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Wyniki wyszukiwania dla: ELECTROCHEMICAL CAPACITORS
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Identification of volatile compounds based on the electrocatalytic gas sensor responses
PublikacjaMeasured response in case of electrocatalytic gas sensors is in form of a voltamperometric characteristic. Current-voltage (I-V) response shape depends on the gas type and its concentration. Such response contains significantly more information comparing with typical electrochemical sensors, but is quite difficult to analyze. When I-V curve contains current peaks, position of such peaks can be used...
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Synthesis of novel dinuclear ruthenium polypyridine dye for dye-sensitized solar cells application
PublikacjaA new dinuclear ruthenium(II) polypyridine complex has been successfully synthesized. The new compound has been characterized by spectroscopic and electrochemical methods. Its potential application as a sensitizing dye in dye-sensitized solar cells has been checked under AM 1.5 G irradiation conditions (100 mW cm−2) and its performance was compared to that of a commercially available mononuclear analogous dye. The overall light-to-electricity...
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Hard carbon derived from rice husk as low cost negative electrodes in Na-ion batteries
PublikacjaHere, we report the synthesis of hard carbon materials (RH) made from natural rice husk through a single pyrolysis process and their application as an anode in sodium-ion batteries. The studies show that the electrochemical properties of RHs are affected by the treatment temperatures, which determine the materials morphology, in particular, their degree of graphitization and extent of continuous channels (nanovoids). The latter...
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Research on causes of corrosion in the municipal water supply system
PublikacjaThis paper presents results of failure analysis study to characterize the corrosion damage that occurred in the water supply system in Krakow. This analysis includes: electrochemical noise, linear polarization and resistometric measurements. Water aggressiveness of four water intakes was defined using Langelier and Ryznar indices. Results from this indices did not reveal the causes of considerable corrosion losses in water systems....
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High-performance method of carbon nanotubes modification by microwave plasma for thin composite films preparation
PublikacjaIn this work we present a simple and efficient method of nitrogen plasma modification of carbon nanotubes (CNTs). The process allows for treatment of the nanotubes in the form of powder with quite a high yield (65 mg of CNTs per hour). The modified carbon nanotubes contain approx. 3.8% of nitrogen, mostly in the pyridinic form. Plasma treated CNTs exhibit better dispersibility in water and higher electric capacitance than pristine...
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Surface and Corrosion Properties of AA6063-T5 Aluminium Alloy in Molybdate-containing Sodium Chloride Solutions
PublikacjaCorrosion properties of aluminium alloy AA6063-T5 were investigated in molybdate-containing NaCl solutions. Electrochemical, microscopic, and spectroscopic experiments were utilized to examine the mechanism of corrosion inhibition by molybdates. SEM-EDX, magnetic force, and intermodulation electrostatic force microscopy data suggested that the inhibition initiation preferentially occurred over Fe-rich cathodic IMPs. Spectroscopic...
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Method of sacrificial anode dual transistor-driving in stray current field
PublikacjaIn order to control a magnesium anode in a stray current interference field, a dual transistor driving system has been proposed. It consisted of a combination of PNP and NPN transistors. Dual transistor driven system and direct anode to cathode connection were electrochemically tested in 3% NaCl solution. The dual transistor driven system increased the anode efficiency and reduced hydrogen evolution and the risk of embrittlement....
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Design and Evaluation of the Compact and Autonomous Energy Subsystem of a Wave Energy Converter
PublikacjaThis paper presents the results of the design process focused on the development of the energy subsystem (ES) of a wave energy converter (WEC). The ES is an important electrical part that significantly affects the energy reliability and energy efficiency of the entire WEC device. The designed ES was intended for compact WECs powering IoT network devices working in the distributed grid. The developed ES is an electronic circuit...
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Direct design of Controlled Modulus Columns (CMC) based on in-situ testing
PublikacjaIn this paper, the serviceability limit state and bearing capacity of tension screw displacement piles were analyzed using the results of static pile load tests, carried out on the test plot near the Elbląg city, and field, and laboratory tests. The paper presents the methodology of determining the pile load-settlement curve using different types of t-z transfer functions. The new method of constructing the pile load-settlement...
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Characterization of magnesium doped lanthanum orthoniobate synthesized by molten salt route
PublikacjaMolten salt synthesis method has been used to prepare the single phase magnesium doped lanthanum orthoniobate. The phase composition has been checked by X-ray diffraction method and the microstructure studies have been performed by scanning electron microscopy. The high temperature properties of the material have been investigated by thermogravimetry and electrochemical impedance spectroscopy. A dependence between sample total...
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Corrosion behavior of concrete produced with diatomite and zeolite exposed to chlorides
PublikacjaChloride induced reinforcement corrosion is widely accepted to be the most frequent mechanism causing premature degradation of reinforced concrete structures. The electrochemical impedance of reinforcing steel in diatomite- and zeolite-containing concrete exposed to sodium chloride was assessed. Chemical, physical and mineralogical properties of three concrete samples (20% diatomite, 20% zeolite, and a reference containing neither)...
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Green sample preparation techniques for chromatographic determination of small organic compounds
PublikacjaAccurate monitoring of the state of the environment requires the introduction of additional isolation and/or preconcentration step prior to the chromatographic determination. In this work the information about novel methodological and instrumental solutions in relation to different variants of microextraction techniques are presented. Attention is focused on analytical procedure and suitable analytical tools for extraction of the...
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Electrophoretically Deposited Chitosan/Eudragit E 100/AgNPs Composite Coatings on Titanium Substrate as a Silver Release System
PublikacjaDue to the possibility of bacterial infections occurring around peri-implant tissues, it is necessary to provide implant coatings that release antibacterial substances. The scientific goal of this paper was to produce by electrophoretic deposition (EPD) a smart, chitosan/Eudragit E 100/silver nanoparticles (chit/EE100/AgNPs) composite coating on the surface of titanium grade 2 using different deposition parameters, such as the...
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Performance of organic coatings upon cyclic mechanical load
PublikacjaA number of engineering structures fail due to the fatigue damage resulting from cyclic mechanical stress. However, as far as organic coatings are concerned this degradation factor remains underestimated. In the paper the authors propose a methodology combining global electrochemical impedance spectroscopy and local atomic force microscopy measurements for evaluation of coating resistance to an impact of repetitive mechanical stress. Typical...
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Badania stabilności chemicznej kompozytowego elektrolitu 3-YSZ-Al2O3 w stosunku do materiałów elektrodowych do zastosowania w średniotemperaturowych ogniwach paliwowych
PublikacjaJednym z podstawowych wymogów stawianych mate- riałom na elektrolity do średniotemperaturowych ogniw paliwowych IT-SOFC (ang. intermediate-temperature solid oxide fuel cells) jest ich kompatybilność chemiczna z elektrodami w temperaturach zarówno eksploatacji, jak i wytwarzania ogniw. W celu sprawdzenia, czy badany w pracy kompozytowy elektrolit o osnowie z częściowo stabilizowanego ditlenku cyrkonu i z wtrąceniami tlenku glinu...
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In vitro antioxidative and binding properties of phenolics in traditional, citrus and exotic fruits
PublikacjaMany polyphenols bind proteins, therefore our research was focused on the potential of protein binding to polyphenols of investigated fruits and their health-related effects. The contents of polyphenols and related antioxidant activities of traditional, citrus and exotic fruits were compared. The presence of polyphenols (flavonoids and phenolic acids) in the investigated samples and their interaction with human serum albumin (HSA)...
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GDANSK-ORUNIA AS A LIVING LAB FOR INNOVATION IN REVITALISATION
PublikacjaPoland is at the beginning of the revitalization process, which started in 2015, when the legal framework had been provided. The revitalization process, understood as an innovative change that is based on four equally important aspects – the social, the economic, the infrastructural and the ecological ones, has been facing an important barrier in Poland. After over two decades of constant modernization, public involvement in planning...
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Concrete-filled FRP tubular members in marine and bridge structures
PublikacjaConcrete core of the concrete-filled tubes (CFTs) with circular cross-section is in the case of an axial compression subjected to a spatial state of compressive stresses. This state leads to enhancement in the concrete strength. The enhancement is utilized in Eurocode 4 design procedures for CFSTs (i.e. CFTs with tube made of steel). The structural design of CFFTs (i.e. CFTs with tube made of Fibre Reinforced Polymer - FRP) is...
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Evaluation of the resistance of steel–concrete adhesive connection in reinforced concrete beams using guided wave propagation
PublikacjaThe development of the nondestructive diagnostic methods is of significant importance in the last decades. A special attention is paid to diagnostics of reinforced concrete structures, which are very popular in the civil engineering field. A possible use of the guided waves in the estimation of the resistance of steel–concrete adhesive connection is studied in the following paper. The relationships relating adhesive connection...
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Characterization and Technical Application of Fine Photocatalytical Particles - A Study of the Immobilization of Photocatalysts
PublikacjaThe main aim of this dissertation was the transfer of photocatalytical laboratory scale experiments to semi-technical scale. Preliminary experiments of the purification of organic chlorine-loaded waters and the immobilization of photocatalysts were performed, which yielded the research back to the roots of synthesis. The first applied research was carried out on treatment of recreational water. Several light sources, particularly...
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Hydrothermal synthesis of vanadium ammonium compounds – the crucial role of the pressure
PublikacjaDue to the structural diversity and chemical activity, vanadium oxides and their derivatives are continuingly in the great interest of scientist. In a large family of vanadium compounds, one of the most interesting are ammonium vanadates (with the general formula (NH4)xVyOz). They have received much attention because of their promising application as cathode material in mono- and multivalent-ion batteries [1]. Hydrothermal synthesis...
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Electrocatalytic performance of oxygen-activated carbon fibre felt anodes mediating degradation mechanism of acetaminophen in aqueous environments
PublikacjaCarbon felts are flexible and scalable, have high specific areas, and are highly conductive materials that fit the requirements for both anodes and cathodes in advanced electrocatalytic processes. Advanced oxidative modi- fication processes (thermal, chemical, and plasma-chemical) were applied to carbon felt anodes to enhance their efficiency towards electro-oxidation. The modification of the porous anodes results in increased...
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Fabrication and properties of electrode material composed of ordered titania nanotubes and pEDOT:PSS
PublikacjaWe report on the two-stage preparation method of electrode material composed of titania nanotubes and poly(3,4-ethylenedioxythiopene):poly(2-styrenesulphonate) conductive polymer (pEDOT:PSS). Initially, titania nanotube arrays were produced by the anodization process of Ti substrate. Next, the polymer was potentiostatically deposited onto the thermally annealed nanotube arrays from the electrolyte containing monomer and counter...
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Photocatalysts for Solar Energy Conversion
PublikacjaPhotocatalytic oxidation over suspended solid photocatalysts (e.g., titanium dioxide) has been proposed as a sustainable process for treatment and purification of water and wastewater as well as the process for photoconversion of solar energy to hydrogen, methane, and other low hydrocarbons. Solar radiation could be used to drive heterogeneous electrochemical reactions at the surface of an optically active photocatalyst (e.g.,...
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Polymer electrolytes with ionic liquids
PublikacjaSolid polymer electrolytes are solutions of salts in the macromolecular polymeric compound. Excellent process ability, flexibility, non-flammability and non-reactivity make them ideal materials for electrochemical devices. The problem in their use is limited conductivity. It increases with increasing salt concentration in the polymer, but at the same time the condition is to increase the glass transition temperature of the polymer...
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Dynamic impedance measurements of the Direct Methanol Fuel Cell cathode at various operating temperatures
PublikacjaThis article discusses the application of impedance analysis for diagnosing the cathode of a direct methanol fuel cell at various operating temperatures. The Dynamic Electrochemical Impedance Spectroscopy technique coupled with a linear current scan was applied for this purpose. This technique allowed the observation of changes in the cathode's properties in the fuel cell operating under real working conditions. An equivalent model...
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AC-DC-DC Converter for Small Power Energy Storage Systems
PublikacjaThe energy transformation driven by the development of renewable energy sources has become a reality for all power grid users. Prosumer energy, primarily utilizing photovoltaic installations, is one of the fastest-growing market segments. The advancement of technology, a decrease in electrochemical energy storage prices, and changes in the legal framework governing energy billing for grid-fed power have led to a growing interest...
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IMPACT OF DIRECT CURRENT ON NITRIFYING BIOMASS
PublikacjaEffects of short term exposure of nitrifying biomass to direct current were studied. DC was applied to mixed liquor from municipal BNR plant using graphite electrodes in no substrate limiting conditions. Both, ammonia oxidizing bacteria (AOB) and nitrite oxidizing bacteria (NOB) populations were affected by the current, however in opposite ways. The AOB population activity was inhibited by applied voltage. Activity decrease was...
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Tailoring the Size and Shape—New Path for Ammonium Metavanadate Synthesis
PublikacjaAmmonium metavanadate, NH4VO3, plays an important role in the preparation of vanadium oxides and other ammonium compounds, such as NH4V3O8, (NH4)2V3O8, and NH4V4O10, which were found to possess interesting electrochemical properties. In this work, a new route for the synthesis of NH4VO3 is proposed by mixing an organic ammonium salt and V2O5 in a suitable solvent. The one-step procedure is carried out at room temperature. Additionally,...
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Microfluidic devices for photo-and spectroelectrochemical applications
PublikacjaThe review presents recent developments in electrochemical devices for photo- and spectroelectrochemical investigations, with the emphasis on miniaturization (i.e., nanointerdigitated complementary metal-oxide-semiconductor devices, micro- and nano-porous silicon membranes or microoptoelectromechanical systems), silica glass/microreactors (i.e., plasmonic, Raman spectroscopy or optical microcavities) or polymer-based devices (i.e.,...
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Nano Tin/Tin Oxide Attached onto Graphene Oxide Skeleton as a Fluorine Free Anode Material for Lithium-Ion Batteries
PublikacjaHerein, we show a composite formation method of tin/tin oxide nanoparticles with graphene oxide and CMC based on laser ablation technique as an electrode material for energy storage devices. The material exhibited a three-dimensional conducting graphene oxide network decorated with tin or tin oxide nanoparticles. The structure, homogeneous distribution of nanoparticles, and direct contact between inorganic and organic parts were...
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Możliwości zastosowania zasobnikowych jednostek trakcyjnych na liniach kolejowych na przykładzie Pomorskiej Kolei Metropolitalnej
PublikacjaW artykule zwrócono uwagę, że zasobniki stosowane głównie do rekuperacji energii, mogą być również wykorzystane do zasilania pociągów na niezelektryfikowanych i zelektryfikowanych odcinkach linii kolejowych. Innowacyjność tego rozwiązania wykazano na podstawie dwóch aplikacji kolejowych elektrycznych zasobnikowych jednostek trakcyjnych: pierwszej funkcjonującej od 2014 roku na linii Utsunomiya – Karasuyama w Japonii oraz drugiej,...
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Effect of copper and silver modification of NH2-MIL-125(Ti) on the photoreduction of carbon dioxide to formic acid over this framework under visible-light irradiation
PublikacjaCu and Ag enhance the photocatalytic activities of metal–organic frameworks (MOFs) toward CO2 conversion because of their CO2 adsorption capacities and effects on the lowest unoccupied molecular orbital (LUMO) overpotentials of MOFs. However, to date, targeted introduction of metals into MOFs to achieve visible (Vis)- light-active photocatalysts for CO2 photoconversion has not been realized. Herein, a series of aminefunctionalized...
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Biomechanical properties of 3D-printed bone models
PublikacjaBone lesions resulting from large traumas or cancer resections can be successfully treated by directly using synthetic materials or in combination with tissue engineering methods (hybrid). Synthetic or hybrid materials combined with bone tissue’s natural ability for regeneration and biological adaptation to the directions of loading, allow for full recovery of its biological functions. Increasing interest in new production methods...
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Reliable routing and resource allocation scheme for hybrid RF/FSO networks
PublikacjaSignificant success of wireless networks in the last decade has changed the paradigms of communication networks design. In particular, the growing interest in wireless mesh networks (WMNs) is observed. WMNs offer an attractive alternative to conventional cable infrastructures, especially in urban areas, where the cost of new installations is almost prohibitive. Unfortunately, the performance of WMNs is often limited by the cluttered...
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Removal of cyclohexane and ethanol from air in biotrickling filters inoculated with Candida albicans and Candida subhashii
PublikacjaThis paper presents investigations on the removal of cyclohexane and ethanol from air in polyurethane- -packed biotrickling filters, inoculated with Candida albicans and Candida subhashii fungal species. Results on process performance together with flow cytometry analyses of the biofilm formed over packing elements are presented and discussed. The results indicate that the presence of ethanol enhances the removal efficiency of cyclohexane...
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Bibliometric analysis and literature review of ultrasound-assisted degradation of organic pollutants
PublikacjaUltrasound as a clean, efficient, and cheap technique gains special attention in wastewater treatment. Ultrasound alone or coupled with hybrid processes have been widely studied for the treatment of pollutants in wastewater. Thus, it is essential to conduct a review about the research development and trends on this emerging technique. This work presents a bibliometric analysis of the topic associated with multiple tools such as...
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Monitoring the BTEX Volatiles during 3D Printing with Acrylonitrile Butadiene Styrene (ABS) Using Electronic Nose and Proton Transfer Reaction Mass Spectrometry
PublikacjaWe describe a concept study in which the changes of concentration of benzene, toluene, ethylbenzene, and xylene (BTEX) compounds and styrene within a 3D printer enclosure during printing with different acrylonitrile butadiene styrene (ABS) filaments were monitored in real-time using a proton transfer reaction mass spectrometer and an electronic nose. The quantitative data on the concentration of the BTEX compounds, in particular...
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High-Temperature Structural and Electrical Properties of BaLnCo2O6 Positrodes
PublikacjaThe application of double perovskite cobaltites BaLnCo2O6−δ (Ln = lanthanide element) in electrochemical devices for energy conversion requires control of their properties at operating conditions. This work presents a study of a series of BaLnCo2O6−δ (Ln = La, Pr, Nd) with a focus on the evolution of structural and electrical properties with temperature. Symmetry, oxygen non-stoichiometry, and cobalt valence state have been examined...
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Carbon Nanomaterials From Metal-Organic Frameworks: A New Material Horizon for CO2 Reduction
PublikacjaThe rise of CO2 in the atmosphere, which results in severe climate change and temperature increase, is known as the major reason for greenhouse effect. Reducing CO2 to value-added products is an attractive solution to this severe problem, along with addressing the energy crisis, to which the catalysts being employed are of vital importance. Due to their high porosity and tunable compositions, Metal-Organic Frameworks (MOFs) show...
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Detection of gaseous compounds with different techniques
PublikacjaSensing technology has been developed for detection of gases in some environmental, industrial, medical, and scientific applications. The main tasks of these works is to enhance performance of gas sensors taking into account their different applicability and scenarios of operation. This paper presents the descriptions, comparison and recent progress in some existing gas sensing technologies. Detailed introduction to optical sensing...
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Graphene oxide, reduced graphene oxide and composite thin films NO2 sensing properties
PublikacjaA graphene oxide (GO), reduced graphene oxide (RGO) and poly(3,4-ethylenedioxytiophene)-reduced graphene oxide (PEDOT-RGO composite) gas sensors were successfully fabricated using an electrodeposition method. The electrodeposition was carried out in aqueous GO dispersions. To obtain RGO and PEDOT-RGO, the electrochemical reduction of GO and PEDOT-GO was carried out in 0.1 M KCl at a constant potential of −0.85 V. The GO, RGO and PEDOT-RGO...
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Measurements of flicker noise in supercapacitor cells
PublikacjaFlicker noise (1/f-like noise) is often used to assess the quality of various materials and devices. This phenomenon has been observed in different electrochemical devices or reactions (e.g., smart windows, pitting corrosion events). In our exploratory studies we consider how to measure and utilize 1/f noise for the quality assessment of supercapacitors. This task requires special attention because of enormous capacitance of the...
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Dynamic charging of electric buses
PublikacjaDespite the continuous development of electrochemical battery technology and the multitude of electric buses on offer, it is still not possible to exploit electric buses in urban transport on an all-day basis without the necessity of charging them. It is therefore necessary to build point-to-point contact charging stations or induction charging stations at the terminals. This results in substantial financial outlays connected with...
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Widening of the electroactivity potential range by composite formation – capacitive properties of TiO2/BiVO4/PEDOT:PSS electrodes in contact with an aqueous electrolyte
PublikacjaComposites based on the titania nanotubes were tested in aqueous electrolyte as a potential electrode material for energy storage devices. The nanotubular morphology of TiO2 was obtained by Ti anodization. TiO2 nanotubes were covered by a thin layer of bismuth vanadate using pulsed laser deposition. The formation of the TiO2/BiVO4 junction leads to enhancement of pseudocapacitance in the cathodic potential range. The third component,...
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Elektrochemiczny czujnik na bazie cieczy jonowej do oznaczania par benzaldehydu
PublikacjaW pracy przedstawiono prototypowy, laboratoryjny, elektrochemiczny czujnik do oznaczania par benzaldehydu w argonie. Cieczą jonową testowaną jako elektrolit i środowisko reakcji redox była: bis(trifluorometylosulfonylo)imidek 1-butylo,3-metyloimidazolinowy ([BMIM][Tf2N]). W pomiarach użyto komercyjnych elektrod firm: DropSens Co. i BVT Technologies. Walidacji poddano dwa parametry metrologiczne czujnika: granicę wykrywalności i...
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Ligand-Modified Boron-Doped Diamond Surface: DFT Insights into the Electronic Properties of Biofunctionalization
PublikacjaWith the increasing power of computation systems, theoretical calculations provide a means for quick determination of material properties, laying out a research plan, and lowering material development costs. One of the most common is Density Functional Theory (DFT), which allows us to simulate the structure of chemical molecules or crystals and their interaction. In developing a new generation of biosensors, understanding the nature...
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Highly Oriented Zirconium Nitride and Oxynitride Coatings Deposited via High‐Power Impulse Magnetron Sputtering: Crystal‐Facet‐Driven Corrosion Behavior in Domestic Wastewater
PublikacjaHerein, highly crystalline ZrxNy and ZrxNyOz coatings are achieved by the deposition via high‐power impulse magnetron sputtering. Various N2 and N2/O2 gas mixtures with argon are investigated. The chemical composition and, as a result, mechanical properties of the deposited layer can be tailored along with morphological and crystallographic structural changes. The corrosion resistance behavior is studied by potentiodynamic measurements...
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Condition of Reinforced Concrete Structures and Their Degradation Mechanism at the Former Auschwitz Concentration and Extermination Camp
PublikacjaThis paper presents the results of investigations on reinforced concrete structures present in the former Auschwitz I and Auschwitz II-Birkenau concentration and extermination camp. Field inspection employing the non-destructive method of reinforcement potential measurement according to the ASTM-C 876–15 standard, followed by laboratory investigations performed on genuine historic reinforced concrete samples collected from the...
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Structural and electrical properties of titanium-doped yttrium niobate
PublikacjaIn this work, the influence of the substitution of niobium by titanium in Y3Nb1-xTixO7-δ on the structural and electrical properties is reported. Several experimental techniques, i.e. X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), X-Ray Photoelectron Spectroscopy (XPS) and Electrochemical Impedance Spectroscopy (EIS), were applied to investigate the system Y3Nb1-xTixO7-δ. Titanium in Y3Nb1-xTixO7-δ is an acceptor-type...