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Search results for: ION SELECTIVE ELECTRODES
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Understanding the formation of metastable furan dication in collisions with ions
PublicationThis work relies on complementary theoretical and experimental studies of the processes induced by ion-furan collisions. Results of the Molecular Dynamics simulations and exploration of the energy profiles combined with coincidence mass spectrometry provide complete picture of the fragmentation of furan dication.
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Closing the loop: Upcycling secondary waste materials into nanoarchitectured carbon composites for the electrochemical degradation of pharmaceuticals
PublicationIn this study, we demonstrated the application of electrochemical oxidation as a safer and cleaner technology for minimizing the impact of pharmaceuticals in wastewaters, simultaneously mediated by upcycled secondary waste materials (SWMs)-derived electrodes, to further reduce their environmental impact. The modularity, scalability, ease of operation and reliability make electrochemical oxidation an ideal process for the destruction...
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Improvement of Oxygen Electrode Performance of Intermediate Temperature Solid Oxide Cells by Spray Pyrolysis Deposited Active Layers
PublicationIntermediate temperature solid oxide fuel cells oxygen electrodes are modified by active interfacial layers. Spray pyrolysis is used to produce thin (≈500 nm) layers of mixed ionic and electronic conductors: Sm0.5Sr0.5CoO3−δ (SSC), La0.6Sr0.4CoO3−δ (LSC), La0.6Sr0.4Co0.2Fe0.8O3−δ (LSCF), and Pr6O11 (PrOx) on the electrode–electrolyte interface. The influence of the annealing temperature on the electrode polarization (area specific...
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Investigation of electrocatalytic gas sensor properties in presence of chlorine
PublicationProperties of sensor based on Nasicon with two round shaped platinum electrodes are investigated. Influence of different chlorine concentrations on the sensor response is presented. Measurements in different temperatures have been performed in order to determine optimal sensor working temperature.
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Pumping effect measured by PIV method in a multilayer spike electrode EHD device for air cleaning
PublicationDust particles can be harmful for human health when inhaled. Particularly dangerous are submicrometer dust particles, which can contain traces of toxic elements and can easily penetrate into the human respiratory system. Thus, efficient devices for the air cleaning from submicrometer dust particles are needed. Recently, Katatani and Mizuno have proposed an electrohydrody- namic (EHD) device for air cleaning for submicrometer particles....
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Analysis of thoracic regional impedance changes using PCA approach
PublicationA multichannel impedance and one lead electrocardiographic recording system has been developed. The impedance measurement unit is built using a four-electrode technique. It consists of a sinusoidal, 40 kHz, current source and five measurement channels. Circumferential current electrodes have been located at a neck and an abdomen. Voltagemeasurement disk electrodes formed five two-electrode measurement ports. The impedance change...
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Effect of electrode waterproof coating on quality of underwater wet welded joints
PublicationIn this paper, the effects of different hydrophobic coatings on the surface of covered electrodes on the quality of wet welded carbon steel joints were discussed. Commonly available hydrophobic substances used in industrial applications were selected for the research. The aim of using waterproof coatings was to check the possibility to decreasing the susceptibility of highstrength low-alloy S460N steel to cold cracking. During...
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Electrohydrodynamic Flow Patterns in a Narrow Electrostatic Precipitator with Longitudinal Wire Electrode for Various Electrode Geometries
PublicationRecently narrow electrostatic precipitators (ESPs) have become a subject of interest because of their possible application in diesel engines. In this paper results of 2-dimensional (2D) Particle Image Velocimetry (PIV) measurements of the flow patterns in a narrow ESP for a various electrode geometries are presented. The PIV measurements were carried out in the observation plane that is perpendicular to the ESP duct. The ESP was...
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Novel inorganic xerogels doped with CaWO 4 :xDy: Synthesis, characterization and luminescence properties
PublicationA series of novel phosphors based on silica xerogel doped with CaWO4:xDy(III) with various concentration of dysprosium ion was synthesized over a temperature of 800 C. The thermal analysis, XRD measurement and spectroscopic investigations of these materials are presented in this study. Steady state luminescence, luminescence excitation spectra as well as emission spectra have been measured. Under the ultraviolet light, the prepared...
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Simple synthesis route for fabrication of protective photo‐crosslinked poly(zwitterionic) membranes for application in non‐enzymatic glucose sensing
PublicationThis work focuses on the fabrication of non-enzymatic glucose sensing materials based on laser-formed Au nanoparticles embedded in Ti-textured substrates. Those materials possess good catalytic activity toward glucose oxidation in 0.1 × phosphate buffered saline as well as resistance to some interferants, such as ascorbic acid, urea, and glycine. The electrodes are further coated with three different polymers, that is, Nafion,...
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The abrasive wear resistance of coatings manufactured on high-strength low-alloy (HSLA) offshore steel in wet welding conditions
PublicationSome marine and offshore structure elements exploited in the water cannot be brought to the surface of the water as this will generate high costs, and for this reason, they require in-situ repairs. One of the repair techniques used in underwater pad welding conditions is a wet welding method. This paper presents an investigation of the abrasive wear resistance of coatings made in wet welding conditions with the use of two grades...
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Electrochemical impedance spectroscopy spectra measured at 800 °C, 750 °C and 700 °C on porous SrTi0.50Fe0.50O3-d oxygen electrode sintered at 800 °C
Open Research DataThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.50Fe0.50O3-d oxygen electrodes sintered at 800 °C. EIS spectra were measured at 800 °C; 750°C and 700 °C (synthetic air). Results converted to electrode surfaces area and dived by two electrodes.
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Electrochemical impedance spectroscopy spectra measured at 800 °C, 750 °C and 700 °C on porous SrTi0.65Fe0.35O3-d oxygen electrode sintered at 800 °C
Open Research DataThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.65Fe0.35O3-d oxygen electrodes sintered at 800 °C. EIS spectra were measured at 800 °C; 750°C and 700 °C (synthetic air). Results converted to electrode surfaces area and dived by two electrodes.
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Electrochemical impedance spectroscopy spectra measured at 800 °C, 750 °C and 700 °C on porous SrTi0.30Fe0.70O3-d oxygen electrode sintered at 800 °C
Open Research DataThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at 800 °C. EIS spectra were measured at 800 °C; 750°C and 700 °C (synthetic air). Results converted to electrode surfaces area and dived by two electrodes.
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Chemical denudation and the role of sulfide oxidation at Werenskioldbreen, Svalbard
PublicationThis study aims to determine the rate of chemical denudation and the relationships between dominant geochemical reactions operating in the proglacial and subglacial environments of the polythermal glacier Werenskioldbreen (SW Svalbard) during an entire ablation season. Water sampling for major ion chemistry was performed at a proglacial hydrometric station and from subglacial outflows from May to September 2011. These data were...
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Influence of temperature and anion type on thermophysical properties of aqueous solutions of morpholine based amino acid ionic liquids
PublicationDensities and sound velocities of aqueous solutions of N-butyl-N-methylmorpholine based amino acid ionic liquids (AAILs), including N-acetyl-L-alanine, N-acetyl-Lvalinate, N-acetyl-L-leucinate, and N-acetyl-L-izoleucinate anions were measured at a temperature from 293.15 to 313.15 K at 5 K intervals and atmospheric pressure. These data were used to calculate the apparent molar volumes and the apparent molar compressibilities in...
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Gold nanoparticles for cancer radiotherapy: a review
PublicationRadiotherapy is currently used in around 50% of cancer treatments and relies on the deposition of energy directly into tumour tissue. Although it is generally effective, some of the deposited energy can adversely affect healthy tissue outside the tumour volume, especially in the case of photon radiation (gamma and X-rays). Improved radiotherapy outcomes can be achieved by employing ion beams due to the characteristic energy deposition...
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An Analysis of Periodic Arrangements of Cylindrical Objects of Arbitrary Convex Cross Sections with the Use of Field Matching Method
PublicationA problem of electromagnetic wave scattering from multilayered frequency selective surfaces is presented. Each surface is composed of periodically arranged cylindrical posts of arbitrary convex cross-section. The method of analysis is based on the direct field matching technique for a single cell, and the transmission matrix method with the lattice sums technique for periodic arrangement of scatterers.
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Hybrid storage management system consisting of supercapacitors and AHI batteries
PublicationIn the article the hybrid storage, composed of Aqueous Hybrid Ion battery and supercapacitor was presented. The system was tested through simulation studies. The work also describes the construction and properties of the developed device meant to control the energy flow of the storage and a communication system for remote parameter supervision.
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ECG measurement in the bathtub - getting into the bathtub- men
Open Research DataThe measurement data shows the measurement of the ECG signal in water in the bathtub. The data includes the measurement time, the reference ECG signal from the chest, and the ECG signal measured by electrodes placed in the bathtub without contact with the human body. Using the presented data, it is possible to estimate the optimal arrangement of measuring...
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Influence of sintering temperature of porous SrTi0.30Fe0.70O3-d oxygen electrode on electrochemical impedance spectroscopy spectra measured at 800 °C
Open Research DataThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at different temperatures (800 °C; 900 °C and 1000 °C). Measure temperature was 800 °C (syntetic air, 40 ml min-1). Results converted to electrode surfaces area and dived by two electrodes.
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Influence of sintering temperature of porous SrTi0.50Fe0.50O3-d oxygen electrode on electrochemical impedance spectroscopy spectra measured at 800 °C
Open Research DataThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.50Fe0.50O3-d oxygen electrodes sintered at different temperatures (800 °C; 900 °C and 1000 °C). Measure temperature was 800 °C (syntetic air, 40 ml min-1). Results converted to electrode surfaces area and dived by two electrodes.
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Influence of sintering temperature of porous SrTi0.65Fe0.35O3-d oxygen electrode on electrochemical impedance spectroscopy spectra measured at 800 °C
Open Research DataThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.65Fe0.35O3-d oxygen electrodes sintered at different temperatures (800 °C; 900 °C and 1000 °C). Measure temperature was 800 °C (syntetic air, 40 ml min-1). Results converted to electrode surfaces area and dived by two electrodes.
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GAS SENSORS WITH TEMPERATURE MODULATION – AN OVERVIEW
PublicationAlthough different methods of improving semiconductor gas sensor properties have been proposed, a technique involving temperature modulation seems to be the most promising. Semiconductor gas sensors working with modulated temperature can be more stable and are more selective comparing with sensor working at one temperature. In this paper, various approaches to temperature modulation are reviewed.
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Collection Efficiency in Narrow Electrostatic Precipitators with a Longitudinal or Transverse Wire Electrode
PublicationRecently narrow electrostatic precipitators (ESPs) have become a subject of interest because of their possible application in diesel engine exhaust systems. In this work, results of particle collection efficiency measurements in narrow electrostatic precipitators for negative and positive dc voltage polarity are presented. The ESP usedin this work was a parallelepiped equipped with wire discharge electrode and two collecting plate-electrodes....
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Evolving gene regulatory networks controlling foraging strategies of prey and predators in an artificial ecosystem
PublicationCo-evolution of predators and prey is an example of an evolutionary arms race, leading in nature to selective pressures in positive feedback. We introduce here an artificial life ecosystem in which such positive feedback can emerge. This ecosystem consists of a 2-dimensional liquid environment and animats controlled by evolving artificial gene regulatory networks encoded in linear genomes. The genes in the genome encode chemical...
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Macrocyclic derivatives of imidazole as chromoionophores for bismuth(III)/lead(II) pair
Publication18-membered diazomacrocycles with imidazole or 4-methylimidazole residue as a part of macrocycle were used as chromoionophores in bismuth(III) and lead(II) dual selective optodes for the first time. Cellulose triacetate membranes doped with macrocyclic chromoionophores are bismuth(III) and lead(II) selective with color change from orange/red to different shades of blue and violet, respectively. Results obtained for model and real...
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Thermal behaviour of NH4VO3 microcasketoids
Open Research DataThe DataSet contains the results of the thermal behavior of the ammonium metavanadate microcasketoids under argon and nitrogen atmosphere. Thermogravimetric analysis (TG) was carried out under argon or nitrogen atmosphere from 40C to 560C (with a heating rate of 10 C/min) using Netzsch STA 449 F1. The thermal behavior was also studied with mass spectrum...
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Thermal behaviour of NH4VO3 nanoflowers
Open Research DataThe DataSet contains the results of the thermal behavior of the ammonium metavanadate nanoflowers under argon and nitrogen atmosphere. Thermogravimetric analysis (TG) was carried out under argon or nitrogen atmosphere from 40C to 560C (with a heating rate of 10 C/min) using Netzsch STA 449 F1. The thermal behavior was also studied with mass spectrum...
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Thermal behaviour of NH4VO3 elongated microcrystals
Open Research DataThe DataSet contains the results of the thermal behavior of the ammonium metavanadate elongated microcrystals under argon and nitrogen atmosphere. Thermogravimetric analysis (TG) was carried out under argon or nitrogen atmosphere from 40C to 560C (with a heating rate of 10 C/min) using Netzsch STA 449 F1. The thermal behavior was also studied with mass...
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Thermal behaviour of commercial avaible NH4VO3
Open Research DataThe DataSet contains the results of the thermal behavior of the commercially available ammonium metavanadate (CAS 7803-55-6) under argon and nitrogen atmosphere. Thermogravimetric analysis (TG) was carried out under argon or nitrogen atmosphere from 40C to 560C (with a heating rate of 10 C/min) using Netzsch STA 449 F1. The thermal behavior was also...
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Thermal behaviour of NH4VO3 microflowers
Open Research DataThe DataSet contains the results of the thermal behavior of the ammonium metavanadate microflowers under argon and nitrogen atmosphere. Thermogravimetric analysis (TG) was carried out under argon or nitrogen atmosphere from 40C to 560C (with a heating rate of 10 C/min) using Netzsch STA 449 F1. The thermal behavior was also studied with mass spectrum...
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Thermal behaviour of ammonium vanadate nanocrystals
Open Research DataThe DataSet contains the thermal behavior of the ammonium vanadate nanostructures obtained by the hydrothermal method with different conditions. Thermogravimetric analysis (TG) was carried out under an argon atmosphere from 40C to 560C (with a heating rate of 10 C/min) using Netzsch STA 449 F1. The thermal behavior was also studied with mass spectrum...
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Investigation of electrocatalytic gas sensor properties in presence of chlorine
PublicationIn this paper performance of an electrocatalytic sensor in presence of chlorine is investigated. Presented studies concern sensor prepared in ceramic technology based on NASICON as a solid electrolyte with two round shaped platinum electrodes. Measurements in different temperatures have been performed in order to determine optimal sensor working temperature.
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ECG measurement in the bathtub - drl on the outside of the bathtub on one side- men
Open Research DataThe measurement data shows the measurement of the ECG signal in water in the bathtub. The data includes the measurement time, the reference ECG signal from the chest, and the ECG signal measured by electrodes placed in the bathtub without contact with the human body. Using the presented data, it is possible to estimate the optimal arrangement of measuring...
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ECG measurement in the bathtub - one side of the bathtub is grounded, drl outside the bathtub - men
Open Research DataThe measurement data shows the measurement of the ECG signal in water in the bathtub. The data includes the measurement time, the reference ECG signal from the chest, and the ECG signal measured by electrodes placed in the bathtub without contact with the human body. Using the presented data, it is possible to estimate the optimal arrangement of measuring...
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ECG measurement in the bathtub - drl on one side of the bath mass on the other - the person is moving- men
Open Research DataThe measurement data shows the measurement of the ECG signal in water in the bathtub. The data includes the measurement time, the reference ECG signal from the chest, and the ECG signal measured by electrodes placed in the bathtub without contact with the human body. Using the presented data, it is possible to estimate the optimal arrangement of measuring...
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ECG measurement in the bathtub - drl outside the bathtub on both sides- men
Open Research DataThe measurement data shows the measurement of the ECG signal in water in the bathtub. The data includes the measurement time, the reference ECG signal from the chest, and the ECG signal measured by electrodes placed in the bathtub without contact with the human body. Using the presented data, it is possible to estimate the optimal arrangement of measuring...
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ECG measurement in the bathtub - drl on one side of the bath, the mass of the system on the other- men
Open Research DataThe measurement data shows the measurement of the ECG signal in water in the bathtub. The data includes the measurement time, the reference ECG signal from the chest, and the ECG signal measured by electrodes placed in the bathtub without contact with the human body. Using the presented data, it is possible to estimate the optimal arrangement of measuring...
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Bromidotetrakis(2-ethyl-1H-imidazole-KN3)copper(II) bromide
PublicationThe CuII ion in the title complex, [CuBr(C5H8N2)4]Br, is coordinated in a square-pyramidal geometry by four N atoms of imidazole ligands and one bromide anion in the apical position. In the crystal, the ions are linked by a 3-D network of N-H---Br and CH---Br hydrogen bonds.
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Reactivation of seizure‐related changes to interictal spike shape and synchrony during postseizure sleep in patients
PublicationOBJECTIVE: Local field potentials (LFPs) arise from synchronous activation of millions of neurons, producing seemingly consistent waveform shapes and relative synchrony across electrodes. Interictal spikes (IISs) are LFPs associated with epilepsy that are commonly used to guide surgical resection. Recently, changes in neuronal firing patterns observed in the minutes preceding seizure onset were found to be reactivated during postseizure...
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Comparison of classical and modern approach of determination of highly polar compounds by High Performance Liquid Chromatography coupled with Tandem Mass Spectrometry
PublicationAbstract: Sugars and sugar alcohols are known as highly polar compounds. Four analytes were taken into consideration for comparison of classical and modern approach of separation of highly polar substances. Mannitol was chosen as an example of simple sugar alcohol, sucrose and lactulose as examples of disaccharides and structural isomers, raffinose as an example of complex trisaccharide. Raffinose was also used as internal standard...
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Anionic states of C6Cl6 probed in electron transfer experiments
PublicationThis is the first comprehensive investigation on the anionic species formed in collisions of fast neutral potassium (K) atoms with neutral hexachlorobenzene (C6Cl6) molecules in the laboratory frame range from 10 up to 100 eV. In such ion-pair formation experiments, we also report a novel K+ energy loss spectrum obtained in the forward scattering giving evidence of the most accessible electronic states. The vertical electron affinity...
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ECG measurement in the bathtub - drl on one side of the bathtub, the other side of the bathtub is grounded and the system ground is grounded- men
Open Research DataThe measurement data shows the measurement of the ECG signal in water in the bathtub. The data includes the measurement time, the reference ECG signal from the chest, and the ECG signal measured by electrodes placed in the bathtub without contact with the human body. Using the presented data, it is possible to estimate the optimal arrangement of measuring...
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Application of electrochemical impedance spectroscopy to monitoring discharging process of nickel/metal hydride battery.
PublicationThis paper presents the possibility of applying impedance analysis to cell diagnostics. In order to obtain characteristic curves of both electrodes of a NiMH battery simultaneously, a reference electrode was added into the circuit. The authors analysed the cell under three cases, i.e. when its properties are determined only by the state of the positive electrode, only by the state of the negative electrode, or when both electrodes...
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Effect of underwater wet welding conditions on the diffusible hydrogen content in deposited metal
PublicationIn the study mercury displacement method was used for determination of diffusible hydrogen amount in deposited metal obtained during underwater wet welding with covered electrodes in laboratory conditions according to a two-level full factorial design for three factors. The factors and their levels were chosen among conditions and parameters of welding in accordance with the results of own preliminary studies. A statistical analysis...
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Laser patterned platform with PEDOT–graphene composite film for NO2 sensing
PublicationThis work presents a simple and fully electrochemical route used for fabricating of a NO2 gas sensor made of reduced-graphene-oxide-poly(3,4-ethylenedioxythiophene) composite film. The sensing platform was fabricated from alumina substrate and equipped with gold interdigitated electrodes and built-in heater.The temperature distribution on the surface of interdigitated electrodes was investigated by a thermalimaging camera and compared...
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Application of bismuth film electrode for determination of heavy metals by stripping voltammetry
PublicationWhen Wang's research group introduced a new type of a working electrode: bismuth film plated electrode (BiFE), it has started attracting increasing attention in the field of electrochemical stripping analysis. These electrodes are shown to be very attractive alternative to common mercury-based electrodes, which are predominantly used in analysis of trace heavy metals.For the determination of heavy metals (Zn, Cd, Pb, Cu) used square...
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Investigation of Narrow Electrostatic Precipitator with Wire Multi-Electrode
PublicationDiesel engines emit fine particles, which are harmful to human and animal health. There are several methods for decrease particulate emission from a diesel engines, but up to now, these methods are notenough effective or very expensive. An electrostatic precipitation was proposed as an alternative method for control of a diesel particulate emission. Therefore, narrow electrostatic precipitators (ESPs) have become a subject of interest...
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The Effect of C45 Carbon Black-Phosphomolybdic Acid Nanocomposite on Hydrogenation and Corrosion Resistance of La2Ni9Co Hydrogen Storage Alloy
PublicationIn this paper, we analysed the influence of corrosion processes and the addition of a carbon black-heteropoly phosphomolybdic acid (C45-MPA) nanocomposite on the operating parameters of a hydride electrode obtained on the basis of the intermetallic compound La2Ni9Co. The electrochemical properties of negative electrodes for NiMH batteries were studied using galvanostatic charge/discharge curves, the potentiostatic method, and electrochemical...