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Wyniki wyszukiwania dla: METHANE YIELD
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Development and Validation of SPE-HPLC-MS/MS Method for Determining Cyclophosphamide in Surface Waters
PublikacjaA rapid and selective method for trace amounts determination of cyclophosphamide in surface water samples has been developed. A solid phase extraction SPE method for extraction and clean-up procedure has been optimized for determination by reversed-phase high-performance liquid chromatography with tandem mass spectrometry. The analyses proceed in the positive ion mode by means of the electrospray ionization method (ESI). Clean...
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Polska leksykografia terminologiczna z komponentem rosyjskim z zakresu ekonomii, handlu i zarządzania. Bibliografia słowników wydanych w latach 1887–2015 [Polish terminological lexicography in the field of economics, trade, management, including a Russian component. A bibliography of dictionaries published between 1887–2015]
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Positron Scattering and Annihilation in Organic Molecules
PublikacjaIn this paper, we address the problem of connecting positron lifetimes in liquids with collision cross sections in gases. We present the analyses of annihilation lifetime spectra of positrons in the liquid benzene, c-hexane, n-hexane, methanol and ethanol and calculations of scattering cross sections of positrons with benzene and c-hexane in the gas phase.
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Elementary analysis and energetic potential of the sludge from the Gdynia Dębogórze and Lębork wastewater treatment plants
PublikacjaThe paper aims to show the results of the elementary analysis of the sewage sludges from wastewater treatment plants in Gdynia Dębogórze and Lębork as well as measurements of the heat of combustion and the calculated calorific values according to regulation PN-93/Z-15008, taking into account water content and the composition of sewage sludge at different utilisation stages. The results presented in this paper are based on the analysis...
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Investigation of functional layers of solid oxide fuel cell anodes for synthetic biogas reforming
PublikacjaSolid oxide fuel cells (SOFCs) are one of the most promising energy conversion devices due to their high efficiency, low pollution and fuel flexibility. Unfortunately, when hydrocarbons are used as a fuel, for example in the form of a biogas, solid carbon can deposit on the anode surface. This process leads to the degradation of the fuel cell performance. A possible solution to this problem is to apply an additional catalytic material,...
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Influence of Different Biofuels on the Efficiency of Gas Turbine Cycles for Prosumer and Distributed Energy Power Plants
PublikacjaThe efficiency of a gas turbine can be affected by the use of different biofuels usually with a relatively Lower Heating Value (LHV). The paper evaluates the impact of calorific value of fuel on turbine performance and analyzes the possibilities of optimizing turbine construction from the point of view of maximum efficiency for a particular fuel. The several variants of design of small power microturbines dedicated to various biofuels...
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Estimation of Stresses in a Dry Sand Layer Tested on Shaking Table
PublikacjaTheoretical analysis of shaking table experiments, simulating earthquake response of a dry sand layer, is presented. The aim of such experiments is to study seismic-induced compaction of soil and resulting settlements. In order to determine the soil compaction, the cyclic stresses and strains should be calculated first. These stresses are caused by the cyclic horizontal acceleration at the base of soil layer, so it is important...
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A Planar-Structured Circularly Polarized Single-Layer MIMO Antenna for Wideband Millimetre-Wave Applications
PublikacjaIn this paper, a simple geometry, planar-structured printed multiple-input-multiple-output (MIMO) antenna utilizing dual circular polarization (CP) is presented. The proposed numerically and experimentally validated design features a fully grounded coplanar waveguide (CPW) and a systematically perturbed feedline radiator. The fringing electric (E) field along the feedline is altered by extruding periodic stubs on each side of the...
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SPEKTROSKOPOWE BADANIA WYŁADOWANIA MIKROFALOWEGO W ŹRÓDLE PLAZMY TYPU KOMORA REZONANSOWA ZASILANA FALOWODOWO
PublikacjaW pracy przedstawiono wyniki spektroskopowych badań wyładowania mikrofalowego (2,45 GHz) pod ciśnieniem atmosferycznym, generowanego w źródle plazmy typu komora rezonansowa. Gazami roboczymi były: argon, azot oraz metan, a także mieszaniny argon/metan oraz azot/metan. Natężenie przepływu gazu roboczego zmieniano w zakresie od 50 do 100 l/min, natomiast moc mikrofal absorbowanych przez wyładowanie wynosiła od 300 do 4000 W. Zmierzone...
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A Concept of Thermal Effort for Heat-Induced Metal Plasticity
PublikacjaThis paper proposes a new concept of material effort that considers heat-induced plasticity for heat-resistant steels. These steels indicate a strength differential effect, a stress shearness effect, pressure sensitivity, and other features. Therefore, a three-parameter, temperature-dependent yield function was presented and, next, analytically and geometrically researched. To validate the accuracy of the formulated yield function,...
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Some problems with operation of engines fueled with landfill biogas
PublikacjaW referacie przedstawiono wybrane problemy związane z eksploatacją tłokowych silników spalinowych zasilanych biogazem pozyskiwanym z wysypiska śmieci. Biogaz wysypiskowy charakteryzuje się znaczną zmiennością zawartości metanu, co ma istostny wpływ na pracę silników zasilanych tym paliwem. W referacie przedstawiono wyniki badań przeprowadzonych na wysypisku śmieci, w wyniku których zaprezentowano zrówno wielkość zmian zawartości...
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Electromodulation of photoluminescence in vacuum-evaporated films of bathocuproine
PublikacjaElectric field-modulated photoluminescence (EML) was measured in vacuum-evaporated films of bathocuproine (BCP), electron-transporting material commonly used in organic light-emitting diodes (OLEDs). The external electric field of 106 V/cm strength decreases long-wavelength photoluminescence (PL) up to 10% but the same effect on short-wavelength PL is above one order of magnitude smaller. The distinctive difference between the...
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The Influence of Calcium Glycerophosphate (GPCa) Modifier on Physicochemical, Mechanical, and Biological Performance of Polyurethanes Applicable as Biomaterials for Bone Tissue Scaffolds Fabrication
PublikacjaIn this paper we describe the synthesis of poly(ester ether urethane)s (PEEURs) by using selected raw materials to reach a biocompatible polyurethane (PU) for biomedical applications. PEEURs were synthesized by using aliphatic 1,6-hexamethylene diisocyanate (HDI), poly(ethylene glycol) (PEG), α,ω-dihydroxy(ethylene-butylene adipate) (Polios), 1,4-butanediol (BDO) as a chain extender and calcium glycerolphosphate salt (GPCa) as...
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On the relationship between the structural and volumetric properties of solvated metal ions in O-donor solvents using new structural data in amide solvents
PublikacjaThe structures of the N,N-dimethylformamide (dmf), N,N-dimethylacetamide (dma), and N,N-dimethylpropionamide (dmp) solvated strontium and barium ions have been determined in solution using large angle X-ray scattering and EXAFS spectroscopy. The strontium ion has a mean coordination number (CN) between 6.2 and 6.8, and the barium ion has a mean CN between 7.1 and 7.8 in these amide solvents. The non-integer numbers indicates that...
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Mono- and bimetallic (Pt/Cu) titanium(IV) oxide core–shell photocatalysts with UV/Vis light activity and magnetic separability
PublikacjaTitanium(IV) oxide is one of the most widely investigated photocatalysts. However, separation of nano-sized particulate titania might result in profitless technologies for commercial applications. Additionally, bare titania is almost inactive under the Vis range of solar spectrum due to its wide bandgap. Therefore, the present study aims to prepare novel coreinterlayer- shell TiO2 magnetic photocatalysts modified with metal nanoparticles...
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A Triplet-Learnt Coarse-to-Fine Reranking for Vehicle Re-identification
PublikacjaVehicle re-identification refers to the task of matching the same query vehicle across non-overlapping cameras and diverse viewpoints. Research interest on the field emerged with intelligent transportation systems and the necessity for public security maintenance. Compared to person, vehicle re-identification is more intricate, facing the challenges of lower intra-class and higher inter-class similarities. Motivated by deep...
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Acoustic heating produced in the thermoviscous flow of a Bingham plastic
PublikacjaThis study is devoted to the instantaneous acoustic heating of a Bingham plastic. The model of the Bingham plastic's viscous stress tensor includes the yield stress along with the shear viscosity, which differentiates a Bingham plastic from a viscous Newtonian fluid. A special linear combination of the conservation equations in differential form makes it possible to reduce all acoustic terms in the linear part of of the final equation...
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Acoustic heating produced in the thermoviscous flow of a bingham plastic
PublikacjaThis study is devoted to the instantaneous acoustic heating of a Bingham plastic. The model of the Bingham plastic's viscous stress tensor includes the yield stress along with the shear viscosity, which differentiates a Bingham plastic from a viscous Newtonian fluid. A special linear combination of the conservation equations in differential form makes it possible to reduce all acoustic terms in the linear part of of the final equation...
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Synthesis of amides under microwave irradiation
PublikacjaAmides belong to the most important carboxylic acid derivatives. They are constituents of natural compounds like peptides and proteins. They found applications in many branches of science and industry, especially in pharmaceutical and polymer science. Conventional procedures for amide preparation involve reaction between amine and carboxylic acid or their more active derivatives such as acid chlorides, acid anhydrides or esters....
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Effect of Microplastics Pollution on Hydrogen Production from Biomass: A Comprehensive Review
PublikacjaHydrogen production from biomass and organic wastes is considered as a potential alternative energy source and is known as a clean and CO2-free fuel energy carrier. H2 is considered very promising among the other energy sources; therefore, the effective conversion of biomass and organic solid waste to this secondary energy source is urgently sought. As a result, it is of importance to assess the impact of the existence of microplastics...
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Identification analysis of dynamic changes in the composition of biogas and their impact on the operation of internal combustion engines
PublikacjaW pracy zamieszczono wyniki badań składu biogazu pozyskiwanego na komunalnym wysypisku śmieci. Pozyskiwany biogaz jest wykorzystywany do zasilania biogazowych zespołów prądotwórczych wyposażonych w silniki o zapłonie iskrowym dostosowanych do zasilania tym paliwem. Pozyskiwany biogaz powstaje w sposób naturalny w procesie beztlenowej fermentacji zachodzącej przez ok. 20 lat, w organicznej części pryzmy odpadów składowanych na wysypisku...
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Modeling of low calorific gas burning in a deficient oxygen environment and high-temperature oxidizer
PublikacjaThe experimental research will be performed using the experimental facility with a combustion chamber. The oxygen concentration in combustion oxidizers will be varied from 21% by volume (normal) air to 2%. The test combustion chamber will be fed with propane or methane as the reference fuel, then with low calorific fuels as test gases obtained by mixing various combustible components, e.g. H2, CH4, CO, and neutral gases, e.g. N2,...
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Precipitation and Transformation of Vaterite Calcium Carbonate in the Presence of Some Organic Solvents
PublikacjaIn this paper, the production of CaCO3 particles via the carbonation route in the reaction of CaCl2 and CO2, using NH3 as a promoter of CO2 absorption, was studied. The solvents used as the reaction media for CaCO3 precipitation were aqueous solutions of methanol, isopropanol and dimethyl sulfoxide (DMSO), in a concentration range of 0–20% (v/v). It was found that the presence of an organic additive influenced the precipitation...
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Statistical analysis and robust design of circularly polarized antennas using sequential approximate optimization
PublikacjaIn the paper, reliable yield estimation and tolerance-aware design optimization of circular polarization (CP) antennas is discussed. We exploit auxiliary kriging interpolation models established in the vicinity of the nominal design in order to speed up the process of statistical analysis of the antenna structure at hand. Sequential approximate optimization is then applied to carry out robust design of the antenna, here, oriented...
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Enzyme Conjugation - A Promising Tool for Bio-catalytic and Biotransformation Applications – A Review
PublikacjaEnzymes have revolutionized conventional industrial catalysts as more efficient, eco-friendly, and sustainable substitutes that can be used in different biotechnological processes, food, and pharmaceutical industries. Yet, the enzymes from nature are engineered to make them adapt and enhance their durability in the industrial environment. One promising approach involves the combined use of multiple enzymes that catalyze highly...
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Waste Tyres Pyrolysis for Obtaining Limonene
PublikacjaThis review deals with the technologies of limonene production from waste tyre pyrolysis. Thermal decomposition is attractive for tackling the waste tyre disposal problem, as it enables both: energy to be recovered and limonene to be obtained. This material management recycling of tyres is environmentally more beneficial than the burning of all valuable products, including limonene. Given this recoverability of materials from waste...
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Numerical modelling and analysis of steel specimens subjected to marine immersed corrosion and tensile load
PublikacjaThe present study develops numerical models to analyse the behaviour of steel specimens subjected to marine immersed corrosion degradation and tensile load. The finite element method with the use of the explicit dynamic solver LS-DYNA, satisfying the quasi-static conditions, is employed. Two numerical models are developed, where in the first one, the scans of surfaces gathered from corroded plate specimens are implemented directly...
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Alternative Methods of Preparation of Soluble Keratin from Chicken Feathers
PublikacjaHuge amount of keratinous waste, especially birds’ feathers, demands more value-added application instead of dumping. The present work reports the results of experiments aimed at preparing soluble keratin useful for novel bioproduct formation. The effect of thermo-chemical treatments with various reducing agents, i.e. 2-mercaptoethanol, dithiothreitol, sodium m-bisulphite, and sodium bisulphite, as well as sodium hydroxide, on...
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Gas Turbine Cycle with External Combustion Chamber for Prosumer and Distributed Energy Systems
PublikacjaThe use of various biofuels, usually of relatively small Lower Heating Value (LHV), affects the gas turbine efficiency. The present paper shows that applying the proposed air by-pass system of the combustor at the turbine exit causes tan increase of efficiency of the turbine cycle increased by a few points. This solution appears very promising also in combined gas/steam turbine power plants. The comparison of a turbine set operating...
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Rheology of potato starch chemically modified with microwave-assisted reactions
PublikacjaNative potato starch was sulfated, selenated, borated, silicated and zincatated by means of microwave-assisted reactions with varying doses of relevant reagents. Resulting products were characterized involving rheological behavior of pastes, their weight-average molecular weight (Mw), and radius of gyration (Rg). Most of the pastes showed shear-thinning behavior, with the flow behavior index (n) below unity. The pastes of starch...
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Nanotechnologia, chemia i medycyna
PublikacjaKsiążka przedstawia chemiczne metody otrzymywania nanomateriałów oraz metody ich funkcjonalizacji. Opisano struktury zero, jedno i dwuwymiarowe zbudowane z różnych materiałów (metale, ceramika, związki organiczne, alotropowe odmiany węgla, chalkogenki metali). Podano wybrane przykłady zastosowania nanostruktur w medycynie i naukach pokrewnych.
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A geophysical, geochemical and microbiological study of a newly discovered pockmark with active gas seepage and submarine groundwater discharge (MET1-BH, central Gulf of Gdańsk, southern Baltic Sea)
PublikacjaHigh-resolution bathymetric data were collected with a multi-beam echosounder in the southern part of the Baltic Sea (region MET1, Gulf of Gdańsk) revealing the presence of a 10 m deep and 50 m in diameter pockmark (MET1-BH) on the sea bottom (78.7 m). To date, no such structures have been observed to reach this size in the Baltic Sea. The salinity of the near-bottom water in the pockmark was about 2 PSU (about 31.22 mmol/l...
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Determination of flavanols by liquid chromatography with fluorescence detection. Application to the characterization of cranberry-based pharmaceuticals through profiling and fingerprinting approaches
PublikacjaIn this work, a new method based on reversed-phase high-performance liquid chromatography (HPLC) with fluorescence detection (FLD) was established for the determination of catechins and related oligomeric proanthocyanidins (PACs) in cranberry-based pharmaceuticals. Compounds were recovered by liquid extraction using methanol/water/hydrochloric acid (60:39:1, v:v:v) as the extraction solvent. The chromatographic separation was carried...
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Size Exclusion Coupled to Reversed Phase Liquid Chromatography for the Characterization of Cranberry Products
PublikacjaA combination of solvent extraction, size exclusion purification, and reversed-phase liquid chromatography with UV absorption and fluorescence detection was here used for the determination of flavan-3-ols and related oligomeric compounds in cranberry products. The method relied on robust, simple, and inexpensive instrumental equipment present in most of routine analytical laboratories. Sample extracts in methanol/water/hydrochloric...
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Polyurethane Glycerolysate as a Modifier of the Properties of Natural Rubber Mixtures and Vulcanizates
PublikacjaChemical recycling of polyurethanes can be realized in several different ways, but the most important methods are glycolysis and glycerolysis. Both methods permit recovery of polyols (when the process is realized with the mass excess of depolymerizing agent) or substitutes of polyols, which contain urethane moieties in the main chains and terminate mainly in hydroxyl groups (when the process is realized with the mass excess of...
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Biowodór, „paliwo przyszłości”, dotychczasowe metody otrzymywania , porównanie metod otrzymywania
PublikacjaWodór jest ważnym pierwiastkiem w przemyśle chemicznym. Biowodór wydaje się być użytecznym odnawialnym nośnikiem energii, który mógłby zastąpić paliwa kopalne. Największym problemem wodoru jest jego rzadkie występowanie w czystej formie molekularnej H 2 . Dlatego otrzymanie biowodoru w objętościach opłacalnych ja ko surowiec czy biopaliwo wiedzie przez bioodpady „przesycone” wodorem. Każdy związek...
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TOTAL CROSS SECTION MEASUREMENTS FOR ELECTRON SCATTERING ON METHYL FORMATE (HCOOCH3) MOLECULE: METHYLATION EFFECT
PublikacjaWe present the absolute total cross section (TCS) for electron scattering from the methyl formate (HCOOCH3) molecule measured in the 10-300 eV energy range, with electrostatic electron spectrometer working in the linear transmission mode. Comparison of TCS for the HCOOCH3 molecule with that measured earlier for the formic acid (HCOOH) compound manifests the methylation effect i.e. the response of the electron scattering dynamics...
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The Influence of Co-Fermentation of Agri-Food Waste with Primary Sludge on Biogas Production and Composition of the Liquid Fraction of Digestate
PublikacjaEnergy self-sufficiency is a current trend in wastewater treatment plants. This effect can be achieved by increasing the production of electricity from biogas and by reducing energy consumption for technological processes. One idea, in line with the circular economy concept, is the use of waste rich in organic matter as co-substrates for the fermentation process. The aim of this study was to determine the effect of waste co-fermentation...
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Investigation of the 0.4C-35Cr-45Ni-Nb Alloy after Service in High-Temperature Steam and Hydrocarbons Environment
PublikacjaThe paper presents the results of investigation of the 0.4C-35Cr-45Ni-Nb alloy, which operated in the cracked hydrocarbon feeds and dilution steam at 1125 C. The material originated from the pyrolytic furnace coil tubes, of which internal walls were in contact with the aforementioned medium, whereas the external walls were in contact with the flue gases. The examination included metallographic and mechanical tests on the material...
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Hydrological responses to large-scale changes in land cover of river watershed: Review
PublikacjaDespite many studies on the hydrological responses to forest cover changes in micro and mesoscale watersheds, the hydrological responses to forest cover alterations and associated mechanisms through the large spatial scale of the river watershed have not been comprehensively perceived. This paper thus reviews a wide range of available scientific evidence concerning the impacts exerted by the forest removal on precipitation, water...
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Processing, physico-mechanical and thermal properties of reclaimed GTR and NBR/reclaimed GTR blends as function of various additives
PublikacjaIn this work, ground tire rubber (GTR) was mechano-chemically reclaimed in the presence of bitumen and various additives. During studies three types of processing and curing additives: (i) peptizer P300; (ii) vulcanization accelerator tetramethylthiuram disulfide (TMTD) and (iii) organic peroxide di(2-tert-butyl-peroxyisopropyl)benzene (BIB1) were applied to enhance reclaiming of GTR. Reclaiming process was evaluated by oscillating...
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Separation of CO2 from biogas using absorption columns
PublikacjaBiogaz zawiera ok. 50-70% metanu, 30-40% di tlenku węgla oraz niewielkie ilości innych związków jak siarkowodór czy amoniaku. Dla uzyskania wysokokalorycznego gazu konieczne jest usunięcie ze strumienia di tlenku węgla. Praca opisuje potencjał użycia do tego celu kolumn absorpcyjnych oraz cieczy jonowych jako absorbenta
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Eter dimetylowy - paliwo przyszłości
PublikacjaEter dimetylowy /DME/ jest uznawany za przyjazne środowisku paliwo przyszłości, ważny związek do magazynowania i dystrybucji energii, a także podstawowy substrat w technologii chemicznej. Produkuje się go z gazu syntezowego /który można otrzymać z węgla kamiennego/, gazu ziemnego, metanu z innych źródeł, koksu naftowego, biomasy, odpadów komunalnych.
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Orientacja na klienta. Fundamentalna zasada doskonalenia jakości
PublikacjaW niniejszym artykule zaprezentowano podstawowe aspekty doskonalenia jakości w odniesieniu do kluczowej zasady doskonałości jaką jest orientacja na klienta. Autor odniósł się do takich aspektów jak przewidywanie potrzeb, identyfikacja i zrozumienie oczekiwań, dostosowanie oferty do potrzeb klienta oraz pomiar satysfakcji.
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Zaangażowanie i rozwój pracowników każdego szczebla. Kolejna z fundamentalnych zasad doskonalenia jakości
PublikacjaW niniejszym oracowaniu poddano analizie zaangażowwanie i rozwój pracowników jako podstawę funcjonowania podmiotów dążących do zwiększenia swojej dojrzałości projakościowej. Autor wskazał odniesienia do tego obszaru w teorii Kompleksowego Zarządzania Jakością wraz z podstawowymi uwarunkowaniami zaangażowania proacowników.
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Wytwarzanie blach bimetalowych al 99,98 -m1e wstępnie łączonych metodą zgrzewania wybuchowego
PublikacjaW artykule omówiono proces wytwarzania blach bimetalowych AL99,8-M1E obejmujący etap łączenia warstw stanowiących wsad bimetalowy oraz etap związany z ich plastycznym kształtowaniem poprzez walcowanie. Przedstawiono i omówiono wpływ parametrów procesu walcowania na nierównomierność odkształcenia warstw stanowiących bimetal.
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Czynniki generujące skuteczne zarządzanie
PublikacjaW niniejszym artykule zarezentowano wybrane aspekty, które należy wziąć pod uwagę w przypadku zarządzania pracownikami w celu doskonalenia tego obszaru zarówno z punktu widzenia pracownika, jak i pracodawcy
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Szlifowanie na docierarkach tarczowych
PublikacjaPrzedstawiono technologie szlifowania powierzchni płaskich na docierarkach tarczowych. Omówiono stosowane narzędzia segmentowe, obrabiarki dwutarczowe i zalety mikroszlifowania. Porównano proces docierania konwencjonalnego luźnym ścierniwem z mikroszlifowaniem z kinematyką docierania.
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Docierarki do płaszczyzn. Cz. II. Docierarki dwutarczowe.
PublikacjaPrzedstawiono wsółczesne konstrukcje docierarek dwutarczowych do obróbki powierzchni płasko-równoległych. Omówiono kinematykę obiegowego układu wykonawczego obrabiarek dwutarczowych oraz tendencje rozwoju ich konstrukcji.
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Docierarki do płaszczyzn. Cz.I. Docierarki jednotarczowe
PublikacjaPrzedstawiono konstrukcje współcześnie produkowanych docierarek jednotarczowych do płaszczyzn. Omówiono standardową kinematykę układu wykonawczego tego typu docierarek.