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Wyniki wyszukiwania dla: atp synthase
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Overview of the Synthesis and Catalytic Reactivity of Transition Metal Complexes Based on C═P Bond Systems
PublikacjaThis report provides an overview of the use of phosphaalkenes (C=P) in syntheses of various complexes. Going through successive complexes containing the d-block metals, we sought how this area of chemistry was formed over the years. Additionally, this work contains information on the possible coordination types and means of constructing the complexes. In addition, this review reveals the reactivities of phosphaalkene complexes...
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Uogólnione układy dynamiczne w ujęciu rachunku operatorów
PublikacjaPo przedstawieniu wiadomości wstępnych dotyczących przestrzeni liniowych, operacji liniowych, izomorfizmów itp. zdefiniowano uogólniony układ dynamiczny, wykorzystując do tego nieklasyczny rachunek operatorów. Omówiono metody wyznaczania odpowiedzi uogólnionych układów dynamicznych, badanie ich stabilności, pojęcie układów dynamicznych równoważnych, uogólnioną transmitancję operatorową itp.
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Badania laboratoryjne wybranych sposobów koordynacji regulatora transformatora blokowego oraz regulatora generatora
PublikacjaWprowadzenie wymogu stosowania transformatorów blokowych z przekładnią regulowaną pod obciążeniem spowodowało konieczność określenia właściwego sposobu podziału kryteriów sterowania pomiędzy regulator generatora a regulator transformatora blokowego. W referacie zwrócono uwagę na aspekt miejsca pomiaru napięć. Ma to istotny wpływ zarówno na algorytm jak i jakość regulacji. Rozważania teoretyczne zilustrowane zostały wynikami prób...
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Nienasycenie w architekturze - pragmatyczne i ideologiczne przyczyny wznoszenia drapaczy chmur na przykładzie Gdańska
PublikacjaArtkuł w syntetyczny sposób omawia przyczyny, dla których na przestrzeni wieków ludzie decydowali się budować obiekty skierowane ku niebu. Dzieli te przyczyny na dwie główne grupy: ideologiczne (religigne, prestiżowe, kulturowe, itp) oraz pragmatyczne (ekonomiczne, polityczne, ale inne niż prestiżowe, itp), ilustrując je przykładami z Gdańska.
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Interfacial water controls the process of adsorption of hyperactive antifreeze proteins onto the ice surface
PublikacjaA mechanism of interactions between the ice-binding surface of a hyperactive antifreeze protein molecule and the ice surface is proposed, involving the influence of water present between the two surfaces on the behavior of the approaching molecule. It is demonstrated that the interfacial water, even before its full solidification, can act as a factor that pushes away or pulls nearer the protein molecule to ensure its proper positioning....
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Zastosowanie hierarchicznej analizy problemowej w badaniach efektywności inwestowania w elektroenergetyce
PublikacjaPrzedstawiono metodę AHP w badaniach efektywności inwestowania w elektroenergetyce.
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The sources of contamination and reasons of damage of the flow part of the marine turbine engine in operation
PublikacjaThe aim of this paperis to show particular sensitivity of the flow part of the marine turbine engine to the presence of contaminations in the intake air. The contaminations form hard-to-remove deposits in the intervene channels that result in a reduced efficiency and performance of the engine. The paper classifies the contaminants according the source of their formation and their destructive force. The performed analyses and syntheses...
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Consequences of lysine auxotrophy for Candida albicans adherence and biofilm formation
PublikacjaA number of factors are known to be involved in Candida albicans virulence, although biofilm development on the surfaces of indwelling medical devices is considered to promote superficial or systemic disease. Based on previously reported up-regulation of saccharopine and acetyllysine in biofilm cells and activation of the lysine biosynthesis/degradation pathway, we investigated...
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Analytical Expression for the Time-Domain Discrete Green's Function of a Plane Wave Propagating in the 2-D FDTD Grid
PublikacjaIn this letter, a new closed-form expression for the time-domain discrete Green's function (DGF) of a plane wave propagating in the 2-D finite-difference time-domain (FDTD) grid is derived. For the sake of its verification, the time-domain implementation of the analytic field propagator (AFP) technique was developed for the plane wave injection in 2-D total-field/scattered-field (TFSF) FDTD simulations. Such an implementation of...
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Wielokryterialna analiza porównawcza lokalizacji źródeł wytwórczych energii elektrycznej
PublikacjaArtykuł przedstawia ranking lokalizacji czterech źródeł wytwórczych energii elektrycznej: biogazowni rolniczej, biogazowni utylizacyjnej oraz dwóch elektrowni fotowoltaicznych, wykonany przy użyciu połączonych metod Analitycznego Procesu Hierarchicznego (AHP) oraz taksonomii numerycznej. Omówiono zalety połączenia metod, przedstawiono przykład zastosowania oraz wskazano kryteria o największym i najmniejszym wpływie na realizację...
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Complexes of silanethiolate ligands: Synthesis, structure, properties and application
PublikacjaThe purposeful syntheses of silanethiolate complexes started approximately in the mid-eighties of the 20th century but no summary of the synthetic efforts has been reported till now. The synthetic methods and the resulting complexes have some common features, which are emphasized throughout the review. Thereby specific difficulties during synthesis are outlined and the structures, properties and possible applications of the resulting...
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Guaranteeing Threshold Attendance of W/WSAN nodes in a reverted security paradigm
PublikacjaWe consider a Wireline/Wireless Sensor and Actor Network composed of sensor/actor nodes and a data sink/command center (DSCC). Each node controls a generic device that can be in- or out-of-service, corresponding to the ENABLED or DISABLED node state. The node senses the device's intention to change state, and notifies and/or requests the DSCC for authorization to act upon the device. Motivated by requirements for critical infrastructures...
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Modelowanie nieliniowej charakterystyki łącznika w obwodzie elektrycznym.
PublikacjaZaprezentowano model obwodowy łącznika elektroenergetycznego z łukiem elektrycznym. Łuk jest modelowany w oparciu statyczną charakterystykę prądowo- napięciową z uwzględnieniem w sposób uproszczony charakterystyki dynamicznej. Rezystancja łuku jest uzależniona nie tylko od prądu łuku ale również od czasu rozchodzenia się styków łącznika. Założono, że po obniżeniu się warto-ści prądu poniżej zadanego progu następuje całkowite...
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Long-Period Gratings and Microcavity In-Line Mach Zehnder Interferometers as Highly Sensitive Optical Fiber Platforms for Bacteria Sensing
PublikacjaSelected optical fiber sensors offer extraordinary sensitivity to changes in external refractive (RI), which make them promising for label-free biosensing. In this work the most sensitive ones, namely long-period gratings working at (DTP-LPG) and micro-cavity in-line Mach-Zehnder interferometers (µIMZI) are discussed for application in bacteria sensing. We describe their working principles and RI sensitivity when operating in water...
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Structural, optical and electrochemical performance of black phosphorus and black arsenic-phosphorus nanostructures
PublikacjaBlack phosphorus (BP)-based nanostructures have drawn a lot of attention due to their tunable bandgap and extraordinary properties such as: high surface-to-volume ratio, large number of active sites, and prominent edges. However, low dimensional structures of black phosphorus oxidize easily, which hamper their application on a broader scale. One way to overcome these difficulties is to modify the black phosphorus structure by substituting...
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Evaluating experimental molecular physics studies of radiation damage in DNA*
PublikacjaThe field of Atomic and Molecular Physics (AMP) is a mature field exploring the spectroscopy, excitation, ionisation of atoms and molecules in all three phases. Understanding of the spectroscopy and collisional dynamics of AMP has been fundamental to the development and application of quantum mechanics and is applied across a broad range of disparate disciplines including atmospheric sciences, astrochemistry, combustion and environmental...
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BUILDINGS AND CONSTRUCTIONS FROM BUILDING WASTE MATERIALS IN ACCORDANCE WITH THE NEW CIRCULAR ECONOMY TREND
PublikacjaMATERIALS April 18-22, 2022 / BOSTON, MA Abstract Book 3rd INTERNATIONAL CONFERENCE ON MATERIALS SCIENCE & ENGINEERING Day 5 Friday, April 22, 2022 Parallel Sessio II- (Virtual EST Zone) pp. 154 3rd INTERNATIONAL CONFERENCE ON MATERIALS SCIENCE & ENGINEERING APRIL 18-22, 2022 | BOSTON, MAAt: Boston, MAAffiliation: UNICEF at: USA BOSTONVolume: 2022
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Improving flexibility and performance of PVM applications by distributed partial evaluation
PublikacjaA new framework for developing both flexible and efficient PVM applications is described. We propose Architecture Templates Interface (ATI) that allows to control application granularity and parallelism. To ensure high application efficiency we extend partial evaluation strategy into domain of distributed applications obtaining Distributed Partial Evaluation (DPE). Both ATI and DPE were implemented using a new distributed programming...
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On effective properties of beam-lattice structures made of flexoelectric materials
PublikacjaThe e-Workshop Advances in ELAstoDYNamics of architected materials and BIOmaterials International Research Project (IRP) Coss&Vita of the CNRS
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Ensuring the QoE-Related Fairness to Reduce the User Abandonment Ratio
PublikacjaThese days, it is quite a challenge for app owners to keep users engaged with an app. Currently, the level of user abandonment is one of the key parameters that application owners are interested in. To meet these challenges, we are conducting an extended study of a previously proposed solution that significantly reduces the abandonment rate of a given application. The investigated solution is based on the methods of fairness using...
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Assessing vehicle restraint systems on horizontal curves
PublikacjaHorizontal curves, an element of road infrastructure, have a statistically high number of accidents. Considering that horizontal curves in the last ten years have had app. 10% of all road accidents representing app. 14% of all fatalities on Polish roads, the issue is serious and requires more research and proper road safety treatments. Data for 2007 - 2016 show that in the case of accidents on horizontal curves app. 45% of the...
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Endothelial Dysfunction Driven by Hypoxia—The Influence of Oxygen Deficiency on NO Bioavailability
PublikacjaCardiovascular diseases (CVDs) are the leading cause of death worldwide. The initial stage of CVDs is characterized by endothelial dysfunction, defined as the limited bioavailability of nitric oxide (NO). Thus, any factors that interfere with the synthesis or metabolism of NO in endothelial cells are involved in CVD pathogenesis. It is well established that hypoxia is both the triggering factor as well as the accompanying factor...
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Procognitive activity of nitric oxide inhibitors and donors in animal models
PublikacjaNitric oxide is a small gaseous molecule that plays important roles in the majority of biological functions. Impairments of NO-related pathways contribute to the majority of neurological disorders, such as Alzheimer’s disease (AD), and mental disorders, such as schizophrenia. Cognitive decline is one of the most serious impairments accompanying both AD and schizophrenia. In the present study, the activities of NO donors, slow (spermine...
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‘Acridines’ as New Horizons in Antifungal Treatment
PublikacjaFrequent fungal infections in immunocompromised patients and mortality due to invasive mycosis are important clinical problems. Opportunistic pathogenic Candida species remain one of the leading causes of systemic mycosis worldwide. The repertoire of antifungal chemotherapeutic agents is very limited. Although new antifungal drugs such as lanosterol 14α-demethylase and β-glucan synthase inhibitors have been introduced into clinical...
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Suppressors of lapC mutation identify new regulators of LpxC, which mediates the first committed step in lipopolysaccharide biosynthesis
PublikacjaGram-negative bacteria, such as Escherichia coli, are characterized by an asymmetric outer membrane (OM) with lipopolysaccharide (LPS) located in the outer leaflet and phospholipids facing the inner leaflet. E. coli recruits LPS assembly proteins LapB, LapC and LapD in concert with FtsH protease to ensure a balanced biosynthesis of LPS and phospholipids. We recently reported that bacteria either lacking the periplasmic domain of...
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Important Facts and Observations about Pairwise Comparisons (the special issue edition)
PublikacjaThis study has been inspired by numerous requests for clarification from researchers who often confuse Saaty’s Analytic Hierarchy Process (AHP) with the pairwise comparisons (PC) method, taking AHP as the only representation of PC. This study should be regarded as an interpretation and clarification of past investigations of PC. In addition, this article is a reflection on general PC research at a higher level of abstraction: the...
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Novel therapeutic compound acridine–retrotuftsin action on biological forms of melanoma and neuroblastoma
PublikacjaPURPOSE: As a continuation of our search for anticancer agents, we have synthesized a new acridine-retrotuftsin analog HClx9-[Arg(NO2)-Pro-Lys-Thr-OCH3]-1-nitroacridine (named ART) and have evaluated its activity against melanoma and neuroblastoma lines. Both tumors develop from cells (melanocytes, neurons) of neuroectodermal origin, and both are tumors with high heterogeneity and unsatisfactory susceptibility to chemotherapies....
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Mechanochemically synthesized Mn3O4@β-cyclodextrin mediates efficient electron transfer process for peroxymonosulfate activation
PublikacjaThe rational surface engineering of heterogeneous catalysts is of great significance in advanced oxidation processes (AOPs) for eliminating refractory contaminants but remains challenging. In this study, β-cyclodextrin modified Mn3O4 (Mn3O4@β-CD) was prepared through a mechanochemical approach for peroxymonosulfate (PMS) activation, which achieved efficient bisphenol A (BPA) removal via electron transfer process (ETP). The reactive...
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Ab initio and experimental studies of polarization and polarization related fields in nitrides and nitride structures
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Maximizing the output power of magnetically geared generator in low-speed applications using subdomain modeling and particle swarm optimization
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Volume optimization of high-speed surface-mounted permanent magnet synchronous motor based on sequential quadratic programming technique and analytical solution
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Thermal analysis and experimental verification of permanent magnet synchronous motor by combining lumped-parameter thermal networks with analytical method
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Catalytic Asymmetric Synthesis of Isochroman Derivatives
PublikacjaThe isochroman scaffold constitutes an important structural unit, which is present in various bioactive natural products and synthetic pharmaceutical compounds exhibiting wide arrays of biological properties. Hence the synthesis of this class of heterocyclic compounds in a stereoselective fashion is highly significant and desirable. In the last decade, a substantial advancement has been witnessed ln the catalytic asymmetric...
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Turmeric nanofiber-encapsulated natural product formulation act as a phytogenic feed additive—A study in broilers on growth performance, biochemical indices of blood, and E. coli in cecum
PublikacjaA phytogenic feed additive (PFA) formulation was prepared with bioactive molecules—curcuminoids, gingerol, and carvacrol by encapsulating in nanofiber isolated from turmeric spent (turmeric nanofiber, TNF). This formulation was completely characterized by scanning electron microscope, ultra performance liquid chromatography, and gas chromatography and evaluated for its efficacy. PFA-encapsulated TNF (PFA@TNF) considerably increased...
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Chloroacridine derivatives as potential anticancer agents which may act as tricarboxylic acid cycle enzyme inhibitors
PublikacjaThe chloroacridines affect biological forms of melanoma in different ways. Amelanotic (Ab) melanoma (with inhibited melanogenesis and higher malignancy) was particularly sensitive to the action of the chloroacridines. The Ab melanoma cells died through apoptosis and through death without caspase activation. Diminished activity of TAC enzymes was noticed among Ab melanoma cells together with ATP/NAD depletion, especially in the...
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Możliwości zastosowań, potencjalne źródła oraz ewolucja technologiczna sposobu otrzymywania trehalozy ze szczególnym uwzględnieniem enzymu syntazy trehalozy [EC 5.4.99.16]
PublikacjaJedna z wiodących gałęzi współczesnej biotechnologii opiera się na produkcji białek – przede wszystkim enzymów. Są one powszechnie wykorzystywane: od przemysłu chemicznego poprzez przemysł spożywczy aż po medycynę i życie codzienne (czy ktoś wyobraża sobie w dzisiejszych czasach proszek do prania „bez enzymu”). Przed rozwojem nowoczesnych metod biologii molekularnej i inżynierii genetycznej pozyskiwano interesujące substancje z...
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Wróżenie ze ścieków. Projektowanie kanalizacji.
PublikacjaZmienione zasady projektowania kanalizacji sanitarnej jako knsekwencja zmian zużycia wody i odpływu ścieków. aktualizacja wskaźników projektowych w konsekwencji aktualnej wytycznej ATV A118 (edycja 1999).
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Chromogenic macrocyclic derivatives of azoles - synthesis and properties,
PublikacjaNew azocrown ethers comprising imidazoles in the macrocycle have been synthesized. Imidazole, 2-methyl-, 4-methyl-, and 4-phenylimidazole were incorporated to form macrocyclic units by coupling with the appropriate bis-diazonium salts. The syntheseswere performed under high dilution conditions. The X-ray structure of a water adduct of the 21-membered crown ether derivative of 4-methylimidazole 8 has been solved. Metal...
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Azomacrocyclic derivatives of imidazole: synthesis, structure, and metal ion complexation properties
PublikacjaNew azocrown ethers comprising imidazoles in the macrocycle have been synthesized. Imidazole, 2-methyl-, 4-methyl-, and 4-phenylimidazole were incorporated to form macrocyclic units by coupling with the appropriate bis-diazonium salts. The syntheseswere performed under high dilution conditions. The X-ray structure of a water adduct of the 21-membered crown ether derivative of 4-methylimidazole 8 has been solved. Metal...
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4-(Cyclic-amidino)phenols. Preparation and Use in a Diamidine Synthesis
PublikacjaThe Pinner synthesis was applied to the prepn. of phenols 4-substituted with cyclic amidines in high yields from readily available 4-HOC6H4C(OMe):NH.HCl and aliph. diamines. An alternative attempt was made to convert 4-HOC6H4CSNH2 to 4-(1,4,5,6-tetrahydro-5-hydroxy-2-pyrimidinyl)phenol. A procedure for the prepn. of 3,6-bis(4-hydroxyphenyl)-1,2,4,5-tetrazine is reported. The syntheses of 2,4-bis[4-(4,5-dihydro-1H-imidazol-2-yl)phenoxy]pyrimidine...
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Synthesis and Spectroscopic Properties of New Bis-tetrazoles
PublikacjaSyntheses of N,N'-phenyltetrazole podands link with aliphatic chains containing oxygen, nitrogen and sulphur atoms, are described. The complexing properties of these compounds towards metal cations (Fe2+, Cu2+, Zn2+, Co2+, Ni2+) were investigated by absorption and infrared spectroscopy. The UV-Vis titrations were performed to estimate the stability constant values of the respective complexes with Cu2+ ion. Changes in UV-Vis absorption...
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Enhancing Security of Advanced Metering Infrastructure by Introducing Threshold Attendance Protocol
PublikacjaThe industry pushes towards smart grid systems in order to resolve current limitations of the unidirectional legacy power grid infrastructure. By introducing Advanced Metering Infrastructure (AMI) as an integral part of the smart grid solution, the utility company obtains an invaluable tool to optimize its network, lower the operational costs, and improve quality of service. Unfortunately, introducing two-way communication poses...
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Monitoring system of the road embankment
PublikacjaThe paper presents the monitoring system of the embankment supported on concrete columns and overlaid by a load transfer platform (LTP) with the embedded steel grid. This field investigation was to study the complex inter-action between the columns, the LTP layer, and steel reinforcement via full-scale in situ measurements during erection of the embankment. The study was focused on the behaviour of steel reinforcement and the behaviour...
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Structure and properties of liquid Al–Cu alloys: Empirical potentials compared
PublikacjaWe report on the structure and mass transport properties of liquid Al–Cu alloys predicted by two recently-developed empirical many-body potentials: MEAM (Jelinek et al., 2012) and EAM-ADP (Apostol and Mishin, 2011), and by the well-known Gupta potential. Total and partial pair correlation functions, angular distribution functions, densities, coordination numbers and self-diffusion coefficients are compared with published experimental...
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Stimulated by cyclodextrins high yield synthesis of azocrown analogues comprising pyrrole or imidazole residues
PublikacjaThe influence of cyclodextrins (CDs) on the formation of azocrown ethers comprising pyrrole, imidazole and substituted imidazole has been studied. Pyrrole, imidazole, 2-methyl-, 4-methyl- and 4-phenylimidazole were coupled with bisdiazonium salts derived from bis-1,5-(2-aminophenoxy)-3-oxapentane or bis-1,8-(2-aminophenoxy)-3,6-dioxaoctane to form macrocyclic compounds with two azo units. The syntheses were performed under standard...
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Tester wydajności centralek IP PABX
PublikacjaW artykule przedstawiono koncepcję i sposób realizacji testera wydajności centralek IP PABX pracujących z protokołem SIP i RTP. Jako kryterium określania wydajności przyjęto spełnienie granicznych wartości wielkości opisujących GoS i QoS. Zaproponowano architekturę testera wydajności, jego podział na bloki funkcjonalne i ich opis. Omówiono sposób generacji strumieni SIP i RTP koniecznych do badania wydajności centralek IP PABX,...
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Endothelial dysfunction due to eNOS uncoupling: molecular mechanisms as potential therapeutic targets
PublikacjaNitric oxide (NO) is one of the most important molecules released by endothelial cells, and its antiatherogenic properties support cardiovascular homeostasis. Diminished NO bioavailability is a common hallmark of endothelial dysfunction underlying the patho‑ genesis of the cardiovascular disease. Vascular NO is synthesized by endothelial nitric oxide synthase (eNOS) from the substrate L‑arginine (L‑Arg), with tetrahydrobiopterin...
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Ball milling treatment of Mn3O4 regulates electron transfer pathway for peroxymonosulfate activation
PublikacjaHeterogeneous metal catalysts have attracted considerable interest in advanced oxidation processes (AOPs) for wastewater treatment by activating peroxymonosulfate (PMS). However, it remains challenging to the rational design of efficient reaction pathway for high-performance contaminants removal by regulating the inherent structure of metal oxides. Herein, a high-energy ball milling method was employed to modulate the electronic...
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Teloxantron inhibits the processivity of telomerase with preferential DNA damage on telomeres
PublikacjaTelomerase reactivation is one of the hallmarks of cancer, which plays an important role in cellular immortalization and the development and progression of the tumor. Chemical telomerase inhibitors have been shown to trigger replicative senescence and apoptotic cell death both in vitro and in vivo. Due to its upregulation in various cancers, telomerase is considered a potential target in cancer therapy. In this study, we identified...
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Zastosowanie spektrofotometrii w bliskiej podczerwieni NIR w kontroli i technologii produkcji leków
PublikacjaMetody wykorzystywane w badaniach trwałości mają na celu w prosty i stosunkowoszybki sposób ilościowo ocenić zmiany zachodzące w związkach chemicznych będącychsubstancjami czynnymi leków. Właściwy dobór metody analitycznej jest więc niezwyklewaŜnym aspektem pracy. Badaniom fotochemicznego rozkładu poddano chlorowodorekranitydyny oraz leki zawierające tę substancję. Zmiany w substancjach poddanych ekspozycji