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Search results for: CORROSION DEGRADATION
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Hydrogen induced degradation of structural steel exposed to the technical liquid hydrocarbons
PublicationSusceptibility of the differently heat treated 26H2MF steel to stress corrosion cracking has been evaluated in the constant strain rate tension tests done at the strain rate 10-6s-1 and in the constant load tests done at the 0,98 of fracture load. The boiler fuel and the aged mineral oil at 135C and 80C respectively, have been used as the aggressive environments.
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Hydrogen Damage in Superaustenitic 904L Stainless Steels
Publicationresults on the influence of hydrogen on corrosion resistance and of hydrogen embrittlement of 904L superaustenitic stainless steel were investigated. The cracking behavior was studied by performing a slow strain rate test in synthetic seawater under varying cathodic polarization conditions. The results showed that the steel’s plasticity varied with the applied cathodic current density. Significant reductions in ductility were found,...
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Metal dusting phenomena of 501 AISI furnace tubes in refinery fractional distillation unit
PublicationThe purpose of this investigation was to conduct the failure analysis of 501 AISI furnace tubes places before distillation column in fractional distillation unit. The investigated furnace tubes were planned to work for ten years however after just two years of exploitation <30% of the material left. The observed corrosion process had the intense and complex character. The well-adhered shiny black deposits and deep, round pits were...
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Conducting polymers for biodegradable metallic implants
PublicationNowadays permanent metallic cardiovascular stents are long-term implants. The long-time presence of such an implant in human body can cause overgrowth of tissue within the treated portion of the vessel, blockage of the circulatory system and many other clinical complications, such as thrombosis, prolonged physical irritations or chronic inflammation. Therefore, in recent years, there is an interest to create biodegradable metallic...
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X-Ray Computer Tomography Study of Degradation of the Zircaloy-2 Tubes Oxidized at High Temperatures
PublicationThe investigations of high-temperature oxidation of zirconium alloys, applied for fuel pellets in nuclear power plants, are usually limited to oxidation kinetics, phase transformations and microstructural characterization. The purpose of this research was to characterize the degradation phenomena occurring within oxide layer and at the interface oxide/metal, on internal and external Zircaloy-2 tube...
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Random field modelling of mechanical behaviour of corroded thin steel plate specimens
PublicationThe objective of this work is to explore the possibility of corrosion degradation modelling of thin steel plate specimens with the use of random field approach. The mechanical properties are obtained via the nonlinear Finite Element Analysis with the use of an explicit dynamic solver. The fully nonlinear material model is adopted to obtain the proper stress-strain response. Sensitivity analysis considering the main statistical...
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THE ROLE OF THIN FUNCTIONAL LAYERS IN SOLID OXIDE FUEL CELLS
PublicationWidespread commercialization of solid oxide fuel cells requires lowering its cost. It is generally accepted that to lower the cost of solid oxide fuel cells it is necessary to use metal alloys as interconnectors and, consequently, lower its operating temperature to slow down interconnectors degradation. As a result the area specific resistance of the cathodes should be lowered to sustain the performance of the cells. In order to...
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Model of noise sources in supercapacitors
PublicationThe paper presents detailed model of noise sources in supercapacitors. Noise phenomena observed in supercapacitors may be used as a diagnostic tool for assessment of supercapacitor quality or degradation mechanisms (e.g. corrosion of the electrodes or cloggin g up the pores) during ageing. Therefore, it is important to consider where noise is generated. The equivalent circuit of noise sources existing...
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Properties of nano-Fe3O4 incorporated epoxy coatings from Cure Index perspective
PublicationThe mission of an advanced epoxy-based nanocomposite coating is to provide a given substrate with protection against an unwelcome guest; e.g. corrosive molecules/media, environmental stress, flame, thermal degradation or microorganisms. In such systems, the degree to which superior properties can be guaranteed depends on the state of network formation in the epoxy in the presence of nanoparticles. For low-filled epoxy nanocomposite coatings,...
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Biocompatibility and bioactivity of load-bearing metallic implants
PublicationThe main objective of here presented research is to develop the titanium (Ti) alloy base composite materials possessing better biocompatibility, longer lifetime and bioactivity behaviour for load-bearing implants, e.g. hip joint and knee joint endoprosthesis. The development of such materials is performed through: modeling the material behaviour in biological environment in long time and developing of new procedures for such evaluation;...
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Experimental and numerical investigations of ultimate strength of imperfect stiffened plates of different slenderness
PublicationThe objective of this study is to analyse the behaviour of compressed stiffened plates of different slenderness using experimental and numerical methods. The presented results are part of a long-term project to investigate the ultimate strength of geometrically imperfect structures subjected to different degradation phenomena, including corrosion degradation and locked cracks. Several specimens were subjected to a uniaxial compressive...
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Electrophoretic deposition and characterization of composite chitosan/Eudragit E 100 or poly(4-vinylpyridine)/mesoporous bioactive glass nanoparticles coatings on pre-treated titanium for implant applications
PublicationTitanium implants are surface-modified to achieve bioactivity and often antibacterial properties. Such surface coatings may increase corrosion degradation and be weakly attached to the substrate. In the present research, biodegradable composite coatings, investigated so far as smart environment-sensitive, slowly releasing silver to the implant neighborhood, were produced as a combination of chitosan (CS) with Eudragit E 100 (EE100)...
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Investigation of the 0.4C-35Cr-45Ni-Nb Alloy after Service in High-Temperature Steam and Hydrocarbons Environment
PublicationThe paper presents the results of investigation of the 0.4C-35Cr-45Ni-Nb alloy, which operated in the cracked hydrocarbon feeds and dilution steam at 1125 C. The material originated from the pyrolytic furnace coil tubes, of which internal walls were in contact with the aforementioned medium, whereas the external walls were in contact with the flue gases. The examination included metallographic and mechanical tests on the material...
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Effect of Storage Conditions of Rutile Flux Cored Welding Wires on Properties of Welds
PublicationThe influence of storage locations of two grades of rutile flux cored welding wires on their surface condition and the strength of the welds made with them were studied. Wires were stored in real urban conditions (Gdańsk and Katowice) for 1 month, simultaneously recording changes in conditions: temperature and relative humidity of the environment. Visual tests of wires in the delivered and stored condition as well as visual and...
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Structural Reliability Assessment Of Corroded Tanker Ship Based On Experimentally Estimated Ultimate Strength
PublicationThis work deals with the reliability assessment of a tanker ship hull structure subjected to a vertical bending moment and corrosion degradation. The progressive collapse and ultimate load carrying capacity are estimated based on experimentally tested scaled box-shaped-specimens. The translation of the strength estimate of the scaled specimen to the real tanker ship hull structure is performed based on the dimensional theory developing...
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Mn-Co spinel coatings on Crofer 22 APU by electrophoretic deposition: Up scaling, performance in SOFC stack at 850 °C and compositional modifications
PublicationCeramic coatings for metallic interconnects play a key role in limiting corrosion and chromium evaporation in solid oxide cells. This study presents the upscaling of the electrophoretic deposition (EPD) technique to process Mn-Co spinels on real-dimension Crofer 22 APU interconnects and the test in a SOFC stack. Area specific resistance of long-term test conducted for 5000 h at 850 °C demonstrated that two-steps sintering has a...
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Correlation between partial inhibition of hydrogen evolution using thiourea and catalytic activity of AB5-type hydrogen storage alloy towards borohydride electrooxidation
PublicationDirect borohydride fuel cells (DBFCs) are devices which directly convert the chemical energy stored in the borohydride ion and oxidant into electrical energy as a result of redox reactions. Unfortunately, a significant amount of fuel is lost as a result of the undesirable hydrolysis reaction. The selection of an efficient borohydride hydrolysis inhibitor requires detailed knowledge regarding the interaction mechanism between the...
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A simplified method to assess the impact of ship-to-ship collision on the risk of tanker ship hull girder breaking accounting for the effect of ageing
PublicationOne of the most critical structural failures is the exceedance of the ship hull girder’s ultimate strength, which may result in hull breaking, and subsequent severe consequences, including loss of life and property as well as environmental damage in case of an oil spill. A cause for such loss of structural continuity can be triggered by a collision with another vessel. In addition, the ageing mechanisms of the hull structure could...
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Hydrogen degradation of structural steels in technical hydrocarbon liquids
PublicationDla stali stopowych przeprowadzono badania absorpcji wodoru, mechaniczno-korozyjne przy stałej małej prędkości odkształcania, przy stałym obciążeniu i przy obciążeniu cyklicznie-zmiennym. Środowiskiem było paliwo kotłowe, przepracowany olej mineralny oraz gliceryna. Stwierdzono, iż pochłonięty wodór nie powoduje przedwczesnego zniszczenia stali poddanych działaniu stałego obciążenia ponizej granicy plastyczności oraz, że zaabsorbowany...
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Wpływ azotowania jarzeniowego i laserowego nadtapiania na odporność kawitacyjną stali X5CrNi18-10
PublicationNierdzewne stale austenityczne charakteryzują się doskonałą odpornością korozyjną, aczkolwiek niskimi właściwościami mechanicznymi. W wielu przypadkach ogranicza to ich eksploatację w warunkach przemysłowych. Ponadto, nierdzewne stale austenityczne są wrażliwe na korozję lokalną w obecności jonów halogenkowych. Technologie materiałowe, które dają potencjalne możliwości otrzymywania korzystnego wpływu na właściwości mechaniczne...
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Assessment of Supercapacitor’s Quality by Means of Low Frequency Noise
PublicationLow frequency noise is a well-known tool for quality and reliability assessment of electronic devices. This phenomenon is observed in different electrochemical devices as well (e.g., smart windows, electrochemical corrosion processes). Thus, we can assume that the same tool can be used to asses quality of supercapacitors. Their quality is usually determined only by capacitance and/or equivalent series resistance (ESR), or impedance....
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Determination of stepped plate thickness distribution using guided waves and compressed sensing approach
PublicationGuided waves recently have attracted significant interest as a very promising research area. The signals registered by a specially designed sensor network are processed to assess the state of the tested structure. Despite the constant development of novel damage detection algorithms employing guided waves, the phenomenon of wave propagation still needs detailed recognizing and understanding for the further progress of non-destructive...
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Influence of CeO2 and TiO2 Particles on Physicochemical Properties of Composite Nickel Coatings Electrodeposited at Ambient Temperature
PublicationThe Ni-TiO2 and Ni-CeO2 composite coatings with varying hydrophilic/hydrophobic characteristics were fabricated by the electrodeposition method from a tartrate electrolyte at ambient temperature. To meet the requirements of tight regulation by the European Chemicals Agency classifying H3BO3 as a substance of very high concern, Rochelle salt was utilized as a buffer solution instead. The novelty of this study was to implement a...
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The impedance method of monitoring the degradation of rubber linings in applications where progressive deterioration is the predominant failure mechanism
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Application of the corrosion tester in corrosion tests using the acoustic emission method.
PublicationThe article presents an innovative method of corrosion tests using the acoustic emission method and the corrosion tester. The problem of corrosion occurring in ballast tanks and tanks carrying petroleum products is discussed. The acoustic method is presented which, due to the use of a unique corrosion tester, is used to monitor the course of corrosion processes in steel. The principle of operation of the corrosion tester, its construction...
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Corrosion Monitoring in Petroleum Installations—Practical Analysis of the Methods
PublicationThis paper presents the most typical corrosion mechanisms occurring in the petroleum industry. The methods of corrosion monitoring are described for particular corrosion mechanisms. The field and scope of the application of given corrosion-monitoring methods are provided in detail. The main advantages and disadvantages of particular methods are highlighted. Measurement difficulties and obstacles are identified and widely discussed...
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Corrosion mechanisms in columns for atmospheric distillation of crude oil
PublicationThe paper presents the most common corrosion processes occurring in the columns for atmospheric distillation of crude oil. It describes the mechanisms leading to formation of the chemical compounds, which contribute to corrosion phenomena. The main technological factors influencing corrosion processes have been indicated. The paper also presents the interactions between particular corrosion mechanisms resulting in acceleration...
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DETERMINATION OF THE EFFECT OF ENVIRONMENTAL FACTORS ON THE CORROSION OF WATER DISTRIBUTION SYSTEM BASED ON ANALYSIS OF ON-LINE CORROSION MONITORING RESULTS
PublicationCorrosion of water distribution system is a significant issue causing problems with quality, safety and continuity of distribution. The changes of corrosion rates of the water distribution systems in Cracow made of carbon steel were investigated by analysis of online corrosion monitoring system results. Corrosion rates were determined using the linear polarization method. The impact of rain, temperatures, conductivity, dissolved...
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Corrosion hazards and inhibitor protection in the seawater injection system on the Baltic sea rig
PublicationOil extraction efficiency in LOTOS Petrobaltic Company is increased by means of injection of seawater into an oilfield aquifer, which is implemented on the Baltic Beta rig, operating on the Baltic Sea. Operational experience has shown a significant degree of corrosion aggressiveness in the injected water, which necessitates frequent repairs of the seawater injection installation. Evaluation of the corrosion phenomena is crucial...
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Multi-sensor monitoring of the corrosion rate and the assessment of the efficiency of a corrosion inhibitor in utility water installations
PublicationThis paper presents an implementation of the monitoring of the corrosion rate and the assessment of the efficiency of a corrosion inhibitor in a utility water installation using an automated corrosion monitoring system. Due to the fact that the corrosion inhibitor was added to water intended for human consumption, it was necessary to build a multi-sensor monitoring system. In order to implement corrosion monitoring using a linear...
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Corrosion performance of super duplex stainless steel and pipeline steel dissimilar welded joints: a comprehensive investigation for marine structures
PublicationThis study investigates the corrosion behavior of dissimilar gas tungsten arc (GTA) welded joints between super duplex stainless steel (sDSS 2507) and pipeline steel (X-70) using electrochemical and immersion corrosion tests. The GTA welds were fabricated using ER2594 and ER309L fller metals. The study examined the electrochemical characteristics and continuous corrosion behavior of samples extracted from various zones of the weldments...
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The protection and monitoring of a distribution piping network for potable water supply
PublicationPurpose – The purpose of this paper is to implement the corrosion protection method for steel pipes used in a municipal water-pipe network. Results of an inhibitor protection system installed on the system are presented. Inhibitor protection was required due to the high corrosivity of the water collected by a surface intake, which had resulted in a large number of failures and low water quality, due to the presence of corrosion...
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Determination of pitting corrosion stage of stainless steel by galvanodynamic impedance spectroscopy
PublicationThis paper investigates the methodology for differentiation of multistep process of pitting corrosion of AISI 304 stainless steel in the environment of iron (III) chloride. Measurements were performed using Galvanodynamic Electrochemical Impedance Spectroscopy (GDEIS). Application of this methodology allowed monitoring of natural corrosion process without external current (IDC = 0A) nor potential perturbation of the system. Applied...
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Novel fast non-linear electrochemical impedance method for corrosion investigations
PublicationThe paper presents a novel approach to corrosion rate monitoring using non-linear electrochemical impedance spectroscopy. The authors propose a new variant of non-linear impedance measurement using amplitude-modulated multi-frequency ac perturbation signal. It allows shortening of measurement duration so it is possible to monitor corrosion rate of the systems experiencing rapid changes. In this way a limitation resulting from lack...
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Corrosivity of environment and the current state of the steel elements at the former Auschwitz concentration camp
PublicationThe objective of this study was to assess corrosivity of the atmospheric environment in the former Auschwitz I and Auschwitz II-Birkenau concentration and extermination camp, and to identify the protective properties of existing corrosion products in order to estimate the actual corrosion rate of original steel elements located there. The current atmospheric corrosivity of the former Auschwitz camp, specified during one year of exposure...
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Instantaneous Impedance Analysis of Non-Stationary Corrosion Process: a Case Study of Carbon Steel in 1M HCl
PublicationThe paper concerns the problem of evaluation of stationarity of carbon steel corrosion in 1M HCl. Comparison of corrosion rate with addition of corrosion inhibitor to the reference measurement is the most often used way of evaluating inhibitor efficiency. Such an approach is valid only if corrosion rate is a stationary process. Two complementary techniques were used simultaneously: volumetric analysis of evolved hydrogen and instantaneous...
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Determination of causes of accelerated local corrosion of austenitic steels in water supply systems
PublicationThis paper concerns an inspection of a water supply system, made of AISI 304 steel, which showed signs of local corrosion at the weld. Such corrosion caused material perforation after very short periods of operation. It was revealed that steel was sensitised during the welding process. It was also proven that chromium micro-segregation occurred in the alloy leading to galvanic cell formation which initialised the process of pitting...
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Properties of surface layers of duplex stainless steel after burnishing processes
PublicationStress corrosion cracking resistance of cold worked layers of 25 Cr duplex stainless steel grade UR52N+ has been investigated. The surface layers were performed through burnishing treatment. The residual stresses at surface layers were determined using grazing angle incidence X-ray diffraction method (g-sin2 Ψ). Corrosion tests were performed with the use of Slow Strain Rate Test technique in boiling 35% MgCl2 solution. It has...
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New Method of Non-Linear Electrochemical Impedance Spectroscopy with an Amplitude-Modulated Perturbation Signal
PublicationThe paper presents a new method of non-linear electrochemical impedance spectroscopy (NLEIS), which allows fast and nondestructive evaluation of the corrosion rate and determination of the Tafel coefficients values for a corrosion system under investigation. This method employs amplitude modulation of the ac perturbation signal. The study demonstrated that it was possible to obtain impedance characteristic as a function of the...
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Corrosion monitoring by harmonic analysis in aqueous environments
PublicationThis paper presents tests concerning the rate of corrosion in non-alloy steel (type S235JR) in an aqueous environment, with an additive of sodium chloride by means of polarization resistance measurements and harmonic analysis. The tests have been carried out for steel samples exposed to the testing environment for six weeks, in order to obtain a constant rate of corrosion in the function of time. The measurements have aimed at...
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Research on causes of corrosion in the municipal water supply system
PublicationThis paper presents results of failure analysis study to characterize the corrosion damage that occurred in the water supply system in Krakow. This analysis includes: electrochemical noise, linear polarization and resistometric measurements. Water aggressiveness of four water intakes was defined using Langelier and Ryznar indices. Results from this indices did not reveal the causes of considerable corrosion losses in water systems....
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Electrochemical investigations on corosivity of de-icing liquids for railway infrastructure
PublicationThe paper presents the results of electrochemical tests of the de-icing fluid for railway infrastructure. DC and AC electrochemical tests were performed to determine the corrosion rates of structural steel, cast iron and aluminium in the newly produced fluid. The results were compared with the corrosion rates of the same materials in the fluid without corrosion inhibitors. The obtained test results indicate a low corrosion risk...
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Evaluation of organic coating systems for corrosion protection of industrial equipment using impedance spectroscopy
PublicationThe high economic impact of corrosion can be reduced by enhanced corrosion management and prevention based on appropriate means. This applies in particular to the protection of structures with organic protective coatings. Steel is subject to corrosion that reduces its service life and leads to destruction in most severe cases. The application of paints to metallic objects for corrosion control has been known for a long time and...
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Effect of the Post-Weld Surface Condition on the Corrosion Resistance of Austenitic Stainless Steel AISI 304
PublicationSurfaces of welded elements made of corrosion-resistant (stainless) steels develop temper colours. The removal of thickened oxide layers off steels exposed to temperatures below 300°C is necessary and entails the restoring of high corrosion resistance of the stainless steel. The article presents tests concerned with the effect of a method applied to remove post-weld temper on the corrosion resistance of austenitic stainless steel...
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Application of quartz crystal microbalance and dynamic impedance spectroscopy to the study of copper corrosion inhibitors
PublicationThe study investigates the application of Dynamic Electrochemical Impedance Spectroscopy (DEIS) and Electrochemical Quartz Crystal Microbalance (EQCM) techniques to examine the corrosion inhibition of copper by Benzotriazole and Sodium Folate in a 0.1 M NaCl solution. DEIS, an advanced version of Electrochemical Impedance Spectroscopy (EIS), allows for real-time monitoring of non-stationary electrochemical systems,...
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An investigation of microstructural basis for corrosion behavior of Al-CNT composites fabricated by SPS
PublicationIn this research effect of the addition of multi-wall carbon nanotubes (MWCNTs) as additive powder on microstructure and corrosion behavior of fabricated Al-CNT composites was studied. The aluminum powder and CNTs were mixed with high energy planetary ball-mill. It is observed that by increasing milling time, the uniformity of CNTs on aluminum matrix and consequently corrosion resistance of Al-CNT composite is increased. On the...
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Influence of pitting corrosion on fatigue and corrosion fatigue of ship and offshore structures. Part II: Load - pit crack interaction
PublicationIn the paper has been discussed influence of stresses on general corrosion rate and corrosion pit nucleation and growth rate, whose presence has been questioned by some authors but accepted by most of them. Influence of pit walls roughness on fatigue life of a plate suffering pit corrosion and presence of so called "non damaging" pits which never lead to initiation of fatigue crack, has been presented. Possibility of prediction...
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Effect of Thermal Shock During Legionella Bacteria Removal on the Corrosion Properties of Zinc-Coated Steel Pipes
PublicationThe purpose of this investigation was to conduct the failure analysis of a water-supply system made from zinc-coated steel. The observed corrosion process had an intense and complex character. The brownish deposits and perforations were present after 2-3 years of exploitation. The electrochemical study based on the Tafel polarization, corrosion potential monitoring, and electrochemical impedance spectroscopy together with microscopic...
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The effect of pre-hydrogen charging on corrosion behaviour of superduplex stainless steel welded joints
PublicationThe paper presents results of research undertaken to determine the influence of hydrogen on passivity and corrosion resistance of 2507 super duplex stainless steel welded joints. Butt welded joints were made with low heat input using flux corded arc welding (FCAW) method. Coupons of 5.0 x 5.0 mm were cut from the welded joints containing weld metal (WM), heat affected zone (HAZ) and parent metal (PM). Hydrogen was introduced...
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Corrosion monitoring as a factor increasing the safety of hydrotechnical infrastructure
PublicationWater distribution systems at KGHM S.A. are of great importance for the efficient production of copper and environmental protection. For failures leading to perforation and leakage, the corrosion processes are responsible. This paper aims to assess corrosion on the basis of the analysis of the exposure of the Hydrotechnical Plant pipelines. To this end, the system of transfer and deposition of post-flotation waste as well as the...