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Search results for: Heavy Metal Stress
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Influence of alkali metal cations on the photoactivity of crystalline and exfoliated amorphous WO3 – photointercalation phenomenon
PublicationIn order to investigate the effect of photointercalation on photoelectrochemical properties, two types of WO3-based photoanodes, bulk and exfoliated have been prepared and investigated. An aqueous exfoliation method is introduced for the simple fabrication of amorphous and hydrated WO3 nanomaterial using commercial bulk WO3 precursor. The comparison of obtained material with bulk WO3 was performed using Raman, UV–vis, and XPS as...
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Application of the Barkhausen effect probe with adjustable m agnetic field direction for stress state determination in the P91 ste el pipe
PublicationThe paper presents the results of application of a novel Barkhausen effect (BE) probe with adjustable magnetizing field direction for the stress level evaluation in ferromagnetic materials. The investigated sample was in a form of a pipe, made of P91 steel that was anisotropic due to the production process. The measurements were performed before and after welding, revealing the influence of welding process on the residual stress...
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A Review on Metal–Organic Framework as a Promising Catalyst for Biodiesel Production ENERGY & FUELS
PublicationThe rapid depletion of fossil-derived fuels along with rising environmental pollution have motivated academics and manufacturers to pursue more environmentally friendly and sustainable energy options in today’s globe. Biodiesel has developed as an ecologically favorable alternative. However, the mass manufacturing of biodiesel on an industrial scale confronts substantial cost and pricing challenges. To address this issue, high-efficiency...
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Diiodo-BODIPY Sensitizing of the [Mo3S13]2– Cluster for Noble-Metal-Free Visible-Light-Driven Hydrogen Evolution within a Polyampholytic Matrix
PublicationWe report on a photocatalytic setup that utilizes the organic photosensitizer (PS) diiodo-BODIPY and the non-precious-metal-based hydrogen evolution reaction (HER) catalyst (NH4)2[Mo3S13] together with a polyampholytic unimolecular matrix poly(dehydroalanine)-graft-poly(ethyleneglycol) (PDha-g-PEG) in aqueous media. The system shows exceptionally high performance with turnover numbers (TON > 7300) and turnover frequencies (TOF...
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Stress-driven nonlocal elasticity for nonlinear vibration characteristics of carbon/boron-nitride hetero-nanotube subject to magneto-thermal environment
PublicationStress-driven nonlocal theory of elasticity, in its differential form, is applied to investigate the nonlinear vibrational characteristics of a hetero-nanotube in magneto-thermal environment with the help of finite element method. In order to more precisely deal with the dynamic behavior of size-dependent nanotubes, a two-node beam element with six degrees-of freedom including the nodal values of the deflection, slope and curvature...
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The effect of numerical 2D and 3D FEM element modelling on strain and stress distributions at laser weld notches in steel sandwich type panels
PublicationLike other means of transport, merchant ships face the problem of increasing requirements concerning the environment protection, which, among other issues, implies the reduction of fuel consumption by the ship. Here, the conventional approach which consists in making use of higher strength steels to decrease the mass of the ship hull can be complemented by the use of new steel structures of sandwich panel type. However, the lack...
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Environmental characteristics of a tundra river system in Svalbard. Part 2: Chemical stress factors
PublicationBacterial communities in the Arctic environment are subject to multiple stress factors, including contaminants, although typically their concentrations are small. The Arctic contamination research has focused on persistent organic pollutants (POPs) because they are bioaccumulative, resistant to degradation and toxic for all organisms. Pollutants have entered the Arctic predominantly by atmospheric and oceanic long-range transport,...
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Photocatalytic activity of TiO2 loaded with metal clusters
PublicationTiO2 modyfikowano powierzchniowo klasterami metali: srebra, złota i platyny. Zbadano wpływ rodzaju i ilości wprowadzonej domieszki, oraz matrycy TiO2 na aktywność fotokatalityczną otrzymanych próbek. Fotoaktywność próbek badano w reakcji degradacji fenolu (Co = 0,21 mmol/dm3 ) w zakresie światła Vis lub UV. Najwyższą aktywność zaobserwowano dla fotokatalizatorów zawierających 2%Ag, 1%Au oraz 0,5%Pt. Po 60 min naświetlania światłem...
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Manufacturing of metal-polymer composites for medical applications
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Metal–Organic Frameworks in Green Analytical Chemistry
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Insulator to correlated metal transition inV1−xMoxO2
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Nature and properties of metal cations in aqueous solutions
PublicationOpisano i przeanalizowano budowę chemiczną, właściwości chemiczne i właściwości kinetyczne kationów metali w roztworach wodnych. Zwrócono uwagę na czynniki decydujące o właściwościach fizycznych roztworów.Wskazano na korelacje między stanami koordynacyjnymi soli i właściwościami roztworów. Zwrócono uwagę na nowe elementy chemii roztworów wodnych.
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Investigation and operation problems of metal tanks in Poland
PublicationThe paper consists of three parts concerned with steel cylindrical, vertical tank for liquid fuel. In the first part the present trends in tank design and building in Poland are described. The main are: · reduction of environment contamination danger caused by tank leakage and hydrocarbons evaporation, · increasing capacity of new tanks (100000 m3 and more) due to economic factor - reduction of steel amount per m3 of storage capacity....
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Metal salts reduction during parylenes polymerization
PublicationPublikacja o wynikach obliczeń kwantowych o możliwości redukcji niektórych soli metali przy pomocy rodników parylenu w czasie jego polimeryzacji.
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Metal–Organic Frameworks (MOFs) for Cancer Therapy
PublicationMOFs exhibit inherent extraordinary features for diverse applications ranging from catalysis, storage, and optics to chemosensory and biomedical science and technology. Several procedures including solvothermal, hydrothermal, mechanochemical, electrochemical, and ultrasound techniques have been used to synthesize MOFs with tailored features. A continued attempt has also been directed towards functionalizing MOFs via “post-synthetic...
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Metal-Organic Frameworks in Green Analytical Chemistry
PublicationTaking into consideration the rapid expansion of MOFs applications in the analytical chemistry area, it is important to evaluate the existing and future analytical MOF-based methods according to GAC principles. From this point of view, eco-friendly MOFs-based methods should include features such as: green design and synthesis of MOF, evaluation of toxicity issues of MOFs, and incorporation of MOFs in GAC methods. This Chapter will...
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Metal dusting phenomena of 501 AISI furnace tubes in refinery fractional distillation unit
PublicationThe purpose of this investigation was to conduct the failure analysis of 501 AISI furnace tubes places before distillation column in fractional distillation unit. The investigated furnace tubes were planned to work for ten years however after just two years of exploitation <30% of the material left. The observed corrosion process had the intense and complex character. The well-adhered shiny black deposits and deep, round pits were...
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ATTEMPT AT EVALUATING THE INFLUENCE OF BENDING STRESS ON SHAFT WEAR PROCESSES IN WATER LUBRICATED SLIDING BEARING WITH A RUBBER BUSHING
PublicationWater lubricated bearings find increasingly wide application in shipbuilding or hydro–power industry, the popularity stemming from their numerous advantages. Unfortunately, as it turns out, water lubricated bearings do not always meet expectations, as on occasion they become subject to intense, premature wear which requires costly repair. One of the still unexplained phenomena is the process of excessive bearing wear, in particular...
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The impact of stress and selected environmental factors on cows’ reproduction
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A Review: Structural Shape and Stress Control Techniques and their Applications
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The Stomatal Response of Ginkgo biloba L. to Water Stress
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Estimation of Oxidative Stress Markers in Chronic Kidney Disease
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Theoretical studies of the pyranose ring under mechanical stress
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Key Role of CRF in the Skin Stress Response System
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Oxidative stress in humans: validation of biomarkers of DNA damage
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Oxidative stress as a hidden cost of attractiveness in postmenopausal women
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Discussion:Horizontal stress increase induced by deep vibratory compaction
PublicationDeep compaction control of granular material using the results of field tests. The analysis include the CPTU and DMT tests terformed before and after compaction works.
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Police stress: The role of professional and organizational demands on burnout
PublicationJob demands - resources - empirical study in police officers
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Flow-induced stress corrosion failure of SS piping
PublicationPrzedstawiono uszkodzenie eksploatacyjne rurociągu ze stali austenitucznej typu 18Cr-10Ni-Ti w instalacji przepracowanych olejów napędowych w rafinerii ropy naftowej. Wyjaśniono mechanizm niszczenia środowiskowego stali w wyniku mechanicznego i elektrochemicznego działania strumieni procesowych.
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On stress singularity near the tip of a crack with surface stresses
PublicationIn the framework of the simplified linear Gurtin–Murdoch surface elasticity we discuss a singularity of stresses and displacements in the vicinity of a mode III crack. We show that inhomogeneity in surface elastic properties may significantly affect the solution and to change the order of singularity. We also demonstrate that implicitly or explicitly assumed symmetry of the problem may also lead to changes in solutions. Considering...
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Methods of Assessment of Metal Contamination in Bottom Sediments (Case Study: Straszyn Lake, Poland)
PublicationThe concentrations of six metals (Zn, Cu, Pb, Ni, Cr, and Cd) were investigated in bottom sediments of Straszyn Lake (North Poland). This study was designed to determine a total content of metals and to assess their mobility and bioavailability. The sequential extraction was used to fractionate metals into five fractions: exchangeable, bound to carbonates, bound to Fe–Mn oxides, bound to organic matter, and residual. The evaluation...
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The Metal-Free Regioselective Deuteration of 2-Methylquinolin-8-ol and 2,5-Dimethylquinolin-8-ol, Spectroscopic and Computational Studies
PublicationAbstract: Aim and Background: Introducing deuterium to a molecule is of interest to a wide variety of research, including investigation of reaction mechanisms or kinetics, analysis of drug metabolism, structural elucidation of molecules, and syntheses of isotopically labeled materials used for NMR spectroscopy and medicinal research. Objective: The transition-metal-free regioselective deuteration of 2-methylquinolin-8-ol...
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The role of aluminium in metal–organic frameworks derived carbon doped with cobalt in electrocatalytic oxygen evolution reaction
PublicationWater electrolysis is one of the most crucial processes in the development of new energy sources, where ultra-clean fuel is produced - hydrogen. Oxygen evolution reaction (OER) is the sluggish process of overall water splitting. Therefore, this study presents the design, characterization and electrochemical study of cobalt-based electrocatalysts embedded into porous carbons derived from an Al-metal–organic...
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Functionalization of the transition metal oxides FeO, CoO, and NiO with alkali metal atoms decreases their ionization potentials by 3–5 eV
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Miniaturized Metal-Mountable U-shaped Inductive-Coupling-Fed UHF RFID Tag Antenna with Defected Microstrip Surface
PublicationThis study presents a novel miniature ultra-high frequency (UHF) radio frequency identification (RFID) tag for metallic objects. Its arrangement includes a U-shaped feeder, which is inductively coupled to two E-type connected patches. Size reduction is achieved by means of utilizing the U-shaped feeder, and introducing a defection in the connection between the two E-type patches. The defection in the connection area between the...
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16S rDNA Pyrosequencing Analysis of Bacterial Community in Heavy Metals Polluted Soils
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Antiferromagnetic ordering and Kondo lattice behavior in moderate heavy fermion system Ce3NiSi3
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Heavy Metals in Waters and Sediments of Rivers Affected by Brown Coal Mine Waters
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XRF analysis of heavy metals contents in oak wood (Quercur robur L.)
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Distribution and concentration of heavy metals in ash during thermal process sewage sludge
PublicationKażdego roku na świecie, obserwuje się znaczący wzrost produkcji osadów ściekowych. Przykładowo w 2006 roku, w Polsce ich ilość osiągnęła 1 mln ton w przeliczeniu na sucha masę, w tym ok. połowa pochodziła z oczyszczalni komunalnych. Problem ich zagospodarowania stanowi przedmiot zainteresowania wielu instytucji zajmujących się ochroną środowiska, zarówno w Polsce, jak i na całym świecie. Ich dotychczasowe wykorzystania polegało...
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The application of acetylacetone for the separation of heavy metals in roadside soil belts by extraction methods
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Heavy metals partition between leachate and soilds the course of municipal sewage treatment.
PublicationAnalizowano zawarotści metali ciężkich w cieczy nadosadowej i zawiesinie w ściekach oraz osadach ściekowych po stabilizacji oraz odwadnianiu.Badania prowadzono w miejskiej oczyszczalni ścieków ''Wschód'' w Gdańsku.
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Retention of selected heavy metals: Cd, Cu, Pb in a hybrid wetland system
PublicationWykonano bilans wybranych metali ciężkich Cd2+, Pb2+, Cu2+ dla pilotowej oczyszczalni hydrofitowej w Przywidzu k. Gdańska. Wykazano m.i. że sorpcja była głównym mechanizmem odpowiedzialnym za usuwanie tych pierwiastków ze ścieków.
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Metal-Organic Frameworks-Based Sensors for the Detection of Toxins in Food: A Critical Mini-Review on the Applications and Mechanisms
PublicationUsing scientific technologies to detect toxins in food is significant to prevent food safety problems and protect people’s health. Recently, the rise of sensors has made rapid, efficient, and safe detection of food toxins possible. One of the key factors impacting the sensor’s performance is the nanomaterials employed. Metal-organic frameworks (MOFs), with high specific surface area, tunable composition, porous structure, and flexible...
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Changes in Epigenetic Patterns Related to DNA Replication in Vicia faba Root Meristem Cells under Cadmium-Induced Stress Conditions
PublicationExperiments on Vicia faba root meristem cells exposed to 150 µM cadmium chloride (CdCl2) were undertaken to analyse epigenetic changes, mainly with respect to DNA replication stress. Histone modifications examined by means of immunofluorescence labeling included: (1) acetylation of histone H3 on lysine 56 (H3K56Ac), involved in transcription, S phase, and response to DNA damage during DNA biosynthesis; (2) dimethylation of histone...
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Kinetics of Intermetallic Phase Precipitation in Manual Metal Arc Welded Duplex Stainless Steels
PublicationThe article presents the influence of heat treatment on the kinetics of transformations in lean duplex LDX2101 steel and a weld made of standard duplex 2209 material, which was welded by manual metal arc welding. Changes in the microstructure, hardness, and magnetic phase content were analyzed after heat treatment was conducted at a temperature of 800 °C for a period ranging from 15 to 1440 min. Light and scanning microscopy, Vickers...
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Electro-mechanical shear buckling of piezoelectric nanoplate using modified couple stress theory based on simplified first order shear deformation theory
PublicationThis paper studies the electro-mechanical shear buckling analysis of piezoelectric nanoplate using modified couple stress theory with various boundary conditions.In order to be taken electric effects into account, an external electric voltage is applied on the piezoelectric nanoplate. The simplified first order shear deformation theory (S-FSDT) has been employed and the governing differential equations have been obtained using...
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Corrigendum to “Fatigue life improvement using low transformation temperature weld material with measurement of residual stress” [Int. J. Fatigue 164 (2022) 107137]
PublicationWelding processes often produce high levels of tensile residual stress. Low transformation temperature (LTT) welding wires utilise phase transformation strains to overcome the thermal contraction of a cooling weld. In this paper, the residual stress within each weld was quantified using the milling/strain gauge method, being the strain change measured as the weldment was milled away. The fatigue tests were conducted under uniaxial...
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Experimental investigation on welding of 2.25 Cr-1.0 Mo steel with regulated metal deposition and GMAW technique incorporating metal-cored wires
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Preparation of methanation catalysts for high temperature SOEC by β-cyclodextrin-assisted impregnation of nano-CeO2 with transition metal oxides
PublicationThe aim of this work was to prepare and examine the catalytic activity of nanometric CeO2 decorated with transition metal oxides – Ni, Co, Cu, Fe and Mn – towards a high-temperature methanation process under SOEC CO2/H2O simulated co-electrolysis conditions. Samples were prepared using the wet impregnation method via the conventional process and with the addition of native cyclodextrin. The influence of β-cyclodextrin (βCD) onto...