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Wyniki wyszukiwania dla: ANALYTICAL METHODS
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Nuclear Activation Methods in the Estimation of Environmental Pollution and the Assessment of the Industrial Plant Impact on the Citizens of Gdansk (Poland)
PublikacjaNeutronowa Analiza Aktywacyjna została wykorzystana do oceny stanu jakości powietrza atmosferycznego na podstawie badań analitycznych stopnia kumulacji zanieczyszczeń nieorganicznych w mchu torfowca, a także składu wód opadowych. Ponadto przedstawiono wyniki badań dotyczących szacowania ryzyka zawodowego pracowników zakładów przemysłowych na podstawie analizy próbek materiału biologicznego pobranego od osób narażonych.
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The experience of movement in the built form and space: A framework for movement evaluation in architecture
Publikacja“Movement in architecture” is an organized system of various types of movements stimulated by specific architectural elements. This research was conducted through a qualitative-analytical method and empirical and bibliographical research methods with the aim to categorize different types of movements based on the explorer and observer relationships with the built space and form. So far, most of the related studies have focused...
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Communication and Documentation Practices in Agile Requirements Engineering: A Survey in Polish Software Industry
PublikacjaRequirements engineering, system analysis and other analytical activities form the basis of every IT project. Such activities are not clearly defined in Agile development methods, but it does not mean that they are absent in an agile project. The aim of our work was to determine which practices related to requirements-related communication and which requirements documenting techniques are used in agile software projects. For this...
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DISTRIBUTION OF FLOWS IN A CHANNEL NETWORK UNDER STEADY FLOW CONDITIONS
PublikacjaThe article presents an algorithm for calculating the distribution of flow in a junction of open channel network under steady flow conditions. The article presents a simplified calculation algorithm used to estimate the distribution of flow in a network of channels under steady flow conditions. The presented algorithm is based on the continuity equation and a simplified energy equation. To describe the relationship between the...
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The concept of a new two-stage fuse for high power pulse forming
PublikacjaThis manuscript introduces the concept, physical operating principle and studies on a new and unique two stage forming fuse (TSFF) with interstage spark gap commutation and presents its application for forming high power pulses of extreme parameters. The paper classifies TSFF performance and compares it with conventional single-stage forming fuses. The conclusions are supported by analytical and experimental studies in laboratory...
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Próba oceny efektów projektowania układów geometrycznych toru z wykorzystaniem komercyjnych programów komputerowych
PublikacjaW pracy podjęto kwestię dokładności uzyskiwanej w projektowaniu układów geometrycznych toru z wykorzystaniem komercyjnych programów komputerowych typu CAD. Opisano w sposób ogólny funkcjonowanie wybranego programu. Do celów weryfikacji wykorzystano własną, analityczną metodę projektowania układów torowych. W analizie porównawczej rzędnych poziomych rozpatrzono trzy warianty układu geometrycznego zawierającego łuk koszowy z trzema...
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Wielokryterialna analiza porównawcza lokalizacji źródeł wytwórczych energii elektrycznej
PublikacjaArtykuł przedstawia ranking lokalizacji czterech źródeł wytwórczych energii elektrycznej: biogazowni rolniczej, biogazowni utylizacyjnej oraz dwóch elektrowni fotowoltaicznych, wykonany przy użyciu połączonych metod Analitycznego Procesu Hierarchicznego (AHP) oraz taksonomii numerycznej. Omówiono zalety połączenia metod, przedstawiono przykład zastosowania oraz wskazano kryteria o największym i najmniejszym wpływie na realizację...
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The state-of-the-art determination of urinary nucleosides using chromatographic techniques “hyphenated” with advanced bioinformatic methods
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How to evaluate methods used in chemical laboratories in terms of the total chemical risk? – a ChlorTox Scale
PublikacjaReliable assessment of the health and environmental risk associated with the use of chemicals is critical to ob- jectively evaluate the greenness and whiteness of an analytical method. An objective and useful way of risk assessment should take into account all the relevant properties of used substances, their actual amounts needed for application of the method, and quantify the assessment result using a standardized unit. This...
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Topological-numerical analysis of a two-dimensional discrete neuron model
PublikacjaWe conduct computer-assisted analysis of a two-dimensional model of a neuron introduced by Chialvo in 1995 [Chaos, Solitons Fractals 5, 461–479]. We apply the method of rigorous analysis of global dynamics based on a set-oriented topological approach, introduced by Arai et al. in 2009 [SIAM J. Appl. Dyn. Syst. 8, 757–789] and improved and expanded afterward. Additionally, we introduce a new algorithm to analyze the return times...
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Application of a Gas Sensor Array to Effectiveness Monitoring of Air Contaminated with Toluene Vapors Absorption Process
PublikacjaThis article demonstrates the application of a gas sensor array to monitor the effectiveness of the absorption process of air stream purification from odorous compounds (toluene vapors). A self-constructed matrix consisting of five commercially available gas sensors was used. Multiple linear regression (MLR) was selected as the statistical technique used to calibrate the matrice. Gas chromatography coupled with a flame ionization...
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Life cycle assessment - a new approach to the question of environmental strain caused by analytical laboratories = Ocena cyklu życia - nowe podejście do zagadnienia uciążliwości środowiskowej laboratorów analitycznych
PublikacjaPraca przedstawia wyniki porównawczej oceny cyklu życia dla procesów pozyskiwania ekstraktów końcowych metodą ekstrakcji w układzie ciecz - ciecz i ekstrakcji do fazy stałej. Rozważano jedynie aspekt ekologiczny pozyskiwania wyników, nie bacząc na koszty ekologiczne i inne. Badania oparte są na informacjach uzyskanych w określonym laboratorium analitycznym oraz danych zawartych w bibliotece programu SimaPro. Techniką bardziej przyjazną...
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Density functional theory-based simulations of sum frequency generation spectra involving methyl stretching vibrations: effect of the molecular model on the deduced molecular orientation and comparison with an analytical approach
PublikacjaThe knowledge of the first hyperpolarizability tensor elements of molecular groups is crucial for a quantitative interpretation of the sum frequency generation (SFG) activity of thin organic films at interfaces. Here, the SFG response of the terminal methyl group of a dodecanethiol (DDT) monolayer has been interpreted on the basis of calculations performed at the density functional theory (DFT) level of approximation. In particular,...
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The improvement of the analytical performance of direct current atmospheric pressure glow discharge generated in contact with the small-sized liquid cathode after the addition of non-ionic surfactants to electrolyte solutions
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Determination of Selected Organic Acids in Animal Farm Water Samples by Ion Chromatography
PublikacjaLow molecular mass carboxylic acids (LCAs) occur in many environmental compartments due to natural processes and human activity. They are an important group of organic pollutants of waste water that mainly includes, volatile fatty acids, and also dicarboxylic, aromatic, hydroxy- and ketoacids. LCAs are present in the environment at concentrations between 1 to 5000 ppm and different methods have been reported for their determination...
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Analysis of odour interactions in model gas mixtures using electronic nose and fuzzy logic
PublikacjaMeasurement and monitoring of air quality in terms of odour nuisance is an important problem. Although the source of these nuisances is different (e.g. wastewater treatment plants, municipal landfills), their common feature is that they are a complex mixture of odorants with different odour thresholds. An additional problem is occurrence of the odour interactions between mixture components. From a practical point of view, it would...
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Validating data acquired with experimental multimodal biometric system installed in bank branches
PublikacjaAn experimental system was engineered and implemented in 100 copies inside a real banking environment comprising: dynamic handwritten signature verification, face recognition, bank client voice recognition and hand vein distribution verification. The main purpose of the presented research was to analyze questionnaire responses reflecting user opinions on: comfort, ergonomics, intuitiveness and other aspects of the biometric enrollment...
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Cold atmospheric plasma-induced chemical vapor generation in trace element analysis by spectrometric methods
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Wykorzystanie membran na etapie ekstrakcji analitów organicznychz ciekłych próbek środowiskowych i płynów biologicznych = Analytical applications of membrane extraction for liquid sample preparation in biomedical and environmental analysis
PublikacjaPrzedstawiono informacje dotyczące technik ekstrakcji membranowej wykorzystywanych do oznaczania związków organicznych w ciekłych próbkach środowiskowych i biologicznych. Szczególną uwagę zwrócono na podstawy teoretyczne oraz możliwości ich połączenia z technikami oznaczeń końcowych oraz obszarom praktycznego ich wykorzystania.
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Novel analytical approach for real-time monitoring of volatile Maillard reaction products emitted from the sugar-amino acid model system using proton transfer reaction mass spectrometry
PublikacjaIn the presented research, volatile Maillard reaction products formation in the two sugar-amino acid model systems, namely glucoselysine and ribose-lysine model systems were investigated using proton transfer reaction mass spectrometry. Obtained data were supported by the reference method, i.e., UV/Vis spectrometry. A number of volatile organic compounds were selected based on the correlation of the effect of Maillard reaction...
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Determination of chlorinated solvents in industrial water and wastewater by DAI- GC-ECD
PublikacjaA very simple and quick analytical method, basedon direct aqueous injection, for determination of halogenatedsolvents in refinery water and wastewater, is described.There is a need to determine halogenated solvents in refinerywater streams, because they may originate from severalprocesses. There is also a need to develop methods enablingVOX to be determined in samples containing oil fractions.The method described enables simultaneous...
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Reaktory elektrochemiczne w przemyśle - konstrukcja i zastosowania
PublikacjaZ biegiem lat reakcje elektrochemiczne przestały być postrzegane jedynie jako eksperymenty laboratoryjne lub proste baterie. Chociaż mechanizm reakcji i budowa prostych reaktorów znana jest ludzkości już od ponad 100 lat w ostatnich latach można zauważyć największy wzrost zainteresowania tą dziedziną. Nowy stale opracowywane są lepsze projekty budowy reaktorów. Modyfikacje to nie tylko rodzaje i formy materiałów, z których wykonane...
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Effects of Deck-Abutment Pounding on the Seismic Fragility Curves of Box-Girder Highway Bridges
PublikacjaEarthquake-induced pounding in bridges is a complex contact phenomenon in which the dynamic responses of structures, including collisions between deck and abutments, are strongly related to structural properties and earthquake excitation. The goal of this study is to develop and compare the seismic fragility curves of overall system and individual components of regular and irregular box-girder highway bridges in two cases: with...
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A Parallax Shift Effect Correction Based on Cloud Height for Geostationary Satellites and Radar Observations
PublikacjaThe effect of cloud parallax shift occurs in satellite imaging, particularly for high angles of satellite observations. This study demonstrates new methods of parallax effect correction for clouds observed by geostationary satellites. The analytical method that could be found in literature, namely the Vicente et al./Koenig method, is presented at the beginning. It approximates a cloud position using an ellipsoid with semi-axes...
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Development and validation of a GC–MS/MS method for the determination of 11 amphetamines and 34 synthetic cathinones in whole blood
PublikacjaPurpose Psychoactive compounds that contain a phenylethylamine structure (such as amphetamine-type stimulants and synthetic cathinones) are one of the major classes of stimulants on the recreational drug market. Approximately 670 new psychoactive substances (NPS) are monitored only in Europe; however, new psychoactive compounds are being developed for illicit trade each year. In this context, the development of new analytical procedures...
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Model studies to identify input parameters of an algorithm controlling electric supply/consumption process by underground iron ore enterprises
PublikacjaPurpose is the development of the research format of a mathematical model to select and assess input parameters of an algorithm controlling distribution of electric energy flows in the monitoring structure of electricity supply/ consumption by using equipment of mining enterprises engaged in underground iron ore raw materials extraction. Methods. The analytical research involved a theory of random processes adapted to the real...
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Uniwersalna metoda projektowania regulacji osi toru z wykorzystaniem pomiarów satelitarnych i optymalizacji
PublikacjaW pracy zwrócono uwagę na ograniczenia stosowanej w naszym kraju metodyki regulacji osi toru związane w głównym stopniu z uzyskiwaną dokładnością określania istniejącego kształtu toru. Jako rozwiązanie alternatywne wskazano opracowaną przez interdyscyplinarny zespół naukowy Politechniki Gdańskiej i Akademii Marynarki Wojennej / Akademii Morskiej w Gdyni i stosowaną od 2009 roku nowatorską technikę mobilnych pomiarów satelitarnych....
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Metodyka projektowania i eksploatacji dróg szynowych z wykorzystaniem mobilnych pomiarów satelitarnych
PublikacjaW pracy zostały przedstawione aplikacyjne możliwości metody mobilnych pomiarów satelitarnych w projektowaniu i eksploatacji dróg szynowych. Pokazano wizualizację położenia toru kolejowego, omówiono sposoby oceny odcinków prostych toru i odcinków położonych w łuku oraz tworzenie poligonu kierunków głównych trasy. Szczególną uwagę poświęcono opracowanej analitycznej metodzie projektowania, omawiając jej algorytmy obliczeniowe: projektowania...
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Cyclic Behavior of Masonry Shear Walls Retrofitted with Engineered Cementitious Composite and Pseudoelastic Shape Memory Alloy
PublikacjaThe behavior of masonry shear walls reinforced with pseudoelastic Ni–Ti shape memory alloy (SMA) strips and engineered cementitious composite (ECC) sheets is the main focus of this paper. The walls were subjected to quasi-static cyclic in-plane loads and evaluated by using Abaqus. Eight cases of strengthening of masonry walls were investigated. Three masonry walls were strengthened with different thicknesses of ECC sheets using...
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Endocrine disrupting compounds in the baby's world - A harmful environment to the health of babies
PublikacjaGlobally, there has been a significant increase in awareness of the adverse effects of chemicals with known or suspected endocrine-acting properties on human health. Human exposure to endocrine disrupting compounds (EDCs) mainly occurs by ingestion and to some extent by inhalation and dermal uptake. Although it is difficult to assess the full impact of human exposure to EDCs, it is well known that timing of exposure is of importance...
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Determination of 3-MCPD and 2-MCPD esters in edible oils, fish oils and lipid fractions of margarines available on Polish market
Publikacja3-monochloropropane-1,2-diol (3-MCPD) and 2-monochloropropane-1,3-diol (2-MCPD) are intensively investigated food contaminants, which recently emerged as a serious problem within the discovery of high levels of their fatty acid esters in lipid samples. In order to monitor the concentrations of mentioned toxicants in edible oils and fats, several analytical methods have been developed so far. This paper presents the screening research...
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Effectiveness of Random Field Approach in Serviceability Limit State Analysis of Strip Foundation
PublikacjaThis work conducts a probabilistic inquiry on how the variability of the parameter defining soil deformability affects the settlement of the foundation located on the soil. The analysis addresses the random foundation model to relevantly estimate the probability of allowable deflection exceedance. The constitutive model parameter is based either on a single random variable or a random field. The computations incorporate direct...
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Monolithic capsule phase microextraction prior to gas chromatography-mass spectrometry for the determination of organochlorine pesticides in environmental water samples
PublikacjaIn this study, a capsule phase microextraction (CPME) protocol followed by gas chromatography-mass spectrometry is proposed for the accurate and sensitive monitoring of organochlorine pesticides (OCPs) in environmental water samples. Different monolithic sol–gel encapsulated sorbents were compared and monolithic sol–gel poly(ethylene glycol)-based sorbent incorporated into porous microextraction capsules resulted in the highest...
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Common methods for the chiral determination of amphetamine and related compounds I. Gas, liquid and thin-layer chromatography
PublikacjaThis article reviews the most common, useful methods for the chiral determination of amphetamine (AM) and AM-deriveddesigner drugs in different of matrix, including blood, hair, urine, medicaments or standard solutions, taking into considerationarticles published in the past 15 years. We consider chromatographic methods (e.g., gas, liquid, high-performance liquid, and thinlayer). We describe several types of chiral derivatization...
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Simple Physics-Based Analytical Formulas for the Potentials of Mean Force for the Interaction of Amino Acid Side Chains in Water. 3. Calculation and Parameterization of the Potentials of Mean Force of Pairs of Identical Hydrophobic Side Chains
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Preparation of gaseous standard mixtures: methods for controlling the amount of components generated in the process of thermal decomposition of immobilized compounds.
PublikacjaGazowe mieszaniny wzorcowe odgrywają ważną rolę w ocenie metod analitycznych i urządzeń pomiarowych. W tym przypadku gazowe mieszaniny wzorcowe mogą być traktowane jako specjalny rodzaj materiału odniesienia.Proces walidacji wymaga użycia tzw. matrycowych materiałów odniesienia. Wybór techniki umożliwiającej uzyskanie gazowej mieszaniny wzorcowej o żądanych parametrach użytkowych zależy od natury składników mierzonych i gazu...
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Aktywności stymulujące refleksję w nauczaniu języka pisanego w wirtualnej klasie
PublikacjaThe paper aims to show how to engage students attending an online language course in various activities which by stimulating reflection enhance the learning process and result in better learning outcomes. By blending cognitivist, constructivist, constructionist and behavioural ideas, course developers and tutors can produce materials and use methods which satisfy the varied needs of adults who want to improve their writing skills....
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Application of GC-MS/MS technique for the determination of benzodiazepines in blood samples
PublikacjaAbstract Benzodiazepines (BZD) are widely used as pharmaceuticals in medicine. However, due to psychostimulatory effect of BZD, in the last decade, they are more and more often used as drugs of abuse. These compounds produce similar effects to classical illicit drugs and are sold as “legal” alternatives to them as new psychoactive substances (NPS). Currently new BZD, named designer benzodiazepines (DBZD), are synthesized each year...
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Hydrophobic deep eutectic solvents in microextraction techniques–A review
PublikacjaOver the past decade, deep eutectic solvents (DES) have been widely studied and applied in sample preparation techniques. Until recently, most of the synthesized DES were hydrophilic, which prevented their use in the extraction of aqueous samples. However, after 2015 studies on the synthesis and application of hydrophobic deep eutectic solvents (HDES) has rapidly expanded. Due to unique properties of HDES i.e. density, viscosity,...
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How pesticides affect neonates? - Exposure, health implications and determination of metabolites
PublikacjaThis review covers key information related to the effects of pesticides on fetal and child health. All humans are exposed to environmental toxicants, however child's health, due to their high vulnerability, should be of special concern. They are continuously exposed to environmental xenobiotics including a wide variety of pesticides, and other pollutants. These compounds can enter the child's body through various routes, both during...
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Sensors for Rapid Detection of Environmental Toxicity in Blood of Poisoned People
PublikacjaRecently, the diagnosis and treatment of poisoned person can be done only in specialized centers. Furthermore, currently used clinical methods of intoxication diagnosis are not sufficient for early detection. Conventional laboratory tests based on urine and blood require professional, high skilled staff, high cost equipment as well as they are arduous and lasting analytical procedures. There is a need to elaborate relatively cheap...
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Niebezpieczeństwo ukryte w żywności-aminy biogenne. Cz. II. Metody oznaczania i wyzwania.
PublikacjaZe względu na aktywność biologiczną amin biogennych ich oznaczanie zarówno jakościowe, jak i ilościowe w żywności ma istotne znaczenie w celu zapewnienia ochrony zdrowia i życia ludzkiego. Obecnie do monitoringu amin biogennych w żywności najczęściej wykorzystuje się: wysokosprawną chromatografię cieczową (HPLC), chromatografię cienkowarstwową (TLC) oraz absorpcyjną spektrofotometrię cząsteczkową. Są to jednak techniki czasochłonne,...
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In-situ generation of Ag, Cd, Hg, In, Pb, Tl and Zn volatile species by flowing liquid anode atmospheric pressure glow discharge operated in gaseous jet mode – Evaluation of excitation processes and analytical performance
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Polychlorinated Biphenyls (PCBs) and Polycyclic Aromatic Hydrocarbons (PAHs): Sediments and Water Analysis
PublikacjaUnfavorable side effects of different forms of anthropogenic activities can be found anywhere in the world. One of the basic characteristics of pollutants entering marine and ocean waters is their spread and movement in the global ocean. A portion of the substances entering the marine environment is rapidly degraded by chemical processes occurring in the air, sediments, and water, thereby losing their toxic properties. The biggest...
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Arsenic-Based Warfare Agents: Production, Use, and Destruction
PublikacjaSince the beginning of time, civilizations have looked for more creative ways to dominate and defeat their enemies. The rapid development of the chemical industry just before the Second World War started the era of modern chemical weapon production based on poisons, including toxic arsenic compounds. This paper provides a detailed overview of the production, usage and destruction of this dangerous chemical weapon. Milestones include:...
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Identification and properties of the psychrophilic bacterium Desulfolatea psychrophila single-stranded DNA binding proteins
PublikacjaTo study the biochemical properties of SSB from Desulfolatea psychrophila (DpsSSB), we have cloned the ssb genes obtained by PCR and have developed Escherichia coli overexpression systems. The gene consists of an open reading frame of 426 nucleotides encoding SSB protein of 142 amino acids with a calculated molecular mass of 15.6 kDa and it is the smallest known bacterial SSB protein indentified to date. The amino-acid sequence...
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Two highly thermostable paralogous single-stranded DNA-binding proteins from Thermoanaerobacter tengcongensis
PublikacjaThe thermophilic bacterium Thermoanaerobacter tengcongensis has two single-stranded DNA-binding (SSB) proteins, designated TteSSB2 and TteSSB3. In a SSB complementation assay in Escherichia coli, only TteSSB3 took over the in vivo function of EcoSSB. We have cloned the ssb genes obtained by PCR and have developed E. coli overexpression systems. The TteSSB2 and TteSSB3 consist of 153 and 150 amino acids with a calculated molecular...
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Three-dimensional geographically weighted inverse regression (3GWR) model for satellite derived bathymetry using Sentinel-2 observations
PublikacjaCurrent trends of development of satellite derived bathymetry (SDB) models rely on applying calibration techniques including analytical approaches, neuro-fuzzy systems, regression optimization and others. In most of the cases, the SDB models are calibrated and verified for test sites, that provide favourable conditions for the remote derivation of bathymetry such as high water clarity, homogenous bottom type, low amount of sediment...
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Determination of the active ingredient in pharmaceutical gel formulation by NIR spectroscopy
PublikacjaPharmaceuticals of their intended must be thoroughly controlled. The traditional analytical methods are very costly and time consuming. NIR spectroscopy allows to analyze pharmaceutical materials very quickly and with very low costs. First pharmaceutical applications of the NIR spectroscopy appeared with some incuriosity in the late 1960s. Application of NIR in the contemporary pharmaceutical industry is very large. The most common...
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Comprehensive Comparison of a Few Variants of Cluster Analysis as Data Mining Tool in Supporting Environmental Management
PublikacjaA few variants of hierarchical cluster analysis (CA) as tool of assessment of multidimensional similarity in environmental dataset are compared. The dataset consisted of analytical results of determination of metals (Na, K, Ca, Sc, Fe, Co, Zn, As, Br, Rb, Mo, Sb, Cs, Ba, La, Ce, Sm, Hf and Th) in ambient air dried and kept alive, by the means of hydroponics, moss baskets collected in 12 locations on the area of Tricity (Poland)....