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Wyniki wyszukiwania dla: zinc oxide coating
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Organic filed effect transistor with zinc phthalocyanine.
PublikacjaW pracy przedstawiono wyniki badań doświadczalnych organicznego tranzystora polowego z warstwą ftalocyjaniny cynku. Jako podłoże zastosowano wysoko domieszkowane wafle krzemu pokryte warstwą tlenku krzemu (IV) o grubości 100 nm, na którą techniką fotolitograficzną była naniesiona struktura elektrod (tzw. geometria dolnych kontaktów). Złote elektrody źródła i drenu tworzyły kanał o długości 5 m (jest to odległość między elektrodą...
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The Disturbances of the Zinc Concentration in the Blood in Selected Neoplasms
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Oxide nanoparticle exsolution in Lu-doped (Ba,La)CoO3
PublikacjaThis study investigated Lu doping of Ba0.5La0.5CoO3 and its influence on the exsolution of oxide nanoparticles (NPs). As a result of Lu doping, we observed the phase segregation into the main Ba0.4La0.6Co0.85Lu0.15O3 (BLCO–Lu) phase and the secondary Ba0.85La0.15Co0.75Lu0.25O3 (BCO–Lu) phase. We noticed the exsolution of BCO–Lu nanoparticles on the main BLCO–Lu phase. Moreover, the BLCO–Lu phase exsolved in the form of nanoparticles...
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BET specific surface area measurements of silica-coated bismuth oxide(Bi2O3) and gadolinium oxide (Gd2O3) structures
Dane BadawczeThe BET specific surface area was measured using an N2 adsorption/desorption isotherm (Micromeritics ASAP 2460, Norcross, GA, USA).
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Graphene Oxide as Mine of Knowledge: Using Graphene Oxide To Teach Undergraduate Students Core Chemistry and Nanotechnology Concepts
PublikacjaThe aim of this laboratory experiment is to utilize graphene oxide (GO) material to introduce under-graduate students to many well-known concepts of general chemistry. GO is a new nanomaterial that has generated worldwide interest and can be easily produced in every well-equipped undergraduate chemical laboratory. An in-depth examination of GO synthesis, as well as a study of its structure and properties, allows students to familiarize...
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Thermogravimetry of heteroleptic zinc tri-tert-butoxysilanethiolates: synthesis and crystal structure of bis(tri-tert-butoxysilanethiolato)(pyridine) zinc(II)
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Signature of Oxide-Ion Conduction in Alkaline-Earth-Metal-Doped Y3GaO6
PublikacjaWe have studied alkaline-earth-metal-doped Y3GaO6 as a new family of oxide-ion conductor. Solid solutions of Y3GaO6 and 2% −Ca2+-, −Sr2+-, and −Ba2+-doped Y3GaO6, i.e., Y(3−0.06)M0.06GaO6−δ (M = Ca2+, Sr2+, and Ba2+), were prepared via a conventional solid-state reaction route. X-ray Rietveld refined diffractograms of all the compositions showed the formation of an orthorhombic structure having the Cmc21 space group. Scanning electron...
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Developing Screen-Printing Processes for Silver Electrodes Towards All-Solution Coating Processes for Solar Cells
PublikacjaIn recent years, third-generation solar cells have experienced a remarkable growth in efficiency, making them a highly promising alternative energy solution. Currently, high-efficiency solar cells often use top electrodes fabricated by thermal evaporation, which rely on high-cost and high energy-consumption vacuum equipment, raising significant concerns for mass production. This study develops a method for fabricating silver electrodes...
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Imaging and chemical investigation of silver coating
Dane BadawczeThe recovery of silver from materials such as plates, still used in clinical radiography [1], or scrap jewelery is still very popular. The subject of the research, part of which was microscopic imaging, was to recreate the behavior of an electrochemically deposited silver coating. The copper electrodes were covered with a layer of silver obtained from...
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Multivariate analysis of impedance data obtained for coating systems of varying thickness applied on steel
PublikacjaElectrochemical impedance spectroscopy (EIS) has proven to be a valuable test method for the electrochemical characterization of protective coatings on metals. The common way of analysis in impedance spectroscopy is to model the impedance spectrum by means of an equivalent circuit and to extract the quantity of interest using optimization techniques. A model, corresponding to the behavior of the sample under testing, is important...
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Drop-coating deposition surface-enhanced Raman spectroscopy on silver substrates for biofluid analysis
PublikacjaUtilization of surface-enhanced Raman spectroscopy as a measurement technique is of particular interest in biodetection due to its superb chemical specificity and high sensitivity. The use of SERS substrates further improve this method by massive enhancement of the molecule Raman spectrum, permitting very low levels of detection. Therefore it is important to seek for new ways to develop reliable substrates, which are quickly and...
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Nonlinear impedance in oxide glasses containing single and mixed alkali ions
PublikacjaThe aim of the present was to find more clues on the nonlinearities in impedance of oxide glasses. The first family of researched glasses has a composition of FeO-P2O5-Na2O. Oxide glasses containing iron and alkali are well known for a very low alkali ion mobility and may be considered purely polaron conducting. These glasses show no detectable nonlinearities in the impedance spectra. The second was a family of ionic conducting...
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Self-Organized Nanotubular Oxide Layers on Ti and Ti Alloys
PublikacjaTo improve bioactivity of titanium and titanium, the implant surface modification by formation of self-organized TiO2 nanotube arrays with electrochemical techniques is presented. The influence of electrolyte composition and deposition parameters during anodization is characterized. The enhancement of phosphates deposition by titanium nanotubular structure is discussed. The calcium phosphate ceramics is shown to be uniformly deposited...
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Functionalization of graphene oxide coatings with phosphorus atoms and their corrosion resistance in sodium chloride environment
PublikacjaIn this work, we compared corrosion resistance of graphene oxide, and phosphorus functionalized reduced graphene oxide coatings obtained as a result of electrophoretic deposition on the copper substrate. Doping graphene oxide with phosphorus atoms was performed by a hydrothermal method in the presence of different amounts of phosphoric acid. Structural studies confirmed the insertion of phosphorus atoms into the graphene oxide...
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Hydroxyapatite films as biocompatibile coating for artifical bone
PublikacjaW artykule została szczegółowo opisana budowa kości oraz materiał biokompatybilny hydroksyapatyt (HAp). Autorzy wykazali jak wielkie podobieństwo do budowy kości przejawia sztuczny hydroksyapatyt. opisali syntezy powłoki z HAp.
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The lubricant-coating interaction in rolling and sliding contacts
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Impedance measurements of coating properties on bridge structures
PublikacjaPomiary impedancyjne pozwalają na prostą ocenę właściwości ochronnych powłok ochronnych i wykładzin. Pomiary stosuje się w celu porównania powłok, monitorowania ich właściwości i oceny mechanizmu działania. Metodyka jest z powodzeniem stosowana w pomiarach laboratoryjnych. Pomiary terenowe są bardziej skomplikowane ponieważ wymagają w pełni kontrolowanych komputerowo przyrządów, kontroli warunków pogodowych oraz wielu innych parametrów...
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Evaluation of coating systems using impedance spectroscopy
PublikacjaTrwałość powłokowych systemów ochronnych zależy od oddziaływań środowiska i związana jest nieodwracalnymi procesami chemicznymi i fizycznymi. Zastosowanie spektroskopii impedancyjnej pozwala na określenie obszaru zastosowań danej powłoki i prognozowanie okresu jej trwałości. W pracy zamieszczono przykłady oceny trwałości systemów powłokowych stosowanych w strategicznych konstrukcjach.
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Synergistic effects of nitrogen-doped carbon and praseodymium oxide in electrochemical water splitting
PublikacjaHybrid materials featuring perovskite-type metal oxide in conjunction with heteroatom-doped graphene hold immense promise as alternatives to costly noble metal catalysts for electrochemical water splitting, facilitating the generation of environmentally friendly hydrogen. In this study, perovskite-type oxide containing praseodymium, barium, strontium, cobalt, and iron atoms dispersed in a carbon matrix as a catalyst is synthesized...
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Synthesis, dispersion, and cytocompatibility of graphene oxide and reduced graphene oxide
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Nickel Oxide Thin Film Sensor for Fluctuation-Enhanced Gas Sensing of Formaldehyde
PublikacjaNanocrystalline nickel-oxide-based thin films were prepared by advanced reactive gas deposition, and the response of these films to formaldehyde was studied by fluctuationenhanced sensing. Morphological and structural analyses showed porous deposits of nickel oxide particles with face-centered cubic structure. Resistance fluctuations were measured upon exposure to ethanol, formaldehyde and methane at 200 °C. Power density spectra...
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Morphology and properties of nanotubular oxide layer on the Ti13Zr13Nb alloy
PublikacjaThe Ti13Zr13Nb alloy in solid and porous form was oxidised. The constant voltage 20 V, oxidation time 0.5 and 1 h, and 1 M H3PO4 (orthophosphoric acid) with addition of HF (hydrofluoric acid) as a test solution were applied. SEM (Scanning Electron Microscope) examinations of surface, EDS (Energy Dispersive X-ray Spectroscopy) chemical analysis, nanohardness and nano-scratch tests, and corrosion potentiokinetic tests at various...
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Electrochemically assisted deposition of hydroxyapatite on Ti6Al4V substrates covered by CVD diamond films — Coating characterization and first cell biological results
PublikacjaAlthough titaniumand its alloys are widely used as implant material for orthopedic and dental applications they show only limited corrosion stability and osseointegration in different cases. The aim of the presented research was to develop and characterize a novel surface modification system from a thin diamond base layer and a hydroxyapatite (HAp) top coating deposited on the alloy Ti6Al4V widely used for implants in contact with bone....
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Solid Oxide Fuel Cells with Ni infiltrated perovskite anode
PublikacjaNiobium-doped strontium titanate was used as the anode for a solid oxide fuel cell. Electrolyte-supported cells were prepared with pure perovskite and composite perovskite–yttria–stabilized-zirconia (YSZ) anodes. Fuel cell tests demonstrated significant improvement in power density after infiltration with a small amount of Ni. The obtained values of power densities are comparable with conventional Ni/YSZ cermet anode. In addition,...
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Microwave-assisted synthesis of zinc derivatives of potato starch
PublikacjaZincatated potato starch was prepared in a solid-state, microwave-assisted reaction using generated in situ sodium tetrahydroxozincate [Na2Zn(OH)4]. For comparison, zincatation of starch was also carriedout on convectional heating. Depending on the irradiation conditions, the products of either mono- or crosslinking esterification were formed. Higher power applied at shorter exposition offered products ofmonoesterification, and...
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Toward elucidation of delithiation mechanism of zinc-substituted LiFePO4
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The application of membrane extraction in the separation of zinc and cadmium ions
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Endometrial nitric oxide production and nitric oxide synthases in the equine endometrium: Relationship with microvascular density during the estrus cycle
PublikacjaNitric oxide (NO) plays an important role in angiogenesis and in the regulation of the blood flow. This study was carried out to investigate (i) the effects of endogenous estrogens and progestins and exogenous progesterone (P(4)) (5 ng/ml or 1 microg/ml) or estradiol 17beta (E(2)beta) (50 pg/ml or 1 microg/ml) on in vitro endometrial NO synthesis; (ii) the presence of different isoforms of NO synthase;...
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Preliminary design of the last stage of supercritical steam turbine and proposition of anti-erosion coating for blades surface
PublikacjaIn this article a preliminary design of the last stage of supercritical steam turbine has been presented. A computational model of supercritical thermal cycle has been created in order to determine steam parameters at the stage inlet and outlet. The model was based on the structure of German coal-fired power plant Datteln 4. Further steam-flow parame-ters and dimensions of stator and rotor blades have been calculated analytically....
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Composites of tin oxide and different carbonaceous materials as negative electrodes in lithium-ion batteries
PublikacjaAbstract Tin and tin oxide have been considered as suitable materials with high theoretical capacity for lithium ion batteries. Their low cost, high safety and other technical benefits placed them as promising replacements for graphite negative electrodes. The problem to overcome with tin oxide, as well as with other metallic materials, is high volume changes during alloying/dealloying, subsequent pulverization, delamination from...
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Bioactive and biodegradable cotton fabrics produced via synergic effect of plant extracts and essential oils in chitosan coating system
PublikacjaFunctional antibacterial textile materials are in great demand in the medical sector. In this paper, we propose a facile, eco-friendly approach to the design of antibacterial biodegradable cotton fabrics. Cotton fiber fabrics were enhanced with a chitosan coating loaded with plant extracts and essential oils. We employed Fourier-transform infrared (FTIR) and X-ray photoelectron spectroscopy (XPS), UV–Vis spectrophotometry, optical...
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Using differential pressure sensor to measure nitrous oxide level in a tank
PublikacjaA method for measuring the level of liquid nitrous oxide oxidizer in a hybrid rocket motor oxidizer tank is proposed. Presented approach is more accurate than the most commonly used method of this measurement, which employs weighting of the whole sounding rocket or an oxidizer tank. In our solution we use a differential pressure sensor to measure the change of pressure at the bottom of an oxidizer tank in comparison to the pressure...
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Electrochemical measurements of borophene functionalized with nickel(II) oxide (NiO)
Dane BadawczeThis dataset contains linear sweep voltammetry (LSV) and chronopotentiometry (CP) technique results for borophene functionalized with nickel(II) oxide (NiO) and reference samples: ruthenium(IV) oxide (RuO2), nickel(II) oxide (NiO) and pristine borophene. Linear sweep voltammetry (LSV) results show the oxygen evolution reaction permormance of the obtained...
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Nanotubular Oxide Layer Formed on Helix Surfaces of Dental Screw Implants
PublikacjaSurface modification is used to extend the life of implants. To increase the corrosion resistance and improve the biocompatibility of metal implant materials, oxidation of the Ti-13Nb- 13Zr titanium alloy was used. The samples used for the research had the shape of a helix with a metric thread, with their geometry imitating a dental implant. The oxide layer was produced by a standard electrochemical method in an environment of...
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Novel method for metal-oxide glass composite fabrication for use in thermoelectric devices
PublikacjaA novel method for thermoelectric materials fabrication using a reduction of oxide precursors in hydrogen was reported. On the example of Bi-Sb, Bi-Sb-Te and Te-Ag-Ge-Sb compounds it was shown that this simple and easy method is suitable for fabrication of two-, three- and even multicomponent thermoelectric materials. It allows controlling a composition, microstructure and even type a of electrical charge carriers. As a result...
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Reduced graphene oxide–bismuth oxide composite as electrode material for supercapacitors
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Improved surface coverage of an optical fibre with nanocrystalline diamond by the application of dip-coating seeding
PublikacjaGrowth processes of diamond thin films on the fused silica optical fibres (10 cm in length) were investigated at various temperatures. Fused silica pre-treatment by dip-coating in a dispersion consisting of detonation nanodiamond (DND) in dimethyl sulfoxide (DMSO) with polyvinyl alcohol (PVA) was applied. Nanocrystalline diamond (NCD) films were deposited on the fibres using the microwave plasma assisted chemical vapour deposition...
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Study of the effect of thermally reduced graphene oxide on the physical and mechanical properties of flexible polyurethane foams
PublikacjaFlexible polyurethane foams were obtained from a two-component system via the one-step method. The foams were modified with thermally reduced graphene oxide added in the amount equal to 0.25, 0.5 and 0.75 wt%. The morphology, static and dynamic properties, and thermal stability of modified foams were determined. The application of carbon filler resulted in the visible increase in the cell size, apparent density and rigidity of...
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Separation of C6 hydrocarbons on sodium dithionite reduced graphene oxide aerogels
PublikacjaThe ability of reduced graphene oxide aerogels (rGOAs) for challenging gas-phase separation was investigated with hexane isomers and benzene (C6 hydrocarbons) using inverse gas chromatography (IGC). For the first, rGOAs were synthesized with sodium dithionite (DTN) as a reductant. Experiments revealed that the most optimal DTN to graphene oxide mass ratio was 2:1, resulting in the highest specific surface area of 432.3 m2 g−1 and...
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Linear and nonlinear impedance in iron oxide glasses containing alkaline ions and alkali free
PublikacjaThe linear and nonlinear impedance spectra of oxide glasses were measured in the frequency range of 1 mHz to 1 MHz and in the temperature range of 153K to 483K. Two groups of iron oxide glass samples were prepared, the first one containing alkaline ions and the second one without alkali. In the first group, compositions of glasses were as follows: (in %mol) 50% SiO2 , 25% PbO, 15% Fe2O3 and 15% one of alkaline oxides: Na2O, K2O,...
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Capacitance Enhancement by Incorporation of Functionalised Carbon Nanotubes into Poly(3,4-Ethylenedioxythiophene)/Graphene Oxide Composites
PublikacjaThis paper reports on the role of oxidised carbon nanotubes (oxMWCNTs) present in poly-3,4-ethylenedioxytiophene (PEDOT)/graphene oxide (GOx) composite. The final ternary composites (pEDOT/GOx/oxMWCNTs) are synthesised by an electrodeposition process from the suspension-containing monomer, oxidised carbon nanotubes and graphene oxide. Dissociated functional groups on the surface of graphene oxide play a role of counter-ions for the...
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Synthesis and modification of reduced graphene oxide aerogels for biofuel cell applications
PublikacjaWe have carried out the preparation of reduced graphene oxide aerogels using eco-friendly method that is based on the Hummers method of graphite oxidation without the use of NaNO3 that produces toxic gases. To obtain a porous 3D structure of reduced graphene oxide, we performed the hydrothermal reduction at elevated temperature. We also prepared the rGO aerogel/CNT composite using multiwalled carbon nanotubes as linkers. The rGO...
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Accelerated ageing of organic coating systems by thermal treatment
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Bio-based semi-aromatic polyesters for coating applications
PublikacjaLinear and branched bio-based semi-aromatic (co)polyesters were evaluated as resins for solvent-basedand powder coatings. Dimethyl-2,5-furandicarboxylate (DMF), 2,3-butanediol and various multifunc-tional comonomers were used to synthesize amorphous hydroxyl-end-capped (co)polyesters. The resinswere cross-linked using the -caprolactam blocked trimer of isophorone diisocyanate. Both the solvent-based and powder coatings proved to...
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THE PROPERTIES OF NANOSILVER – DOPED NANOHYDROXYAPATITE COATING ON THE Ti13Zr13Nb ALLOY
PublikacjaThe aim of this research was to study the properties of nanohydroxyapatite (nanoHAp) and nanohydroxyapatite, doped with nanosilver (nanoHAp/nanoAg), coatings obtained by an electrophoretic deposition process. The suspensions was prepared by dispersing 0.1 g of HAp nanopowder for nanoHAp coatings and 0.1 g of nanoHAp and 0.025 g nanoAg for nanoHAp/nanoAg coatings. The deposition was carried out for 1 min at 50 V voltage followed...
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Special Issue “Corrosion Resistance of Alloy and Coating Materials”
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A study of a reduction of a micro- and nanometric bismuth oxide in hydrogen atmosphere
PublikacjaA reduction of bismuth oxide in hydrogen atmosphere was investigated. The reaction was performed with a material in various structural forms: powder: with micrometric grains, powder with nanometric grains and powder pressed into pellets. The process was performed in both isothermal and non-isothermal conditions. An activation energy of the reaction calculated with Friedman method was found to be about 85 kJ/mol for the reduction...
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Fabrication, Microstructure and High Temperature Corrosion Resistance of Porous Alloys for Solid Oxide Fuel Cells
PublikacjaPorous alloys find use in modern Solid Oxide Fuel Cells as the supporting structures. As they are exposed to high temperatures (> 500°C) an oxide scale forms on their surface due to high temperature corrosion phenomena. Since the ratio between the surface area and volume is much higher than for planar samples, formation of the oxide can lead to a breakaway oxidation after relatively short times. Therefore corrosion properties of...
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Structure and thermoelectric properties of Cs-Bi-Te alloys fabricated by different routes of reduction of oxide reagents
PublikacjaCesium-bismuth-telluride polycrystalline materials were fabricated using a cost-effective method based on a reduction of oxide reagents, leading to a production of a material with good thermoelectric properties. Several samples with various initial stoichiometry were prepared by melting of oxide powders at 1050 °C, quenching, milling to powders and then reducing in pure hydrogen at 400 °C. Another concept was to obtain the CsBi4Te6...
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Electroactive polymer/graphene oxide nanostructured composites; evidence for direct chemical interactions between PEDOT and GOx
PublikacjaThis work concerns electrochemical synthesis of nanocomposites consisting of conducting polymer and reduced graphene oxide (rGOx) as electrode materials for supercapacitors. The electrosynthesis was performed in an aqueous solution of the 3,4-ethylenedioxytiophene (EDOT) monomer and graphene oxide (GOx) without supporting electrolyte. The amount of GOx was optimized to obtain the best electrochemical performance of the nanocomposite...