Wyniki wyszukiwania dla: BLACK PHOSPHORUS ELECTRODES
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Solid-Contact Ion-Selective Electrodes with Highly Selective Thioamide Derivatives of p-tert-Butylcalix[4]arene for the Determination of Lead(II) in Environmental Samples
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Impedance Evaluation of the Effect of Ru[sub 0.3]Ti[sub 0.7]O[sub 2] on Electrochemical Properties of Polymeric Conducting Electrodes Used in Cathodic Protection
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Designing high-performance quasi-symmetrical solid oxide cells with a facile chemical modification strategy for Sr2Fe2−xWxO6−δ ferrites electrodes with in situ exsolution of nanoparticles
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Lower Rim Substituted tert-Butyl Calix[4]arenes (Part IV). Calix[4]arene-Crown Ethers as Ionophores in Plasticized PVC-membrane electrodes.
PublikacjaPrzedstawiono syntezę i charakterystykę trzech p-tert-butylokaliks[4]aren-koron-4, -5, -6 (związki 2 - 4 o różnej długości łańcucha polyoksaetylenowego łączącego distalne grupy OH). Syntezowane związki wykazują wysoką selektywność na kationy sodu, potasu lub cezu. Badano zależność pomiędzy stereochemiczną strukturą tych ligandów, a wyznaczonymi potencjometrycznie współczynnikami selektywności oraz wyznaczonymi stałymi trwałości...
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Lower rim substituted tert-butylcalix[4]arenes. Part 10. New Pb(II)-selective electrodes based on tetrasubstituted calix[4]arenes amides
PublikacjaOpracowano elektrody selektywne na jony Pb(II) oparte na lipofilowych tetrapodstawionych amidowych pochodnych kaliks[4] arenu. Charakterystyki elektrod mają nachylenie nernstowskie w szerokim zakresie stężeń 10 (-1.3) do 10 (-7.2).
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Manganese–Cobalt Based Spinel Coatings Processed by Electrophoretic Deposition Method: The Influence of Sintering on Degradation Issues of Solid Oxide Cell Oxygen Electrodes at 750 °C
PublikacjaThis paper seeks to examine how the Mn–Co spinel interconnect coating microstructure can influence Cr contamination in an oxygen electrode of intermediate temperature solid oxide cells, at an operating temperature of 750 °C. A Mn–Co spinel coating is processed on Crofer 22 APU substrates by electrophoretic deposition, and subsequently sintered, following both the one-step and two-step sintering, in order to obtain significantly...
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Lower rim substituted tert-Butylcalix[4]arenes. Part 13. Interaction of calix-hydroxamates with Fe(III) and Pb(II); studies in ion-selective membrane electrodes (ISE)
PublikacjaPrzedmiotem pracy są badania oddziaływań pomiędzy trzema wybranymi hydroksamowymi pochodnymi t-butylo-kaliks[4]arenu i jonami metali z wykorzystaniem membranowych elektrod jonoselektywnych (ISE). Elektrody zawierające jako materiał aktywny wymienione związki jonoforowe charakteryzują się nernstowskim nachyleniem i szerokim zakresem liniowości na jony Pb(II), a także dobrą selektywnością na jony Pb(II)w stosunku do jonów UO2(II),...
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Jarosław Chojnacki prof. dr hab. inż.
OsobyUrodzony w 1961 w Bydgoszczy, absolwent Technikum Chemicznego im. I. Łukasiewicza w Bydgoszczy. Studia chemiczne ukończył na Wydziale Chemicznym Politechniki Gdańskiej w 1986 roku, broniąc pracy dotyczącej elektrod jonoselektywnych. Późniejsze badania związane były z syntezą organiczną i krzemoorganiczną a od 2002 roku z krystalografią. Praca doktorska dotyczyła silanotiolanów miedziowców, a dysertacja habilitacyjna (2010) opisywała...
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Lower rim substituted tert-butyl calix[4]arene (part VII): ionophoric properties of calix[4]arene-crown-6 derivatives in plasticized PVC-membrane electrodes and in solution.
PublikacjaW pracy przedstawiono syntezę i charakterystykę otrzymanych produktów (2-9), pochodnych p-tert-butylokaliks[4]-korony-6. Zdolności kompleksujące tych związków badano w elektrodach jonoselektywnych, stosując te związki jako jonofory w plastyfikowanej membranie PCW.Wyznaczono wartości stałych trwałości kompleksów z jonami metali I grupy. Stwierdzono, że selektywność kompleksowania zależy od rozmiaru i natury podstawnika wprowadzonego...
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Lower Rim Substitutedp-tert-Butyl-Calix[4]arene. Part 15. Pb(II)-Ion-Selective Electrodes Based onp-tert-Butyl-calix[4]arene Thioamides
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Lower Rim Substituted p-tert-Butyl-Calix[4]arene. Part 15. Pb(II)-Ion-Selective Electrodes Based on p-tert-Butyl-calix[4]arene Thioamides.
PublikacjaTetra podstawione tioamidowe pochodne para-tert-butylokaliks[4]arenu (1-5) zostały zastosowane jako jonofory w membranowych elektrodach jonoselektywnych (EJS) selektywne na kationy Pb(II). Wyznaczono współczynniki selektywności. Czwartorzędowe kaliks[4]aren-tioamidy (1,2) wykazują nadzwyczaj dobrą selektywność na kationy Pb(II) w porównaniu z kaliks[4]aren-amidami. Membrany z tymi ligandami wykazują dużą trwałość, a charakterystyki...
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Wpływ surfaktantu anionowego LAS na mobilność frakcji fosforu w osadzie czynnym w zmiennych warunkach fizyczno-chemicznych
PublikacjaPrzedstawiono wyniki badań wpływu anionowego surfaktantu LAS na mobilność frakcji fosforu w osadzie czynnym. Podstawową rolę w procesie uwalniania fosforu do cieczy nadosadowej w warunkach beztlenowych pełniły: frakcja związana z substancją organiczną i frakcja związana z żelazem.
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La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3-δ oxygen electrodes for solid oxide cells prepared by polymer precursor and nitrates solution infiltration into gadolinium doped ceria backbone
PublikacjaInfiltration is a method, which can be applied for the electrode preparation. In this paper oxygen electrode is prepared solely by the infiltration of La0.6Sr0.4Co0.2Fe0.8O3‐δ (LSCF) into Ce0.8Gd0.2O2-δ (CGO) backbone. The use a polymer precursor as an infiltrating medium, instead of an aqueous nitrate salts solution is presented. It is shown that the polymer forms the single-phase perovskite at 600 °C, contrary to the nitrates...
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Materials for energy storage and conversion devices 2022/2023
Kursy OnlineElectrodes: Metals as electrodes in aqueous and non-aqueous systems, metal nanoparticles. Collectors current. 3D, 2D, 1 D carbons, carbon nanomaterials. Organic semiconductors "Synthetic metals" - p-type, n-type. Inorganic semiconductors: oxides, selenides, sulfides, others. Intercalated electrodes. Mixed conductors (MIEC). Photo-active semiconductor materials. Electrolytes. Water electrolytes in commercial products. Electroactive...
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Możliwości odzysku fosforu z odcieków, osadów ściekowych i popiołów po termicznym przekształcaniu osadów ściekowych
PublikacjaW ostatnich latach zaobserwowano rosnącą świadomość o ograniczonych zasobach fosforu. Szacuje się, że mogą one ulec wyczerpaniu w ciągu 100 lat, przy obecnym zaawansowaniu technologii. Ponad 80% wydobywanego złoża wykorzystywane jest do produkcji nawozów sztucznych oraz w przemyśle chemicznym. Taka perspektywa zwiększa zainteresowanie recyklingiem fosforu, który może być odzyskiwany ze ścieków w fazie płynnej, z odwodnionych osadów...
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The set of 22 sessions of 14-channel eeg signals recorded during watching pictures
Dane BadawczeThe data were collected in order to perform research on the possibility of controlling the content displayed on the monitor screen using human emotional states extracted from EEG signals. The dataset contains recordings of 14-channel EEG signals collected from 10 persons within 22 sessions, during which 45 different random photos taken from the ImageNet...
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Influence of the particle size of carbonate-siliceous rock on the efficiency of phosphorous removal from domestic wastewater
PublikacjatThe aim of the study was to determine the influence of the particle size of carbonate–silica rock (opoka)used in rock filters on the efficiency of phosphorus removal from domestic wastewater. The investigationswere carried out in a laboratory using a model consisting of three vertical flow filters with carbonate–silicarock of different particle sizes (G1= 1–2 mm; G2= 2–5 mm; G3= 5–10 mm). The tested rock was subjectedto decarbonising...
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The efficiency and technological reliability of biogenic compounds removal during long-term operation of a one-stage subsurface horizontal flow constructed wetland
PublikacjaThe paper presents the results of a study of the efficiency and technological reliability of total nitrogen and total phosphorus removal during long term operation of a one-stage constructed wetland system with subsurface horizontal wastewater flow. The flow rate of the wastewater treatment plant was 1.2m3/d during the research period. Physical and chemical analyses of raw wastewater and treated effluent were carried out in the...
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Lower Rim Substituted p-tert-Butyl Calix[4]arenes(V). Synthesis of New 5,11,17,22-tetrakis-p-tert-Butyl-25-27-bis(dialkoxyphosphorylmethoxy)calix[4] arenes and Cation Complexation Studies in Ion Selective Membrane Electrodes.
PublikacjaZaprezentowano syntezę i właściwości trzech nowych związków (2-4), bis podstawionych na dolnym obrzeżu grupami z resztą fosforylową. Związki te były badane jako jonofory w membranowych elektrodach jonoselektywnych (ISE) wykazując selektywność na kationy Rb+,K+ oraz duży i płaski kation guanidyniowyG+). Badano korelację pomiędzy stereo-strukturą związków a ich selektywnością w ISE. Stałe trwałości kompleksów z kationami metali...
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Binder-induced surface structure evolution effects on Li-ion battery performance
PublikacjaA comparative investigation on binder induced chemical and morphological evolution of Li4Ti5O12 electrodes was performed via X-ray photoemission spectroscopy, scanning electron microscopy, and electrochemical measurements. Composite electrodes were obtained using three different binders (PAA, PVdF, and CMC) with 80:10:10 ratio of active material:carbon:binder. The electrochemical performances of the electrodes, were found to be...
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A comprehensive lipidomic analysis of oilseeds using LC-Q-TOF-MS and dispersive micro-solid phase (D-μ-SPE) extraction techniques
PublikacjaGrowing public health awareness increased the demand for natural products with positive health benefits. Vegetable oils containing omega-3 fatty acids (FA) such as alpha-linolenic acid (ALA) has been proposed as a possible source of eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA). In this work, a comprehensive lipidome analysis and comparison of seven oilseeds, including flaxseed, chia, hemp, black cumin, white sesame,...
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The influence of the distance of the pyrometer from the surface of the radiating object on the accuracy of measurements
Dane BadawczeDuring the COVID-19 epidemic, non-contact body temperature measurement has become very important. This dataset contain results of measurements of the four professional commercially available pyrometers. The CHY 314P, TM-F03B, TFA 31.1125 and Abatronic AB-8855 where tested in function of measuring distance from the surface of the radiating black body....
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COMPUTER-AIDED DESIGN OF ORGANOPHOSPHORUS INHIBITORS OF UREASE
PublikacjaBased on the structure of the most potential inhibitor diamidophosphate, various novel groups of inhibitors were developed by knowledge-based design approach with covalent carbon-phosphorus or carbon-phosphorus-carbon bond to improve hydrolytic stability to inhibit the microbial ureases. Designed compounds were evaluated with 10 (LigScore1, LigScore2, PLP1, PLP2, JAIN, PMF, PMF04, LUDI_1, LUDI_2 and LUDI_3) different scoring functions...
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Anna Danuta Dettlaff dr inż.
OsobyTytuł magistra inżyniera uzyskała z wyróżnieniem w 2013 roku w Wydziale Chemii Analitycznej. W latach 2013-2017 była doktorantką na kierunku Technologia Chemiczna, podczas których zajmowała się pracą pt. "Badania nad nanokompozytami bazującymi na polimerach przewodzących oraz materiałach węglowych w celu zastosowania ich w superkondensatorach". W 2015 roku odbyła trzymiesięczny staż naukowy w Oldenburgu w Niemczech. Stopień doktora...
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Supercapacitors - charge redistribution and restoring voltage
PublikacjaThe charge in supercapacitor is stored on electrodes and in electrolyte. The charges on electrodes create the Helmholtz double layer which is formed immediately with time constant of the order of seconds, while the charge storage in electrolyte is going on with time constant of the order of hundreds seconds. When the charged supercapacitor is shorted for few seconds, the charge from electrodes is discharged while the charge in...
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Wpływ kształtu elektrody woltamperometrycznej na jej właściwości metrologiczne w dziedzinie czasu
PublikacjaW artykule omówiono właściwości metrologiczne elektrod woltamperometrycznych. Wykazano, że w przypadku oznaczania małych wartości stężeń jonów metali, elektrody te zachowują się tak jak przetworniki pomiarowe I rzędu. Ich właściwości metrologiczne opisuje czułość i stała czasowa. Wartości tych wielkości są uzależnione od mechanizmu transportu jonów do/od powierzchni elektrod oraz od ich kształtu. Wykonano symulacje wpływu kształtu...
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A Computationally Efficient Model for Predicting Successful Memory Encoding Using Machine-Learning-based EEG Channel Selection
PublikacjaComputational cost is an important consideration for memory encoding prediction models that use data from dozens of implanted electrodes. We propose a method to reduce computational expense by selecting a subset of all the electrodes to build the prediction model. The electrodes were selected based on their likelihood of measuring brain activity useful for predicting memory encoding better than chance (in terms of AUC). A logistic...
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Analiza osadów dennych pod kątem ich właściwości nawozowych
PublikacjaThe analysis of bottom sediments in terms of their fertilizing properties. In paper the characterize of sediments as product to nature usage was done. Analyzed material was taken from ecological treatment system located in wastewater treatment plant in Swarzewo (Pomerania Region) about flow Q= 6000 m3/d. Measurements of dry matter and organic matter content, as well as nitrogen concentrations and phosphorus fractions: loosely...
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Układy regulacji turbin parowych w procesie odbudowy systemu elektroenergetycznego
PublikacjaW artykule przedstawiono analizę udziału układu regulacji turbiny parowej w procesie odbudowy systemu elektroenergetycznego po black-oucie.
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Art Workshop I
Kursy OnlineThe subject of drawing exercises in the semester is a study of a still life and a study of figures made in black and white on the basis of observation of the arrangement of forms in space. In these exercises, particular emphasis is placed on the issues of composition and light.
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Oznaczanie tlenu – od metody Winklera do czujników enzymatycznych (Determination of oxygen – from Winkler Method to enzymatic sensor)
PublikacjaMonitoring of dioxygen levels is of utmost importance from the view-point of life processes, medical diagnostics, nutrition and chemical industries. In all these measurements both low and high levels of this element are important. The common methods for the determination of dioxygen are the Winkler method, Clark electrode and pulsoxymeters. A new, already strong field of research can be now recognized – the development of miniaturized...
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PRĄDY WYRÓWNAWCZE W UZIOMACH FUNDAMENTOWYCH I SZTUCZNYCH
PublikacjaW artykule omówiono zasady wykonywania uziomów fundamentowych i sztucznych. Przedstawiono wyniki pomiarów prądów w instalacji zawierającej stal zbrojeniową w fundamencie, połączoną z układem uziomu sztucznego w ziemi wykonanym z stali ocynkowanej.
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N-phosphonomethylglycine utilization by the psychrotolerant yeast Solicoccozyma terricola M 3.1.4.
PublikacjaSolicoccozymaterricolaM 3.1.4., the yeast strain isolated from soil sample from blueberry cultivation in MiedzyrzecPodlaski in Poland, is capable to split of phosphorus to nitrogen and nitrogen to carbon bonds inN-phosphono-methylglycine (PMG, glyphosate). The biodegradation process proceeds in the phosphate-independent manner. Itis the first example of a psychrotolerant yeast strain able to degrade PMGviaCeN bond cleavage accompanied...
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Voltage Dependence of Supercapacitor Capacitance
PublikacjaElectronic Double-Layer Capacitors (EDLC), called Supercapacitors (SC), are electronic devices that are capable to store a relatively high amount of energy in a small volume comparing to other types of capacitors. They are composed of an activated carbon layer and electrolyte solution. The charge is stored on electrodes, forming the Helmholtz layer, and in electrolyte. The capacitance of supercapacitor is voltage- dependent. We...
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Melamine-modified boron-doped diamond towards enhanced detection of adenine, guanine and caffeine
PublikacjaThis work describes the electrochemical method of boron-doped diamond (BDD) modification by poly-melamine to obtain organic film. The detection of adenine, guanine and caffeine were carried out by differential pulse wave voltammetry. The poly-melamine modified B-NCD electrodes exhibit excellent activity towards the electrochemical oxidation of all examined analytes. The poly-melamine modified BDD electrodes in all measurements...
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COLOUR SYMBOLISM IN FINANCE
PublikacjaColour symbolism plays an important role in everyday life and science. The subject is interdisciplinary and receives significant attention in the literature. It is increasingly entering the field of economics and finance. The authors are the first to research the connotations and symbolism of colours in finance. The following research aims to: identify and determine the meaning of col-ours in connection with the word “finance”,...
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Scanning electron microscopy (SEM) images of boron-doped diamond thin films at poly(lactic acid)
Dane BadawczeThe dataset contains the photos obtained by scanning electron microscope(SEM), revealing the surface morphology and cross-section of boron-doped diamond electrodes on commercially available graphene-doped polylactide acid. The boron doping level expressed as the [B]/[C] ratio in the gas phase for these studies was 500 and 10,000 ppm. The top views of...
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Selected Methods for the Chemical Phosphorylation and Thiophosphorylation of Phenols
PublikacjaThis Focus Review gathers together a selection of methods for the chemical phosphorylation of phenols that employ three‐ and four‐coordinate phosphorus compounds. Phosphorylated scaffolds can exhibit enhanced properties compared to their non‐phosphorylated analogues, such as increased biological activity and increased/decreased solubility; as such, phosphorus compounds have gained more and more interest in organic and medicinal...
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New bis(azobenzocrown)s with dodecylmethylmalonyl linkers as ionophores for sodium selective potentiometric sensors
PublikacjaNovel biscrowns 1 and 2 were synthesized from 13-membered azobenzocrown ethers containing bromoalkylenoxy chains in para position relative to the azo group. The synthesized diester molecules are dodecylmethylmalonic acid derivatives differing by the linker length. The synthesized compounds have the potential of being used as sodium ionophores in ion-selective electrodes. They were characterized and used as ionophores in classic...
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Potentiometric taste sensor application for liquid product taste estimation
PublikacjaThe principles of taste sense and kinds of tastes (sweet, salty, sour, bitter, umami and fat) have been described. Food quality estimation by taste sense: organoleptic testing and sensory analysis has been presented. The principle of operation of potentiometric sensor composed of several Ion Selective Electrodes or All Solid State Electrodes with polymeric membranes and macromolecular chemical compounds sensitive to substances...
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Morze możliwości
PublikacjaZ Karolem Moszykiem, Kierownikiem ds. Rozwoju Operacyjnego/ Lean Six Sigma Black Belt, DCT Gdańsk SA i prelegentem pierwszego Gdańskiego Manager Clubu - o ciągłbym doskonaleniu w głębokowodnym terminalu kontenerowym - rozmawiał Łukasz Rogatka
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MINERAL CONTENT OF TREE SAP FROM THE SUBCARPATHIAN REGION
Publikacjabut also as medicinal substance in folk medicine. Traditionally, it was used to treat various conditions, mostly anaemia and chronic fatigue. This study has been designed to establish the content of metallic elements (sodium, potassium, calcium, magnesium, zinc and copper) in sap collected from eight different species (silver birch, downy birch, hornbeam, Norway maple, boxelder maple, black walnut, black alder and white willow)...
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TASTE QUALITIES ESTIMATION BY TASTE SENSE AND ELECTROCHEMICAL SENSORS
PublikacjaThe principles of taste sense and kinds of tastes (sweet, salty, sour, bitter, umami and fat) have been described. Food quality estimation by taste sense: organoleptic testing and sensory analysis has been presented. The principle of operation of potentiom etric sensor composed of several Ion Selective Electrodes or All Solid State Electrodes with polymeric membranes and macromolecular chemical compounds sensitive to substances...
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Neural modelling of dynamic systems with time delays based on an adjusted NEAT algorithm
PublikacjaA problem related to the development of an algorithm designed to find an architecture of artificial neural network used for black-box modelling of dynamic systems with time delays has been addressed in this paper. The proposed algorithm is based on a well-known NeuroEvolution of Augmenting Topologies (NEAT) algorithm. The NEAT algorithm has been adjusted by allowing additional connections within an artificial neural network and...
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Calix[4]arenes appended with thioamide moieties as powerful tool for heavy metals recognition
PublikacjaSelectivity of new thioamide derivatives was assessed using those ligands as sensor materials in ion-selective membrane electrodes and tested towards Pb2+ - selectivity. The influence of the nature of the thioamide function (linear, branched or cyclic substituents) on their ionophoric properties was investigated. Electrodes based on cyclic thioamide moieties are promising analytical tools for monitoring Pb2+ concentration in natural...
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Pollutants removal effectiveness in hydrophyte filters with sequential vertical and horizontal flow
PublikacjaThe object of investigations was the constructed wetland in Wiedersberg in Saxonia in Germany supplied with domestic sewage from 145 inhabitants. The biological part was composed of sequential reed beds with vertical and horizontal flow of sewage. It in one of new solutions, because up till now configuration with vertical bed situated at front of biological part of treatment was applied.The evaluation of object performance was...
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New procedure for the examination of the degradation of volatile organonitrogen compounds during the treatment of industrial effluents
PublikacjaWe present a new procedure for the determination of 32 volatile organonitrogen compounds in samples of industrial effluents with a complex matrix. The procedure, based on dispersive liquid–liquid microex-traction followed by gas chromatography with nitrogen-phosphorus and mass spectrometric detection, wasoptimized and validated. Optimization of the extraction included the type of extraction and disperser sol-vent, disperser solvent...
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Topic 1: Transformations / Spatial form design, scale 1:1
Kursy OnlineBrief description: The subject matter of the spatial form design classes is transformation. First, a black square becomes a flat graphic composition, which is then converted to color. The final stage of the transformation process is a spatial object, which is by assumption devoid of any utilitarian functions. Course content / classes schedule: 1. Graphic. The task is to create an achromatic flat composition in the contrast...
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O-substituted tetrahydroxamate derivatives of p-tert-butylcalix[4]arene as receptors for transition and heavy metal cations
PublikacjaTetrasubstituted O-hydroxamate derivatives of p-tert-butylcalix[4]arene were applied as active materials in ion-selective membrane electrodes and were tested towards Pb-selectivity. The electrodes gave near-Nernstian characteristics for Pb2+ cations. The selectivity coefficients were determined. The influence of plasticizer on the electrode behaviour was studied. The dependence of the chemical structure on selectivity coefficients...
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The electrical conductivity of pristine, La-, and Nb-doped SFM measured in air and hydrogen atmospheres
Dane BadawczeThis dataset consists of an Excel sheet with the result of DC4W method of electrical measurements. The measurements were conducted on pristine strontium ferrite molubdate as well as ones doped with La and Nb. Additionally two samples co-doped with La and Ni/Co were analyzed. Pellets were prepared by high temperature sintering at 1400 deg. C, then cut...