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Wyniki wyszukiwania dla: CO2 REDUCTION
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Wyznaczanie współczynników dyfuzji tlenku węgla (IV) przez membrany wysycone cieczą jonową = Determination of carbon dioxide diffusion coefficients in supported ionic liquids membranes
PublikacjaWykazano możliwość zastosowania imidazoliowych cieczy jonowych osadzonych na nośnikach polimerowych SILM (supported ionic liquids membranes) do absorpcji CO2. W badaniach wykorzystano sole imidazoliowe posiadające w strukturze aniony fluoroalkilowe typu [Tf2N] i [TfO], które selektywnie separują tlenek węgla (IV). Wyznaczono współczynniki dyfuzji CO2 przez poszczególne SILM na podstawie ilości dyfundującego CO2 przez powierzchnię...
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CO2 Separation Using Supported Deep Eutectic Liquid Membranes Based on 1,2-propanediol
PublikacjaIn this work, deep eutectic solvents (DESs) composed of choline chloride, acetylcholine chloride or tetrabutylammonium chloride, and 1,2-propanediol were used as a liquid phase for polypropylene-based supported liquid membranes (SLMs) and evaluated for the separation of carbon dioxide from CO2/N2 mixtures. Fourier transform infrared spectra were obtained to confirm DES formation, and the thermal stability of solvents was investigated...
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All solid state electrodes taste sensor with modified polymer membranes for discrimination of mineral water with different CO2 content
PublikacjaA potentiometric taste sensor with All Solid State Electrodes containing five all solid state electrodes with appropriate lipophilic compounds (benzyldimethyltetradecylammonium chloride, dodecyltrimethylammonium bromide, palmitic acid, stearic acid, and phytol) embedded in a polymer membrane was applied for discrimination of mineral water samples differed in CO2 content. Samples of still, slightly sparkling, and sparkling Naleczowianka...
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Evaluating the effect of different operational strategies on the carbon footprint of wastewater treatment plants – case studies from northern Poland
PublikacjaNowadays, low greenhouse gas (GHG) emission is expected at wastewater treatment plants (WWTPs). However, emission quantification and evaluation still faces difficulties related to data availability and uncertainty. The objective of this study was to perform carbon footprint (CF) analysis for two municipal WWTPs located in northern Poland. Slupsk WWTP is a large biological nutrient removal (BNR) facility (250,000 PE) which benefits...
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Effect of copper and silver modification of NH2-MIL-125(Ti) on the photoreduction of carbon dioxide to formic acid over this framework under visible-light irradiation
PublikacjaCu and Ag enhance the photocatalytic activities of metal–organic frameworks (MOFs) toward CO2 conversion because of their CO2 adsorption capacities and effects on the lowest unoccupied molecular orbital (LUMO) overpotentials of MOFs. However, to date, targeted introduction of metals into MOFs to achieve visible (Vis)- light-active photocatalysts for CO2 photoconversion has not been realized. Herein, a series of aminefunctionalized...
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Numerical analysis of CO2-water separation in a horizontal double T-junction
PublikacjaCarbon dioxide is considered one of the main factors leading to global warming. Considering the significant impacts of CO2 on climate change, various technologies have been developed in recent decades to control carbon emission, such as for example CO2 capture and storage. The developed cycle of a negative CO2 emission power plant includes some devices, out of which, separator plays an indispensable role. To this end, T-junction...
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Deep Eutectic Solvents: Properties and Applications in CO2 Separation
PublikacjaNowadays, many researchers are focused on finding a solution to the problem of global warming. Carbon dioxide is considered to be responsible for the “greenhouse” effect. The largest global emission of industrial CO2 comes from fossil fuel combustion, which makes power plants the perfect point source targets for immediate CO2 emission reductions. A state-of-the-art method for capturing carbon dioxide is chemical absorption using...
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CO2 capture using steam ejector condenser under electro hydrodynamic actuator with non-condensable gas and cyclone separator: A numerical study
PublikacjaThe concept for condensation of steam and CO2 separation in a negative CO2 emission gas power plant involves the utilization of a steam ejector condenser (SEC) for direct-contact condensation of vapor with inert gas (CO2) on a spray of subcooled liquid, integrated with a separator to produce pure CO2. Due to the increasing diffusion resistance and reduced convective heat transfer between the steam and subcooled water phases...
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Comparative study of a combined heat and power plant retrofitted by CO2 capture during the combustion of syngas from sewage sludge gasification versus zero-emission combustion of hydrogen produced using renewables
PublikacjaWith ecological requirements aimed at limiting the production of CO2, it is necessary to produce all, or most of the energy from RES. During the transformation process, ecological and highly efficient combustion power plants will be needed. The classic cycle of combined heat and power (CCGT) with green improvements will continue to be one of the most suitable technologies for this task. This article presents the modernization of...
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Searching for Solvents with an Increased Carbon Dioxide Solubility Using Multivariate Statistics
PublikacjaIonic liquids (ILs) are used in various fields of chemistry. One of them is CO2 capture, a process that is quite well described. The solubility of CO2 in ILs can be used as a model to investigate gas absorption processes. The aim is to find the relationships between the solubility of CO2 and other variables—physicochemical properties and parameters related to greenness. In this study, 12 variables are used to describe a dataset...
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Effect of selected ammonia escape inhibitors on carbon dioxide capture and utilization via calcium carbonate precipitation
PublikacjaCarbon dioxide was used to precipitate CaCO3 with CaCl2 solution in the presence of NH3 as a CO2 absorption promoter. Compounds that were previously indicated as inhibitors of ammonia escape during CO2 absorption were also added to the reaction mixture. Inorganic salts, i.e. ZnCl2, CuCl2, CoCl2, and organic substances, i.e. glycerol, ethylene glycol and triethanolamine were tested inhibitors in this work. A model post-distillation...
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Precypitacja węglanu wapnia metodą karbonatyzacji z dodatkiem glicerolu w obecności wybranych promotorów absorpcji CO2
PublikacjaJednym ze sposobów produkcji węglanu wapnia jest metoda gaz-ciecz, w której jako reagent stosuje się gazowy CO2 oraz roztwór soli wapnia, do którego dodawane są związki sprzyjające absorpcji CO2, tzw. promotory. Reakcja z gazowym CO2 jest specyficzna, ponieważ powstawanie jonów wodorowęglanowych podczas absorpcji CO2 z reakcją chemiczną jest etapem decydującym o szybkości procesu strącania CaCO3. Celem niniejszej pracy było określenie...
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Fotokonwersja CO2 do lekkich węglowodorów
PublikacjaZagadnieniem o istotnym znaczeniu w kontekście problematyki ogranicznia emisji CO2 jako gazu cieplarnianego jest jego sekwestracja. Termin ten, odnoszący do zagadnienia recyklingu CO2, jest stosowany do opisu całego ciągu postępowania z ditlenkiem węgla, począwszy od jego separacji, a kończąc na operacji składowania
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Influence of Ionic Liquid Structure on Supported Ionic Liquid Membranes Effectiveness in Carbon Dioxide/Methane Separation
PublikacjaThis paper indicates the possibility of application of imidazolium ionic liquids immobilized in polymeric supports—supported ionic liquid membranes—in CO2 separation from gaseous streams (e.g., biogas). Imidazolium salts containing alkyl fluoride anions, bis(trifluoromethylsulfonyl)imide and trifluoromethanesulfonate, selectively separating CO2 were used. The permeability of CO2 through membranes was investigated under gas pressure...
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Improving carbon dioxide capture in aqueous ammonia solutions by fine SiO2 particles
PublikacjaAmmonia solutions are considered to be effective solvents for carbon dioxide absorption. Despite the numerous advantages of these solvents, their high volatility is a significant technical and economic problem. Therefore, in this work, silica particles were used as additives to improve CO2 absorption and inhibit NH3 desorption. SiO2 microparticles and colloidal SiO2 particles in the concentration range of 0-0.15 wt.% were used...
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Development of a spray-ejector condenser for the use in a negative CO2 emission gas power plant
PublikacjaOne promising solution for developing low-emission power technologies is using gaseous fuel combustion in pure oxygen when the exhaust gas mixture is composed of H2O and CO2, and where CO2 is separated after steam condensation. The paper presents the results of computational analyses providing to the Spray-Ejector Condenser (SEC) development, which is one of the crucial components of the negative CO2 gas power plant (nCO2PP) cycle...
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Separacja i zagopodarowanie CO2 z gazów spalinowych
PublikacjaGłównymi źródłami emisji antropogenicznego dwutlenku węgla w skali światowej są: produkcja energii elektrycznej, transport, przemysł. Jednym z zaproponowanych sposobów zmniejszenia emisji CO2 do atmosfery jest sekwestracja dwutlenku węgla. Separacja CO2 z gazów spalinowych ma sens przede wszystkim w elektrociepłowniach spalających paliwa kopalne.
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Thermodynamic analysis of the double Brayton cycle with the use of oxy combustion and capture of CO2
PublikacjaIn this paper, thermodynamic analysis of a proposed innovative double Brayton cycle with the use of oxy combustion and capture of CO2, is presented. For that purpose, the computation flow mechanics (CFM) approach has been developed. The double Brayton cycle (DBC) consists of primary Brayton and secondary inverse Brayton cycle. Inversion means that the role of the compressor and the gas turbine is changed and firstly we have expansion...
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Niepewności w kwestii CO2 na tle globalnego ocieplenia
PublikacjaDitlenek węgla to powszechnie znany gaz, uczestniczący m.in. w procesie fotosyntezy. W ostatnich latach zyskał on jednak miano czynnika, który w głównej mierze przyczynia się do powstania efektu cieplarnianego, a walka z emisjami CO2 stała się jednym z najważniejszym elementów polityki UE. Powiązanie tezy antropogenicznego wpływu na ocieplenie klimatu ze wzrostem stężenia ditlenku węgla w atmosferze, pociągnęło za sobą konsekwencje...
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Analysis of cyclone separator solutions depending on SEC outlet conditions in nCO2PP
PublikacjaUtilization of spray ejector condenser in order to carry out direct-contact condensation of vapour with inert gas (CO2) on a spray of subcooled liquid integrated with separator (to make pure CO2) has been proposed for the task of condensation and CO2 separation in the negative CO2 emission gas power plant. Condensation and separation has a significant impact on the thermodynamic efficiency of the entire negative CO2 emission gas...
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Photoconversion of carbon dioxide to methane and light hydrocarbons
PublikacjaFotokonwersja ditlenku węgla do lekkich węglowodorów jest czystym i przyjaznym dla środowiska procesem, pozwalającym na obniżenie emisji CO2 przy jednoczesnym generowaniu paliwa. Badanie efektywności procesu fotokonwersji CO2 prowadzono w obecności promieniowania UV-Vis, pary wodnej oraz fotokatalizatorów Ag-TiO2, Au-TiO2, Ag/Au-TiO2 otrzymanych w mikroemulsji woda/AOT/cykloheksan. Najwyższą aktywność w procesie fotoredukcji...
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Zr‐Based Metal‐Organic Framework UiO‐66/Ultem® 1000 Membranes for Effective CO2/H2 Separation
PublikacjaMixed-matrix membranes (MMMs) using UiO-66 nanofillers as dispersing inorganic phase and polyetherimide (PEI) as continuous polymeric matrix were synthesized. Different UiO-66 loadings of 10, 20, and 30 wt % were applied. The morphology and UiO-66 dispersion over the prepared MMMs were examined. Gas separation measurements were performed for H2/CO2 gas mixture to evaluate the influence of UiO-66 on the separation yield of resulting...
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Free volume in physical absorption of carbon dioxide in ionic liquids: Molecular dynamics supported modeling
PublikacjaUnderstanding the mechanisms underlying the carbon dioxide (CO2) absorption in ionic liquids (ILs) is the key to their efficient utilization in industrial flue gas treatment. One of the parameters considered substantially important in the process is the Free Volume. In this study, the Fractional Free Volume (FFV) of 73 ILs was calculated using Molecular Dynamics (MD). A quantitative Structure-Property Relationship (QSPR) study...
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In situ study of a composition of outlet gases from biogas fuelled Solid Oxide Fuel Cell performed by the Fourier Transform Infrared Spectroscopy
PublikacjaThe purpose of this study was to develop a method and software based on the Fourier Transform Infrared Spectroscopy for the in-situ, quantitative analysis of the composition of outlet gases from Solid Oxide Fuel Cell (SOFC). The calibration procedure performed at the beginning of the experiment indicated a polynomial dependence between the concentration of a calibrating gas (CO, CO2, CH4) and the corresponding integrated absorbance in...
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Advanced local energy planning using the ALEP-PL computer software
PublikacjaPrzedstawiono autorski system komputerowy ALEP-PL do gromadzenia i agregacji danych o lokalnych obiektach energetycznych. System pozwala na analizy senariuszowe poprzez bilanse zapotrzebowania na paliwa i energie oraz poprzez wskaźnikowe wyznaczanie wilekości emisji CO2. Dodatkowo, dzięki wybudowanemu w system ALEP-PL zestawowi technologii modernizacyjnych, aplikacja umożliwia opracowywanie strategii redukcji emisji CO2, poprawy...
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Solvent dependency of carbon dioxide Henry's constant in aqueous solutions of choline chloride-ethylene glycol based deep eutectic solvent
PublikacjaThe Henry's constants of carbon dioxide absorbed in aqueous solutions of ethaline (choline chloride-ethylene glycol) were determined for temperatures ranging from 303.15 to 323.15 K based on solubility measurement at CO2 pressure ranging from 0 to 6 bar (0.6 MPa). These studies revealed that the Henry's constant increased with the increase of temperature. Data indicated the highest capacity of CO2 absorption is obtained for ethaline...
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Thermodynamic interpretation and prediction of CO2 solubility in imidazolium ionic liquids based on regular solution theory
PublikacjaRegular solution theory (RST) is the most popular model for the interpretation of the interaction between CO2 and ionic liquids. In the present work, the parameters of this model were determined for the CO2 absorption in eleven imidazolium ionic liquids. The y-intercept (A) of the RST model for the investigated imidazolium liquids increases with increasing temperature whereas the slope (B) remains constant. The values of RST parameters...
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Cement kiln dust
PublikacjaThe volume of cement production in the world has remained at the level of approxi mately 4.1 billion tons/year. The cement production process is energy intensive and is the world’s leading emitter of carbon dioxide. Therefore, the main activities cement plants are aimed at introducing technologies changes in production of clinkier.The construction industry is responsible for the majority of CO2 emissions to the atmosphere: the...
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Influence of Selected Saccharides on the Precipitation of Calcium-Vaterite Mixtures by the CO2 Bubbling Method
PublikacjaCalcium carbonate is a compound existing in living organisms and produced for many biomedical applications. In this work, calcium carbonate was synthesized by a CO2 bubbling method using ammonia as a CO2 absorption promotor. Glucose, fructose, sucrose, and trehalose were added into the reaction mixture to modify characteristics of precipitated calcium carbonate particles. To determine the polymorphic form of produced calcium carbonate...
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CO2 EMISSION TO THE ATMOSPHERE FROM CARBONATE WATERS: THE STUDY CASE OF THE LUBLIN UPLAND AND ROZTOCZE REGIONS
PublikacjaThe concentration of carbon dioxide dissolved in water (CO2(aq)) was measured in consecutive phases of the hydrological cycle. Its potentially possible degassing from groundwaters to the atmosphere was also assessed. The research was conducted in the area of occurrence of carbonate rocks of the Lublin Upland and Roztocze (SE Poland). The results of the measurements of CO2(aq) concentration varied as follows (min-max/mean): precipitation...
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Badania naprężeń własnych laserowo przetapianej stali C45.
PublikacjaPraca prezentuje badania wpływu parametrów laserowego przetapiania stali C45 za pomocą wiązki lasera CO2 o mocy 6 kW na wielkość naprężeń własnych.
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Wpływ fazy nagrzewania silnika samochodowego na zużycie paliwa
PublikacjaW referacie przedstawiono wybrane problemy wpływu parametrów rozgrzewania silnika na zużycie paliwa. Wymieniono przewidywane ograniczenia prawne Unii Europejskiej co do emisji CO2.
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Measurements of electron drift velocity in OCS
PublikacjaWykonano pomiary prędkości dryfu elektronów w funkcji zredukowanego pola elektrycznego E/N. Wyniki tych pomiarów porównano z wynikami pomiarów w CO2 i N2O.
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Możliwość redukcji emisji C02 dzięki zastosowaniu geosyntetyków
PublikacjaZastosowanie geosystemów jako rozwiązania zamiennego do konstrukcji klasycznych. Wybór geosystemu - względy techniczne, ekonomiczne i środowiskowe. Metodologia obliczania emisji CO2. Geosyntetyki wsparciem zrównoważonego rozwoju
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Synteza bio-cyklicznych węglanów z wykorzystaniem oligoeteroli różniących się masą molową
PublikacjaCykliczne węglany mogą być otrzymywane w wyniku cykloaddycji CO2 do eterów glicydylowych. Biorąc pod uwagę stopniowe wyczerpywanie się, a co za tym idzie, zauważalny wzrost cen substratów ropopochodnych należy wziąć pod uwagę zastąpienie surowców petrochemicznych przez związki pochodzenia naturalnego. Ponadto, wykorzystanie CO2 przyczynić się może do rozwoju perspektyw utylizacji tego gazu w syntezach organicznych. Otrzymanie węglanów...
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Thermodynamic Analysis of Negative CO2 Emission Power Plant Using Aspen Plus, Aspen Hysys, and Ebsilon Software
PublikacjaAbstract: The article presents results of thermodynamic analysis using a zero-dimensional mathematical models of a negative CO2 emission power plant. The developed cycle of a negative CO2 emission power plant allows the production of electricity using gasified sewage sludge as a main fuel. The negative emission can be achieved by the use this type of fuel which is already a “zeroemissive” energy source. Together with carbon capture...
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Properties of Nasicon-based CO2 sensors with Bi8Nb2O17 reference electrode
PublikacjaPotentiometric CO2 sensors based on Nasicon (Na+ conductor, Na3Zr2Si2PO12) electrolyte, Bi8Nb2O17/Pt reference electrode and different sensing electrodes have been prepared. Besides the sensing electrode material, sensors differ from each other in the reference electrode preparation technique. The main aim of this study is to investigate sensor construction and electrode fabrication process influence on sensor properties. The optimal...
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Utilization of ionic liquids for the enrichment of biogas
PublikacjaThis article discusses the dependence of biogas composition on organic feed material. High amounts of CO2 decrease the calorific value of biogas. Several technologies are reviewed which can be used to increase the calorific value. Special emphasis is laid on ionic liquids as a new absorbing material. ILs have a number of advantages due to their unique properties such as: low melting point, high thermal conductivity, no flammability,...
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Effects of CO2 and Nd:YAG Laser Remelting of the Ti6Al4V Alloy on the Surface Quality and Residual Stresses
PublikacjaThe titanium alloys are materials susceptible to tribological wear and the laser treatment can be applied in surface treatment processes to obtain for example higher hardness level. From the other side, it is important to take into consideration, that hardness increase that can be connected with cracks . The aim of this research was to investigate the effects of different lasers and the process parameters on the form and level...
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Ag modified ZnO microsphere synthesis for efficient sonophotocatalytic degradation of organic pollutants and CO2 conversion
PublikacjaThe synthesis and design of non-precious and efficient sonophotocatalyts by an environment friendly technique are requisites for solar energy conversion and environmental remediation. This work reports the preparation of Ag/ZnO microspheres with different Ag contents through deposition–precipitation method for pollutant degradation and CO2 conversion. Detail structural investigation reveals that ZnO microspheres and Ag-ZnO microspheres...
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Wpływ prędkości przesuwu wiązki lasera CO2 na odporność kawitacyjną stali 2H13
PublikacjaPrzedstawiono badania odporności kawitacyjnej stali 2H13 po przetapianiu jej powierzchni wiązką lasera CO2, przy różnych prędkościach obróbki laserowej. Stwierdzono wzrost odporności kawitacyjnej przy wzroście prędkości obróbki.
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Double ZIF-L structures with exceptional CO2 capacity
PublikacjaCarbon dioxide emission is an emerging problem nowadays and new methods are designed for its control. In this article, a report on the formation of zeolitic imidazole framework with an apparent double leaf-like morphology DZIF-L is given. The special structure of the materials prevents from aggregation of the particles providing remarkable CO2 capacity. At 0.1 MPa the CO2 uptake was 2.99 ± 0.06 mmol/g. The capacity of synthesized...
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Wpływ podatku węglowego na efektywność pracy elektrociepłowni.
PublikacjaArtykuł prezentuje metodę wprowadzania podatku węglowego z progiem emisji dopuszczalnej, zwolnionej od podatku i jedną z metod podziału emisji CO2 między energią elektryczną i ciepło wytwarzane w elektrociepłowni.
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Diphosphinoboranes as Intramolecular Frustrated Lewis Pairs: P–B–P Bond Systems for the Activation of Dihydrogen, Carbon Dioxide, and Phenyl Isocyanate
PublikacjaHerein, we present the first example of the activation of small molecules by P-B-P bond systems. The reactivity study involves reactions of two selected diphosphinoboranes, (tBu2P)2BPh (1’) and (Cy2P)2BNiPr2 (2), that differ in terms of their structural and electronic properties for the activation of dihydrogen, carbon dioxide, and phenyl isocyanate. Diphosphinoborane 1’ activates H2 under very mild conditions in the absence of...
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User-assisted methodology targeted for building structure interpretable QSPR models for boosting CO2 capture with ionic liquids
PublikacjaTask-specific ionic liquid (IL) is an emerging class of compounds that may be environmentally friendly. Properly selected, these compounds may be green alternative to amine solutions and can replace them in post-combustion carbon dioxide (CO2) capture processes on an industrial scale. However, owing to the vast diversity of ions and their possible combinations, laboratory research is time consuming and expensive. Therefore, computational...
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Odporność kawitacyjna stali 2H13 przetapianej wiązką lasera i stopowanej niobem
PublikacjaPrzedstawiono badania odporności kawitacyjnej stali 2H13 po dwóch wariantach obróbki laserowej. W pierwszym wariancie powierzchnie stali przetapiano wiązką lasera CO2, a w drugim powierzchnie wzbogacano Nb w ilości 5% masowego.
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Photocatalysts for Solar Energy Conversion
PublikacjaPhotocatalytic oxidation over suspended solid photocatalysts (e.g., titanium dioxide) has been proposed as a sustainable process for treatment and purification of water and wastewater as well as the process for photoconversion of solar energy to hydrogen, methane, and other low hydrocarbons. Solar radiation could be used to drive heterogeneous electrochemical reactions at the surface of an optically active photocatalyst (e.g.,...
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Yields and Time-of-Flight Spectra of Neutral High-Rydberg Fragments at the K Edges of the CO2 Molecule
PublikacjaWe have studied the production of neutral fragments in high-Rydberg (HR) states at the C 1s and O 1s edges of the CO2 molecule by performing two kinds of experiments. First, the yields of neutral HR fragments were measured indirectly by ionizing such fragments in a static electric field and by collecting resulting singly charged positive ions as a function of the photon energy. Such measurements reveal not only excitations below...
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Influence of selected CO2 absorption promoters on the characteristics of calcium carbonate particles produced by carbonation of the post-distillation liquid from the Solvay process
PublikacjaThe aim of this work is to compare the effect of selected process parameters, gas flow rate, CO2 absorption promoter concentration and its pKa, on the precipitation of CaCO3 by the gas-liquid method using a model post-distillation liquid from the Solvay process. To ensure effective capture of CO2, the absorption promoters used were ammonia, triethanolamine and triethylamine. The Box-Behnken Design was applied to plan the experiments....
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Sztuczna fotosynteza - utopia, czy szansa na tanie paliwa?
PublikacjaUwalnianie CO2 w procesach przemysłowych i inne czynniki wynikające z aktywności człowieka spowodowały, że naturalna równowaga między emisją tlenku węgla(IV) a pochłanianiem go przez rośliny i w owdach powierzchniowych została zakłócona