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- Publikacje 1552 wyników po odfiltrowaniu
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Wyniki wyszukiwania dla: BALL MILL SYNTHESIS
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Synthesis of ester derivatives of propylene glycol in the presence of zinc carboxylates.
PublikacjaZbadano wpływ temperatury i stężenia karboksylanów cynku na przebieg estryfikacji glikolu propylenowego kwasami tłuszczowymi. Otrzymano emulgatory, w których maksymalne stężenie monoestru wynosiło 55-57%.
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Chlorophylls c—Occurrence, synthesis, properties, photosynthetic and evolutionary significance
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Proximity: Synthesis, Six-Dimensional Typology, and Significance for Cooperation Performance
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A Novel Reactor for Microwave Hydrothermal Scale-up Nanopowder Synthesis
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Microwave solvothermal synthesis and characterization of manganese-doped ZnO nanoparticles
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Unexpected thioketene derivative formation during thioacyl dithiophosphate synthesis.
PublikacjaZbadano zakres i ograniczenia tioacylowania opartego na ditiofosforanach tioacylu. Ditiofosforany tioacylo otrzymano w wyniku reakcji ditiofosforanów acylu z kwasem ditiofosforowym. Obecność dwóch podstawników w pozycji alfa we fragmencie acylowym faworyzowała tworzenie pochodnych tioketenu tym samym obniżając wydajność oczekiwanych ditiofosforanów tioacylu.
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Oxolane Ammonium Salts (Muscarine-Like)—Synthesis and Microbiological Activity
PublikacjaCommercially available 2-deoxy-D-ribose was used to synthesize the appropriate oxolane derivative—(2R,3S)-2-(hydroxymethyl)oxolan-3-ol—by reduction and dehydration/cyclization in an acidic aqueous solution. Its monotosyl derivative, as a result of the quaternization reaction, allowed us to obtain eight new muscarine-type derivatives containing a quaternary nitrogen atom and a hydroxyl group linked to the oxolane ring. Their structure...
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The template synthesis and complexation properties of the methoxypyrogal-lo[4]arene
PublikacjaZaprezentowano metodę syntezy templatowej MPA. Obserwowano kompleksowanie silnych akceptorów elektronów przez MPA. Analiza widm ESI-MS wykazała właściwości kompleksujące w stosunku do kationów metali alkalicznych. Właściwości jonoforowe związku badano w membranowych elektrodach jonoselektywnych.
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Synthesis, Antimicrobial and Mutagenic Activity of a New Class of d-Xylopyranosides
PublikacjaEight N-[2-(2′,3′,4′-tri-O-acetyl-α/β-d-xylopyranosyloxy)ethyl]ammonium bromides, a new class of d-xylopyranosides containing a quaternary ammonium aglycone, were obtained. Their complete structure was confirmed using NMR spectroscopy (1H, 13C, COSY and HSQC) and high-resolution mass spectrometry (HRMS). An antimicrobial activity against fungi (Candida albicans, Candida glabrata) and bacteria (Staphylococcus aureus, Escherichia...
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Synthesis of acceptor-doped Ba-Ce-Zr-O perovskites
PublikacjaPublikacja przedstawia wyniki badań stukturalnych i elektrycznych domieszkowanego akceptorow cerianu baru.
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Cell-penetrating peptides – mechanism of transduction and synthesis – short review
PublikacjaPotential antimicrobial agents may be effective if they are delivered efficiently to their site of action. In many cases, lack of permeability through the cell membrane is the main problem. One of the possible solutions could be a novel intracellular delivery system involving cell-penetrating peptides (CPPs), which may improve the efficiency of many new biophar-maceuticals. Among other things, CPPs are capable of trans-porting...
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Synthesis and biological activity of mycophenolic acid-amino acid derivatives
PublikacjaIn search of new immunosuppressants, mycophenolic acid (MPA) was coupled with amino acid methyl esters followed by hydrolysis to analogs bearing free carboxylic groups. The obtained compunds were tested in vitro as growth inhibitors of lymphoid cell line (Jurkat) and human peripheral blood mononuclear cells (PBMC) from healthy donors. According to obtained results recovering of free carboxylic group increased their activity. Additionally,...
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Facile and continuous synthesis of graphene nanoflakes in RF thermal plasma
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Novel nanocarbons via facile one-pot combustion synthesis
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ChemInform Abstract: Novel and Efficient Methods for the Synthesis of Symmetrical Trisulfides.
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Pyrrole azocrown ethers - synthesis, crystal structures, and fluorescence properties
PublikacjaZsyntezowano nowe związki makrocykliczne zawierające w makropierścieniu pierścień pirolowy, grupy azowe oraz reszty chromoforowe i fluorescencyjne. Scharakteryzowano strukturę krystaliczną dwóch spośród otrzymanych makrocykli metodą rentgenografii strukturalnej. Stwierdzono, że zaprezentowane pirolowe azokorony to związki czułe i selektywne na jony ołowiu(II) oraz, że mogą być użyte jako chemosensory zarówno w spektroskopii UV-Vis,...
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Au–Si plasmonic platforms: synthesis, structure and FDTD simulations
PublikacjaPlasmonic platforms based on Au nanostructures have been successfully synthesized by directional solidification of a eutectic from Au and the substrate. In order to determine homogeneous shape and space distribution, the influence of annealing conditions and the initial thickness of the Au film on the nanostructures was analyzed. For the surface morphology studies, SEM and AFM measurements were performed. The structure of platforms...
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Synthesis and characterization of ruthenium and rhenium dyes with phosphonate anchoring groups
PublikacjaRe(L1)–Re(L3), a series of rhenium(I) tricarbonyl chloride complexes with bpy-R2 derivatives L1–L3 (bpy = 2,2′-bipyridine, R represents the substitution at the 4- and 4′-positions), and their corresponding trishomoleptic Ru(L1)3–Ru(L3)3 as well as heteroleptic ruthenium(II) complexes Ru(tbbpy)2(L1) and Ru(tbbpy)2(L2) have been synthesized and characterized. Their applicability as immobilizable metal–organic chromophores in solar...
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Synthesis and hydrogen evolving catalysis of a panchromatic photochemical molecular device
PublikacjaA dinuclear hydrogen evolution photocatalyst [(tbbpy)2Os(tpphz)PtI2](PF6)2 (tbbpy = 4,4′-tert-butyl-2,2′-bipyridine; tpphz = tetrapyrido[3,2-a:2′,3′-c:2′′,3′′-h:2′′′,3′′′-j]phenazine) is synthesized in order to make use of the broader range of visible light absorption mitigated by the osmium center. In a first step, the activity of the complex for hydrogen evolution is investigated by evaluating the role of different electron donors...
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Evaluation of the glycerolysis process and valorisation of recovered polyol in polyurethane synthesis
PublikacjaIn this study, the glycerolysis of polyurethane (PU) foam and the applicability of obtained glycerolysate (GLY) for cast PUs were investigated. It was found that crude glycerine with purity grade of 84% might be successfully used for the glycerolysis. The optimal conditions were determined as follows: reaction time of 60 min at 220 °C using dibutyltin dilaurate catalyst (0.5%). Moreover, the purification of GLY by means of liquid-liquid...
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Synthesis and Physicochemical Characteristics of Chitosan-Based Polyurethane Flexible Foams
PublikacjaThe use of shrimp waste to obtain chitosan (Ch) is an essential issue, considering a circular economy, waste management, and its application to environmentally friendly materials. In this study, northern prawn shells were utilized to obtain Ch, which could then be used for synthesizing chitosan-based polyurethane (PUR+Ch) foams with different Ch concentration. The chemical structure, morphology, hardness, thermal properties, viscoelastic...
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Synthesis and Characterization of Poly(zwitterionic) Structures for Energy Conversion and Storage
PublikacjaZwitterions are unique class of molecules that possess two functional groups bearing electric charges, one positive and second negative. This setup results in peculiar properties such as high water retention and anti-fouling capability. Therefore, zwitterionic coatings and gels are commonly applied in e.g. biosensing and bioelectronic devices. Despite those applications, there are other perspectives for zwitterionic materials....
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Design, synthesis, and biological evaluation of tetrahydroquinolinones and tetrahydroquinolines with anticancer activity
PublikacjaColorectal cancer (CRC) is the most commonly diagnosed cancer in Europe and the United States and the second leading cause of cancer related mortality. A therapeutic strategy used for the treatment of CRC involves targeting the intracellular levels of reactive oxygen species (ROS). In this study, we synthesized a series of novel tetrahydroquinolinones and assessed their ability to inhibit CRC growth and proliferation by evoking...
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Synthesis, physical and chemical properties of polyetherurethanes modified by natural antioxidant
PublikacjaOtrzymano nowe polieterouretany modyfikowane witaminą E. Ten naturalny przeciwutleniacz związany został z makrocząsteczkami w postaci bocznych odgałęzień poprzez wiązanie eterowe lub uretanowe, zależnie od użytego w syntezie jednego z dwóch rodzajów otrzymanych uprzednio monomerów. Polimery scharakteryzowano mierząc wytrzymałość na rozciąganie i twardość oraz absorpcję wody i oleju słonecznikowego. Odporność chemiczną badano oznaczając...
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Novel molecules containing structural features of NSAIDs and 1,2,3-triazole ring: Design, synthesis and evaluation as potential cytotoxic agents
PublikacjaFor the first time the template containing structural features of more than one NSAIDs and the 1,2,3-triazole ring was explored for the identification of potential cytotoxic agents. These new and complex molecules were predicted to be effective inhibitors of PDE4B by molecular modelling studies in silico. The multi-step synthesis of these compounds were carried out starting from the well-known drug nimesulide and involved the use...
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Copper and copper-manganese 1D coordination polymers: Synthesis optimization, crystal structure and preliminary studies as catalysts for Baylis–Hillman reactions
PublikacjaThis work reports the influence of experimental parameters (pH and counter-ion) in the synthesis of the 1D coordination polymer [Cu(IDA)(H2O)2]n (IDA = iminodiacetate), named here Cu-IDA. Copper-manganese bimetallic coordination polymers were also obtained by isomorphic replacement into Cu-IDA structure, with different molar ratio of Cu2+ and Mn2+ ions, denoted here as Cu/Mn-IDA (0.9/0.1; 0.7/0.3 and 0.5/0.5). New coordination...
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A versatile and convenient preparation of unsymmetrical diaryl disulfides
PublikacjaWe have developed a convenient method for the synthesis of unsymmetrical diaryl disulfides under mild conditions in excellent yields. The described method is based on the straightforward preparation of 5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinane-2-sulfenyl bromide from readily available 5,5-dimethyl-2-thiolo-2-thioxo-1,3,2-dioxaphosphorinane or bis(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl) disulfide. The unsymmetrical...
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Synthesis of thiol derivatives of azobenzocrown ethers. The preliminary studies on recognition of alkali metal ions by gold nanoparticles functionalized with azobenzocrown and lipoic acid
PublikacjaThe article presents the synthesis of novel 13- and 16-membered azobenzocrown derivatives with peripheral thiol moieties and preliminary studies assessing their possible application in plasmonic sensors based on gold nanoparticles. The effect of the length of the chain connecting the macrocycle with the thiol group and the effect of the presence of the additional functional compound,...
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Synthesis and structural properties of (Y, Sr)(Ti, Fe, Nb)O3−δ perovskite nanoparticles fabricated by modified polymer precursor method
PublikacjaThe yttrium, iron and niobium doped-SrTiO3 powders have been successfully fabricated by a modified low–temperature synthesis method from a polymer complex. The usage of strontium hydroxide precursor instead of conventional strontium nitrate or strontium carbonate provides to the possibility of significant decrease of annealing temperature. It allows to prepare a material with sphere-shape grains of nanometric size (15–70 nm). The...
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VIbration monitoring in reciprocating siding friction tests. Ball-on-flat contact. Sintered alumina ceramics (98%). Lubricant - PARAFFIN OIL. Specim. set K09A - full-run
Dane BadawczeVIbration monitoring in reciprocating siding friction tests in ball-on-flat contact. Both specimens made of sintered alumina ceramics (98%) - self-mated contact.Linear reciprocating motion.Lubrication: PARAFFIN OIL. Sliding velocity (peak): 0.1 m/s. Load (normal force): 5N. Test rig: TPZ-1 Tribometer.Running time: progressive increments of 10, 15, 30,...
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VIbration monitoring in reciprocating siding friction tests. Ball-on-flat contact. Sintered alumina ceramics (98%). Lubricant - PARAFFIN OIL. Specim. set K09 - pre-run
Dane BadawczeVIbration monitoring in reciprocating siding friction tests in ball-on-flat contact. Both specimens made of sintered alumina ceramics (98%) - self-mated contact.Linear reciprocating motion.Lubrication: PARAFFIN OIL. Sliding velocity (peak): 0.1 m/s. Load (normal force): 5N. Test rig: TPZ-1 Tribometer.Running time: progressive increments of 10, 15, 30,...
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Transition-Metal-Promoted Oxidative Cyclization To Give 1,2,4-Trisubstituted Carbazole Scaffolds
PublikacjaHerein, we describe the synthesis of a 1,2,4-trisubstituted carbazole core from 5-(1H-indol-3-yl)-3-oxopentanoic acid esters or amides. For oxidative cyclization, we tested two different approaches. First, we used manganese triacetate as a conventional moderate oxidizer to ensure the radical course of the reaction. Second, we examined the use of a more complex oxidizing agent I2/Me(OTf)3. In both cases, formation of a fused-ring...
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Effect of synthesis method parameters on properties and photoelectrocatalytic activity under solar irradiation of TiO2 nanotubes decorated with CdS quantum dots
PublikacjaThe growing research interest on photoelectrocatalysis has encouraged the search for new materials with high activity and the development of methods for their synthesis. The successive ionic layer adsorption and reaction (SILAR) method is an effective way to synthesize materials with photoelectrocatalytic (PEC) properties that are active under visible radiation. Therefore, studies on the impact of the parameters of the SILAR method...
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Modelling and optimisation of MXene-derived TiO2/Ti3C2 synthesis parameters using Response Surface Methodology based on the Box–Behnken factorial design. Enhanced carbamazepine degradation by the Cu-modified TiO2/Ti3C2 photocatalyst
PublikacjaIn the present study, a hydrothermal method in a water/ethanol environment was used for the first time to obtain novel Cu/TiO2/Ti3C2 composites with high photocatalytic activity for the degradation of carbamazepine (CBZ) under simulated solar light. The Box–Behnken factorial design was coupled with Response Surface Methodology (RSM) for synthesis parameter optimisation. The effect of different synthesis parameters, including temperature, time...
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Ultrasound assisted synthesis of 3-alkynyl substituted 2-chloroquinoxaline derivatives: Their in silico assessment as potential ligands for N-protein of SARS-CoV-2
PublikacjaIn view of recent global pandemic the 3-alkynyl substituted 2-chloroquinoxaline framework has been explored as a potential template for the design of molecules targeting COVID-19. Initial in silico studies of representative compounds to assess their binding affinities via docking into the N-terminal RNA-binding domain (NTD) of N-protein of SARS-CoV-2 prompted further study of these molecules. Thus building of a small library of...
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Nanoparticle coatings for stir bar sorptive extraction, synthesis, characterization and application
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Imprinted polymer particles for iron uptake: Synthesis, characterization and analytical applications
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Synthesis and Biological Activity of Strongly Fluorescent Tricyclic Analogues of Acyclovir and Ganciclovir
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Synthesis and singlet oxygen generation of pyrazinoporphyrazines containing dendrimeric aryl substituents
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Azomacrocyclic derivatives of imidazole: synthesis, structure, and metal ion complexation properties
PublikacjaNew azocrown ethers comprising imidazoles in the macrocycle have been synthesized. Imidazole, 2-methyl-, 4-methyl-, and 4-phenylimidazole were incorporated to form macrocyclic units by coupling with the appropriate bis-diazonium salts. The syntheseswere performed under high dilution conditions. The X-ray structure of a water adduct of the 21-membered crown ether derivative of 4-methylimidazole 8 has been solved. Metal...
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From Hollow to Solid Carbon Spheres: Time-Dependent Facile Synthesis
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Magnetic Silica Nanotubes: Synthesis, Drug Release, and Feasibility for Magnetic Hyperthermia
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Synthesis of Polylysine/Silica Hybrids through Branched-Polylysine-Mediated Biosilicification
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Template method synthesis of mesoporous carbon spheres and its applications as supercapacitors
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Recent developments in the synthesis and applications of graphene-family materials functionalized with cyclodextrins
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Synthesis and Evaluation of Biological Activity of Antimicrobial – Pro-Proliferative Peptide Conjugates
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Synthesis of linear tuftsin analogues modified at the epsilon-amino group of lysine
PublikacjaZsyntetyzowano na fazie stałej nowe analogi tuftsyny i retro-tuftsyny zawierające wiązanie isopeptydowe na epsilon-aminowej grupie lizyny jako potencjalne immunostymulatory. Do syntezy wykorzystano standardową procedurę Fmoc. Po zdjęciu osłon kwasem TFA końcowe związki były oczyszczane, liofilizowane i charakteryzowane: MS, HPLC i NMR.
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Fast multiplexer cad using surrogate models for channel filters synthesis
Publikacjaartykuł przedstawia metodę szybkiego projektowania multiplekserów mikrofalowych wykorzystującą dokładne modele zastępcze na etapie projektowania kanałów. przedstawiony został przykład trój-kanałowego multipleksera z filtrami dwurodzajowymi.
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Combretastatin A-4 (CA-4) and its analogues. Synthesis and biological activity
PublikacjaSpośród wielu związków przeciwnowotworowych otrzymanych w ostatnich dwóch dekadach, na szczególną uwagę zasługują te, które powodują reorganizację mikrotubul. Jedną z takich substancji jest opisana w artykule kombretastatyna A-4 (CA-4), związek który indukuje apoptozęproliferujących komórek śródbłonka naczyń guza nowotworowego. Hamuje on polimeryzację tubuliny, prowadząc do rozpadu mikrotubul. CA-4 wyizolowana została z kory wierzby...
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Synthesis and conformational analysis of salivary proline-rich peptide P-B
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