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wyświetlamy 1000 najlepszych wyników Pomoc
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Heterogeneous distribution of surface electrochemical activity in polycrystalline highly boron-doped diamond electrodes under deep anodic polarization
PublikacjaThe surface homogeneity of boron-doped diamond electrodes is variable and depends on anodic polarization conditions. The differentiation factor is the gradual and localized change in surface termination. A series of measurements under different polarization conditions was performed in order to investigate the scale of this effect. Nanoscale impedance microscopy (NIM) revealed large variation of surface resistance in individual...
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DNA methylation as a mediator of HLA-DRB1*15:01 and a protective variant in multiple sclerosis
PublikacjaThe human leukocyte antigen (HLA) haplotype DRB1*15:01 is the major risk factor for multiple sclerosis (MS). Here, we find that DRB1*15:01 is hypomethylated and predominantly expressed in monocytes among carriers of DRB1*15:01. A differentially methylated region (DMR) encompassing HLA-DRB1 exon 2 is particularly affected and displays methylation-sensitive regulatory properties in vitro. Causal inference and Mendelian randomization...
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One-step formation of n-alkenyl-malonamides and n-alkenyl-thiomalonamides from carbamoyl meldrum's acids.
PublikacjaA one-pot synthesis for the preparation of N-alkenyl-malonamides and N-alkenyl-thiomalonamides was developed. 5-[Hydroxy/mercapto(aryl/alkylamino)methylene]-2,2-dimethyl-1,3-dioxane-4,6-dione act as a source of ketenes that react with the tautomeric form of alkyl-(2-phenyl-propylidene)-amines. A possible [2+2] or [4+2] cycloaddition product of ketene to imines was not observed.
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Powerful connection of laccase and carbon nanotubes: Material for mediator-free electron transport on the enzymatic cathode of the biobattery
PublikacjaOpisany został sposób wytwarzania koniugatów lakaza - jednościenne nanorurki węglowe i ich zastosowanie jako materiałów modyfikujacych katodę w hybrydowym bioogniwie paliwowym z cynkową anodą. Nanorurki węglowe z przyłączonymi grupami aminoetylowymi stanowiły materiał wyjściowy do chemicznego związania lakazy na ich powierzchni. Otrzymany materiał wykazywał wysoką aktywność bioelektrokatalityczną i jest obiecujacym materiałem do...
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Generic emergence of classical features in quantum Darwinism
PublikacjaQuantum Darwinism posits that only specific information about a quantum system that is redundantly proliferated to many parts of its environment becomes accessible and objective, leading to the emergence of classical reality. However, it is not clear under what conditions this mechanism holds true. Here we prove that the emergence of classical features along the lines of quantum Darwinism is a general feature of any quantum dynamics:...
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A large family of filled skutterudites stabilized by electron count
PublikacjaThe Zintl concept is important in solid-state chemistry to explain how some compounds that combine electropositive and main group elements can be stable at formulas that at their simplest level do not make any sense. The electronegative elements in such compounds form a polyatomic electron-accepting molecule inside the solid, a ‘polyanion’, that fills its available energy states with electrons from the electropositive elements...
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Closed-loop stimulation of temporal cortex rescues functional networks and improves memory
PublikacjaMemory failures are frustrating and often the result of ineffective encoding. One approach to improving memory outcomes is through direct modulation of brain activity with electrical stimulation. Previous efforts, however, have reported inconsistent effects when using open-loop stimulation and often target the hippocampus and medial temporal lobes. Here we use a closed-loop system to monitor and decode neural activity from direct...
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Widespread theta synchrony and high-frequency desynchronization underlies enhanced cognition
PublikacjaThe idea that synchronous neural activity underlies cognition has driven an extensive body of research in human and animal neuroscience. Yet, insufficient data on intracranial electrical connectivity has precluded a direct test of this hypothesis in a whole-brain setting. Through the lens of memory encoding and retrieval processes, we construct whole-brain connectivity maps of fast gamma (30-100 Hz) and slow theta (3-8 Hz) spectral...
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Diphosphination of CO2 and CS2 mediated by frustrated Lewis pairs - catalytic route to phosphanyl derivatives of formic and dithioformic acid
PublikacjaThe first example of CO2 diphosphination is described. Reactions of unsymmetrical diphosphanes with CE2 (E = O, S) catalyzed by BPh3 insert a CE2 molecule into the P-P bond with formation of the products of the general formula R2P-E-C(=E)-PR2. The obtained CO2 adducts arise from synergistic interaction of diphosphane and borane with CO2 molecule.
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New thiourea organocatalysts and their application for the synthesis of 5-(1H-indol-3-yl)methyl-2,2-dimethyl-1,3-dioxane-4,6-diones a source of chiral 3-indoylmethyl ketenes
PublikacjaThe stereoselective properties of modified thiourea organocatalysts were tested in the Friedel–Crafts alkylation of indole with 5-arylidene-2,2-dimethyl-1,3-dioxane-4,6-diones, which produces chiral 5-((1H-indol-3-yl)(aryl)methyl)-2,2-dimethyl-1,3-dioxane-4,6-diones. Based on a tentative reaction mechanism for ((S)-N-benzyl-2-(3-(3,5-bis (trifluoromethyl)phenyl)thioureido)-N,3,3-trimethylbutanamide organocatalysts, modifications...
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Preparation of bicyclic β-lactam and bicyclic 1,3- oxazinone scaffolds using combined cycloaddition and metathesis processes
PublikacjaA simple, efficient two-step method for the preparation of heterobicyclic compounds was developed. Starting from 5-acyl or 5-carbamoyl-2,2- dimethyl-1,3-dioxa-4,5-dione bicyclic scaffolds of 1-azabicyclo[5.2.0]non- 3-en-9-one, 6,9,10,10a-tetrahydro-4H-[1,3]oxazino[3,2-a]azepin-4-one, and 6,9,10,10a-tetrahydro-2H-[1,3]oxazino[3,2-a]azepine-2,4(3H)-dione were prepared using cycloaddition of thermally generated ketenes to aldimines...
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Steering is an essential feature of non-locality in quantum theory
PublikacjaA physical theory is called non-local when observers can produce instantaneous effects over distant systems. Non-local theories rely on two fundamental effects: local uncertainty relations and steering of physical states at a distance. In quantum mechanics, the former one dominates the other in a well-known class of non-local games known as XOR games. In particular, optimal quantum strategies for XOR games are completely determined...
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Realistic noise-tolerant randomness amplification using finite number of devices
PublikacjaRandomness is a fundamental concept, with implications from security of modern data systems, to fundamental laws of nature and even the philosophy of science. Randomness is called certified if it describes events that cannot be pre-determined by an external adversary. It is known that weak certified randomness can be amplified to nearly ideal randomness using quantum-mechanical systems. However, so far, it was unclear whether randomness amplification...
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Measurement and Modeling of Computer Systems (ACM SIG on Computer and Communications Metrics and Performance)
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CROWDSOURCING A KOMUNIKACJA Z KONSUMENTAMI
PublikacjaRozdział prezentuje wybrane modele komunikacji w Internecie oraz crowdsourcing jako nową metodę pozyskiwania pomysłów i informacji od konsumentów. W ciągu ostatnich 5 lat rozwój technologii komunikacyjnych znacząco zmienił sposób komunikowania się ludzi, a w konsekwencji również organizacji z konsumentami. Nie tylko firmy z branży IT mogą wzmocnić swoją markę, reputację oraz zwiększyć przychody dzięki opracowaniu atrakcyjnej, społecznie...
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The Impact of Information and Communication Technology on the Rise of Urban Social Movements in Poland
PublikacjaThe chapter examines the relationship between the use of Information and Communications Technology (ITC) and the emergence of social movements focused on urban agenda in Poland. The aim is to investigate how and to what extent a growing body of smaller activist groups use opportunities provided by the ITC to achieve their political objectives. The research results indicate that Web-based media have helped to raise the profile...
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Krzysztof Karwaczyński
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Michał Pióro prof. dr hab. inż.
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Teresa Pluta mgr
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Maciej Szczodrak dr inż.
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A Survey of Vehicular Network Systems for Road Traffic Management
PublikacjaIn this survey, we analyze the proposals of vehicular communication systems in the context of road traffic management. Starting with the definition of communications between vehicles (V2V), vehicles-to-infrastructure (V2I) and vehicles-to-everything (V2X), we first focus on the requirements and current standards for the Intelligent Transport Systems (ITS), including the maximum communication delay, the communication range and the...
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Influence of User Mobility and Antenna Placement on System Loss in B2B Networks
PublikacjaIn this paper, the influence of user mobility and on-body antenna placement on system loss in body-to-body communications in indoor and outdoor environments and different mobility scenarios is studied, based on system loss measurements at 2.45 GHz. The novelty of this work lies on the proposal of a classification model to characterise the effect of user mobility and path visibility on system loss, allowing to identify the best...
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Algorytmy samostabilizujące w sieciach o wybranych topologiach
PublikacjaIdea algorytmów samostabilizujących została zapoczątkowana przez E. Dijkstrę artykułem pt. „Self-stabilizing systems in spite of distributed control” (Communications of the ACM, 1974). W rozprawie został położony nacisk na algorytmy samostabilizujące działające w sieciach o pewnych specyficznych topologiach, jak na przykład w grafach maksymalnych zewnętrznie planarnych, iloczynach kartezjańskich tych grafów ze ścieżkami i w drzewach. Wykorzystując...
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Maximizing SDN resilience to node‐targeted attacks through joint optimization of the primary and backup controllers placements
PublikacjaIn Software Defined Networks (SDN) packet data switches are configured by a limited number of SDN controllers, which respond to queries for packet forwarding decisions from the switches. To enable optimal control of switches in real time the placement of controllers at network nodes must guarantee that the controller-to-controller and switch-to-controller communications delays are bounded. Apart from the primary controllers that...
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Path Loss Analysis in Off-Body Channels in Indoor Environment
PublikacjaThis temporary document describes an analysis of path loss in off-body channels in an indoor environment. The influence of body orientation and on-body antenna placement on path loss in off-body communications as well as of different bodies has been investigated. Five static scenarios, six distances between body and antenna and eight body orientations were analysed; moreover, two dynamic scenarios were investigated. The smallest...
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A novel architecture for e-learning knowledge assessment systems
PublikacjaAbstract. In this paper we propose a novel e-learning system, dedicated strictly to knowledge assessment tasks. In its functioning it utilizes web-based technologies, but its design differs radically from currently popular e-learning solutions which rely mostly on thin-client architecture. Our research proved that such architecture,while well suited for didactic content distribution systems is ill-suited for knowledge assessment...
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A novel architecture for e-learning knowledge assessment systems
PublikacjaIn this paper we propose a novel e-learning system, dedicated strictly to knowledge assessment tasks. In its functioning it utilizes web-based technologies, but its design differs radically from currently popular e-learning solutions which rely mostly on thin-client architecture. Our research proved that such architecture, while well suited for didactic content distribution systems is ill-suited for knowledge assessment products....
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A novel architecture for e-learning knowledge assessment systems
PublikacjaIn this paper we propose a novel e-learning system, dedicated strictly to knowledge assessment tasks. In its functioning it utilizes web-based technologies, but its design differs radically from currently popular e-learning solutions which rely mostly on thin-client architecture. Our research proved that such architecture, while well suited for didactic content distribution systems is ill-suited for knowledge assessment products....
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A Highly Scalable, Modular Architecture for Computer Aided Assessment e-Learning Systems
PublikacjaIn this chapter, the authors propose a novel e-learning system, dedicated strictly to knowledge assessment tasks. In its functioning it utilizes web-based technologies, but its design differs radically from currently popular e-learning solutions which rely mostly on thin-client architecture. The authors' research proved that such architecture, while well suited for didactic content distribution systems is ill-suited for knowledge...
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Loosely-Tied Distributed Architecture for Highly Scalable E-Learning System
PublikacjaVast majority of modern e-learning products are based on client-server architecture and utilization of web-based technologies (WBT). Such approach permits easy creation of e-learning systems that do not require a complex, operating system dependant client software. Unfortunately there are also drawbacks of such solution. Because of the majority of mechanisms are located on the server, its usage levels trend to build up quickly...
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Code development of a DSP-FPGA based control platform for power electronics applications
PublikacjaThis paper focuses on the implementation of power electronics algorithms in control platforms based on DSP-FPGA. Today’s power electronics technology demands high power computation with high speed interfacing at the same time. The most popular configuration is a DSP for the former and a FPGA for the latter. The main goal of this work was to develop a generic control system for power electronics application, but it is explained...
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Wireless Link Selection Methods for Maritime Communication Access Networks—A Deep Learning Approach
PublikacjaIn recent years, we have been witnessing a growing interest in the subject of communication at sea. One of the promising solutions to enable widespread access to data transmission capabilities in coastal waters is the possibility of employing an on-shore wireless access infrastructure. However, such an infrastructure is a heterogeneous one, managed by many independent operators and utilizing a number of different communication...
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Jakub Grochowski mgr inż.
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Morphology and local chain structure of polyamide 6 modified in the solid state with a semi-aromatic nylon salt
PublikacjaStructural and conformational differences between the polyamide 6 (PA6) homopolymer and two copolymers of PA6 modified in the solid state with 20 and 30 wt% of the semi-aromatic nylon salt of 1,5-diamino-2-methylpentane (Dytek A) and isophthalic acid (IPA) in the feed were investigated. Room temperature wide-angle X-ray diffraction (WAXD) analysis together with 13C{1H} cross-polarization/magic-angle spinning solid-state (CP/MAS)...
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In-situ synthesis and characterization of biocompatible magnetic ginger nanofiber composites for copper (II) removal from water
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Magnetic properties of charge ordered complex TCNQ salts with lattice distortions
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An extended basis inexact shift–invert Lanczos for the efficient solution of large-scale generalized eigenproblems
PublikacjaThis paper proposes a technique, based on the Inexact Shift–Invert Lanczos (ISIL) method with Inexact Jacobi Orthogonal Component Correction (IJOCC) refinement, and a preconditioned conjugate-gradient (PCG) linear solver with multilevel preconditioner, for finding several eigenvalues for generalized symmetric eigenproblems. Several eigenvalues are found by constructing (with the ISIL process) an extended projection basis. Presented...
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Improving performance of large thrust bearings through modeling and experimentation
PublikacjaLarge thrust bearings are highly loaded machine elements and their failures cause serious losses. Start ups and stoppages of the bearing under load are specially critical regimes of operation. Load carrying capacity depends on the profile of the oil gap. In transient states this profile is also changing. In the design of large thrust bearings minimizing thermo-elastic deformations is an important goal, which can be accomplished...
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The effect of social media communication on consumer perceptions of brands
PublikacjaResearchers and brand managers have limited understanding of the effects social media communication has on how consumers perceive brands. We investigated 504 Facebook users in order to observe the impact of firm-created and user-generated (UG) social media communication on brand equity (BE), brand attitude (BA) and purchase intention (PI) by using a standardized online survey throughout Poland. To test the conceptual model, we...
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Synthesis, structure and magnetic properties of neutral Ni(II) tri-tert-butoxysilanethiolate cluster
PublikacjaNowy klaster niklu(II) [Ni6(μ-O)6{SSi(tBuO)3}6(H2O)6(NH3)4] został otrzymany w reakcji NiCl2·6H2O z tri-tert-butoksysilanotiolu i amoniakiem w roztworze wodnym. Pomiary właściwości magnetycznych badanego związku pokazują obecność silnych antyferromagnetycznych oddziaływań pomiędzy centrami metalicznymi.
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Fourth International Workshop on Reliable Networks Design and Modeling (RNDM 2012)
Publikacjaartykuł sprawozdawczy z konferencji
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Two almost homoclinic solutions for second-order perturbed Hamiltonian systems
PublikacjaW niniejszym artykule badamy problem istnienia rozwiązań prawie homoklinicznych (rozwiązań znikających w nieskończonościach) dla układów Hamiltonowskich drugiego rzędu (układów Newtonowskich) z zaburzeniem. Nasz wynik jest uogólnieniem twierdzenia Rabinowitza-Tanaki o istnieniu rozwiązania homoklinicznego dla układów bez zaburzenia [Math. Z. 206 (1991) 473-499]. O zaburzeniu zakładamy, że jest dostatecznie małe w przestrzeni funkcji...
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Networks 2010 Conference in Warsaw, Poland
PublikacjaArtykuł sprawozdawczy z konferencji.
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IEEE RNDM 2010 Workshop, Moscow, Russia
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Fabrication and characterizations of hybrid materials based on polyaniline, metal oxide, and graphene nano-platelets for supercapacitor electrodes
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Robust effectiveness behavior of synthesized cobalt doped Prussian blue graphene oxide ferrite against EMI shielding
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I-V, dielectric, antibacterial, and robust EMI shielding effectiveness properties of graphene/Fe3O4
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Electrical, dielectric, I-V and antimicrobial behavior of cobalt incapacitated Prussian blue graphene ferrites composite
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Effect of a characteristic length on crack spacing in a reinforced concrete bar under tension
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Chemical instability of the cobalt oxyhydrate superconductor under ambient conditions
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