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Wyniki wyszukiwania dla: materials properties
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A facile preparation method and proof of cycle-stability of carbon-coated metal oxide and disulfide battery materials
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Selected metrological aspects of permeation cells used for testing the resistance of polymeric materials to penetration by liquid chemicals
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Manual work in cold environments and its impact on selection of materials for protective gloves based on workplace observations
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Permeation of mineral oils through protective glove materials in view of literature data and authors’ own studies
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Electromodulation of fluorescence in hole-transporting materials for organic light-emitting diodes. Part II: Straburst amines
PublikacjaPraca jest kontynuacją artykułu, który został opublikowany wChem. Phys. vol. 256 (2000) s. 351-362. Zaobserwowano silne wygaszenie fluorescencji w dendrymerach aminowych zbudowanych na bazie trifenyloaminy. Efekt ten został przypisany rozpadowi stanów emitujących światło pod działaniem silnego pola elektrycznego.
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Polygons vs. clumps of discs: A numerical study of the influence of grain shape on the mechanical behaviour of granular materials
PublikacjaWe performed a series of numerical vertical compression tests on assemblies 01 20 granular material using a Discrete Element code and studied the results with regard to the grain shape. The samples consist of 5000 grains made from either 3 overlapping discs (clumps - grains with concavities) or six-edged polygons (convex grains). These two grain type have similar external envelope, which is a fund ion of a geometrical parameter...
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Synthesis and characterization of cycloaliphatic hydrophilic polyurethanes, modified with l-ascorbic acid, as materials for soft tissue regeneration
PublikacjaIn this paper we described synthesis and characteristic of obtained hydrophilic polyurethanes (PURs) modified with ascorbic acid (commonly known as vitamin C). Such materials may find an application in the biomedical field, for example in the regenerative medicine of soft tissues, according to ascorbic acid wide influence on tissue regeneration Flora (2009), Szymańska-Pasternak et al. (2011), Taikarimi and Ibrahim (2011), Myrvik...
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Quenching of bright and dark excitons via deep states in the presence of SRH recombination in 2D monolayer materials
PublikacjaTwo-dimensional (2D) monolayer materials are interesting systems due to an existence of optically non-active dark excitonic states. In this work, we formulate a theoretical model of an excitonic Auger process which can occur together with the trap-assisted recombination in such 2D structures. The interactions of intravalley excitons (bright and spin-dark ones) and intervalley excitons (momentum-dark ones) with deep states located...
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Experimental study on the feasibility of alternative materials for tilting pad thrust bearings operating in transition to mixed friction
PublikacjaIn hydrodynamic bearings traditional bearing alloys: Babbitts and bronzes are most frequently utilized. Polymer sliding layers are sometimes applied as a valuable alternative. Hard diamond-like carbon (DLC) coatings, which are also considered for certain applications may show some advantages, as well. Although material selection is of secondary importance in a full film lubrication regime it becomes important in mixed friction...
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Effectiveness of various types of coating materials applied in reinforced concrete exposed to freeze–thaw cycles and chlorides
PublikacjaThis study assesses the durability of coated and uncoated concrete surfaces protected with four Different coating materials: water-soluble (BW), solvent-based (BR), mineral (MI), and epoxy (EP). The durability assessment includes evaluating the absorption rate of water, pull-of adhesion strength, and coating material thickness. Concrete samples were subjected to immersion in regular water and a 7% urea solution, followed by cyclic...
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FE-modeling of shear resistance degradation in granular materials during cyclic shearing under CNS condition
PublikacjaW artykule przedstawiono wyniki numerycznej analizy degradacji wytrzymałości na ścinanie w materiałach granulowanych podczas cyklicznego ścinania z warunkiem stałej sztywności normalnej. Obliczenia wykonano przy zastosowaniu metody elementów skończonych i mikropolarnego modelu hipoplastycznego.
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Non-coaxiality and stress-dilatancy rule in granular materials: FE-investigation within micro-polar hypoplasticity
PublikacjaW artykule przedstawiono wyniki numerycznej analizy nieosiowości i zasady naprężenie-dylatancja w materiałach granulowanych podczas ściskania dwuosiowego. Obliczenia wykonano przy zastosowaniu metody elementów skończonych i mikropolarnego modelu hipoplastycznego.
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Quantitative estimation of volume changes of granular materials during silo flow using X-ray tomography.
PublikacjaW artykule przedstawiono wyniki badań doświadczalnych nad zmianami objętościowymi materiału granulowanego podczas przepływu silosowego. Badania wykonano przy zastosowaniu tomografii rentgenowskiej. Wyniki porównano z wynikami doświadczalnymi przy zastosowaniu cyfrowej obróbki zdjęć płynącego materiału.
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Photo-elastic and DIC techniques to study development of dilatant and compaction shear bands within granular materials
PublikacjaW artykule omówiono wyniki doświadczalne w odniesieniu do rozwoju stref ścinania w materiałach granulowanych. Wyniki stref ścinania otrzymano stosując metodę foto-sprężystą oraz technikę korelacji cyfrowych obrazów DIC. Pokazano zalety i wady obu metod to wykrywania stref scinania.
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Luminescent properties of LiF crystals for fluorescent imaging of nuclear particles tracks
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Effect of perlite waste addition on the properties of autoclaved aerated concrete
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Symmetrical and unsymmetrical azomethines with thiophene core: structure–properties investigations
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Dispersion, compatibility, and rheological properties of graphene-modified asphalt binders
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The Influence of Synthesis Temperature on Manufacturing and Properties of SrSi2O2N2:Eu2+ Powders
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Reliable method of assessing fracture properties of asymmetric bonded joints
PublikacjaTwo methods of assessing fracture properties of adhesive joints were studied. Two wedge tests: with continuous deflection and with force measurements were compared. Asymmetric geometry of the bonded joint was considered, i.e. two different plates of aluminium alloys: Al-Cu and Al-Mg, were bonded with epoxy DGEBA adhesive. The analytical model is shown to estimate the values of fracture properties: crack position and critical fracture...
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Measurements of the optical and thermal properties of the 2D black phosphorus coating
PublikacjaBlack phosphorus is a 2D material, which properties are still being discovered. In this paper, the sensitivity to the temperature of a few-layer black phosphorus coating deposited, on the surface of a microsphere-based fiber-optic sensor, by a dip-coating method is presented. The coating was investigated after 2, 3, and 5 deposition cycles and during temperature growth from 50 °C to 300 °C in an interferometric setup. The intensity...
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Effects of V2O5 Additive on Structure and Dielectric Properties of BiNbO4 Ceramics
PublikacjaGoal of the present research was to investigate the influence of V2O5 additive on the structure and dielectric properties of BiNbO4 ceramics. To fabricate BiNbO4 ceramics with V2O5 added the solid state reaction route and pressureless sintering was utilized. Thus obtained ceramics was characterized in terms of its microstructure (SEM), chemical composition (EDS), phase composition and crystalline structure (X-ray phase and structural...
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Hybrid TiO2–Polyaniline Photocatalysts and their Application in Building Gypsum Plasters
PublikacjaHybrid materials of conjugated polymer and titanium(IV) oxide have attracted considerable attention concerning their potential benefits, including (i) ecient exploitation of visible light, (ii) a high adsorption capacity for organic contaminants, (iii) and eective charge carriers separation. The new class of the photocatalysts is promising for the removal of environmental pollutants in both aqueous and gaseous phases. For the first...
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Organomercury compounds in environmental samples: emission sources, toxicity, environmental fate and determination.
PublikacjaIn view of the specific properties of mercury and its capability of forming compounds that can be bioaccumulated and biomagnified at successive levels of the trophic pyramid, it has become necessary to gather detailed information on the sources of emission of this element into the environment and its fate there. Moreover, the increasing awareness of the relationship between the toxicity of mercury and its chemical form has sharpened...
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Flexomagneticity in Functionally Graded Nanostructures
PublikacjaFunctionally graded structures have shown the perspective of materials in a higher efficient and consistent manner. This study reports a short investigation by concentrating on the flexomagnetic response of a functionally graded piezomagnetic nano-actuator, keeping in mind that the converse magnetic effect is only taken into evaluation. The rule of mixture assuming exponential composition of properties along with the thickness...
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Preparation and characterization of bis‐phosphonated polycarbohydrates
PublikacjaA simple, cost-effective, one-pot method was proposed to introduce bis-phosphonic groups onto alginic acid and carboxymethyl cellulose (CMC). New derivatives were characterized by means of nuclear magnetic resonance, X-ray photoelectron, and attenuated total reflectance Fourier transform infrared spectroscopy. These analyses confirmed the successful transformation of carboxylic groups present in alginic acid and CMC into bis-phosphonic...
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A new finite element with variable Young's modulus
PublikacjaThe Finite Element Method (FEM) is a numerical technique that is well-established in the field of engineering. However, in biological sciences, it is justtaking its first steps. Bone tissue is an example of biological material which isexposed to high loads in its natural environment. Practically every movementof the body results in changing stress levels in the bone. Nature copes with thisvery well but when human intervention is...
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Luminescence properties of Eu3+ and Tb3+ doped silica-based xerogels
PublikacjaPure SiO2 xerogels and SiO2 xerogels containing SrF2: Eu3+/: Tb3+ crystals were prepared using sol-gel method. Luminescent spectra showed excitation and emission peaks characteristic to Eu3+ and Tb3+ 4f - 4f transitions. ET Tb3+→Eu3+ has been observed. XRD pattern of SiO2 matrix confirmed lack of long range order. Patterns of SiO2-SrF2:Eu3+ and SiO2-SrF2:Tb3+ showed peaks corresponding to SrF2. SEM images have shown agglomerates...
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Characterization of Mechanical and Bactericidal Properties of Cement Mortars Containing Waste Glass Aggregate and Nanomaterials
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Effect of Nano-SiO2 on the Microstructure and Mechanical Properties of Concrete under High Temperature Conditions
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Chemical, Physical, and Mechanical Properties of 95-Year-Old Concrete Built-In Arch Bridge
PublikacjaThis research aimed to determine the durability and strength of an old concrete built-in arch bridge based on selected mechanical, physical, and chemical properties of the concrete. The bridge was erected in 1925 and is located in Jagodnik (northern Poland). Cylindrical specimens were taken from the side ribs connected to the top plate using a concrete core borehole diamond drill machine. The properties of the old concrete were...
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The Influence of Nanometals, Dispersed in the Electrophoretic Nanohydroxyapatite Coatings on the Ti13Zr13Nb Alloy, on Their Morphology and Mechanical Properties
PublikacjaIn this work, nanohydroxyapatite coatings with nanosilver and nanocopper have been fabricated and studied. The presented results concern coatings with a chemical composition that has never been proposed before. The present research aims to characterize the effects of nanosilver and nanocopper, dispersed in nanohydroxyapatite coatings and deposited on a new, non-toxic Ti13Zr13Nb alloy, on the physical and mechanical properties of...
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Ligand-Modified Boron-Doped Diamond Surface: DFT Insights into the Electronic Properties of Biofunctionalization
PublikacjaWith the increasing power of computation systems, theoretical calculations provide a means for quick determination of material properties, laying out a research plan, and lowering material development costs. One of the most common is Density Functional Theory (DFT), which allows us to simulate the structure of chemical molecules or crystals and their interaction. In developing a new generation of biosensors, understanding the nature...
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Tailoring Electro/Optical Properties of Transparent Boron-Doped Carbon Nanowalls Grown on Quartz
PublikacjaCarbon nanowalls (CNWs) have attracted much attention for numerous applications in electrical devices because of their peculiar structural characteristics. However, it is possible to set synthesis parameters to vary the electrical and optical properties of such CNWs. In this paper, we demonstrate the direct growth of highly transparent boron-doped nanowalls (B-CNWs) on optical grade fused quartz. The effect of growth temperature...
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Nanokrystaliczne tlenki metali jako katalizatory reakcji wydzielania tlenu w środowisku zasadowym
PublikacjaW pracy poruszona została tematyka opracowania oraz zastosowania nanokrystalicznych tlenków metali jako katalizatorów reakcji wydzielania tlenu w elektrolicie zasadowym, tj. jednej z reakcji zachodzących podczas elektrolizy wody. Szczególną uwagę poświęcono tlenkom o strukturze spinelu i perowskitu, które znane są z wyjątkowych właściwości elektrycznych, magnetycznych, optycznych oraz katalitycznych. Materiały zostały przygotowane...
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Poly-L-Lysine-functionalized fluorescent diamond particles: pH triggered fluorescence enhancement via surface charge modulation
PublikacjaRecently, the interest in applying fluorescent diamond particles (FDPs) containing nitrogen-vacancy (NV) centers for enhancing the mechanical and chemical properties of some materials, biological imaging, and sensing has been expanding rapidly. The unique properties of NV centers such as intensive, time-stable fluorescence, and an electron spin, which exhibits long coherence time and may be manipulated using external stimuli, such...
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Tailoring Diffusional Fields in Zwitterion/Dopamine Copolymer Electropolymerized at Carbon Nanowalls for Sensitive Recognition of Neurotransmitters
PublikacjaThe importance of neurotransmitter sensing in the diagnosis and treatment of many psychological illnesses and neurodegenerative diseases is non-negotiable. For electrochemical sensors to become widespread and accurate, a long journey must be undertaken for each device, from understanding the materials at the molecular level to real applications in biological fluids. We report a modification of diamondized boron-doped carbon nanowalls...
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Comparative Study of the Mechanical Behaviour of Bitumen- and Cement-Dominated Mixtures with Reclaimed Asphalt
PublikacjaThe bitumen emulsion-based recycling is a commonly used maintenance treatment in the rehabilitation of low-and medium-volume roads in Europe. Nevertheless, the wide range of climatic conditions across the continent resulted in the variety of mixture concepts and the requirements being adopted for various local conditions. In this regard, the most commonly used parameter to distinguish between the main mixture concepts is bitumen...
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Enhanced acceptor concentration, proton conductivity, and hydration in multicomponent rare‐earth ortho‐niobates
PublikacjaThe structural properties of (La0.2Nd0.2Sm0.2Gd0.2Eu0.2)1−xCaxNbO4−δ (x = 0–0.05) series have been studied by X-ray powder diffraction at room temperature. The thermal properties were investigated using thermogravimetry, from which the concentration of proton defects was determined. Additionally, dilatometry studies were carried out, from which the thermal expansion coefficients and the phase transition temperature between low-...
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l-ascorbic acid modified poly(ester urethane)s as a suitable candidates for soft tissue engineering applications
PublikacjaIn this paper we created novel poly(ester urethane)s (PESUs) designed specifically for tissue engineering. The PESUs were derived from oligomeric α,ω-dihydroxy(ethylene-butylene adipate) (dHEBA), 1,4-butanediol (BDO) and aliphatic 1,6-hexamethylene diisocyanate (HDI) and modified with l-ascorbic acid to improve their biocompatibility. In addition, we determined their mechanical properties (such as tensile strength, elongation at...
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Simplified Approach for Broadband RF Testing of Low Loss Magneto-Dielectric Samples
PublikacjaIn this paper, an attractive measurement techniqueis proposed to retrieve the broadband permittivity and permeabil-ity of the magneto-dielectric materials. The proposed techniqueis quite novel which mitigates the major problems associatedwith the conventional broadband RF material characterizationtechniques such as numerical instability and phase uncertaintywhen the length of the sample exceeds...
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Hyaluronic acid/tannic acid films for wound healing application
PublikacjaIn this study, thin films based on hyaluronic acid (HA) with tannic acid (TA) were investigated in three different weight ratios (80HA/20TA, 50HA/50TA, 20HA/80TA) for their application as materials for wound healing. Surface free energy, as well as their roughness, mechanical properties, water vapor permeability rate, and antioxidant activity were determined. Moreover, their compatibility with blood and osteoblast cells was investigated....
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Study on polymer modified road asphalt mixture
PublikacjaThe formulation of ternary asphalt-additives blend composed of crumb rubber : low-density polyethylene (CR : LDPE) and crumb rubber : textile fiber (CR : TF) couples, and quaternary asphalt additives-blend composed of (CR : LDPE : TF) triplets on the virgin asphalt to optimize the asphalt basic and rheological properties and to use the extrusion process of two or three additives to obtain composite materials of them, as well as...
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Rubber wastes recycling for developing advanced polymer composites: A warm handshake with sustainability
PublikacjaRecycling and management of rubber wastes experiences an early-stage maturity in the quest for sustainable and circular materials. Up to now, solutions proposed for sustainable development of rubber wastes are limited, so that properties and performance features of recycled products are inadequate for practical applications. Herein, an experimental protocol is introduced for manufacturing semi-sustainable polymer composites based...
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Creation and properties of the (Mn-N-O) layers on aluminium
Publikacjaprzedstawiono metodę wytwarzania warstw powierzchniowych zawierających mangan, azot i tlen na stopie Al-Si-Mg-Cu-Ni. Określono ich mikrostrukturę, mikrotwardość, wlaściwości tribologiczne oraz korozyjne w roztworze 0,01M H2SO4. Stwierdzono wielokrotny wzrost odporności na ścieranie stopu aluminium z wytworzoną warstwą wierzchnią we współpracy ciernej z żeliwem szarym perlitycznym.
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Physical properties of polyazomethine thin films doped with iodine
PublikacjaPurpose: The aim of this paper is to show influence of doping 1,4-phenylene-methylenenitrilo-1,4-phenylenenitrilomethylene (PPI) with iodine and to propose doping mechanism and its impact on electronicstructure of doped PPI thin films.Design/methodology/approach: Influence of iodine doping on electronic structure of polyazomethine thinfilms was investigated. Optical absorption spectra, XRD spectra and AFM images of doped PPI...
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Microstructure and corrosion properties of the laser treated SUPERSTON alloy
PublikacjaPrzedstwiono wyniki laserowego nadtapiania powierzchni stopu SUPERSTON w warunkach kriogenicznych. Zaprezentowano obraz powierzchni stopu po badaniach korozyjnych oraz wyniki pomiarów mikrotwardości i odporności korozyjnej.
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A dissimilar welded joint of grade 92 steel and AISI 304L steel obtained using IN82 buttering and IN617 fller: relationship of microstructure and mechanical properties
PublikacjaUnfavourable operating conditions of equipment in the energy industry resulting from high-temperature loads determine the need to use special materials and technological solutions, including welding procedures. In this article, buttering using IN82 (ERNiCr-3) consumables was proposed as a method to improve the weldability of grade 92 steel joined by the gas tungsten arc welding (GTAW) process with AISI 304L (IN617 fller). The...
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Characteristics of silver-dopped carbon nanotube coating destined for medical applications
PublikacjaCarbon nanotubes are materials demonstrating outstanding mechanical, chemical, and physical properties and are considered coatings of titanium implants. The present research is aimed to characterize the microstructure and properties of the multi-wall carbon nanotubes (MWCNTs) layer decorated with silver nanoparticles (Ag NPs) on the Ti13Nb13Zr alloy destined for long-term implants. The electrophoretic deposition of coatings...
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Novel Complementary Resonator for Dielectric Characterization of Substrates Based on Permittivity and Thickness
PublikacjaThis paper presents a novel complementary resonator featuring high sensitivity, low fabrication cost, and improved performance. The proposed structure consists of a complementary concentric square and circular ring resonator (CCSCRR) with multiple splits to enhance the inductance of the resonator. The proposed CCSCRR is coupled to a microstrip transmission line with an impedance of fifty ohms to create a high-sensitivity sensor....