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Analytical chemistry in technical approaches: immobilization of biosorbent waste containing heavy metals in cemented materials
PublikacjaAn ecologically safe and economically justified method of stabilization of the used biosorbents was developed. Sorbent contaminated with heavy metals has been successfully solidified/stabilized using a hydraulic binder. The test results indicated that up to 1% of the biosorbent residue used could be added without compromising the compressive strength of the mortar. The compressive strength of the modified mortars did not change...
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Self-compacting grout to produce two-stage concrete
PublikacjaTraditional concrete (TC) is primarily composed of a mixture of cement, fine and coarse aggregates, and water. TC is made by mixing together all the components before placing them. Using non-traditional concrete (two-stage concrete) to solve and to eliminate the problem of the aggregate segregation which appears in TC and in the self-compacting concrete. Two-stage concrete (TSC) consists of two main components, namely the grout...
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Preliminary Results from the Removal of Phosphorus Compounds with Selected Sorption Material
PublikacjaDue to the resources of phosphorous are limited and are exhausted in the next 30 years the management of the resources is become current issue. Most of the phosphorus compounds is lost forever, because it is discharged with sewage into surface waters, causing eutrophication and in this way causing a further problem and challenge. On the other hand, there is a considerable need for phosphorus compounds, primarily in bioavailable...
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Green adsorbents and solvents in food analysis
PublikacjaGreen analytical chemistry aims to minimize the negative impact of analytical procedures on the environment and human health. This can be achieved through the use of non-toxic and environmentally friendly reagents. Classical green solvents include water, ethanol, acetone, and supercritical fluids. Water has been used for the extraction of water-soluble compounds (sugars, amino acids). Ethanol and acetone have been used for the...
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Obtaining and Characterization of the PLA/Chitosan Foams with Antimicrobial Properties Achieved by the Emulsification Combined with the Dissolution of Chitosan by CO2 Saturation
PublikacjaA new method of obtaining functional foam material has been proposed. The materials were created by mixing the poly lactic acid (PLA) solution in chloroform, chitosan (CS) dissolved in water saturated with CO2 and polyethylene glycol (PEG), and freeze-dried for removal of the solvents. The composite foams were characterized for their structural (SEM, FT-IR, density, porosity), thermal (DSC), functional (hardness, elasticity, swelling...
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Obtaining and Characterization of the PLA/Chitosan Foams with Antimicrobial Properties Achieved by the Emulsification Combined with the Dissolution of Chitosan by CO2 Saturation
PublikacjaA new method of obtaining functional foam material has been proposed. The materials were created by mixing the poly lactic acid (PLA) solution in chloroform, chitosan (CS) dissolved in water saturated with CO2 and polyethylene glycol (PEG), and freeze-dried for removal of the solvents. The composite foams were characterized for their structural (SEM, FT-IR, density, porosity), thermal (DSC), functional (hardness, elasticity, swelling...
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Self-compacting grout to produce two-stage concrete
PublikacjaTraditional concrete (TC) is primarily composed...
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Mater-Bi/Brewers’ Spent Grain Biocomposites—Novel Approach to Plant-Based Waste Filler Treatment by Highly Efficient Thermomechanical and Chemical Methods
PublikacjaThermoplastic starch (TPS) is a homogenous material prepared from native starch and water or other plasticizers subjected to mixing at a temperature exceeding starch gelatinization temperature. It shows major drawbacks like high moisture sensitivity, poor mechanical properties, and thermal stability. To overcome these drawbacks without significant cost increase, TPS could be blended with bio-based or biodegradable polymers and...
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Recent progress in ultra-low formaldehyde emitting adhesive systems and formaldehyde scavengers in wood-based panels: a review
PublikacjaTraditional wood-based panels are produced with synthetic, formaldehyde-based adhesives, commonly made from fossil-derived constituents, such as urea, phenol, melamine, etc. Along with their numerous advantages, such as chemical versatility, high reactivity and excellent adhesive performance, these adhesives are characterized by certain problems, connected with the hazardous volatile organic compounds (VOCs), mostly free formaldehyde...
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Influence of Asphalt Binder on the Compactability of Asphalt Mixtures Using Locking Point
PublikacjaCompaction is an important process for the asphalt mixture service life. A properly compacted mixture is crucial for long-lasting pavement. The objective of this study was to evaluate the influence of asphalt binders on the compactability of the asphalt mixtures by utilizing the concept of the locking point. To achieve this objective, two compaction methods (impact and gyration), different temperatures and asphalt content, and...
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A novel concept of enhanced direct-contact condensation of vapour- inert gas mixture in a spray ejector condenser
PublikacjaAn analytical model of direct steam condensation (DCC) in the novel idea of spray ejector condenser (SEC) in the presence of inert gas has been developed. It is based on continuity, momentum and energy equations for the steam-carbon dioxide mixture and direct contact condensation mechanisms due to heat transfer and concentration. Crucial in the process of DCC is atomisation of the motive fluid in the ejector. The effect of atomised...
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Imitating Quantum Probabilities: Beyond Bell’s Theorem and Tsirelson Bounds
PublikacjaLocal hidden-variable model of singlet-state correlations discussed in M. Czachor, Acta Phys. Polon. A 139, 70, is shown to be a particular case of an infinite hierarchy of local hidden-variable models based on an infinite hierarchy of calculi. Violation of Bell-type inequalities can be interpreted as a `confusion of languages' problem, a result of mixing different but neighboring levels of the hierarchy. Mixing of non-neighboring...
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Effect of Compounding Conditions on Static and Dynamic Mechanical Properties of High Density Polyethylene/Ground Tire Rubber Blends
PublikacjaSearching for new and cost-effective methods of waste rubber recycling is a subject of research in many scientific centers in the world. In this paper there are presented results of the research of the extrusion process of cheap and environmentally friendly thermoplastic compositions containing 50 % wt. of masses of ground tire rubber (GTR). The aim of this study was to determine the relationship between the mixing conditions and...
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Optimization of Bread Production Using Neuro-Fuzzy Modelling
PublikacjaAutomation of food production is an actively researched domain. One of the areas, where automation is still not progressing significantly is bread making. The process still relies on expert knowledge regarding how to react to procedure changes depending on environmental conditions, quality of the ingredients, etc. In this paper, we propose an ANFIS-based model for changing the mixer speed during the kneading process. Although the...
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Effects of FSW Tool Plunge Depth on Properties of an Al-Mg-Si Alloy T-Joint: Thermomechanical Modeling and Experimental Evaluation
PublikacjaOne of the main challenging issues in friction stir welding (FSW) of stiffened structures is maximizing skin and flange mixing. Among the various parameters in FSW that can affect the quality of mixing between skin and flange is tool plunge depth (TPD). In this research, the effects of TPD during FSW of an Al-Mg-Si alloy T-joint are investigated. The computational fluid dynamics (CFD) method can help understand TPD effects on FSW...
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Application of Monte-Carlo method to modelling influence of selected soil heterogeneity on macrodispersion of pollutants in unsaturated soil medium
PublikacjaThe influence of soil heterogeneity on miscible solute transport in soil is analyzed. The transport process is simulated numerically using the Monte-Carlo method. This paper shows how different types of soil heterogeneity influence the process of contaminant spreading. If independent flow paths exist in the soil, the degree of the mixing of pollutants in the outflow from the soil profile is larger. If the preferential flow paths...
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Effect of slag coal ash and foamed glass on the mechanical properties of two-stage concrete
PublikacjaTwo-stage concrete (TSC) is known by various names such as colcrete, Polcrete, preplaced aggregate concrete and prepacked concrete. It is different from traditional concrete in two fundamental ways, namely method of construction and mix proportion. Two-stage concrete (TSC) is defined as firstly, coarse aggregates are placed into the formwork and grout is applied to fill in the between coarse aggregate particles voids. Secondly,...
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Manufacture and research of TPS/PE biocomposites properties
PublikacjaIn this paper the process of native starch preparing for modification by extrusion and manufacture of biocomposites is presented. The first aim of this study was to determine the mixing and granulating condition of native starch to obtain granulated native starch. For mixing and granulation of native starch Intensive Mixer manufactured by Maschinenfabrik Gustav Eirich was used. Mixing and granulation in a single process is a new...
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Nowoczesne technologie uszczelniania wałów przeciwpowodziowych.
PublikacjaOpisano zastosowanie wąskoszczelinowych przesłon przeciwfiltracyjnych wykonywanych w technologii WIPS wibracyjnie iniektowana przesłona szczelinowa oraz DSM ( ang. deep soil mixing - mieszanie wgłębne gruntu). Przedstawiono przykłady zastosowania w Polsce.
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Experimental and theoretical investigation of pressure field in a shroudclearance. Part II: Theoretical results
PublikacjaPrzedstawiono wyniki obliczeń teoretycznych metodami CFD rozkładu ciśnienia w uszczelnieniu nadbandażowym stopnia powietrznej turbiny modelowej. Badania przeprowadzono stosując metody: Miltiple Reference Frame, Mixing Plane iSliding Mesch. Wyniki porównano z rezultatami badań eksperymentalnych.
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Research into flows in turbine blade seals. Part II: Numerical analysis
PublikacjaPrzedstawiono wyniki badań numerycznych programem Fluent przepływów w uszczelnieniu nadbandażowym stopnia turbinowego. Badania wykonano przy zastosowaniu różnych typów siatek obliczeniowych, różnych rodzajów "zszywek" oraz różnych metod obliczeniowych (Mixing Plane, Sliding Mesh, Multiple ReferenceFrame).
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Concept of a swirling diffuser in batch blending tanks
PublikacjaThe mixing of two or more components belongs to the category of the most common unit operations, both in technology and in nature. One particular version is homogenization (blending), the effectivity of which is strongly related to the blending time. Among many differentiated individual solutions of mixing systems used in blenders, one should distinguish the class of agitators with diffusers. An analysis of the character of the...
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Prevalence Problem in the Set of Quadratic Stochastic Operators Acting on L1
PublikacjaThis paper is devoted to the study of the problem of prevalence in the class of quadratic stochastic operators acting on the L1 space for the uniform topology. We obtain that the set of norm quasi-mixing quadratic stochastic operators is a dense and open set in the topology induced by a very natural metric. This shows the typical long-term behaviour of iterates of quadratic stochastic operators.
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Modeling of low calorific gas burning in a deficient oxygen environment and high-temperature oxidizer
PublikacjaThe experimental research will be performed using the experimental facility with a combustion chamber. The oxygen concentration in combustion oxidizers will be varied from 21% by volume (normal) air to 2%. The test combustion chamber will be fed with propane or methane as the reference fuel, then with low calorific fuels as test gases obtained by mixing various combustible components, e.g. H2, CH4, CO, and neutral gases, e.g. N2,...
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A Loophole of All ‘Loophole-Free’ Bell-Type Theorems
PublikacjaBell’s theorem cannot be proved if complementary measurements have to be represented by random variables which cannot be added or multiplied. One such case occurs if their domains are not identical. The case more directly related to the Einstein–Rosen–Podolsky argument occurs if there exists an ‘element of reality’ but nevertheless addition of complementary results is impossible because they are represented by elements from different...
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Mechanical Properties of a Dike Formed from a Soil-ash Composite
PublikacjaThe paper presents the research results on application of composite soils for dike construction. The composite soil is produced by mixing bottom ash (by-product of energetics) with dredged material (sand) taken from the mouth of The Vistula river. The optimum composite for dike core was chosen with respect to mechanical parameters: high internal friction angle, good compaction and reduced hydraulic conductivity. The test dike was...
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Interrelated shape memory and Payne effect in polyurethane/graphene oxide nanocomposites
PublikacjaWe report the fabrication of graphene oxide (GO) based polyurethane (PU) nanocomposites by a simple method of mixing and their shape memory properties at different temperatures. Both the polymer and the filler were synthesized in the laboratory by simple and easy methods – PU by pre-polymer method and GO by improved graphene oxide synthesis method. High molecular level dispersion of GO platelets within the PU matrix and thus good...
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THE COMPOSITION MODULATION EFFECT IN GaInPAs SOLID SOLUTIONS AS A MANIFESTATION OF ENERGY RESONANCE AFTER MATERIAL'S SPINODAL DECOMPOSITION
PublikacjaThe Cahn-Hilliard model concepts are extended to describe the spinodal decomposition of Ga$_x$In$_{1-x}$P$_y$As$_{1-y}$ solid solutions grown on the InP substrate. The energy of elastic deformation of the thin layer of a solid solution was calculated on the assumption of its coherent conjugation with the massive InP substrate. The excess energy of component mixing in the solid phase was modeled in accordance with the simple solution...
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Blurred quantum Darwinism across quantum reference frames
PublikacjaQuantum Darwinism describes objectivity of quantum systems via their correlations with their environment--information that hypothetical observers can recover by measuring the environments. However, observations are done with respect to a frame of reference. Here, we take the formalism of [Giacomini, Castro-Ruiz, & Brukner. Nat Commun 10, 494 (2019)], and consider the repercussions on objectivity when changing quantum reference...
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Zastosowanie mieszania wgłębnego i iniekcji strumieniowej do wzmocnienia podłoża pod budynkiem basenu.
PublikacjaPrzedstawiono jeden z pierwszych przykładów zastosowania w Europie nowoczesnej technologii wgłębnego mieszania gruntu na mokro (ang. wet Deep Soil Mixing) w celu posadowienia budynku basenu na uwarstwionym podłożu zawierającym grunt organiczny. Technologia DSM, wprowadzona w Polsce przez firmę Keller, polega na mechanicznym mieszaniu in situ gruntu z zaczynem cementowym i pozwala na formowanie w gruncie kolumn z cementogruntu w...
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Structure of the interlayer between Au thin film and Si-substrate: Molecular Dynamics simulations
PublikacjaInteraction between 2, 3, 5 and 7 atomic layers of gold and a (111) silicon surface was investigated with the molecular dynamics simulation method. The simulation of the diffusion interaction between gold and silicon in the temperature range 425-925 K has been carried out. The peculiarities of the concentration changes of the interacting components and the atomic density at the boundary...
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Magnetic field effects in dye-sensitized solar cells controlled by different cell architecture
PublikacjaThe charge recombination and exciton dissociation are generally recognized as the basic electronic processes limiting the efficiency of photovoltaic devices. In this work, we propose a detailed mechanism of photocurrent generation in dye-sensitized solar cells (DSSCs) examined by magnetic field effect (MFE) technique. Here we demonstrate that the magnitude of the MFE on photocurrent in DSSCs can be controlled by the radius and...
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Improving Objective Speech Quality Indicators in Noise Conditions
PublikacjaThis work aims at modifying speech signal samples and test them with objective speech quality indicators after mixing the original signals with noise or with an interfering signal. Modifications that are applied to the signal are related to the Lombard speech characteristics, i.e., pitch shifting, utterance duration changes, vocal tract scaling, manipulation of formants. A set of words and sentences in Polish, recorded in silence,...
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Application of the near-infrared spectroscopy in the pharmaceutical technology
PublikacjaNear-infrared (NIR) spectroscopy is currently the fastest-growing and the most versatile analytical method not only in the pharmaceutical sciences but also in the industry. This review focuses on recent NIR applications in the pharmaceutical technology. This article covers monitoring, by NIR, of many manufacturing processes, such as granulation, mixing or drying, in order to determine the end-point of these processes. In this...
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A conceptual design and numerical analysis of the mixerless urea-SCR system
PublikacjaIn the present study, an innovative design of the urea-selective catalytic reduction (SCR) system without conventional mixing elements was developed. The aim was to obtain a high degree of urea decomposition, and uniform ammonia distribution at the inlet to the catalyst, while minimising the liquid film deposition and keeping the compact design. The concept of the design was based on creating high turbulences and elongating...
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The Progress in Electron Microscopy Studies of Particulate Matters to Be Used as a Standard Monitoring Method for Air Dust Pollution
PublikacjaThe present article reviews studies on air solid particles carried out with the use of electron microscopy. Particle analysis combining scanning and transmission electron microscopy (SEM and TEM) can be used to derive size-resolved information of the composition, mixing state, morphology, and complex refractive index of atmospheric aerosol particles. It seems that electron microscopy is more widely used in atmospheric particulate...
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Effect of electron count and chemical complexity in the Ta-Nb-Hf-Zr-Ti high-entropy alloy superconductor
PublikacjaHigh-entropy alloys are made from random mixtures of principal elements on simple lattices, stabilized by a high mixing entropy. The recently discovered body-centered cubic (BCC) Ta-Nb-Hf-Zr-Ti high-entropy alloy superconductor appears to display properties of both simple crystalline intermetallics and amorphous materials; e.g., it has a well-defined superconducting transition along with an exceptional robustness against disorder....
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What is in a name: Defining “high entropy” oxides
PublikacjaABSTRACT High entropy oxides are emerging as an exciting new avenue to design highly tailored functional behaviors that have no traditional counterparts. Study and application of these materials are bringing together scientists and engineers from physics, chemistry, and materials science. The diversity of each of these disciplines comes with perspectives and jargon that may be confusing to those outside of the individual fields,...
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Effect of Porosity on the Thermo-Mechanical Behavior of Friction-Stir-Welded Spark-Plasma-Sintered Aluminum Matrix Composites with Bimodal Micro- and Nano-Sized Reinforcing Al2O3 Particles
PublikacjaThe thermo-mechanical behavior of nanosized Al2O3 particles reinforcing aluminum was analyzed in the present paper. The material was prepared by spark plasma sintering and friction stir welding. The thermal stresses affecting the composite behavior during welding were modeled through COMSOL MultiPhysics, and the results were validated by the analyses of the composites’ mechanical properties. The spark-plasma-sintered materials...
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Novel Desorber for Online Drilling Mud Gas Logging
PublikacjaThis work presents the construction solution and experimental results of a novel desorber for online drilling mud gas logging. The traditional desorbers use mechanical mixing of the liquid to stimulate transfer of hydrocarbons to the gaseous phase that is further analyzed. The presented approach is based on transfer of hydrocarbons from the liquid to the gas bubbles flowing through it and further gas analysis. The desorber was...
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Stability investigation of the PCM nanocomposites
PublikacjaIn present study was showed the results of research the stability of nanoPCMs in terms of types and concentrations of surfactant used. For stearic acid has been added PVP or oleic acid in concentrations of 0%, 5% and 10%. Nanoparticles TiO2 and Al-2O3 in concentration of 1% were chosen to be researched in this test. The mixing of nanocomposites has been done in an ultrasonic scrubber in which the samples were placed for 45 mins....
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Tailoring the Size and Shape—New Path for Ammonium Metavanadate Synthesis
PublikacjaAmmonium metavanadate, NH4VO3, plays an important role in the preparation of vanadium oxides and other ammonium compounds, such as NH4V3O8, (NH4)2V3O8, and NH4V4O10, which were found to possess interesting electrochemical properties. In this work, a new route for the synthesis of NH4VO3 is proposed by mixing an organic ammonium salt and V2O5 in a suitable solvent. The one-step procedure is carried out at room temperature. Additionally,...
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Analysis of Lombard speech using parameterization and the objective quality indicators in noise conditions
PublikacjaThe aim of the work is to analyze Lombard speech effect in recordings and then modify the speech signal in order to obtain an increase in the improvement of objective speech quality indicators after mixing the useful signal with noise or with an interfering signal. The modifications made to the signal are based on the characteristics of the Lombard speech, and in particular on the effect of increasing the fundamental frequency...
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The effect of tyre rubber grinding method on the rubber-asphalt binder properties
PublikacjaRubber products, especially those used in the automotive industry, are responsible for a significant amount of waste, mainly in the form of worn tyres. One way to recycle tyres is to use them as an asphalt binder modifier. The properties of rubber-asphalt binders vary greatly depending on the morphology of the ground tyre rubber (GTR) grains and the type of tyre to be recycled (car/truck). The paper presents the results of research...
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Environmentally Oriented Models and Methods for the Evaluation of Drug x Drug Interaction Effects
PublikacjaThis detailed review compares known and widely used methods for drug interaction estimation, some of which now have historical significance. Pharmaceutical application has been noted as far back as several thousand years ago. Relatively late in the 20th century, however, researchers became aware that their fate and metabolism, which still remain a great challenge for environmental analysts and risk assessors. For the patient’s...
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Study of preference for surround microphone techniques, used in the recording of choir and instrumental ensemble
PublikacjaThe aim of this paper is to describe the process of choosing the best surround microphone technique for recording of choir with an instrumental ensemble. First, examples of multichannel microphone techniques including those used in the recording are described. Then, the assumptions and details of music recording in Radio Gdansk Studio are provided as well as the process of mixing of the multichannel recording. The extensive subjective...
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Crystal structure and electronic structure of CePt2In7
PublikacjaWe report a corrected crystal structure for the CePt2In7 superconductor, refined from single crystal x-ray diffraction data. The corrected crystal structure shows a different Pt–In stacking along the c-direction in this layered material than was previously reported. In addition, all of the atomic sites are fully occupied with no evidence of atom site mixing, resolving a discrepancy between the observed high resistivity ratio of...
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Lab-in-syringe as a practical technique for automatic microextraction: Evaluation by Blue Applicability Grade Index
PublikacjaLab-in-syringe (LIS) is a powerful automatic technique that is derived from sequential injection analysis. In LIS, a computer-controlled syringe pump is employed, and its syringe barrel serves as a mixing, reaction, and/or extraction chamber. Until now, the LIS concept has been efficiently employed for the automation of solid-phase microextraction and liquid-phase microextraction protocols as a front-end to a plethora of chromatographic...
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Bioactive core material for porous load-bearing implants
PublikacjaSo far state of knowledge on biodegradable materials is reviewed. Among a variety of investigated materials, those composed of polymers and ceramics may be considered as only candidates for a core material in porous titanium alloy. The collagen and chitosan among natural polymers, polyhydroxy acids among synthetic polymers, and hydroxyapatite and tricalcium phosphate among ceramics are proposed for further research. Three essential...
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Study on polymer modified road asphalt mixture
PublikacjaThe formulation of ternary asphalt-additives blend composed of crumb rubber : low-density polyethylene (CR : LDPE) and crumb rubber : textile fiber (CR : TF) couples, and quaternary asphalt additives-blend composed of (CR : LDPE : TF) triplets on the virgin asphalt to optimize the asphalt basic and rheological properties and to use the extrusion process of two or three additives to obtain composite materials of them, as well as...