kanałów dystrybucji. W artykule skoncentrowano się na osobach powyżej 50 roku życia, szczególnie narażonych na zjawisko wykluczenia cyfrowego. Na podstawie przeglądu literatury sformułowano hipotezę badawczą: cechy społeczno – demograficzne osób powyżej 50 roku życia wpływają na ich skłonność do korzystania z usług ubezpieczeniowych...
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Nowoczesne metody termochemicznej konwersji biomasy w paliwa gazowe, ciekłe i stałe
PublicationWykorzystanie biomasy do produkcji ciepła w procesach bezpośredniego spalania lub współspalania z węglem, polegające na konwersji zawartej w niej energii chemicznej związków węgla, wodoru i tlenu w energię cieplną w kotłach, jest jednocześnie najtańszym, lecz - zdaniem wielu ekspertów - najmniej efektywnym i ekonomicznie najmniej opłacalnym rozwiązaniem. W przypadku łącznej produkcji energii cieplnej i elektrycznej w elektrociepłowniach...
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Testy platformy SAN dla sektora elektroenergetycznego
PublicationWspółczesna infrastruktura elektroenergetyczna jest narażona na zagrożenia związane z dużą liczbą nowych luk i słabo- ści architektonicznych wynikających z szerszego wykorzystania technologii informacyjnych i komunikacyjnych (ang. Information and Communication Technologies – ICT). Połączenie infrastruktury elektroenergetycznej z Internetem naraża ją na nowe rodzaje ataków, takie jak ataki typu APT (ang. Advanced Persistent Threats)...
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Machine learning-based prediction of residual drift and seismic risk assessment of steel moment-resisting frames considering soil-structure interaction
PublicationNowadays, due to improvements in seismic codes and computational devices, retrofitting buildings is an important topic, in which, permanent deformation of buildings, known as Residual Interstory Drift Ratio (RIDR), plays a crucial role. To provide an accurate yet reliable prediction model, 32 improved Machine Learning (ML) algorithms were considered using the Python software to investigate the best method for estimating Maximum...
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Wystawa zbiorowa "Póki my żyjemy" na 9. Triennale Młodych w Orońsku
PublicationPóki my żyjemy Jesteśmy świadomi zmiany na naszej planecie i czujemy się za nią odpowiedzialni. Dopóki tu jesteśmy mamy głos i możemy zmieniać rzeczywistość. Mamy prawo poruszać wszystkie ważne tematy dotyczące tego kim jesteśmy i jak będzie wyglądać nasza przyszłość. Wraz z artystami i artystkami tworzymy wystawę opierająca się na sztuce, która jest zarówno reakcją jak i działaniem wobec tego zwrotu. Nasz świat będzie istniał...
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Prezentacja działa "Największe słońce widziane z ziemi, dotyka naszej relacji" na 9. Triennale Młodych w Orońsku "Póki my żyjemy"
PublicationPóki my żyjemy Jesteśmy świadomi zmiany na naszej planecie i czujemy się za nią odpowiedzialni. Dopóki tu jesteśmy mamy głos i możemy zmieniać rzeczywistość. Mamy prawo poruszać wszystkie ważne tematy dotyczące tego kim jesteśmy i jak będzie wyglądać nasza przyszłość. Wraz z artystami i artystkami tworzymy wystawę opierająca się na sztuce, która jest zarówno reakcją jak i działaniem wobec tego zwrotu. Nasz świat będzie istniał...
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Enhancing Seismic Performance of Semi-rigid Connection Using Shape Memory Alloy Bolts Considering Nonlinear Soil–Structure Interaction
PublicationSteel Moment-Resisting Frames (SMRFs) have their lateral resistance for their rigid connections, while real conditions have shown that the rigidity of a connection depends on the bolts and the end-plate thickness, which may not provide the assumed rigidity in design process. In this research, the main goal is to enhance the semi-rigid connections using shape memory alloy (SMA) bolts and explore their effects on the seismic limit-state...
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Pre-Treatment of Furniture Waste for Smokeless Charcoal Production
PublicationThe aim of this study was to assess the possibility of using furniture waste for smokeless fuel production using the pyrolysis process. Four types of wood-based wastes were used in the pyrolysis process: pine sawdust (PS), chipboard (CB), medium-density fiberboard (MDF), and oriented strand board (OSB). Additionally, the slow and fast types of pyrolysis were compared, where the heating rates were 15 C/min and 100 C/min, respectively....
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Rewitalizacyjny Living Lab jako metoda generowania i wdrażania innowacji na rzecz odnowy inteligentnego miasta na przykładzie dzielnicy Orunia w Gdańsku
PublicationW artykule poruszono kwestię możliwości wykorzystania w uspołecznieniu formuły pracy nad rewitalizacją modelu living lab tzw. żywego (żyjącego) laboratorium. Na tle przykładów praktyki zagranicznej (USA, Niemcy) dokonano odniesienia do doświadczeń polskich zebranych przez Autorkę w ramach współpracy ze społecznością gdańskiej dzielnicy Orunia - św. Wojciech. Zespół naukowy KUiPR WAPG Katedry Urbanistyki i Planowania Regionalnego...
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Komutacja synchroniczna w obwodach elektrycznych
PublicationW artykule przedstawiono wyniki analizy numerycznej prądów w gałęziach indukcyjnych z histerezą magnetyczną. Przeprowadzono obliczenia mające na celu określenie wartości maksymalnej prądu pobieranego przez układ po włączeniu napięcia zasilającego. Analizie poddano układ jedno- i trójfazowy. Dla układu jednofazowego zbadano, jaki wpływ na wartość prądu ma chwila włączenia napięcia i wartość strumienia szczątkowego w rdzeniu magnetycznym...
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Hybrydowa technologia wzmacniania gruntu w renowacji wałów przeciwpowodziowych
PublicationW artykule przedstawiono propozycję kompleksowego podejścia do renowacji wałów przeciwpowodziowych z zastosowaniem tzw. technologii hybrydowych. Autorzy prezentują technologię, opracowaną z udziałem Katedry Geotechniki, Geologii i Budownictwa Morskiego Politechniki Gdańskiej, łączącą znane metody dynamicznego wzmacniania podłoża gruntowego. Technologia, w swej hybrydowej formule, zapewnia odpowiednie wzmocnienie podłoża zalegającego...