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Wyniki wyszukiwania dla: ARENE RUTHENIUM COMPLEX
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Molecular Modelling of the Neurophysin II/Vasopressin Complex
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Discussion of Modelling Perspectives for Complex Economic Systems.
PublikacjaW artykule opisano rolę modelowania w ekonomicznych systemach złożonych w kontekście trzech funkcji naukowych: opisu, wyjaśniania i przewidywania. Fazy dekompozycji i opisu jakościowego modelowanych systemów, w tym ekonomicznych, są nieodzowne w całym procesie.
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Soft modelling aspects of complex IT systems development.
PublikacjaZaproponowano metodykę opartą na teorii zbiorów rozmytych do zakresu wspomagania decyzji na etapie budowy złożonych systemów z obszaru information technology (IT). Omówiono wszystkie elementy proponowanego podejścia. Przedstawiona architektura ma zastosowanie głównie do zarządzania projektami IT na etapie ich powstawania.
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Experimental generation of complex noisy photonic entanglement
PublikacjaWe present an experimental scheme based on spontaneous parametric down-conversion to produce multiple-photon pairs in maximally entangled polarization states using an arrangement of two type-I nonlinear crystals. By introducing correlated polarization noise in the paths of the generated photons we prepare mixed-entangled states whose properties illustrate fundamental results obtained recently in quantum information theory, in particular those...
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Complex multidisciplinary optimization of turbine blading systems
PublikacjaThe paper describes the methods and results of direct optimization of turbine blading systems using a software package Opti_turb. The final shape of the blading is obtained from minimizing the objective function, which is the total energy loss of the stage, including the leaving energy. The current values of the objective function are found from 3D RANS computations (from a code FlowER) of geometries changed during the process...
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Isostructural zinc and cadmium silanethiolates with bridging biimidazole co-ligands – Enhanced luminescence of zinc complex
PublikacjaTwo dinuclear complexes of zinc and cadmium with silanethiolate and bridging biimidazole ligands are characterized by X-ray diffraction, FT-IR, UV–Vis and emission spectroscopies. The complexes 1 (Zn) and 2 (Cd) are isostructural but exhibit different electronic structures and different character of frontier HOMO orbitals as indicated by DFT calculations. Lluminescence studies prove strong emission properties of zinc complex.
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Cadmium complex possessing simultaneously silanethiolato- and dithiocarbamato-ligands. A novel single-source precursor of cadmium sulfide
PublikacjaThermal decomposition of suitable coordination compounds may be used as efficient route for fabrication of semiconducting layers. A new potential CdS precursor—a cadmium complex with all-sulfur Cd-coordination sphere [Cd{l-SSi(OBut)3}(S2CNC4H8)]2 (1) —has been prepared and its properties are investigated. The complex was obtained in the reaction between dimeric bis(tri-tert-butoxysilanethiolato) cadmium(II) [Cd{SSi(OBut)3}2]2 and...
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Interdisciplinary research as a form of monument protection and preparation for the investment process on the example of the former Gdańsk Shipyard complex
PublikacjaThe multi-layered heritage of many industrial plants operating until the end of the 20th century creates a particular challenge for conservators, designers and investors. In the process of protecting its values, displaying qualities and managing the property, it is necessary to recognize a wider transformation of technology of the entire plant and the individual functions of its buildings, as well as the context of intangible...
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The optimisation of analytical parameters for routine profiling of antioxidants in complex mixture by HPLC coupled post-column derivatisation
PublikacjaIntroduction: The wide application of natural and artificial antioxidants in food, cosmetic and pharmaceutical industry as well as the recognition of the importance of food antioxidants for supporting human health created demand for reliable and industrially applicable methods of determining antioxidative activity. This requirement can be fullfilled with the recently proposed HPLC-post-column derivatisation approach enabling the...
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Complex Corrosion Monitoring System for Crude Distillation Unit in Form of Neutral Network
PublikacjaComplex and successful corrosion monitoring of refinery processes can significantly reduce material losses and failure risk. The developed corrosion monitoring system is based on online ultrasonic sensors, ER (electrical resistance) probes, gravimetric method and multipoint analytical analysis of chemical composition of the fluids. Additional online LPR (linear polarization resistance) sensors controlling corrosiveness of sour...
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Monosubstituted hydrazone β-cyclodextrin derivatives for pH-sensitive complex formation with aromatic drugs
PublikacjaA new and convenient synthetic pathway was developed to produce monosubstituted cyclodextrins with high yields. Each of the β-cyclodextrin derivatives described in this work has an aromatic substituent connected with cyclodextrin core by a pH-sensitive hydrazone linker and a carbon chain. Carbon chains differ in lengths having one or three carbon atoms. The correlation between water solubility and linker length was determined using...
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Multi-Criteria Knowledge-Based Recommender System for Decision Support in Complex Business Processes
PublikacjaIn this paper, we present a concept of a multi-criteria knowledge-based Recommender System (RS) designed to provide decision support in complex business process (BP) scenarios. The developed approach is based on the knowledge aspects of Stylistic Patterns, Business Sentiment and Decision-Making Logic extracted from the BP unstructured texts. This knowledge serves as an input for a multi-criteria RS algorithm. The output is prediction...
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Solvent Impact on the Diversity of Products in the Reaction of Lithium Diphenylphosphide and a Ti(III) Complex Supported by a tBu2P–P(SiMe3) Ligand
PublikacjaWe present two important trends in the reactivity ofthe titanium complex [MeNacNacTi(Cl){η2-P(SiMe3)-PtBu2}](MeNacNac− = [Ar]NC(Me)CHC(Me)N[Ar]; Ar = 2,6-iPr2Ph)with nucleophilic reagents RLi (R = Ph2P,tBuO, (Me3Si)2N, andtBu2N) depending on the reaction medium. Reaction in nonpolarsolvent (toluene) leads to three main products: via an autoredoxprocess and nucleophilic substitution at the Ti-atom to afford theTi(IV) complex [MeNacNacTi(R){η2-P-PtBu2}]...
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Analysis of Reconstituted Tripartite Complex Supports Avidity-based Recruitment of Hsp70 by Substrate Bound J-domain Protein
PublikacjaHsp70 are ubiquitous, versatile molecular chaperones that cyclically interact with substrate protein(s). The initial step requires synergistic interaction of a substrate and a J-domain protein (JDP) cochaperone, via its J-domain, with Hsp70 to stimulate hydrolysis of its bound ATP. This hydrolysis drives conformational changes in Hsp70 that stabilize substrate binding. However, because of the transient nature of substrate and JDP...
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A new phosphonium calix[4]arene for selective anion recognition: synthesis and studies in solution and in ion selective electrodes
PublikacjaZaprezentowana została synteza i charakteryzacja tetra (trifenylofosfoniowego) p-tert-butylkaliks[4]arenu 2. Oddziaływania z anionami były badane z użyciem (1)H oraz (31)P NMR i spektrofotometrii absorpcyjnej UV. Badania wykazały oddziaływania z anionami: CLO4-, I-, oraz SCN-. Selektywność jonoforu 2 badano również w membranowych elektrodach jonoselektywnych (ISE) PCV/o-NPOE. Elektroda zawierająca związek 2 generuje odpowiedź potencjometryczną...
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Preparation, characterization and anti-colitis activity of curcumin-asafoetida complex encapsulated in turmeric nanofiber
PublikacjaUlcerative colitis (UC) is a main form of inflammatory bowel disease (IBD). Asafoetida (ASF) and turmeric have traditionally been used for the treatment of various inflammatory diseases, including UC, because ASF is rich in sulfur compounds and turmeric contains curcumin (CUR). Turmeric nanofiber (TNF), the modified cell wall component of turmeric is considered to play important role in the human diet, health and can be used as...
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Global Complex Roots and Poles Finding Algorithm Based on Phase Analysis for Propagation and Radiation Problems
PublikacjaA flexible and effective algorithm for complex roots and poles finding is presented. A wide class of analytic functions can be analyzed, and any arbitrarily shaped search region can be considered. The method is very simple and intuitive. It is based on sampling a function at the nodes of a regular mesh, and on the analysis of the function phase. As a result, a set of candidate regions is created and then the roots/poles are verified...
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Estimation of Broadband Complex Permeability Using SIW Cavity-Based Multimodal Approach
PublikacjaIn this article, an attractive multimodal substrate integrated waveguide (SIW) based methodology is presented for the characterization of magnetic materials in the broadband microwave frequency. The proposed approach employs a modified feed under-coupled SIW cavity instead of conventional feed over-coupled multiple SIW cavities; it uses the modified closedform expression, developed from the first principle to consider the effect...
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Polymeric micelle-mediated delivery of half-sandwich ruthenium(II) complexes with phosphanes derived from fluoroloquinolones for lung adenocarcinoma treatment
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Main complications connected with detection, identification and determination of trace organic constituents in complex matrix samples
PublikacjaIt is well known that some problems with the determination of organic analytes at trace level can occur. This issue is connected with contamination during each stage of the analytical procedure from sampling to sample preparation up to chromatographic analysis, which often leads to false-positive or overestimated results. Another problem associated with determination of analytes occurs at trace- and ultra-trace level is a background...
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New Insights into Thermodynamics of Solutes in Neat and Complex Solvents
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On the use of instantaneous complex frequency for pitch and formant tracking.
PublikacjaW pracy opisano algorytm śledzenia częstotliwości podstawowej i formantów mowy z wykorzystaniem zespolonej pulsacji chwilowej. Działanie algorytmu przetestowano na nagraniach polskich samogłosek, których wysokość zmieniała się płynnie. Wyniki testów wraz z porównaniem działania opisanej metody i metody predykcji liniowej zawarto w artykule.
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Charge orderings and lattice distortions in complex TCNQ salts
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A complex variable fractional-delay FIR filter structure
PublikacjaW artykule wprowadzamy strukturę zespolonego filtru o skończonej odpowiedzi impulsowej (ang. finite impulse response - FIR) ze zmiennym opóźnieniem ułamkowym (ang. fractional delay - FD). Strukturę tę otrzymujemy na podstawie przestrajanego filtru FD FIR o współczynnikach rzeczywistych. Stanowi ona połączenie zbioru liniowo-fazowych filtrów FIR o współczynnikach stałych rzeczywistych i dwóch łańcuchów mnożąco-akumulujących, zawierających...
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Complex multiplier based on the polynomial residue number system
PublikacjaPrzedstawiono próbę zaprojektowania mnożnika zespolonego 4x4 opartego na algorytmie Skavantzosa i Stouraitisa. W algorytmie stosuje siękodowanie liczb n-bitowych jako wielomianów stopnia 7 w pierścieniu wielomianów modulo (x^8-1) z n/4-bitowymi współczynnikami. Mnożenie zespolone jest wykonywane jako 8-punktowy splot cykliczny. Podanoopóżnienie i złożoność sprzętową jak również porównanie ze standardowym.rozwiązaniem.
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The structure of levorin A3, a minor component of levorin complex
PublikacjaBudowa chemiczna składnika kompleksu leworyn, leworyny A3, została ustalona na podstawie analizy z wykorzystaniem metod spektroskopowych UV, MS i NMR metoksykarbonylometyloamido pochodnej leworyny A3. Widmo UV wskazało obecność chromoforu heptaenowego. Ciężar cząsteczkowy leworyny A3 ustalono jako 1110 j.m. za pomocą spektrometrii masowej z wykorzystaniem techniki FAB, co po uwzględnieniu uwarunkowań biogenetycznych pozwoliło wydedukować...
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ASIC Design Example of Complex SoC with FPGA Prototyping
PublikacjaThe paper presents an example of the System on a Chip design, where the FPGA prototyping has been used. Two FPGA prototypes have been realized. The first FPGA prototype uses AVNET board containing Xilinx Virtex4 device accompanied by custom board with required devices. The second FPGA prototype has been built using the custom PCB with Xilinx Virtex-4 XC4VLX60 FPGA accompanied by all needed external components. The final system...
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ASIC Design Example of Complex SoC with FPGA Prototyping
PublikacjaThe paper presents an example of the System on a Chip design, where the FPGA prototyping has been used. Two FPGA prototypes have been realized. The first FPGA prototype uses AVNET board containing Xilinx Virtex4 device accompanied by custom board with required devices. The second FPGA prototype has been built using the custom PCB with Xilinx Virtex-4 XC4VLX60 FPGA accompanied by all needed external components. The final system...
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Semi complex navigation with an active optical gesture sensor
PublikacjaThis paper presents the methods of diversified touchless interactions between a user and a mobile platform utilizing the optical gesture sensor. The sensor uses 8 photodiodes to measure the reflected light in the active mode (using embedded LEDs) or it measures shadows caused by fingers in the passive mode. Several algorithms were implemented: automatic mode switching, adaptive illumination level compensation, resolution improvements...
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A Framework for Training and Testing of Complex Pattern Recognition Systems
PublikacjaW pracy przedstawiono szkielet aplikacji stworzony po to, by uprościć konstruowanie systemów rozpoznawania obrazów oraz zapewnić środowisko testowe umożliwiające ocenę algorytmów przy użyciu dużych zestawów danych. Jasno zdefiniowana architektura wraz z wieloma gotowymi do użycia modułami pozwala skoncentrować się na implementacji najważniejszych algorytmów. Szkielet wspiera tworzenie modułów, który mogą być wielokrotnie używane,...
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Online pitch estimation using instantaneous complex frequency
PublikacjaW pracy opisano nowe wyniki dotyczące skuteczności algorytmu potokowego estymującego częstotliwość podstawową sygnału mowy. Algorytm wykorzystuje zespoloną pulsację chwilową dla klasyfikacji mowy na dźwięczną i bezdźwięczną oraz estymacji częstotliwości podstawowej dla każdej próbki sygnału. Skuteczność klasyfikacji oraz dokładność estymacji zostały ocenione eksperymentalnie z wykorzystaniem dwóch baz nagrań, zawierających wypowiedzi...
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Complex Predictive Solution for Computerized Processes in Tire Industry
PublikacjaFollowing increasing market needs of productivity, cost reduction and safety requirements, computerized industry are faced to finding optimum between economic aspects of business and safety-related risk management. Modern factories equipped with computerized processes and extended diagnostic tools to support operator do not often use of all information’s which comes from the equipment. Some of the relations between the events are...
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Procesing the complex signal in the acoustic processor of a sonobuoy system
PublikacjaW artykule przedstawiono metody cyfrowego przetwarzania sygnału kompleksowego w procesorze akustycznym systemu radiohydroboi. Omówiono ogólną postać systemu oraz sygnału kompleksowego. Opisano dwie alternatywne metody przetwarzania sygnału: pierwszą w dziedzinie czasu, drugą w dziedzinie częstotliwości. Zaprezentowano schematy blokowe algorytmów obu sposobów przetwarzania. Omówiono problemy praktycznej realizacji poszczególnych...
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Modelling of complex economic systems : toward conceptual platform
PublikacjaW artykule opisano rolę modelowania opisowego w ekonomicznych systemach złożonych w kontekście trzech funkcji naukowych: opisu, wyjaśniania i przewidywania. Fazy dekompozycji i opisu jakościowego modelowanych systemów, w tym ekonomicznych, są nieodzowne w całym procesie budowania modelu.
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Modeling of Electrified Transportation Systems Featuring Multiple Vehicles and Complex Power Supply Layout
PublikacjaThe paper proposes a novel approach to modeling electrified transportation systems. The proposed solution reflects the mechanical dynamics of vehicles as well as the distribution and losses of electric supply. Moreover, energy conversion losses between the mechanical and electrical subsystems and their bilateral influences are included. Such a complete model makes it possible to replicate, e.g., the impact of voltage drops on vehicle...
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Glossary [Intellectual Output 1] Glossary as a method for reflection on complex research questions
PublikacjaGlobalization and digitization are strongly influencing the process of shaping the built environment. The latter is causing the new design tools to emerge faster than ever before in history, while the former is speeding up not only the development, but also the broad roll-out of more agile and interdisciplinary methodologies and work approaches. The design process is also becoming more and more inter- and trans-disciplinary. This...
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Implementation of magnitude calculation of complex numbers using improved alpha max plus beta min algorithm
PublikacjaThe paper presents the hardware implementation of the improved alpha max plus beta min algorithm for calculating the magnitude of complex numbers. This version of the algorithm requires the general division which is performed using a noniterative multiplicative division algorithm. We analyze in detail the division algorithm, its error and the impact of finite word-length signal representations on the assumed total computation error....
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Jacobi and gauss-seidel preconditioned complex conjugate gradient method with GPU acceleration for finite element method
PublikacjaIn this paper two implementations of iterative solvers for solving complex symmetric and sparse systems resulting from finite element method applied to wave equation are discussed. The problem under investigation is a dielectric resonator antenna (DRA) discretized by FEM with vector elements of the second order (LT/QN). The solvers use the preconditioned conjugate gradient (pcg) method implemented on Graphics Processing Unit (GPU)...
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A novel method of Mycobacterium tuberculosis complex strain differentiation using polymorphic GC-rich gene sequences.
PublikacjaTuberculosis is one of the leading infectious diseases. In this work, a new genotyping method of Mycobacterium tuberculosis (Mtb) complex strain is presented. 27 Mtb genomes were analyzed for the presence of length polymorphism within polymorphic GC-rich gene sequences. Four genes, Rv3345c, Rv3507, Rv0747 and Rv3511, showing variation in length depending on the Mtb strain were selected for designing primer sequences flanking variable...
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Uncertainty of antioxidant profiling in complex mixtures using liquid chromatography involving post-column derivatisation
PublikacjaThe main goal of this paper is to discuss the problems associated with antioxidant profiling in complex samples using a high-throughput HPLC system coupled with post-column derivatisation reactor. Based on the experimental data reported in the literature, we demonstrated that improper optimisation of temperature and/or pH assay conditions performed using an on-line derivatisation reactor may substantially change the antioxidant...
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New achievements in the field of extraction of trace analytes from samples characterized by complex composition of the matrix
PublikacjaWithout any doubt, the monitoring of compounds present in samples at trace or ultra-trace level usually requires a preliminary step of isolation and/or enrichment of analytes due to the fact that majority of analytical techniques are not sensitive enough for direct determination of trace compounds. On the other hand, sample preparation is considered as crucial part of whole analytical procedures, in particular in samples characterized...
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Evaluation of the Possibility of Identifying a Complex Polygonal Tram Track Layout Using Multiple Satellite Measurements
PublikacjaWe present the main assumptions about the algorithmization of the analysis of measurement data recorded in mobile satellite measurements. The research team from the Gda´nsk University of Technology and the Maritime University in Gdynia, as part of a research project conducted in cooperation with PKP PLK (Polish Railway Infrastructure Manager), developed algorithms supporting the identification and assessment of track axis layout....
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Evaluation of the Possibility of Identifying a Complex Polygonal Tram Track Layout Using Multiple Satellite Measurements
PublikacjaWe present the main assumptions about the algorithmization of the analysis of measurement data recorded in mobile satellite measurements. The research team from the Gda´nsk University of Technology and the Maritime University in Gdynia, as part of a research project conducted in cooperation with PKP PLK (Polish Railway Infrastructure Manager), developed algorithms supporting the identification and assessment of track axis layout....
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Intercalation complex of imidazoacridinone C-1311, a potential anticancer drug, with DNA helix d(CGATCG)2: stereostructural studies by 2D NMR spectroscopy.
PublikacjaImidazoacridinone C-1311 (Symadex®) is a powerful antitumor agent, which successfully made its way through the Phase I clinical trials and has been recommended for Phase II few a years ago. It has been shown experimentally that during the initial stage of its action C-1311 forms a relatively stable intercalation complex with DNA, yet it has shown no base-sequence specificity while binding to DNA. In this paper, the d(CGATCG)2:C-1311...
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On the complex formation of iron(III) bromide in the space-demanding solvent N,N'-dimethylpropyleneurea and the structure of the trisbromoiron(III) complex i solution and crystalline state
PublikacjaPrzeprowadzono badania kalorymetryczne równowag kompleksów koordynacyjnych jonu żelaza(III) z jonami bromkowymi w DMPU. Stwierdzono, że w DMPU powstają trzy: mono-, di- i tribromkowe kompleksy żelaza(III) a ich powstawanie jest uwarunkowane zmianą entropii. Badania krystalograficzne dowiodły, że FeBr3 w roztworze DMPU ma konfigurację płaskiego trójkąta równobocznego, żadna cząsteczka rozpuszczalnika nie jest związana z jonem metalu,...
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Efficacious Alkaline Copper Corrosion Inhibition by a Mixed Ligand Copper(II) Complex of 2,2′-Bipyridine and Glycine: Electrochemical and Theoretical Studies
PublikacjaA mixed ligand copper(II) complex, namely, [Cu(BPy)(Gly)Cl]⋅2H2O (CuC) (BPy=2,2′-bipyridine and Gly=glycine), was synthesized and characterized. The synthesized CuC complex was tested as inhibitor to effectively mitigate the corrosion of copper in alkaline solutions using the linear sweep voltammetry (LSV) and linear polarization resistance (LPR) techniques. For the sake of comparison, such two D.C. electrochemical techniques were...
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Project management for the construction sector in the field of foundation of buildings in complex conditions of the subsoil
PublikacjaAutorzy: Gwóźdź-Lasoń Monika, Kohutek...
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Specific Binding of Cholesterol to the Amyloid Precursor Protein: Structure of the Complex and Driving Forces Characterized in Molecular Detail
PublikacjaC99 is the C-terminal membrane-bound fragment of the amyloid precursor protein that is cleaved by γ-secretase to release Aβ peptides, the hallmark of Alzheimer’s disease (AD). Specific interactions of C99 with cholesterol have been proposed to underlie the recognized role of cholesterol in promoting amyloidogenesis. By using molecular dynamics simulations, we studied cholesterol binding to C99 in a lipid bilayer. We determined...
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CRL4CRBN E3 Ligase Complex as a Therapeutic Target in Multiple Myeloma
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On the use of instantaneous complex frequency for analysis and modification of simple sounds
PublikacjaW pracy przedstawiono możliwości wykorzystania zespolonej pulsacji chwilowej do analizy i modyfikacji prostych dźwięków. Opisywany algorytm składa się z dwóch kroków: bifaktoryzacji sygnału na obwiednię minimalnofazową i fazor dodatnipskrętny, a następnie estymacja i modyfikacja zespolonej pulsacji chwilowej obu czynników faktoryzacji.