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Search results for: KETENE
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Other diseases of pericardium - Male, 0 - Tissue image [4050730010686101]
Open Research DataThis is the histopathological image of HEART, MEDIASTINUM, AND PLEURA tissue sample obtained in Medical University Gdańsk and deposited in ZMDL-GUMED. The sample image was taken using: Pannoramic 250 3DHistech slide scanner (20x magnification) and saved to DICOM format.
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Other diseases of pericardium - Male, 0 - Tissue image [405073001068941]
Open Research DataThis is the histopathological image of HEART, MEDIASTINUM, AND PLEURA tissue sample obtained in Medical University Gdańsk and deposited in ZMDL-GUMED. The sample image was taken using: Pannoramic 250 3DHistech slide scanner (20x magnification) and saved to DICOM format.
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Miniaturized passive emission test chamber for in-situ measurement of emissions of organic compounds
PublicationThe results of many different studies have demonstrated unequivocally that the quality of indoor air is often much worse than that of atmospheric air (outdoor). One of the main groups of chemical compounds present in indoor air, with proven harmfulness to health,are volatile organic compounds (VOCs). VOCs present indoor comprise a wide variety of hydrocarbons and hydrocarbons derivatives including aliphatic, aromatics, alkylbenzens,...
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Profiling and Qualitative Assessment of Enzymatically and Thermally Oxidized Egg Yolk Phospholipids using a Two‐Step High‐Performance Liquid Chromatography Protocol
PublicationA two‐step high‐performance liquid chromatography (HPLC) method for the profiling and qualitative assessment of oxidized phospholipids (oxPL) present in foods was developed. The applicability of the investigated two‐step HPLC protocol was verified for separation of enzymatically and thermally oxidized hen egg yolk phospholipids (PL) as a relevant food model. In the first step, seven individual PL classes were separated using hydrophilic...
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Comparison of mass spectrometry data and bioinformatics predictions to assess the bona fide localization of proteins identified in cell wall proteomics studies
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Defining Whole Grain Sorghum Flour and Water Levels to Improve Sensory and Nutritional Quality of Gluten-Free Bread—A Factorial Design Approach
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Anita Maria Dąbrowicz-Tlałka dr
PeopleAnita Dąbrowicz-Tlałka graduated from the Faculty of Mathematics and Physics at the University of Gdańsk with an outstanding grade, having written her thesis in the field of geometric topology. She concurrently obtained a diploma in Postgraduate Studies in the Basics of Computer Science at the University of Gdańsk. In 2001 she received a Ph.D. degree in mathematical studies at the Poznań University of Technology after defending...
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EFEKTYWNOŚĆ PRACY OCZYSZCZALNI HYDROFITOWEJ O PRZEPŁYWIE PIONOWYM
PublicationW artykule opisano wyniki badań w zakresie oceny efektywności pracy hy-drofitowej przydomowej oczyszczalni ścieków. W analizowanym okresie oczyszczalnia spełniała wymagania określone dla jakości ścieków oczysz-czonych, uzyskując efektywność usuwania związków organicznych w 98% dla BZT5 oraz w 93,4% dla zanieczyszczeń organicznych wyrażonych pa-rametrem ChZT. Sprawność usuwania biogenów była stosunkowo niska, przy czy mieściła się...
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Copolymerization of Styrene and Pentadecylphenylmethacrylate (PDPMA): Synthesis, Characterization, Thermomechanical and Adhesion Properties
PublicationThe copolymerization of styrene (St) with a bioderived monomer, pentadecylphenylmethacrylate (PDPMA), via atom transfer radical polymerization (ATRP) was studied in this work.The copolymerization reactivity ratio was calculated using the composition data obtained from1HNMR spectroscopy, applying Kelen-Tudos and Finemann-Ross methods. The reactivity ratio of styrene (r1=0.93) and PDPMA (r2=0.05) suggested random copolymerization...
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GTR/Thermoplastics Blends: How Do Interfacial Interactions Govern Processing and Physico-Mechanical Properties?
PublicationIn this work, GTR/thermoplastics blends (in ratio 50/50 and 75/25 wt.%) were prepared by melt-compounding in an internal mixer. During research, trans-polyoctenamer rubber (TOR), ethylene-vinyl acetate copolymer (EVA), ethylene-octene copolymer (EOC), and linear low-density polyethylene (LLDPE), were used in their thermoplastic phase. Microstructure and processing-performance property interrelationships of the studied materials...
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Effect of the welding environment and storage time of electrodes on the diffusible hydrogen content in deposited metal
PublicationIn the study the glycerin displacement method was used for determination of diffusible hydrogen content in deposited metal. Specimens were welded in the air and in the water with covered rutile electrodes. The first part of the specimens was made immediately after opening the package of the electrodes. The electrodes were then stored in opened packages in laboratory conditions that allowed for contact with the air for three years....
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Elicitation strategies for the improvement of essential oil content in Rhododendron tomentosum (Ledum palustre) bioreactor-grown microshoots
PublicationRhododendron tomentosum Harmaja, previously Ledum palustre L., is a fragrant plant growing in swampy areas, which is characterized by well-known repellent properties and the anti-arthritic potential. In the present study, R. tomentosum microshoots cultivated in RITA® bioreactor, providing the alternative, environment-independent source of the valuable essential oil, were treated for 7 days with copper and nickel salts, methyl jasmonate,...
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Topological, nonreciprocal, and multiresonant slow light beyond the time-bandwidth limit
PublicationTopologically protected transport has recently emerged as an effective means to address a recurring problem hampering the field of slow light for the past two decades: its keen sensitivity to disorders and structural imperfections. With it, there has been renewed interest in efforts to overcome the delay-time-bandwidth limitation usually characterizing slow-light devices, on occasion thought to be a fundamental limit. What exactly...
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Determination of volatile organohalogen compounds in urban precipitation in Tricity area (Gdańsk, Gdynia, Sopot).
PublicationPróbki opadów atmosferycznych pobierano w 4 punktach na terenie Gdańska i Sopotu, od listopada 2000 do maja 2001. Oznaczano chloro- i bromopochodne metanu, etanu i etenu. Lotne związki chlorowcoorganiczne oznaczane były metodą bezpośredniego nastrzyku próbki wody do kolumny kapilarnej z wykorzystaniem detektora wychwytu elektronów na etapie detekcji (DAI-GC-ECD). Najczęściej oznaczanymi związkami na wszystkich stacjach pobierania...
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Occurence volatile halogenoorganic compounds in precipitation in an urban area in Tricity (Gdańsk-Gdynia-Sopot). Występowanie lotnych związków fluorowcoorganicznych w opadach atmosferycznych na terenie miejskim.
PublicationSzczególne znaczenie wśród zanieczyszczeń występujących w wielkomiejskim powietrzu atmosferycznym, mają lotne związki chlorowcoorganiczne, ze względu na powszechność stosowania i trwałość (od 77 dni - CH2Cl2 do 67 lat - CCl4). Większość związków chlorowcoorganicznych stanowi zagrożenie dla życia ludzkiego przez swoje kancerogenne, mutagenne i teratogenne działanie. Związki chlorowcoorganiczne obecne w środowisku są w większości...
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10 JAHRE LIGHT SYMPOSIUM WISMAR (LSW)
PublicationDie Zukunft von Licht und Beleuchtung stand im Mittelpunkt des international ausgerichteten Light Symposiums Wismar (LSW), das vom 4. bis 8. November 2008 im Rahmen des Festjahres zum hundertjährigen Bestehen der Hochschule Wismar an der Fakultät Gestaltung stattfand. Ein weitaus wichtigerer Grund war der Wunsch, das Thema Licht und Gesundheit ganzheitlich zu thematisieren. Licht, Raum und Ästhetik sollten in Kongruenz zum salutogentischen*...
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Two complementary approaches for the synthesis and isolation of stable phosphanylphosphaalkenes
PublicationPhospha-Wittig (phosphanylphosphinidene titanium(IV) complex) and phospha-Peterson (lithiated diphosphane) reactions were used to obtain phosphanylphosphaalkenes with the general formula XYC=P-PtBu2 (X = alkyl, aryl group or H; Y = alkyl or aryl group). Therefore, two series of reactions with different ketones and aldehydes were performed. An examination revealed that the two methods are complementary. For smaller carbonyl compounds,...
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Botanical and geographical origin characterization of polish honeys by headspace SPME-GCxGC-TOFMS
PublicationVolatile organic compounds (VOCs) composition of Polish honeys obtained from various geographical regions was studied. Headspace solid phase microextraction (HS-SPME) using Divinylbenzene/Carboxen/Polydimethylsiloxane-coated fibers was used in combination with comprehensive two-dimensional gas chromatography-time-of-flight mass spectrometry (GC× GC-TOFMS) because of the complexity of the samples. Acacia, linden, rapeseed, buckwheat...
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Synthesis of phosphono and phosphate derivatives of hydroxyimino-D-alditols as new potential antifungal agents
PublicationIn search for new effective we antyfungals we focus on two enzymes involved in biosynthesis of the fungal cell wall. The first enzyme is glucosamine-6-phosphate (GlmS), which catalyzes transformation of D-fructose-6-phosphate (Fru-6P) to D-glucosamine-6-phodphate (GlcN-6P) in the chitin biosynthesis pathway. The second enzyme is phosphomannose isomerase (PMI) repored to play a crucial role in biosynthesis of many mannosylated structures,...
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Application of gas chromatography,mass spectrometry and olfactometry for quality assessment of selected food products = Zastosowanie chromatografii gazowej, spektrometrii mas i olfaktometrii w ocenie jakości wybranych produktów spożywczych
PublicationStosując mikroekstrakcję do fazy stacjonarnej z fazy nadpowierzchniowej jako metodę przygotowania próbek i chromatografię gazową (GC) ze spektrometrią mas (MS) i olfaktometrią (O) jako metodę oznaczeń końcowych oznaczono lotne związki w spirytusach i miodach. Identyfikację przeprowadzono przez porównanie widm masowych z widmami z biblioteki NIST. Dodatkowo, wykrywane przez panel oceniający związki zapachowe rejestrowano w formie...
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First deep eutectic solvent-based (DES) stationary phase for gas chromatography and future perspectives for DES application in separation techniques
PublicationThe paper presents the first application of deep eutectic solvents (DES) as stationary phases for gas chromatography. DES obtained by mixing tetrabutylammonium chloride (TBAC) as a hydrogen bond acceptor (HBA) with heptadecanoic acid being a hydrogen bond donor (HBD) in a mole ratio of HBA:HBD equal to 1:2 was characterized by its ability to separate volatile organic compounds (VOCs). The Rohrschneider – McReynolds constants determined...
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Measurements of Activity Coefficients at Infinite Dilution for Organic Solutes in the Ionic Liquids N-Ethyl- and N-Octyl-N-methylmorpholinium Bis(trifluoromethanesulfonyl)imide. A Useful Tool for Solvent Selection
PublicationIn recent years, many papers describing ionic liquids (IL) as promising solvents in separation techniques have been published. The conscious choice of appropriate ionic liquid as absorption media in effective extraction of selected types of analytes requires deeper understanding of the analyte−IL interactions. Therefore, intensive research is conducted to determine the values of activity coefficient at infinite dilution, which...
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Chemical variability of Rhododendron tomentosum (Ledum palustre) essential oils and their pro-apoptotic effect on lymphocytes and rheumatoid arthritis synoviocytes
PublicationRhododendron tomentosum (Ledum palustre) is an aromatic plant traditionally used for alleviating rheumatic complaints which makes it a potential candidate for a natural drug in rheumatoid arthritis (RA) treatment. However, the effects of plants’ volatiles on apoptosis of synovial fibroblasts and infiltrating leucocytes of RA synovia, have not been reported. Volatile fraction of R. tomentosum is chemically variable and chemotypes...
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Application of dynamic headspace and gas chromatography coupled to mass spectrometry (DHS-GC-MS) for the determination of oxygenated volatile organic compounds in refinery effluents
PublicationThe paper presents a new procedure for the determination of oxygenated volatile organic compounds (O-VOCs) in postoxidative effluents from the production of petroleum asphalt using dynamic headspace coupled to gas chromatography-mass spectrometry in the selected ion monitoring (SIM) mode (DHSGC-MS). Among the GC capillary columns tested, a polar SLB-IL111 column with the ionic liquid stationary phase was found to be superior due...
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Bioreactor shoot cultures of Rhododendron tomentosum (Ledum palustre) for a large-scale production of bioactive volatile compounds
PublicationRhododendron tomentosum Harmaja (Ledum palustre), a peat bog plant from Ericaceae family, has been used in traditional medicine as the anti-arthritis agent. Although modern researches confirm its anti-inflammatory properties, it remains threatened by habitat degradation and possibilities to collect this endangered species from its natural environment for further biological activity studies are limited. Therefore, R. tomentosum...
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Evidence for sex differences in the determinants of homocysteine concentrations
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Investigation of volatile low molecular weight compounds formed during continuous reclaiming of ground tire rubber
PublicationGround tire rubber was thermo-mechanically reclaimed at different temperature conditions (80, 120, 160 °C) using a co-rotating twin screw extruder. The progress of ground tire rubber reclaiming was evaluated with specific mechanical energy, sol fraction and thermogravimetric analysis. Volatile organic compounds (VOCs) including volatile sulfur compounds (VCSs) released from ground tire rubber and ground tire rubber after reclaiming...
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Volatile Compound Emissions from Stereolithography Three-Dimensional Printed Cured Resin Models for Biomedical Applications
PublicationStereolithography three-dimensional printing is used increasingly in biomedical applications to create components for use in healthcare and therapy. The exposure of patients to volatile organic compounds (VOCs) emitted from cured resins represents an element of concern in such applications. Here, we investigate the biocompatibility in relation to inhalation exposure of volatile emissions of three different cured commercial resins...
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Stereoselective Alkylation of Indole with 5-Arylidene-Meldrum’s Acids in the Presence of Organocatalysts
PublicationBackground: Indole motif is frequently present in biologically active compounds. Enantiomerically pure or enriched 2,2-dimethyl-5-(aryl(1H-indol-3-yl)methyl)-1,3-dioxane-4,6-diones can be considered as a convenient starting point for the synthesis of a indole ring fused with cyclic ketones with biological activity. Preparation of chiral 2,2-dimethyl-5-(aryl(1H-indol-3-yl)methyl)-1,3-dioxane- 4,6-diones requires the reaction of...
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Influence of steam cooking on pro-health properties of Small and Large variety of Momordica charantia
PublicationSteam cooking is one of the most common preparations of Momordicacharantia dishes. This method improved the tastiness of the fruits but at the same time, some changes occurred in the volatile and non-volatile parts of their food matrices. In this study, for the first time these properties were correlated with the found substances affecting the bioactivity of this fruit. Two varieties of Momordicacharantia were analysed and compared....
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Association between the NAT1 1095C > A polymorphism and homocysteine concentration
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An insertion/deletion polymorphism of the dihydrofolate reductase (DHFR) gene is associated with serum and red blood cell folate concentrations in women
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The Use of Calcium Phosphate-Based Starter Pellets for the Preparation of Sprinkle IR MUPS Formulation of Rosuvastatin Calcium
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The Reduced Folate Carrier (SLC19A1) c.80G>A Polymorphism is Associated with Red Cell Folate Concentrations Among Women
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Can bottom sediments be a prospective fertilizing material? A chemical composition analysis for potential reuse in agriculture.
PublicationEvery year huge amounts of bottom sediments are extracted worldwide, which need to be dis-posed. The recycling of bottom sediments for soil fertilization is in line with the long-promoted circular economy policy and enables the use of micro and macronutrients accumulated in sedi-ments for soil fertilization. When considering potential agricultural reuse of the dredge sediments, the first necessary step should be to analyze whether...
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Utilization of glass fibres as supports for surface compounds for generation of gaseous standard mixtures using thermal decomposition technique
PublicationPrzy oznaczaniu analitów na śladowym lub ultraśladowym poziomie stężeń, szczególnie w przypadku próbek o złożonym lub niejednorodnym składzie matrycy, analityk napotyka dodatkowe trudności techniczne i metodyczne związane z walidacją stosowanych procedur. Niezbędne jest zatem dysponowanie odpowiednimi wzorcami (lub lepiej materiałami odniesienia), które swoim składem są jak najbardziej zbliżone do składu próbek rzeczywistych. W...
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Usefulness of separation techniques for identification and determination of Oxygenated Volatile Organic Compounds used in process analytics of water and wastewater
PublicationW pracy przedstawiono przegląd i porównanie metodyk identyfikacji i oznaczania Lotnych Związków Tlenoorganicznych (LZT). Porównano metodyki klasyczne umożliwiające oznaczanie wybranej grupy związków chemicznych należących do LZT lub dokonywanie oznaczeń sumarycznej zawartości z metodykiami wykorzystującymi techniki rozdzielania. Lotne związki tlenoorganicze, do których zaliczane są aldehydy, alkohole, ketony, estry, etery oraz...
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Poziomy stężeń lotnych związków chlorowcoorganicznych w wodach opadowych na terenie dużej aglomeracji miejskiej = Measurement of volatile chloroorganic compounds in urban rainwater (Gdańsk, Sopot, Gdynia)
PublicationW 105 próbkach opadów atmosferycznych (deszcz, deszcz ze śniegiem) zebranych z terenu Trójmiasta w okresie od listopada 2000 r. do maja 2001 r. oznaczano chloro - i bromopochodne metanu, etanu i etenu (7 różnych związków). Najczęściej wykrywanymi i oznaczanymi były: chloroform i czterochlorek węgla, (bardzo popularne rozpuszczalniki stosowane jako środki chłodzące i czyszczące). Najwyższe stężenia obserwowano w przypadku chloroformu,...
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Adam Władziński
PeopleAdam Władziński, a PhD Candidate at Gdansk University of Technology, specializes in Biomedical Engineering with a focus on machine learning for image processing and blockchain technology. Holding a BEng and MSc in Electronics, Adam Władziński has developed a keen interest in applying advanced computational techniques to biological systems. During their master’s program, Adam Władziński explored laser spectroscopy, building a database...
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Urządzenie do wytwarzania gazowych mieszanin wzorcowych zawierających substancje zapachowe (lotne alkohole, aldehydy, ketony, alkany, merkaptany, sulfidy oraz siarkowodór i amoniak)
InventionsPrzedmiotem wynalazku jest sposób otrzymywania mieszanin gazowych o żądanym składzie. Sposób ten ma mieć zastosowanie jako przyłącze do elektronicznego nosa w badaniach środowiska, do kalibrowania analizatorów gazu, do odtwarzania mieszanin gazowych występujących w naturze takich jak aromat cytryny, waniliny, przypalonego tłuszczu, kwiatów, benzyny, czosnku, siarki, siarkowodoru. W porównaniu...
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Ćwiczenia audytoryjne z Chemii Organicznej 2021/2022
e-Learning CoursesNa ćwiczeniach z Chemii Organicznej przerabiany będzie materiał zaprezentowany na wykładzie obejmujący: alkany i cykloalkany (nazewnictwo, konformacje, reakcje chemiczne), izomeria w związkach organicznych (strukturalna, geometryczna i optyczna), alkeny, alkiny i dieny (nazewnictwo, reakcje chemiczne, otrzymywanie, izomeria cis-trans, reakcje addycji, reguła Markownikowa, przykłady reakcji polimeryzacji, reakcje Dielsa-Aldera),...
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Największe osiedle mieszkaniowe międzywojennego Gdańska - stan obecny i perspektywy zachowania
PublicationZaprezentowane przykłady budynków modernistycznych pochodzą z największego gdańskiego osiedla mieszkaniowego z okresu dwudziestolecia międzywojennego – Osiedla Kościuszki. W analizowanym zespole zabudowy przeważa architektura mieszkaniowa wielorodzinna w zabudowie ciągłej. Chociaż charakteryzuje ją prostota i zharmonizowanie form, to poszczególne grupy budynków tworzące samodzielne podjednostki osiedla różnią się sposobem opracowania...
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Największe osiedle mieszkaniowe międzywojennego Gdańska - stan obecny i perspektywy zachowania
PublicationZaprezentowane przykłady budynków modernistycznych pochodzą z największego gdańskiego osiedla mieszkaniowego z okresu dwudziestolecia międzywojennego – Osiedla Kościuszki. W analizowanym zespole zabudowy przeważa architektura mieszkaniowa wielorodzinna w zabudowie ciągłej. Chociaż charakteryzuje ją prostota i zharmonizowanie form, to poszczególne grupy budynków tworzące samodzielne podjednostki osiedla różnią się sposobem opracowania...
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Zdolni z Pomorza 2018/19 - Podstawy chemii organicznej
e-Learning CoursesCel kursu: Celem kursu jest zapoznanie uczniów z podstawowymi grupami związków organicznych, ich właściwościami i nazewnictwem. Uczniowie poznają ponadto wybrane rodzaje izomerii oraz niektóre typy reakcji z udziałem związków organicznych. Opis kursu: Historycznie za związki organiczne uważano substancje zawarte w organizmach żywych, których nie można było otrzymać na drodze syntezy chemicznej. Dziś potrafimy takie związki syntezować...
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Climatology of Transient Luminous Events and Lightning Observed Above Europe and the Mediterranean Sea
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Birthweight and the risk of childhood-onset type 1 diabetes: a meta-analysis of observational studies using individual patient data
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Consequences of cathepsin C inactivation for membrane exposure of proteinase 3, the target antigen in autoimmune vasculitis
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A global multinational survey of cefotaxime-resistant coliforms in urban wastewater treatment plants
PublicationThe World Health Organization Global Action Plan recommends integrated surveillance programs as crucial strategies for monitoring antibiotic resistance. Although several national surveillance programs are in place for clinical and veterinary settings, no such schemes exist for monitoring antibiotic-resistant bacteria in the environment. In this transnational study, we developed, validated, and tested a low-cost surveillance and...
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10Kin1day: A Bottom-Up Neuroimaging Initiative
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10Kin1day: A bottom-up neuroimaging initiative
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