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Search results for: POLYMER COLORATION
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Ionophores in polymeric membranes for selective ion recognition; impedance studies
PublicationBadania impedancyjne membran zawierających jonofory selektywne na kation Na+ (L1) i Cs+(L2) wykazały, ze stala dielektryczna materiału membrany zależy od typu uzytego plastyfikatora i zmienia się w zakresie od 28 do 60. Rezystancja membran zawierających ligand L1 i L2 wynosi 0.15 -1.4 Mohm w zależności od stężenia elektrolitu zewnnetrznego. Testowona dwa typy elektrod jonoselektywnych: elektrody typu ASS z polimerem przewodzącym...
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Chemorezystancyjny czujnik gazu na bazie polimeru przewodzącego PEDOT
PublicationPolimery przewodzące, takie jak Poli(3,4-etylenodioksytiofen) (PEDOT) są atrakcyjnymi materiałami elektrodowymi, które posiadają takie zalety, jak biokompatybilność, duża przewodność i elastyczność. Elektroprzewodzące polimery można otrzymać w wyniku chemicznej polimeryzacji lub elektropolimeryzacji. W niniejszej pracy przedstawiono zostanie koncepcja czujnika gazów składająca się z elektrody grzebieniowej oraz polimeru przewodzącego...
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An analytic approach to the conductance and I-V characteristics of polymeric chains
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Behaviour of Asymmetric Structure with Base Isolation Made of Polymeric Bearings
PublicationEarthquake-induced ground motions are the most severe and unpredictable threats to the structures all around the world. Seismic excitations cause a lot of damage in a wide variety of ways, leaving thousands of casualties in their wake. Due to randomness of earthquake occurrence, lack of visible causes and their power of destructiveness, structural engineers need to develop new technical solutions and protection systems against...
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Behaviour of asymmetric structures with base isolation made of Polymeric Bearings
PublicationEarthquake-induced ground motions are the most severe and unpredictable threats to the structures all around the world. Seismic excitations cause a lot of damage in a wide variety of ways, leaving thousands of casualties in their wake. During the last few years alone, the world has witnessed many major earthquakes, five of which have caused far-reaching consequences of a national scale for Haiti (January 2010), Chile (February...
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Electronic excitation energy migration in partly ordered polymeric films
PublicationWieloetapowa migracja energii pomiędzy podłużnymi fluoroforami (karbocyjaniny) w osiowo rozciąganych foliach polimerowych była studiowana na podstawie pomiarów anizotropii emisji i symulacji Monte Carlo. W przeciwieństwie do układów nieuporządkowanych pokazano eksperymentalnie, że stężeniowa depolaryzacja fluorescencji w osiowo orientowanych foliach jest ekstremalnie słaba, mimo tego, że zachodzi zjawisko migracji energii. Opierając...
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Modeling and Evaluation of Electric Treeing Phenomena in Polymeric Cable Insulation
PublicationThis paper investigates the treeing phenomenon in polymeric materials such as crosslinked polyethylene (XLPE) that is widely used in medium and high voltage power cables as primary insulation. The modeling of electrical tree growth in the insulation from its initiation to breakdown is significant research work that illustrates the discharge dynamics and its impact on aging process in polymeric insulation. This study utilizes pulse...
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On the Equations of the Surface Elasticity Model Based on the Theory of Polymeric Brushes
PublicationMotivating by theory of polymers, in particular, by the models of polymeric brushes we present here the homogenized (continual) two-dimensional (2D) model of surface elasticity. A polymeric brush consists of an system of almost aligned rigid polymeric chains. The interaction between chain links are described through Stockmayer potential, which take into account also dipole-dipole interactions. The presented 2D model can be treated...
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Preliminary Testing of the Influence of Modified Polycaprolactones on Anabaena Variabilis Growth in Seawater
PublicationSeveral new biodegradable polymer materials have recently come onto the global market. Mostly the results on degradation kinetic studies are presented. This paper suggests using one of the tests to estimate the impact of polymer packaging material on sea life. The microorganism chosen was Anabaena variabilis (identified in many waters, including those of the Baltic Sea, especially in the Gulf of Gdansk and Puck Bay; this cyanobacterium...
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Magnetic Molecularly Imprinted Polymer Nanoparticles for Selective Extraction of Copper from Aqueous Solutions Prior to Its Flame Atomic Absorption Determination
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Magnetic molecularly imprinted polymer nanoparticles for selective extraction of copper from aqueous solutions prior to its flame atomic absorption determination
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Unusual fluorescence anisotropy spectra of three-component donor-mediator-acceptor systems in uniaxially stretched polymer films in the presence of energy transfer
PublicationW pracy analizowano transfer energii w układzie donor-mediator-akceptor w osiowo rozciąganych foliach polimerowych. Stwierdzono, że informacja zawarta w orientacji wektora pola elektrycznego wiązki światła wzbudzającego układ jest zachowana po zajściu procesu transferu energii pomiędzy molekułami w foliach rozciąganych. Natomiast w foliach nierozciąganych fluorescencja mediatora i akceptora jest bardzo silnie zdepolaryzowana.
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3D dose verification with polymer gel detectors of brain-spine match line for proton pencil beam cranio-spinal: A preliminary study
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Performance evaluation of an improved optical computed tomography polymer gel dosimeter system for 3D dose verification of static and dynamic phantom deliveries
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Dosimetry study of Re-188 liquid balloon for intravascular brachytherapy using polymer gel dosimeters and laser-beam optical CT scanner
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Titania nanotubes infiltrated with conducting polymer PEDOT modified by Prussian Blue – a novel type of organic-inorganic heterojunction characterised with enhanced photoactivity.
PublicationA highly ordered p–n heterojunction was formed based on titania nanotubes containing a conducting polymer with Prussian blue matrix. The study demonstrates, for the first time, cases when a composite based on titania array scaffolding and Prussian blue embedded in PEDOT exhibits reversible FeII/FeIII redox activity. Highly enhanced photoactivity and capacitance of the obtained material are depicted in comparison to pristine titania....
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Synthesis and structural properties of (Y, Sr)(Ti, Fe, Nb)O3−δ perovskite nanoparticles fabricated by modified polymer precursor method
PublicationThe yttrium, iron and niobium doped-SrTiO3 powders have been successfully fabricated by a modified low–temperature synthesis method from a polymer complex. The usage of strontium hydroxide precursor instead of conventional strontium nitrate or strontium carbonate provides to the possibility of significant decrease of annealing temperature. It allows to prepare a material with sphere-shape grains of nanometric size (15–70 nm). The...
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Insightful Analysis of Phenomena Arising at the Metal|Polymer Interphase of Au-Ti Based Non-Enzymatic Glucose Sensitive Electrodes Covered by Nafion
PublicationThis paper focuses on the examination of glucose oxidation processes at an electrode material composed of gold nanoparticles embedded in a titanium template. Three dierent conditions were investigated: the chloride content in the electrolyte, its ionic conductivity and the presence of a Nafion coating. The impact of the provided environment on the oxidation reaction was evaluated by cyclic voltammetry (CV) and electrochemical impedance...
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Spatially Resolved Degradation in Heterophasic Polymers From 1D and 2D Spectral–Spatial ESR Imaging Experiments
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Benzene-induced hydro(solvo)thermal synthesis of Cu2+ and Zn2+ coordination polymers based on 1,3-benzenedicarboxylate
PublicationHydro(solvo)thermal reactions of Cu(NO3)2·2.5H2O or Zn(NO3)2·6H2O with 1,3-H2bdc provided two structurally different coordination polymers; a 2D network “metallacalixarene” based on the paddlewheel-type cluster with the formula [Cu(1,3-bdc)·H2O]·H2O (1) and a 3D framework [Zn(1,3-bdc)] (2), respectively. The use of a base was unnecessary in this synthesis; however, the presence of benzene played a crucial role in the crystallization...
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New devices to capture the temperature effect under dynamic compression and impact perforation of polymers, application to PMMA
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Antibacterial properties of laser-encapsulated titanium oxide nanotubes decorated with nanosilver and covered with chitosan/Eudragit polymers
PublicationTo provide antibacterial properties, the titanium samples were subjected to electrochemical oxidation in the fluoride-containing diethylene glycol-based electrolyte to create a titanium oxide nanotubular surface. Afterward, the surface was covered by sputtering with silver 5 nm film, and the tops of the nanotubes were capped using laser treatment, resulting in an appearance of silver nanoparticles (AgNPs) of around 30 nm in diameter...
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Environmental costs for exploitation variants of Racibórz dry polder
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POLDER AND CITY: SUSTAINING WATER LANDSCAPES ON AN URBAN EDGE
PublicationThe question investigated in this paper is how to maintain the environmental quality of the polder landscape encompassing the city in the condition of urban pressure on this landscape. On the basis of theoretical approaches, historical surveys and introductory study models new ideas are tested on the case study of Gdansk, a city located in the Vistula River delta in northern Poland. Research shows that the city was created as a...
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Studies on removal of Zn(II), Cd(II) and Pb(II) ions in polymer inclusion membrane transport with calix[4]-crown-6 derivatives
PublicationZbadano selektywność procesu wydzielania jonów cynku(II), kadmu(II) i ołowiu(II) z wodnych roztworów azotanowych zawierających równomolową mieszaninę tych trzech metali (cMe= 0,01 M) w procesie transportu przez polimerowe membrany inkluzyjne (PIM) przy użyciu w roli przenośników jonów pochodnych kaliks[4]-korony-6. Membrany typu PIM syntezowano z trójoctanu celulozy (nośnik), eteru o?nitrofenylopentylowego (pastyfikator) i pochodnych...
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Facilitated transport of Zn(II), Cd(II) and Pb(II) ions trough polymer inclusion membranes with calix[4]-crown-6 derivaties
PublicationBadano transport mieszaniny równomolowych ilości jonów Zn(II), Cd(II) i Pb(II)z wodnej fazy azotanowej (cMe=0,001M) przez polimerowe membrany inkluzyjne(PIM) zawierające pochodne kaliks[4]korony-6 jako nośniki jonów. Badany był wpływ różnych podstawników na wydajność procesu. Selektywność transportu przez membrany zawierające jonofory 4 i 5 malała w kolejności Pb(II), Zn(II), Cd(II), natomiast z jonoforem 3 Pb(II), Zn(II)Cd(II)....
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Determination of modifier contents in polymer-modified bitumens and in samples collected from the roads using high performance gel permeation/size exclusion chromatography
PublicationThis paper describes application of high performance gel permeation/size exclusion chromatography (HP-GPC/SEC) for the determination of content of polymer modifiers in modified road bitumens. The obtained results were compared with the measurements based on the procedure recommended by the American Association of State Highway and Transportation Officials, which employs Fourier transform mid-infrared spectroscopy (mid-IR FTIR)....
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Evolution of the nanostructure of Pt and Pt–Co polymer electrolyte membrane fuel cell electrocatalysts at successive degradation stages probed by X-ray photoemission
PublicationWe present a set of XPS (X-ray photoemission spectroscopy) measurements and detailed data-analysis of electrodes for polymer electrolyte membrane fuel cell (PEMFC) based on carbon supported catalysts (Pt and Pt–Co) subjected to a step-like potential cycling (accelerated degradation test). The results of the measurements complete and corroborate parallel TEM (transmission electron microscopy), XRD (X-ray diffraction) and XAS (X-ray...
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Correction: Titania nanotubes infiltrated with the conducting polymer PEDOT modified by Prussian blue – a novel type of organic–inorganic heterojunction characterised with enhanced photoactivity
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β-cyclodextrin-containing polymer based on renewable cellulose resources for effective removal of ionic and non-ionic toxic organic pollutants from water
PublicationA novel, bio-derived cyclodextrin-based trifunctional adsorbent has been successfully synthesized for efficient, rapid and simultaneous removal of a broad-spectrum of toxic ionic (anionic and cationic dyes) and non-ionic organic pollutants from water. The composition, morphology and the presence of functional groups in the obtained sorption material were characterized by elemental analysis, XRD, SEM, and FTIR spectroscopy. The...
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Measurements of guided wave propagation in CFRP/steel adhesive joints obtained by scanning laser vibrometry
Open Research DataThe DataSet contains guided wave signals measured in adhesive joints of steel plates (steel of type S355 with a thickness of 11.9 mm ) and carbon fibre reinforced polymer (CarboDur S1012 with a thickness of 1.24 mm). The samples were as follows: #0 – intact; #1 – 10% disbond; #2 – 20% disbond; #3 – 50% disbond; #4 – 80% disbond; #5 – 100% disbond.
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Size-Dependent in Vitro Biocompatibility and Uptake Process of Polymeric Carbon Nitride
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Bifunctional Polymeric Carbon Nitride via Tuning Fabrication Conditions for Photocatalysis
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Reduction of vibrations of steel structure models with Polymeric Bearings - experimental study
PublicationEarthquake-induced ground motions are the most severe and unpredictable threats to the structures all around the world. Therefore, designing earthquake protective systems has become an extremely challenging problem in civil engineering. Base isolation is one of the most popular and widely adopted methods of protecting structures against earthquake forces. The present paper reports the results obtained from the shaking table experimental...
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Compatibilization of polymeric composition filled with ground tire rubber – short review
PublicationWaste rubber is recognized as valuable materials resource and searching for new recycling methods is the main activity of many research institutions and companies. At the turn of the last years only few scientific papers about foamed polymer compositions filled with ground tire rubber were published. In paper review about progress in compatibilization and foaming of polymeric compositions filled with ground tire rubber.
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Polimery w Medycynie
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Lead(II) coordination polymers with imidazole-4- and pyrazole-3-carboxylate isomeric linkers: Structural diversity and luminescence properties
PublicationUsing 1H-imidazole-4-carboxylic acid (4imCOOH) and 1H-pyrazole-3-carboxylic acid (3pyrCOOH) coordination polymers [Pb(4imCOO)2(H2O)]n (1) and [Pb2(3pyrCOO)4]n (2) were constructed. Obtained polymers were characterized via FT-IR, X-ray, PL and TG methods. The coordination polyhedron around Pb(II) in 1 is described as distorted pentagonal pyramid with hemidirected coordination sphere (based on DFT calculations). Compound 2 consists...
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Study of the Effect of Filling Thermoplastic Medical Polyurethane with PVA, PLA or Diatomite on the Relaxation Times Distributions of 1H NMR
PublicationIn this work, to characterize the mobility of diferent sections of the macromole‑ cules of polyurethane (PUR), polyvinyl alcohol (PVA), and polylactic acid (PLA), as well as the density of crosslinks of the polymer chains when using fllers, we used the distributions of spin–lattice and spin–spin relaxation times for the protons. It is shown that the rigidity of the thermoplastic polymers depends on the sizes of the granules of...
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Thermal, spectroscopic and luminescence investigations of lanthanide(III) coordination polymers based on V-shaped 4,4′-sulfonyldibenzoic acid
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Zn(II) and Cd(II) coordination polymers with tri-tert-butoxysilanethiol and bipyridines. Synthesis, crystal structure and spectroscopy
PublicationTrzy nowe silanotiolany cynku(II) I kadmu(II) [Zn{SSi(OtBu)3}2(μ-bpea) •CH3CN]n 1, [Cd{SSi(OtBu)3}2(μ -bpea) •2CHCl3]n 2 oraz [Cd{SSi(OtBu)3}2(μ -bpey)•C7H8]n 3 otrzymane z użyciem pochodnych bipirydylu [bpea = 1,2-bis(4-pyridyl)etan and bpey = 1,2-bis(4-pyridyl)etylen] zostały zsyntetyzowane i strutkualnie scharakteryzowane przy użyciu rentgenografii strukturalnej XRD. Ich budowa krystaliczna została dodatkowo potwierdzona przy...
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One dimensional coordination polymers generated from Cd(II) tri-tert-butoxysilanethiolates and flexible aliphatic diamines.
PublicationPraca ta dotyczy chemii koordynacyjnej tri-tert-butoksysilanotiolanu kadmu(II) z diaminami alifatycznymi. Reakcja dwucentowego [Cd{SSi(OtBu)3}2]2 z poszczególnymi diaminami pozwala otrzymać pięć nowych obojętnych jednowymiarowych polimerów koordynacyjnych o różnej topologii łańcuchów [Cd{SSi(OtBu)3}2(μ-C4H12N2)(CH3OH)]n (1), [Cd{SSi(OtBu)3}2(μ-C5H14N2)(CH3OH)]n (2) [Cd{SSi(OtBu)3}2(μ-C6H16N2)(CH3OH)]n (3), [Cd{SSi(OtBu)3}2(μ-C7H18N2)]n...
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Polyurethanes modified with natural polymers for medical application. Part II. Polyurethane/gelatin, polyurethane/starch, polyurethane/cellulose
PublicationThis paper is a literature overview of biomedical PUR modifications with natural polymers such as starch, cellulose and gelatin. Properties like biodegradability and biocompatibility of modified PUR cause that these materials may be used as wound dressings, tissue scaffolds, tissue implants and also vascular grafts.
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Preparation and characterization of dummy-template molecularly imprinted polymers as potential sorbents for the recognition of selected polybrominated diphenyl ethers
PublicationThe main aim of this work was to conduct the preliminary/basic research concerning the preparation process of a new dummy molecularly imprinted polymer (DMIP) materials. Developed DMIPs were proposed as a sorption material in solid-phase extraction (SPE) technique for recognition of selected low mass polybrominated diphenyl ethers (PBDEs) e PBDE-47 and PBDE-99. Four new DMIPs were synthesized employing bulky polymerization technique...
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Application of molecularly imprinted polymer pipette tip micro-solid phase extraction of nalidixic acid and acetaminophen from pills and seawater samples and their determination by spectrophotometry
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Application of response surface methodology to optimize pipette tip micro-solid phase extraction of dyes from seawater by molecularly imprinted polymer and their determination by HPLC
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MAX phase ternary carbide derived 2-D ceramic nanostructures [CDCN] as chemically interactive functional fillers for damage tolerant epoxy polymer nanocomposites
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Controllable Synthesis of 3D Hollow-Carbon-Spheres/Graphene-Flake Hybrid Nanostructures from Polymer Nanocomposite by Self-Assembly and Feasibility for Lithium-Ion Batteries
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Ocena wybranych własności materiałowych polimerowej warstwy ślizgowej hydrodynamicznego łożyska wzdłużnego = An estimation of selected material properties of the hydrodynamic thrust bearing polymer lining
PublicationZaprezentowano metody pomiaru najważniejszych własności mechanicznych i cieplnych polimerowego pokrycia segmentowego łożyska wzdłużnego, do których zaliczyć należy moduł sprężystości wzdłużnej oraz współczynnik przewodności cieplnej materiału dodatkowym utrudnieniem planowanego zadania jest fakt, że próbka do badań dostępna będzie jedynie w formie wycinka z segmentu łożyskowego, z tego powodu nie jest możliwe zastosowanie ogólnie...
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Fabrication of a Molecularly Imprinted Polymer Adsorbent for Pipette Tip Micro Solid-phase Extraction of Levofloxacin from Aqueous Samples Prior to its Spectrophotometric Determination
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The comparison of the removal of copper(II) and zinc(II) ions from aqueous solution using 2,6-diaminopyridine in a polymer inclusion membrane and in a classic solvent extraction
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