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Wyniki wyszukiwania dla: DEW CHEMISTRY
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The new investing effectiveness evaluation multi-criteria method in modern supply systems
PublikacjaThe important problem in the processes of modelling and programming the development of sustainable energy sector is the multi-criteria manner of assessing the effectiveness of investments. The goal of this paper is to show how to take into account the impact of investments in multidimensional modelling decision-making processes. This goal can be achieved through the development, presentation, and use of a new multi-criteria method...
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Preparation, characterization, and manufacturing of new polymeric materials for 3D printing for medical applications
PublikacjaThis work concerns the synthesis, formation, and characteristics of new filaments for 3D printing in FDM™/FFF technology for medical purposes. Two types of filaments were developed, i.e. degradable polyurethane and biodegradable polylactide-starch. The influence of the 3D printing process on selected filament properties was investigated. A detailed analysis of the filament formation process by the extrusion method was carried out,...
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Ruthenium(II) and Iridium(III) Complexes as Tested Materials for New Anticancer Agents
PublikacjaThe oncological use of cisplatin is hindered by its severe side eects and a very important resistance problem. To overcome these problems, scientists have attempted to design new generation transition-metal anticancer complexes. In this study, we present new complexes, ruthenium(II) [(6-p-cymene)RuCl(py2CO)]PF6 (1), iridium(III) [(5-Cp)IrCl(py2CO)]PF6 (2), and NH4[IrCl4(py2CO)]H2O (3), based on di-2-pyridylketone (py2CO). The prepared...
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New Carvone-Based Deep Eutectic Solvents for Siloxanes Capture from Biogas
PublikacjaDuring biogas combustion, siloxanes form deposits of SiO2 on engine components, thus shortening the lifespan of the installation. Therefore, the development of new methods for the purification of biogas is receiving increasing attention. One of the most effective methods is physical absorption with the use of appropriate solvents. According to the principles of green engineering, solvents should be biodegradable, non-toxic, and...
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3D DEM SIMULATIONS OF BASIC GEOTECHNICAL TESTS WITH EARLY DETECTION OF SHEAR LOCALIZATION.
PublikacjaW artykule przedstawiono rezultaty numeryczne dla podstawowych testów geotechnicznych: testu trójosiowego ściskania oraz w aparacie bezpośredniego ścinania dla piasku bez kohezji. Wszystkie testy zostały wykonane w 3D, a piasek został wymodelowany w postaci kulek wraz z momentami symulującymi nieregularny kształt ziarna. Podczas badań sprawdzono wpływ parametrów fizycznych (m. in. początkowy wskaźnik porowatości, obciążenie pionowe...
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Sugar Fee in Poland as an Example of New Fiscal Burdens and Stimulation of Consumer Behaviour
PublikacjaDuring the economic downturn caused by the COVID-19 pandemic, the amount and structure of tax burdens imposed by the state on businesses continue to increase, as shown on the example of the newly introduced sugar fee. A new tax-related burden imposed on businesses and consumers producing and consuming sugar-sweetened beverages appeared at the beginning of 2021. The aim of the paper is to present the fiscal burdens that accompany...
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Comparison of the Effectiveness of Health Systems in The European Countries-Two-Stage DEA Model
PublikacjaThis article compares the efficiency of health systems in selected European countries using two-stage data envelopment analysis (DEA), based on data from the EUROSTAT database. In the first step, DEA efficiency scores were calculated for health care systems and, subsequently, the external variables describing lifestyle were used to calculate the truncated regression. Health care resources (physicians, nurses, hospital beds, financial...
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Polynomial description of dynamic impedance spectrogram—introduction to a new impedance analysis method
PublikacjaThis paper presents a polynomial description of spectrograms obtained using Dynamic Electrochemical Impedance Spectroscopy. A method to fit the polynomial degree correctly is discussed. A simple electrical system of a diode connected in parallel with a capacitor was used for testing. Dynamic impedance measurements during potentiodynamic polarization were conducted. This paper presents an alternative analysis method that allows...
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Arctic Freshwater Environment Altered by the Accumulation of Commonly Determined and Potentially New POPs
PublikacjaChemical composition of Arctic freshwater ecosystems depends on several factors. They include characteristics of the surrounding landscape, its lithology, geomorphology, vegetation, and hydrological features, as well as accumulation of anthropogenic pollution. In the Arctic, the problem of environmental contamination is widespread. That is why research on lakes and river catch-ments in terms of their chemical composition has enjoyed...
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Testing of the longest span soil-steel bridge in Europe – new quality in measurements
PublikacjaThe article describes interdisciplinary and comprehensive diagnostic tests of final bridge inspection and acceptance proposed for a soil – steel bridge made of corrugated sheets, being the European span length record holder (25.74 m). As an effect of an original concept a detailed and precise information about the structure response was collected. The load test design was based on the nonlinear numerical simulations performed by...
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VALUATION OF EMBEDDED OPTIONS IN NON-MARKETABLE CALLABLE BONDS: A NEW NUMERICAL APPROACH
PublikacjaThe issue of how to price options embedded in callable bonds has attracted a lot of interest over the years. The usual bond valuation methods rely on yield curves, risk premium, and other parameters to estimate interest rates used in discounted cash flow calculations. The option to retire the bond is, however, neglected in the standard pricing models, causing a systematic overvaluation of callable bonds. In the event of a decline...
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Context of Digitalized Employment for Older Adults with Autism Spectrum Disorder in the New Normal
PublikacjaEmployers are actively considering how to normalize remote work technology across different industries. The residual risk of coronavirus disease-19 (COVID-19) will necessarily lower the bar for allowing some workers to stay remote on a more permanent basis. This is based on the realization that many essential jobs can be teleworked while retaining or enhancing productivity. The decisions employers make regarding future work arrangements...
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Blast Charge Technique as a Method of Soil Improving to Locate the New Supporting Runways
PublikacjaA quick and effective method of reinforcing the ground base designed for the construction of engineering structures used for performing various types of air operations was presented. It allows to use wastelands, wetlands, swamps, etc. for these purposes, thus creating a dispersed network of landing sites, increasing the access of large social groups to air transport and increasing their mobility.
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New synthesis route of highly porous InxCo4Sb12 with strongly reduced thermal conductivity
PublikacjaHighly porous, In-filled CoSb3 skutterudite materials with an attractive thermoelectric figure of merit (ZT * 1) and corresponding dense samples were fabricated through the cost-effective method of reduction in oxides in dry hydrogen and the pulsed electric current sintering (PECS) method, respectively. The reduction process was described in detail using in situ thermogravimetric analysis of Co2O3, Sb2O3 and In(NO3)35H2O separately...
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Machine learning approach to packaging compatibility testing in the new product development process
PublikacjaThe paper compares the effectiveness of selected machine learning methods as modelling tools supporting the selection of a packaging type in new product development process. The main goal of the developed model is to reduce the risk of failure in compatibility tests which are preformed to ensure safety, durability, and efficacy of the finished product for the entire period of its shelf life and consumer use. This kind of testing...
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Further development of the poroelastic road surface within the new Polish project SEPOR
PublikacjaRoad surfaces have a direct impact on noise generated by rolling tyres, the main and dominant source of noise of moving vehicles. Road surface texture, porosity and stiffness/elasticity govern the pavement contribution to tyre/road noise the most. An experimental PoroElastic Road Surface (PERS) is a wearing course with a high content of interconnected voids (pores) and with an elastic behavior due to the use of small particles...
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NEW DESIGNS OF CENTRIFUGAL MAGNETIC FLUID SEALS FOR ROTATING SHAFTS IN MARINE TECHNOLOGY
PublikacjaThe centrifugal magnetic fluid seals have important advantage over the conventional centrifugal seals. They maintain very good sealing capacity at static, medium and high speeds of shaft rotation, with the increased seal lifetime, and minimum torque and static friction. These seals are particularly useful in cases when the angular shaft velocity varies and sometimes decreases to nearly or exactly zero, such as in flywheel applications,...
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SYNTHESIS OF PHOSPHORUS TACRINE ANALOGUES AS A NEW POTENTIAL ANTI-ALZHEIMER’S DISEASE AGENTS
PublikacjaA series of novel phosphorus tacrine derivatives was obtained in three steps, including synthesis of 9-chlorotacrine, connection of 9-chlorotacrine with hexamethylenediamine, 1,8-diaminooctane and 1,12-diaminododecane linkers and reaction of obtained tacrine diamine analogues with corresponding acid ester to give nine tacrine organophosphorus compounds. All of the obtained final structures were characterized by 1H NMR, 13C NMR,...
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The new concept of capillary forces driven evaporator with application to waste heat recovery
PublikacjaW pracy omówiono koncepcję zastosowania rurki ciepła w nowoczesnej konstrukcji parownika wspomagającego za pomocą sił kapilarnych pompę obiegu termodynamicznego czynnika. Rozwiązanie takie może znaleźć zastosowanie w domowej mikrosiłowni CHP
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New Generation of Water lubricated Foil bearing - Numerical Models and Experimental Verification
PublikacjaIn the paper a new idea of foil water lubricated bearing and methodology of hydrodynamic characteristics calculations is presented. To assesses the theoretical characteristics of these bearings two different computer models were built. First is structural model coupled with fluid model. It takes into account: fluid flow in the deformed fluid gap, specific design of bearing support and friction in bearing support. The second is...
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A new method of ship routing on raster grids, with turn penalties and collision avoidance
PublikacjaArtykuł przedstawia nowy algorytm znajdowania optymalnych tras na siatkach rastrowych. Szczegółowo opisano zastosowane struktury danych, dzięki którym algorytm ma liniową złożoność obliczeniową. Na podstawie algorytmu opracowano metodę wyznaczania tras dla statków, uwzględniającą kwestie unikania kolizji z innymi statkami i przeszkodami nawigacyjnymi.Przedstawiono dwa warianty metody, dedykowane odpowiednio systemom pokładowym...
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Investigations of vortex structures in granular materials under earth pressure conditions by DEM
PublikacjaW artykule pokazano rozwój wirów na poziomie ziarna materiału granulowanego podczas parcia pasywnego piasku na sztywną ściankę przemieszczającą się poziomo. Obliczenia wykonano stosując metodę DEM. Przyjęto 3 różne sposoby wyznaczenia wirów i ich czestotliwości.
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Discrete modeling of micro-structure evolution during concrete fracture using DEM
PublikacjaW artykule pokazano wyniki dyskretne DEM dla betonu poddanego ściskaniu i rozciąganiu jednoosiowemu. Wyniki siła-przemieszczenie i zarysowania porównano z doświadczeniami. Szczególną uwagę zwrócono na zjawiska mikrostrukturalne podczas zarysowania na poziomie kruszywa.
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DEM modelling of concrete fracture based on its structure micro-CT images
PublikacjaW rozdziale książki zawarto numeryczne wyniki mezoskopowe dotyczące postępującego pękania betonu na poziomie kruszywa. Do badania procesu pękania belki betonowej z karbem w trzech (3D) i dwóch (2D) wymiarach zastosowano metodę elementów dyskretnych (DEM). Niejednorodność betonu uwzględniono stosując czterofazowy opis: kruszywo, zaprawa, makropustki i międzyfazowe strefy przejściowe. W obliczeniach DEM na podstawie zdjęć rentgenowskich...
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Introduction to MIP synthesis, characteristics and analytical application
PublikacjaOne of the trends in analytical chemistry is associated with designing and developing new types of sample preparation techniques, which might significantly increase the efficiency and selectivity of the analytes isolation or/and preconcentration process. One of the most widely employed solutions are selective sorption materials, defined as molecularly imprinted polymers (MIPs), as well as the sorbents with the molecular fingerprint....
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Architekturführer Danzig: Gdansk Sopot Gdynia
PublikacjaIm Zweiten Weltkrieg bis auf die Grundmauern zerstört, wurde der historische Stadtkern der Hansestadt Danzig als polnisches Gdańsk wiederaufgebaut – ein Paradebeispiel für kritische Rekonstruktion in Polen und zugleich eine bis heute stark umstrittene Entscheidung. Zusammen mit dem mondänen Seebad Sopot und der modernen Hafenstadt Gdynia bildet die Bernsteinstadt eine Metropolregion an der polnischen Ostseeküste: die Dreistadt...
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De profundis ad astra
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Palao de las Artes.
PublikacjaOmówiono najnowszą realizację S. Calatravy Paleo de las Artes", stanowiącą wraz z trzema innymi obiektami przykład rewitalizacji terenów dawnego koryta rzeki Turia w centrum Walencji w Hiszpanii.
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Electron interactions with Bis(pentamethylcyclopentadienyl) titanium(IV) dichloride and difluoride
PublikacjaWe present a combined experimental and theoretical study of the interaction of electrons with Bis(pentamethylcyclopentadienyl)titanium(IV) dichloride (Cp∗2TiCl2) and difluoride (Cp∗2TiF2). We report the experimental measurements of partial cross sections for the dissociative electron attachment (DEA) and the electron ionization (EI) mass spectra of isolated molecules. Estimates of the absolute cross sections are done on the basis...
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Deep eutectic solvents in analytical sample preconcentration Part B: Solid-phase (micro)extraction
PublikacjaOne of the key challenges of modern analytical chemistry is the monitoring of trace amounts of contaminants using sensitive and selective instrumental techniques. Due to the variety and complexity of some samples, it is often necessary to properly prepare a sample and to perform a preconcentration of trace amounts of analytes. In line with the principles of Green Analytical Chemistry (GAC), it is important for an analytical procedure...
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Duhem and Natanson: Two Mathematical Approaches to Thermodynamics
PublikacjaIn this article, the previously unrecognized contributions of Pierre Duhem and Ladislavus Natanson in thermodynamics are shown. The mathematical remodelling of a few of their principal ideas is taken into consideration, despite being neglected in the literature. To emphasize these ideas in an appropriate epistemological order, it would be crucial to first revalue and reconstruct some underrepresented parts of the proceedings process...
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Phosphoroorganic Metal Complexes in Therapeutics
PublikacjaThe present mini-review highlights recent developments on antitumor activity of metal-based therapeutics which have been a subject of researches for the last few decades. In 1965, Rosenberg found that during an electrolysis on platinum electrodes a complex of Pt is generated which inhibited to a great extent a binary fission in Escherichia coli bacteria. This discovery started a new chapter in medicinal chemistry and the interesting...
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Numerical modeling of the combustion in a lab-scale pulverized-coal fired combustion chamber
PublikacjaThis work presents results of numerical modeling of the combustion process inside a lab-scale drop-tube chamber, designed to investigate the slagging properties of the flue ashes, created through the solid fuel firing. Interaction between turbulence and chemistry is accounted by use of probability density function (PDF). FLUENT inputs for non-premixed combustion chemistry modeling are defined. A discrete second phase of the coal...
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Numerical modeling of the combustion in a lab-scale pulverized-coal fired combustion chamber
PublikacjaThis work presents results of numerical modeling of the combustion process inside a lab-scale drop-tube chamber, designed to investigate the slagging properties of the flue ashes, created through the solid fuel firing. Interaction between turbulence and chemistry is accounted by use of probability density function (PDF). FLUENT inputs for non-premixed combustion chemistry modeling are defined. A discrete second phase of the coal...
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Detailed experimental investigations on frictional pressure drop of R134a during flow boiling in 5 mm diameter channel: The influence of acceleration pressure drop component =Études expérimentales détaillées sur la chute de pression frictionnelle du R134a lors de l'ébullition en écoulement dans un canal de 5 mm de diamètre : influence de la composante d'accélération de la chute de pression
PublikacjaThis article presents detailed two-phase diabatic pressure drop data for refrigerant R134a at a saturation pressure of 5.5 bar corresponding to the saturation temperature of 19.4 °C. Study cases have been set for a mass flux varying from 100 to 500 kg m−2 s−1. The obtained data are used as a validation of the void fraction literature models, a set of graphs shows comparisons, for a representative set of experimental conditions,...
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Synthesis of 5-Substituted 1H-Tetrazoles from Nitriles in the Presence of Heterogeneous Catalyst
PublikacjaTetrazoles are five-membered heterocyclic compounds containing in their rings four nitrogen atoms. They have wide applications as corrosion inhibitors, analytical reagents, high-energy materials and gas generating compositions. Tetrazoles also play important role in coordination chemistry as ligands and in medicinal chemistry as metabolically stable surrogates for carboxylic acids. In recent years, investigation of new method of...
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Diethyl carbonate as a green extraction solvent for chlorophenol determination with dispersive liquid–liquid microextraction
PublikacjaThe principles of green analytical chemistry indicate that the search for greener organic solvents for extraction applications is crucial. In this study diethyl carbonate (DEC) is proved to be a green solvent, as it is relatively nontoxic, obtainable from renewable resources and biodegradable. Here it is applied as an extraction solvent for chlorophenol determination in water samples with dispersive liquid–liquid microextraction....
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New Alternative Passive Networks to Improve the Range Output Voltage Regulation of the PWM Inverters
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New high-gain step-up DC/DC converter with high-frequency isolation
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SLIDING MODE-PID FUZZY CONTROLLER WITH A NEW REACHING MODE FOR UNDERWATER ROBOTIC MANIPULATORS
PublikacjaDesign of an accurate and robust controller is a challenging topic in an underwater manipulator control. This is due to hydrodynamic disturbances in underwater environment. In this paper a sliding mode control (SMC) included a PID sliding surface and fuzzy tunable gain is designed. In this proposed controller robustness property of SMC and fast response of PID are incorporated with fuzzy rules to reduce error tracking. In the...
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Response of a New Low-Coherence Fabry-Perot Sensor to Hematocrit Levels in Human Blood
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Shaping New Generations of Managers and Consumers: CSR Implementation and Higher Education System in Poland
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Incorporation of nitrogen in diamond films - A new way of tuning parameters for optical passive elements
PublikacjaThis paper investigates the impact of nitrogen incorporation in diamond films for the construction of an interferometric sensor to measure displacement. Diamond films with different nitrogen levels (0–5%) were deposited on silicon substrates by microwave plasma enhanced chemical vapor deposition. The structural characteristics of these samples are characterized using scanning electron microscopy (SEM), atomic force microscopy...
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Synthesis of New Hydrazone Derivatives and Evaluation of their Efficacy as Proliferation Inhibitors in Human Cancer Cells
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Numerical and physical modeling of water flow over the ogee weir of the new Niedów barrage
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A new approach for the extraction of tetracyclines from soil matrices: application of the microwave-extraction technique
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A new approach to active noise and vibration control - [Part I: the known frequency case]
PublikacjaThis paper presents a new approach to rejection of complex-valued sinusoidal disturbances acting at the output of a discrete-time stable linear plant with unknown dynamics. It is assumed that the frequency of the sinusoidal disturbance is known, and that the output signal is contaminated with wideband measurement noise. The disturbance rejection control rule is first derived and analyzed for a nominal plant model, different from...
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A new approach to active noise and vibration control - [Part II: unknown frequency case]
PublikacjaThis paper presents a new approach to rejection of complex-valued sinusoidal disturbances acting at the output of a discrete-time stable linear plant with unknown and possibly timevarying dynamics. It is assumed that both the instantaneous frequency of the sinusoidal disturbance and its amplitude may be slowly varying with time and that the output signal is contaminated with wideband measurement noise. It is not assumed that a...
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A new approach to provide the differentiated levels of network survivability under a double node failure
PublikacjaW artykule zaproponowano klasową metodę ochrony strumieni ruchu w sieciach WDM zapewniającą szybkie odtwarzanie połączeń w sytuacji jednoczesnej awarii jej dwóch elementów. Szczególny nacisk położono na zagadnienie zapewnienia zróżnicowanych poziomów przeżywalności w celu ich lepszego dopasowania do zróżnicowanych wymagań użytkowników. Pokazano, że w celu zapenienia ochrony przed awarią dwóch elementów, wymagania dotyczące przepustowości...
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PCR melting profile (PCR MP) - a new tool for differentiation of Candida albicans strains
PublikacjaPo raz pierwszy przedstawiliśmy użyteczność techniki PCR MP opartej na metodzie ligacji adaptorów (LM PCR) i obniżonej temperaturze denaturacji w cyklach PCR do wewnątrzgatunkowego różnicowania szczepów Candida albicans. Przebadaliśmy 123 szczepy Candida albicans z zastosowaniem trzech metod genotypowania: PCR MP, REA-PFGE i RAPD i uzyskaliśmy odpowiednio 27, 26 i 25 unikalnych genotypów. Zaprezentowane dane pokazały, że technika...