Wyniki wyszukiwania dla: phase structure
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Roadmap on dynamics of molecules and clusters in the gas phase
PublikacjaThis roadmap article highlights recent advances, challenges and future prospects in studies of the dynamics of molecules and clusters in the gas phase. It comprises nineteen contributions by scientists with leading expertise in complementary experimental and theoretical techniques to probe the dynamics on timescales spanning twenty orders of magnitudes, from attoseconds to minutes and beyond, and for systems ranging in complexity...
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Phase investigations of copper based CuZn38Al2MnFe alloy
PublikacjaW pracy przedstawiono analizę fazową mosiądzu CuZn38Al2MnFe. Wykazano, że obecność fazy Fe4Mn77Si19 powoduje kruchość stopu w teście zginania próbek.
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Structure and water uptake in BaLnCo2O6−δ (Ln =La, Pr, Nd, Sm, Gd, Tb and Dy)
PublikacjaThe structure of BaLnCo2O6-δ (Ln =La, Pr, Nd, Sm, Gd, Tb and Dy) was studied by the means of synchrotron radiation powder X-ray diffraction, neutron powder diffraction and Transmission Electron Microscopy (TEM), while water uptake properties were analysed with the use of thermogravimetry (TG) and water adsorption isotherms. The structure refinement revealed that the dominant phase in all compositions was orthorhombic with an ordering...
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Influence of Antimony Substitution on Spontaneous Strain and Thermodynamic Stability of Lanthanum Orthoniobate
PublikacjaThe analysis of the antimony substitution influence on temperature dependence of unit cell distortion has been done. The values of spontaneous strain and Landau order parameter for three different antimony contents varied had been calculated. The phase transition occurring for antimony substituted lanthanum orthoniobate was found to be second order. The high temperature solution calorimetry method has been used to investigate...
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XRD patterns of ammonium vanadate nanocrystals
Dane BadawczeThe DataSet contains the XRD patterns of ammonium vanadate nanobelts obtained by the hydrothermal method with different conditions. The results show that the structure and phase compositions of samples dependent on reaction conditions.
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Structure and hyperfine interactions in Bi1−xNdxFeO3 solid solutions prepared by solid-state sintering
PublikacjaThe series of polycrystalline ceramic powders, Bi1xNdxFeO3 (x = 0.11) was successfully synthesized by mixed oxide method followed by pressureless sintering. X-ray diffraction and Mössbauer spectroscopy were used as complementary methods to study structure and hyperfine interactions of the samples. It was found that with an increase of Nd content, within the range of x = 0.20.3 a structural phase transition from rhombohedral to...
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Synthesis, Molecular Structure, Anticancer Activity, and QSAR Study of N-(aryl/heteroaryl)-4-(1H-pyrrol-1-yl)Benzenesulfonamide Derivatives
PublikacjaA series of N-(aryl/heteroaryl)-4-(1H-pyrrol-1-yl)benzenesulfonamides were synthesized from 4-amino-N-(aryl/heteroaryl)benzenesulfonamides and 2,5-dimethoxytetrahydrofuran. All the synthesized compounds were evaluated for their anticancer activity on HeLa, HCT-116, and MCF-7 human tumor cell lines. Compound 28, bearing 8-quinolinyl moiety, exhibited the most potent anticancer activity against the HCT-116, MCF-7, and HeLa cell lines,...
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From Structure to Luminescent Properties of B2O3-Bi2O3-SrF2 Glass and Glass-Ceramics Doped with Eu3+ Ions
PublikacjaGlass-ceramics with the composition B2O3 -Bi2O3 -SrF2 were synthesized by the conventional melt-quenching technique and subsequent crystallization of the parental glasses. The temperature at which the ceramization was carried out was selected based on differential scanning calorimetry (DSC) analysis. The structure of the studied materials and the formation of SrF2 nanocrystals were confirmed by the Fourier-transform infrared spectroscopy...
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Comparitive study of heat transfer and pressure drop during flow boiling and flow condensation in minichannels
PublikacjaIn the paper a method developed earlier by authors is applied to calculations of pressure drop and heat transfer coefficient for flow boiling and also flow condensation for some recent data collected from literature for such fluids as R404a, R600a, R290, R32,R134a, R1234yf and other. The modification of interface shear stresses between flow boiling and flow condensation in annular flow structure are considered through incorporation...
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Soft modes of the dielectric response in the twist–bend nematic phase and identification of the transition to a nematic splay bend phase in the CBC7CB dimer
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Analysis of features of stainless steels in dissimilar welded joints in chloride inducted corrosion
PublikacjaStainless steels of femtic-austenitic microstructure that means the duplex Cr-Ni-Mo steels, in comparison with austenitic steel includes less expensive nickel and has much better mechanical properties with good formability and corrosion resistance, even in environments containing chloride ions. Similar share of high chromium ferrite and austenite, which is characterized by high ductility, determines that the duplex steels have...
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Structure-property relationships in peroxide-assisted blends of poly(ε-caprolactone) and poly(3-hydroxybutyrate)
PublikacjaPoly(ε-caprolactone) and poly(3-hydroxybutyrate) (PCL/PHB) blends in two weight ratios (75/25 and 50/50) were reactively compatibilized in the presence of di-(2-tert-butyl-peroxyisopropyl)-benzene and dicumyl peroxide as free radical initiators. Rheological, mechanical, thermal properties and morphological features, as well as the chemical structure of PCL/PHB blends were investigated. It was found that regardless of PCL/PHB blend...
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Multi-Criteria Approach in Multifunctional Building Design Process
PublikacjaThe paper presents new approach in multifunctional building design process. Publication defines problems related to the design of complex multifunctional buildings. Currently, contemporary urban areas are characterized by very intensive use of space. Today, buildings are being built bigger and contain more diverse functions to meet the needs of a large number of users in one capacity. The trends show the need for recognition of...
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Local Structure and Stability of SEI in Graphite and ZFO Electrodes Probed by As K-edge Absorption Spectroscopy
PublikacjaThe evolution of the solid electrolyte interphase (SEI) during the first Li uptake in advanced Li-ion electrodes is studied by X-ray absorption spectroscopy (XAS). The As atoms present in the electrolyte solution were used as a local probe for monitoring the SEI growth on different electrodes. High-quality As K-edge spectra were collected in fluorescence mode for a set of graphite and carbon-coated ZnFe2O4 electrodes. XAS measurements...
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Enantioselective Gel Phase Synthesis of Metal–Organic Materials
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Solid phase synthesis of two muramyl pentapeptide derivatives
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U-Turn Compression to a New Isostructural Ferrocene Phase
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Phase-decoupled refraction–diffraction for spectral wave models
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Effective dielectric constant of two phase dielectric systems
PublikacjaW tym artykule model brick-layer ścianie został rozszerzony na dwufazowe systemy perkolacyjne. Porównano wyniki obliczeń z danymi eksperymentalnymi. Stałe dielektryczne obu faz oraz próg perkolacji pozwala na wyznaczenie efektywnej stałej dielektrycznej systemu dwufazowego.
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Solid Phase Synthesis and Biological Activity of Tuftsin Conjugates
PublikacjaNew tuftsin/retro-tuftsin conjugates were designed and synthesized using a classical fluorenylmethoxycarbonyl (Fmoc) solid phase procedure. All the peptide conjugates were divided into three series: 1,4-dihydroxyanthraquinone (type A), 1-nitroacridine (type B), and 4-carboxyacridone (type C) derivatives. In type A conjugates, the N-terminal group of the peptide chain is directly connected to the anthraquinone ring at C1 (Scheme...
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Interaction of imidazolium type ionic liquids with the solid phase
PublikacjaNiektóre ciecze jonowe, w szczególności te posiadające kation organiczny podstawiony długim łańcuchem alkilowym, wykazują strukturalne podobieństwo do surfaktantów. Samoczynne formowanie się agregatów cieczy jonowych może wpływać na procesy przenoszenia masy w wielu operacjach jednostkowych jak: ekstrakcja, nanofiltracja lub kataliza oraz transport i rozmieszczenie tych związków w środowisku naturalnym. W niniejszej publikacji...
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Superconductivity phase diagram of Na x CoO2·1.3H2O
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Rich magnetic phase diagram of the kagome-staircase compoundMn3V2O8
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The first order phase transition and superconductivity in BaNi2As2single crystals
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An ultrasonic obstacle detector based on phase beamforming principles
PublikacjaW artykule przedstawiono rezultaty prac nad ultradźwiękowym wykrywaczem przeszkód dla niewidomych. Opisano metodę lokalizacji przeszkód w oparciu o algorytm beamformingu fazowego. Zaprezentowano rezultaty badań przeprowadzonych nad prototypem urządzenia.
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Solid phase extraction technique - trends, opportunities and applications
PublikacjaW pracy opisano wykorzystanie ekstrakcji do fazy stałej w chemii analitycznej. Ekstrakcja do fazy stałej może być przydatna nie tylko do izolacji i wzbogacania analitów z fazy wodnej, ale również do wymiany matrycy oraz oczyszczania ekstraktu. Stosowane sorbenty są analogiczne do stosowanych w chromatografii cieczowej. Omówione zostały: mechanizmy ekstrakcji, sposoby przeprowadzania ekstrakcji (kolumienki, krążki, pipety), rodzaje...
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Determination of pKa by pH Gradient Reversed-Phase HPLC
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Solid phase microextraction: state of the art, opportunities and applications
PublikacjaSolid phase microextraction is one of the most popular green techniques used for sample preparations in analytical chemistry. It is a simple, rapid, sensitive, and solvent-free technique. Since SPME was first introduced in the early 1990s, there has been an intensification of research in order to elaborate new methodical solutions in many research facilities around the world, which could increase the use of this technique. More...
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On phase equilibrium of an elastic liquid shell with wedge disclination
PublikacjaBased on the six-parameter shell theory we consider the phase equilibrium of a two-phase liquid membrane containing a wedge disclination. The considered problems are related to modelling of phase transitions in biological or lipid membranes. In order to capture the membrane behaviour we consider a special case of elastic shells which energy is invariant under major transformations of a reference configuration and can be treated...
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Three phase transient model of wet coal pyrolysis
PublikacjaA one-dimensional transient mathematical model was developed to describe the thermal and flow phenomena during coal pyrolysis in a coke oven. The model was solved numerically using partly implicit methods for gas flow and heat transfer problems. It was successfully validated with industrial-scale measurements of temperature change in the middle-plane of the coke oven chamber. The evolution of temperature and pressure, distributions...
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Solid Phase Microextraction: Apparatus, Sorbent Materials, and Application.
Publikacjahe primary objective of this review article is to strategically screen and highlight the advancements in the area of solid phase microextraction (SPME). The plenty of review articles have been written on different aspects of SPME, this review is dedicated to provide the brief but clear overview of the research footprints so produced from SPME. Some of the key advancements in types and designs, coating materials, coating strategies,...
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Energy Modeling of Single-Family Houses in the Conceptual Phase
PublikacjaThe aim of the article is to identify the potential impact of the latest commercial digital tools for building energy analysis on the everyday architectural practice in Poland in the context of typology and energy optimization of single –family houses. The reason for this survey is that “architect friendly” interfaces simulation results’ visualization and energy analysis tools are not given deserved attention in the architectural...
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Hysteresis modelling of a medium frequency single-phase transformer
PublikacjaThe article describes a feedback Preisach hysteresis model equivalent circuit implementation of a medium frequency single-phase transformer being a part of a high power and high efficiency DC-DC converter. The macroscopic models of magnetic hysteresis are introduced and the feedback Preisach model is selected for further analysis. The hysteresis model is developed for a prototype transformer and the hysteresis loops are compared...
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Sample Preparation in Foodomics: Miniaturized Solid-Phase Extraction
PublikacjaAnalytical chemists face a challenge to bring comprehensive information on a given food and biological sample by using the best available analytical techniques and meet the requirements of sustainable development and green chemistry at the same time. A key objective of this chapter is to review selected literature data on the utilization of solid-phase extraction techniques with special attention to their miniaturized modes in...
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Application of the Anammox Process for Treatment of Liquid Phase Digestate
PublikacjaThe liquid phase of the digestate (LPD) contains a relatively high concentration of nitrogen, with total ammonium nitrogen being the dominant form of nitrogen, as well as other essential nutrients such as phosphorus and potassium. Consequently, it must be treated before it is released into the environment. However, there are no reports of co-purification of LPD in the anammox process in sequencing batch reactor with granular sludge,...
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Two-phase thermosiphon heat exchanger for heat recovery
PublikacjaW pracy przedstawiono wyniki badań eksperymentalnych dotyczących wpływu geometrii pęku rur, rodzaju powierzni przejmowania ciepła parownika oraz płynu pośredniego na całkowitą wydajność dwufazowego termosyfonowego wymiennika ciepła (DTWC). Badaniu poddano sześć prototypowych DTWC z dwiema podziałkami rur w parowniku, dla trzech rodzajów powierzchni rur parownika oraz z zastosowaniem trzech rodzajów płynów pośrednich. Lepszą wydajność...
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A review of phase change materials and heat enhancement methodologies
PublikacjaPhase change materials (PCMs) are an efficient alternative to store and release heat at a specific range of temperature. Here PCMs and heat enhancement methodologies for PCM storage are reviewed. A short overview of PCMs and their applications is presented in addition to the progress during the last 10 years. Heat enhancement techniques, that is, extended surfaces, multiple and composite PCMs, and encapsulation techniques, are...
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On iterates of strong Feller operators on ordered phase spaces.
PublikacjaPraca dotyczy asymptotycznych własności iteracji operatorów Markowa. Udowodniono, że operatory Lasoty i ich wielowymiarowe uogólnienia są asymptotycznie stabilne. Wyniki mają zastosowanie w modelowaniu rozwoju komórki.
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The high impedance measuring probe for gain-phase analysers.
PublikacjaAutorzy opracowali tanią sondę pomiarową przeznaczoną do pracy z analizatorami gain-phase jak Solartron 1260 Impedance/Gain-phase Analyser, 1255 Frequency Response Analyser (FRA) lub starszymi wersjami 1250, 1253. Przedstawiona architektura sondy wyznacza jej parametry metrologiczne. Pomiary możliwe są w 8 zakresach obejmujących wartości 100ohm<|Zx|<100Gohm w szerokim zakresie częstotliwości 10uHz-1MHz. Obwód wejściowy sondy pozwala...
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The luminescence study ofNaK2Li[Li3SiO4]4:Ce coumpounds.
Dane BadawczePhosphors with a rigid and symmetrical structure are urgently needed. The alkali lithosilicate family (A[Li3SiO4]) has been extensively studied with a narrow emission band due to its unique cuboid-coordinated environment and rigid structure. However, here we demonstrate for the first time Ce-doped NaK2Li[Li3SiO4]4 phosphors with a broad emission band,...
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Compact Dual-Polarized Corrugated Horn Antenna for Satellite Communications
PublikacjaIn this paper, a structure and design procedure of a novel compact dual-polarized corrugated horn antenna with high gain and a stable phase center for satellite communication is presented. The antenna incorporates an Ortho-Mode Transducer (OMT), a mode converter, and a corrugated structure. The compact OMT section is designed to be fed by standard WR-75 waveguides. The proposed compact design utilizes only ten corrugated slots...
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Chromatographic behavior of a new hybrid type RP material containing silica bonded 1,3-alternate 25,27-bis-[cyanopropyloxy]-26,28-bis-[3-propyloxy]-calix[4]arene
PublikacjaA novel 1,3-alternate 25,27-bis-[cyanopropyloxy]-26,28-bis-[3-propyloxy]-calix[4]arene-bonded silica gel stationary phase (CalixPrCN) was prepared and it's structure was confirmed by ATR-FTIR spectroscopy and elemental analysis. The CalixPrCN phase was characterized in terms of their surface coverage, hydrophobic selectivity, aromatic selectivity, shape selectivity, hydrogen bonding capacity, residue metal content, and silanol...
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Determination of pressure drop in flow condensation of HFE7000 in minichannels with account of non-adiabatic effects
PublikacjaFlow boiling and flow condensation are often regarded as two opposite or symmetrical phenomena involving the change of phase. There is a temptation to describe both these phenomena with one only correlation, however such method has yet to be suggested. From amongst the structures present in flow boiling and flow condensation at least the annular flow structure seems to be mostly appropriate to the common modeling. However, the shear...
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Interaction of cisplatin and two potential antitumoral platinum(ii) complexes with a model lipid membrane: a combined NMR and MD study
PublikacjaIn this study, the interaction of cisplatin (1) and two potential antitumoral Pt(II) complexes (2 and 3) with a model DMPC bilayer was investigated by multinuclear NMR spectroscopy and MD simulations in order to understand its implication for the different antitumoral properties shown by the three complexes. In particular, 31P, 13C and 2H solid state NMR experiments were performed to obtain information on the phase structure, phase...
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Numerical analysis of CO2-water separation in a horizontal double T-junction
PublikacjaCarbon dioxide is considered one of the main factors leading to global warming. Considering the significant impacts of CO2 on climate change, various technologies have been developed in recent decades to control carbon emission, such as for example CO2 capture and storage. The developed cycle of a negative CO2 emission power plant includes some devices, out of which, separator plays an indispensable role. To this end, T-junction...
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Novel sorptive extraction techniques in bioanalysis evaluated by Blue Applicability Grade Index: The paradigm of fabric phase sorptive extraction and capsule phase microextraction
PublikacjaFabric phase sorptive extraction (FPSE) and capsule phase microextraction (CPME) are two sol-gel derived microextraction techniques that emerged in the last decade towards the minimization of the environmental impact of conventional sample preparation approaches. Complementary to the well-established green metric tools, Blue Applicability Grade Index (BAGI) was recently proposed for the evaluation of method’s practicability. In...
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Straightening of ship hull structure made of 316L stainless steel - microstructure of reference material
Dane BadawczeThe AISI 316L type steel belongs to the group of chromium-nickel stainless steels. They are determined according to European standards as X2CrNiMo17-12-2 and belong to the group of austenitic stainless steels. Steels of this group are used for elements working in seawater environments, for installations in the chemical, paper, and food, industries,...
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Study of Integer Spin S = 1 in the Polar Magnet β-Ni(IO3)2
PublikacjaPolar magnetic materials exhibiting appreciable asymmetric exchange interactions can potentially host new topological states of matter such as vortex-like spin textures; however, realizations have been mostly limited to half-integer spins due to rare numbers of integer spin systems with broken spatial inversion lattice symmetries. Here, we studied the structure and magnetic properties of the S = 1 integer spin polar magnet β-Ni(IO3)2...
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Highly porous nanoberyllium for X-ray beam speckle suppression
PublikacjaThe speckle suppressor device containing highly porous nanoberyllium is proposed for manipulating with the spatial coherence length and removing undesirable speckle structure during the imaging experiments. We report a special device called the speckle suppressor, which contains the highly porous nanoberyllium plate, compacted from both sides by two beryllium windows. By insertion the speckle suppressor in the X-ray beam it allows...
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Structural properties of mixed conductor Ba1−xGd1−yLax+yCo2O6−δ
PublikacjaBa1−xGd1−yLax+yCo2O6−δ (BGLC) compositions with large compositional ranges of Ba, Gd, and La have been characterised with respect to phase compositions, structure, and thermal and chemical expansion. The results show a system with large compositional flexibility, enabling tuning of functional properties and thermal and chemical expansion. We show anisotropic chemical expansion and detailed refinements of emerging phases as La is...