Wyniki wyszukiwania dla: electrochemical synthesis
-
Dynamic electrochemical impedance spectroscopy of the adsorption and relaxation of polianiline chains during potentiodynamic redox transformations
PublikacjaZaprezentowano nowe podejście do analizy widm impedancyjnych uzyskanych dla warstwy przewodzącej polianiliny (PAni). Właściwości powyższej warstwy są często modelowane przy użyciu elementu stałofazowego (CPE), który w sposób dokładniejszy odzwierciedla wyniki eksperymentalne niż klasyczny element pojemnościowy (kondensator). W pracy zaproponowano nowy elektryczny obwód zastępczy oparty na modelu adsorpcyjnym Frumkin-Melik-Gaikazyan,...
-
Derivatization of SWCNTs with cobalt phthalocyanine residues and applications in screen printed electrodes for electrochemical detection of thiocholine
PublikacjaJednościenne nanorurki węglowe (SWCNTs) sfunkcjonalizowane resztami ftalocyjaniny kobaltu zostały nałożone na sitodrukowane elektrody grafitowe (SPEs) i zastosowane do elektrochemicznego utleniania tiocholiny (TCh) w zakresie niskich potencjałów. Kowalencyjne przyłączenie ftalocyjaniny kobaltu do SWCNTs trwałym wiązanie sulfonamidowym zostało dowiedzione spektroskopią Ramana i UV-Vis i analizą termograwimetryczną połączoną z detekcją...
-
Metrological characteristics of the flat voltammetric electrode in time domain with a reversible electrochemical reaction running on the surface
PublikacjaW artykule przedstawiono właściwości metrologiczne płaskich elektrod woltamperometrycznych. Omówiono wpływ napięcia polaryzującego na wartości parametrów charakteryzujących te elektrody.
-
Structure and electrochemical reactivity of 3-[tris(2-methoxyethoxy)silyl]-propanethiol adsorbed on silver surface
Publikacja -
Electrochemical performance of MOF-5 derived carbon nanocomposites with 1D, 2D and 3D carbon structures
Publikacja -
Development of the Mobile PoC Graphene-Based Biosensing Device Using Electrochemical Impedance Spectroscopy (EIS)
Publikacja -
Similarity between enzymatic and electrochemical oxidation of 2-hydroxyac ridinone, the reference compound of antitumor imidazoacridinones.
PublikacjaPraca jest częścią szerszych badań zmierzających do poznania molekularnego mechanizmu metabolicznej aktywacji przeciwnowotworowej pochodnej imidazoakrydonu, związku C-1311. Celem prezentowanych badań jest (i) zbadanie reakcji enzymatycznego utleniania związku modelowego, 2-hydroksyakrydonu oraz (ii) zbadanie czy zachodzi podobieństwo między przebiegiem reakcji elektrochemicznego i enzymatycznego utleniania tego związku. Podobieństwo...
-
Dynamic electrochemical impedance spectroscopy measurements of passive layer cracking under static tensile stresses.
PublikacjaDynamiczna Elektrochemiczna Spektroskopia Impedancyjna umożliwia badanie podatności i odporności korozyjnej różnych materiałów konstrukcyjnych, a w szczególności określenie właściwości elektrochemicznych warstw pasywnych występujących na ich powierzchni. W wielu przypadkach pęknięcie warstwy pasywnej pod wpływem działania naprężeń rozciągających prowadzi do korozji naprężeniowej. Z tego względu badania pękania warstw pasywnych...
-
Potential and strain rate impact on the electrochemical properties of 304L stainless steel under tensile stresses.
PublikacjaPraca skupia się na badaniach aspektu elektrochemicznego i mechanicznego pękania warstwy pasywnej obecnej na stali 304L. Przedstawione zostały wyniki chwilowych zmian impedancji oraz zmiany parametrów elektrochemicznych warstwy pasywnej podczas testów rozciągania przy różnych poziomach polaryzacji anodowej oraz szybkości rozciągania. Na ich podstawie można stwierdzić, że zarówno czynnik elektrochemiczny, jak i mechaniczny wpływają...
-
Correlation between destruction of the metal surface caused by pitting corrosion and intensity of the observed electrochemical noise.
PublikacjaPrzedstawiono wyniki badań korelacji między intensywnością szumów elektrochemicznych obserwowanych podczas występowania procesów korozji wżerowej a zmianami obserwowanymi na powierzchni metalu.Badania przeprowadzono dla elektrod metalowych o powierzchni eksponowanej na środowisko korozyjne poniżej 1 mm2. Do wykrywania uszkodzeń powierzchni wykorzystano oprogramowanie MatLab, wykrywające uszkodzenia powierzchni metalu w formie okręgów...
-
Electrochemical behaviour of Cr coating in acidic sulphate solution studied by cyclic polarization and impedance spectroscopy
PublikacjaOdporność korozyjną powłok chromowych w 0.01 M H2SO4 zbadano metodami woltamperometrii cyklicznej i spektroskopii impedancyjnej. Stwierdzono, że właściwości ochronne powłoki chromowej w kontakcie z powietrzem wzrastają dzięki tworzeniu się warstwy tlenkowej zapełniającej defekty w powłoce. W trakcie polaryzacji anodowej następuje częściowe roztwarzanie tej warstwy i penetracja agresywnego środowiska do podłoża (stali), co powoduje...
-
Simultaneous optical and electrochemical label-free biosensing with ITO-coated lossy-mode resonance sensor
PublikacjaIn this work we discuss a new label-free biosensing device based on indium tin oxide (ITO) overlaid section of a multimode optical fiber fused silica core. The sensor has been used to optical measurements also simultaneously interrogated electrochemically (EC). Due to optimized thickness and optical properties of ITO film, a lossy-mode resonance (LMR) could be observed in the optical domain, where electrical properties of the film...
-
Electrochemical oxidation of PFOA and PFOS in landfill leachates at low and highly boron-doped diamond electrodes
PublikacjaPolyfluorinated alkyl substances (PFASs) may reach landfill leachates (LLs) due to improper waste management. In this study perfluorooctanoate (PFOA) and perfluorooctane sulphonate (PFOS) were used as representatives of PFASs in the decomposition on boron-doped diamond electrodes (BDDs) with high (10k ppm) and low (0.5k ppm) boron doping concentrations. The result shows that although better COD removal efficacies are obtained on...
-
Opto-Electrochemical Sensing Device Based on Long-Period Grating Coated with Boron-Doped Diamond Thin Film
PublikacjaThe fabrication process of thin boron-doped nanocrystalline diamond (B-NCD) microelectrodes on fused silica single mode optical fiber cladding has been investigated. The B-NCD films were deposited on the fibers using Microwave Plasma Assisted Chemical Vapor Deposition (MW PA CVD) at glass substrate temperature of 475 ºC. We have obtained homogenous, continuous and polycrystalline surface morphology with high sp3 content in B-NCD...
-
Electrochemical Stability of Few-Layered Phosphorene Flakes on Boron-Doped Diamond: A Wide Potential Range of Studies in Aqueous Solutions
PublikacjaTwo-dimensional phosphorene has attracted great interest since its discovery as a result of its extraordinary properties. Two-dimensional single crystals of phosphorene can be useful for electrochemical (EC) sensing applications due to their enhanced surface-to-volume ratio. We proposed to investigate the electrochemical performance of phosphorene deposited directly on boron-doped diamond (BDD) electrodes. Noncovalent interaction...
-
Laser-Induced Graphitization of Polydopamine on Titania Nanotubes
PublikacjaSince the discovery of laser-induced graphite/graphene, there has been a notable surge of scientific interest in advancing diverse methodologies for their synthesis and applications. This study focuses on the utilization of a pulsed Nd:YAG laser to achieve graphitization of polydopamine (PDA) deposited on the surface of titania nanotubes. The partial graphitization is corroborated through Raman and XPS spectroscopies and supported...
-
Light-improved glucose sensing on ordered Au-Ti heterostructure
PublikacjaNon-enzymatic electrochemical platforms sensitive towards glucose presence have attracted a worldwide attention during last decades. We report on influence of solar light onto response of gold-titanium heterostructures prepared via controllable approach. The material based on Au nanoparticles orderly distributed over the structured titanium foil was obtained by electrochemical anodization followed by chemical etching, magnetron...
-
The Effect of Cobalt Incorporation into Nickel–Iron Oxide/(oxy)hydroxide Catalyst on Electrocatalytic Performance Toward Oxygen Evolution Reaction
PublikacjaThis work presents a study on the influence of the addition of cobalt into state-of-the-art nickel–iron (NiFe) mixed oxides/hydroxides/(oxy)hydroxides on their structural and morphological properties, and oxygen evolution reaction (OER) catalytic activity. A one-step electrodeposition process is performed without any additives to fabricate NiFe and x cobalt-doped nickel/iron (xCoNiFe) layer-double-hydroxide catalysts directly on...
-
Diamond-Phase (Sp3-C) Rich Boron-Doped Carbon Nanowalls (Sp2-C): A Physico-Chemical And Electrochemical Properties
PublikacjaThe growth of B-CNW with different boron doping levels controlled by the [B]/[C] ratio in plasma, and the influence of boron on the obtained material’s structure, surface morphology, electrical properties and electrochemical parameters, such as -ΔE and k°, were investigated. The fabricated boron-doped carbon nanowalls exhibit activity towards ferricyanide redox couple, reaching the peak separation value of only 85 mV. The flatband...
-
Tailoring properties of indium tin oxide thin films for their work in both electrochemical and optical label-free sensing systems
PublikacjaThis work is devoted to the identification properties of indium tin oxide (ITO) thin films responsible for their possible application in combined optical and electrochemical label-free sensing systems offering enhanced functionalities. Since any post-processing would make it difficult to identify direct relation between deposition parameters and properties of the ITO films, especially when deposition on temperature-sensitive substrates...
-
Ultrasensitive electrochemical determination of the cancer biomarker protein sPD-L1 based on a BMS-8-modified gold electrode
PublikacjaThis work describes the modification of a gold electrode with the BMS-8 compound that interacts with the Programmed Death-Ligand 1 (PD-L1), an immune checkpoint protein. The results show that we can confirm the presence of the sPD-L1 in the concentration range of 10−18 to 10−8 M using electrochemical impedance spectroscopy (EIS) with a limit of detection (LOD) of 1.87 × 10−14 M for PD-L1 (S/N = 3.3) and at a concentration of 10−14...
-
A comprehensive evaluation of mimosa extract as a corrosion inhibitor on AA6060 alloy in acid rain solution: part I. Electrochemical AC methods
PublikacjaThe inhibition effect of mimosa extract on the corrosion of AA6060 aluminum alloy in acid rain solution was investigated by electrochemical impedance spectroscopy and dynamic electrochemical impedance spectroscopy (DEIS). All the studied electrochemical parameters showed good corrosion inhibitive characteristics with respect to the aluminum alloy in the tested solution. Inhibitor efficiency increased with the concentration and...
-
Silicon Oxycarbide-Graphite Electrodes for High-Power Energy Storage Devices
PublikacjaHerein we present a study on polymer-derived silicon oxycarbide (SiOC)/graphite composites for a potential application as an electrode in high power energy storage devices, such as Lithium-Ion Capacitor (LIC). The composites were processed using high power ultrasound-assisted sol-gel synthesis followed by pyrolysis. The intensive sonication enhances gelation and drying process, improving the homogenous distribution of the graphitic...
-
Heterogeneous distribution of surface electrochemical activity in polycrystalline highly boron-doped diamond electrodes under deep anodic polarization
PublikacjaThe surface homogeneity of boron-doped diamond electrodes is variable and depends on anodic polarization conditions. The differentiation factor is the gradual and localized change in surface termination. A series of measurements under different polarization conditions was performed in order to investigate the scale of this effect. Nanoscale impedance microscopy (NIM) revealed large variation of surface resistance in individual...
-
Salt melt synthesis of curved nitrogen-doped carbon nanostructures: ORR kinetics boost
PublikacjaImplementing metal-free electrocatalysts for the oxygen reduction reaction (ORR) and revealing crucial chemical or topographical parameters driving their activity are vital for the development of power cells. The carbon-based catalysts are very often synthesized through carbonization of biopolymers, in particular, those one containing nitrogen groups such as chitosan. Unfortunately, the resulting carbonaceous materials usually...
-
Metabolic Profiles of New Unsymmetrical Bisacridine Antitumor Agents in Electrochemical and Enzymatic Noncellular Systems and in Tumor Cells
Publikacja -
The Influence of the Parameters of a Gold Nanoparticle Deposition Method on Titanium Dioxide Nanotubes, Their Electrochemical Response, and Protein Adsorption
Publikacja -
Electrochemical oscillations and bistability during anodic dissolution of vanadium electrode in acidic media—part I. Experiment
Publikacja -
Electrochemical Recognition of Aromatic Species with Ferrocenylated 1,3,5‐Triazine‐ or 1,3,5‐Triphenylbenzene‐Containing Highly Organized Molecules
Publikacja -
Electrochemical oscillations and bistability during anodic dissolution of vanadium elektrode in acidic media. part 1. Experiment
PublikacjaDynamiczne niestabilności, oscylacje prądowe i bistabilność obserwowane były podczas anodowego roztwarzania elektrody wanadowej w trakcie badań wykorzystujących techniki stało i zmienno prądowe. Analizowany był wpływ warunków eksperymentalnych jak: stężenia kwasu, temperatury itd. Badania pozwoliły stworzyć diagramy przedstawiające regiony występowania oscylacji i bistabilności.
-
Electrochemical sensor for measurement of volatile organic compounds = Elektrochemiczny czujnik do oznaczania lotnych związków organicznych
PublikacjaPrzedstawiono rezultaty badań prototypowego czujnika do oznaczania benzaldehydu i formaldehydu w powietrzu. Określono czułość wskazań czujnika i jego granice oznaczalności wykorzystując jako technikę detekcyjną woltamperometrię fali prostokątnej (SWV). Elektrodę roboczą i przeciwelektrodę stanowiły elektrody z Pt. Elektrolitem wewnętrznym były ciecze jonowe: chlorek 1-heksylo,3- metyloimidazolinowy i bis(trifluorometylosulfonylo)imidek...
-
Electrochemical generation of microbubbles by carbon nanotube interdigital electrodes to increase the permeability and material uptakes of cancer cells
Publikacja -
Electrochemical screening of genoprotective and antioxidative effectiveness of Origanum vulgare L. and its functionality in the prevention of neurodegenerative disorders
Publikacja -
Structure and electrochemical behaviour of 4,7-diazaheptyl-trimethoxy-silane and vinyl-trialkoxy-silane adsorbed at silver surface
Publikacja -
Electrochemical and biological characterization of lyotropic liquid crystalline phases – retardation of drug release from hexagonal mesophases
Publikacja -
New possibilities of the passive layer cracking dynamics detection using a new Dynamic Electrochemical Impedance Spectroscopy.
PublikacjaNowa metoda Dynamicznej Elektrochemicznej Spektroskopii Impedancyjnej opracowana w Katedrze Elektrochemii, Korozji i Inżynierii Materiałowej Politechniki Gdańskiej daje możliwości określania charakterystyki impedancyjnej w dziedzinie czasu podczas procesu pękania ochronnej warstwy pasywnej. Fakt ten jest związany z procedurą analizującą wspomnianej techniki, która umożliwia selektywną analizę czasowo-częstotliwościową uzyskanych...
-
Metabolic Profiles of New Unsymmetrical Bisacridine Antitumor Agents in Electrochemical and Enzymatic Noncellular Systems and in Tumor Cells
PublikacjaNew unsymmetrical bisacridines (UAs) demonstrated high activity not only against a set of tumor cell lines but also against human tumor xenografts in nude mice. Representative UA compounds, named C-2028, C-2045 and C-2053, were characterized in respect to their physicochemical properties and the following studies aimed to elucidate the role of metabolic transformations in UAs action. We demonstrated with phase I and phase II enzymes...
-
Optimizing Ni–Cr patterned boron-doped diamond band electrodes: Doping effects on electrochemical efficiency and posaconazole sensing performance
PublikacjaThere is growing interest in developing diamond electrodes with defined geometries such as, for example, micrometer-sized electrode arrays to acquire signals for electroanalysis. For electroanalytical sensing applications, it is essential to achieve precise conductive patterns on the insulating surface. This work provides a novel approach to boron-doped diamond patterning using nichrome masking for selective seeding on an oxidized...
-
Enhanced stability of electrochemical performance of few-layer black phosphorus electrodes by noncovalent adsorption of 1,4-diamine-9,10-anthraquinone
PublikacjaIn this paper, the novel noncovalent functionalisation strategy of few-layer black phosphorus by 1,4-diamine-9,10-anthraquinone electrode was proposed and studied. The degradation of few-layer black phosphorus under exposure to oxygen and water is a significant obstacle to its use as an electroanalytical electrode. The anthraquinone compound adsorbed at black phosphorus flakes results in improved prevention of the phosphorus surface...
-
Synthesis and photoelectrochemical behaviour of hydrogenated titania nanotubes modified with conducting polymer infiltrated by redox active network
PublikacjaIn this work, we show preparation of ordered inorganic-organic composite electrode material where hydrogenated titania nanotubes H-TiO2 with tubularly developed surface modified with poly(3,4-ethylenedioxythiophene) matrix permeated by Prussian Blue (PB) inorganic redox network in order to reach highly photoactive heterojunction. The polymer deposition was realized via two subsequent processes covering: i) potentiostatic polymerization...
-
Electrochemical performance of Co3O4/CeO2 electrodes in H2S/H2O atmospheres in a proton-conducting ceramic symmetrical cell with BaZr0.7Ce0.2Y0.1O3 solid electrolyte
PublikacjaThe electrochemical performance of Co3O4/CeO2 mixed oxide materials as electrodes, when exposed to H2S/H2O atmospheres, was examined employing a proton conducting symmetrical cell, with BaZr0.7Ce0.2Y0.1O3 (BZCY72) as the solid electrolyte. The impact of temperature (700–850 °C) and H2S concentration (0–1 v/v%) in steam-rich atmospheres (90 v/v% H2O) on the overall cell performance was thoroughly assessed by means of electrochemical...
-
Electrochemical determination of nitroaromatic explosives at boron-doped diamond/graphene nanowall electrodes: 2,4,6-trinitrotoluene and 2,4,6-trinitroanisole in liquid effluents
PublikacjaThe study is devoted to the electrochemical detection of trace explosives on boron-doped diamond/graphene nanowall electrodes (B:DGNW). The electrodes were fabricated in a one-step growth process using chemical vapour deposition without any additional modifications. The electrochemical investigations were focused on the determination of the important nitroaromatic explosive compounds, 2,4,6-trinitrotoluene (TNT) and 2,4,6-trinitroanisole...
-
The role of electrolysis and enzymatic hydrolysis treatment in the enhancement of the electrochemical properties of 3D-printed carbon black/poly(lactic acid) structures
PublikacjaAdditive manufacturing, also known as 3D printing, is beginning to play an unprecedented role in developing many applications for industrial or personalized products. The conductive composite structures require additional treatment to achieve an electroactive surface useful for electrochemical devices. In this paper, the surfaces of carbon black/poly(lactic acid) CB-PLA printouts were activated by electrolysis or enzymatic digestion...
-
Proton-Electron Hole Interactions in Sr(Ti,Fe)O3−δ Mixed-Conducting Perovskites
PublikacjaOxides in which total electrical conductivity is determined by the partial conductivities of three types of charge carriers i.e. holes/ electrons, oxygen ions, and protons are key components of well-functioning proton ceramic fuel cells. Apart from electrochemical properties also easily modified microstructure is an important feature of the electrodes. In the paper, a group of SrTi1−xFexO3−δ (STF, x = 0.2–0.8) perovskites prepared...
-
Influence of the boron doping level on the electrochemical oxidation of raw landfill leachates: advanced pre-treatment prior to the biological nitrogen removal
PublikacjaThe electrochemical oxidative treatment of landfill leachates (LLs) containing high amounts of ammonia nitrogen and organic matter was used as a promising method, prior to biological processes, to achieve the final effluent quality that would be acceptable by current regulations. The deposited boron-doped diamond electrodes (BDDs) with different boron doping concentrations (10000, 5000 and 500 ppm of B) were applied as anodes....
-
Effect of cobalt addition on the corrosion behaviorof near equiatomic NiTi shape memory alloy in normal saline solution: electrochemical and XPS studies
PublikacjaThe electrochemical and corrosion (uniform and localized) behavior of a binary Ni52Ti48 shape memory alloy (SMA) and two ternary Ni52Ti48-xCox (x = 1.5 and 4.0 wt.%) SMAs were studied. Measurements were conducted in 0.9% NaCl solution at 37 oC employing various electrochemical methods. These include: linear polarization resistance (LPR), linear sweep voltammetry (LSV), chronoamperometry and dynamic electrochemical impedance spectroscopy...
-
Fabrication of Electrochemical Biosensor Based on Titanium Dioxide Nanotubes and Silver Nanoparticles for Heat Shock Protein 70 Detection
Publikacja -
Correlation between destruction of the metal surface caused by pitting corrosion and intensity of the observed electrochemical noise (Invited Paper)
Publikacja -
Dynamic Electrochemical Impedance Spectroscopy (DEIS) as a Tool for Analyzing Surface Oxidation Processes on Boron-Doped Diamond Electrodes
Publikacja -
Electrochemical characterization of a composite comprising PEDOT/PSS and N doped TiO2 performed in aqueous and non-aqueous electrolytes
PublikacjaNitrogen doped titania (N-TiO2) was used as an inorganic component of composite electrodes containing poly(3,4-ethylenedioxythiophene) with poly(4-styrenesulphonate) PEDOT/PSS/N-TiO2. The composite materials were obtained by direct electrodeposition from an N-TiO2 suspension containing polyelectrolyte (NaPSS) and monomer EDOT. The electrodes were electrochemically tested in aqueous and non-aqueous electrolytes using cyclic voltammetry...