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TG analyses - content of SiO2 and TiO2 in polystyrene
Open Research DataTG analyses were performed for polystyrene spheres coating by SiO2 and then coating by SiO2-TiO2. Thermal analyses of polystyrene spheres only were also performed. The content of inorganic remaining was used for calculation the quantity of coating SiO2 and TiO2 in the polystyrene spheres.
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Dariusz Witt prof. dr hab. inż.
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Photoconduction and magnetic field effect on photoconduction in hole-transporting star-burst amine (m-MTDATA) films
PublicationPhotoconduction and magnetic field effect on photoconduction have been investigated as a function of electric field strength, excitation light intensity and wavelength in vacuum evaporated films of m-MTDATA (4,4′,4″-tris(N-(3-methylphenyl)-N-phenylylamino) triphenylamine), the starburst amine commonly used as hole-transporting material in organic light-emitting diodes. The photocurrent is found to be generated by the singlet exciton...
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Agata Kot-Wasik prof. dr hab. inż.
PeopleAgata Kot-Wasik, born in 1964 in Siedlce, graduated in 1988 from the Faculty of Chemistry, Gdańsk University of Technology in Industrial and Technical Analysis. In 1988-1992 she was employed in the Department of Organic Chemistry. In 1990, she completed postgraduate studies "Instrumental techniques in the traces analysis and Environmental Protection" at GUT, and in 1992 began PhD Studies at the Faculty of Chemistry, GUT, which...
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Sebastian Demkowicz dr hab. inż.
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Snow Cover Studies: a Review on the Intensity of Human Pressure
PublicationSnow cover should be treated as a highly dynamic medium. A variety of physical and chemical processes interact to alter its chemical composition and affect the metamorphism of its individual crystals and layers; this, in turn, has a direct influence on their mutual adhesion, and ultimately on the stability of the entire snow cover. The literature data here reported provide basic information on the forms of solid precipitation,...
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Grzegorz Cholewiński dr hab. inż.
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Maria Jolanta Milewska prof. dr hab. inż.
PeopleMaria Jolanta Milewska, po ukończeniu Technikum Chemiczno-Mechanicznego w Wąbrzeźnie (specjalizacja: przetwórstwo tworzyw sztucznych) kontynuowała naukę na Wydziale Chemicznym Politechniki Gdańskiej. W 1979 r. zdobywa tytuł mgr inżyniera na kierunku Chemia, o specjalizacji Lekka Synteza Organiczna. Studium Doktoranckie PG ukończyła w 1984 r. W 1983 r została zatrudniona na macierzystym wydziale w Katedrze Chemii Organicznej, początkowo...
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Ethylcellulose in Organic Solution or Aqueous Dispersion Form in Designing Taste-Masked Microparticles by the Spray Drying Technique with a Model Bitter Drug: Rupatadine Fumarate
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Synthesis of UiO-66-OH zirconium metal-organic framework and its application for selective extraction and trace determination of thorium in water samples by spectrophotometry
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Emergence of Aggregation Induced Emission (AIE), Room-Temperature Phosphorescence (RTP), and Multistimuli Response from a Single Organic Luminogen by Directed Structural Modification
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Średnio - i trudnolotne związki organiczne w powietrzu wewnętrznym. Analityka i monitoring = Semivolatile organic compounds in indoor air. Analytics and monitoring
PublicationZwiązki organiczne występujące w powietrzu wewnętrznym na różnych poziomach stężeń mogą stanowić poważną przyczynę problemów zdrowotnych mieszkańców i użytkowników pomieszczeń. Bardzo ważnym staje się zagadnienie monitoringu obecności związków organicznych, należących do grupy trwałych zanieczyszczeń organicznych (POP).
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Multifunctional nitrogen-doped nanoporous carbons derived from metal–organic frameworks for efficient CO2 storage and high-performance lithium-ion batteries
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The conversion of multinuclear μ-oxo titanium(IV) species in the reaction of Ti(OiBu)4 with branched organic acids; results of structural and spectroscopic studies
PublicationW reakcji tetraizobutoksylanu tytanu z rozgałęzionymi kwasami karboksylowymi otrzymano szereg wielordzeniowych związków kompleksowych tytanu(IV). Otrzymane produkty scharakteryzowano wykorzystując techniki spektroskopowe: FTIR, 1H i 13C NMR oraz rentgenowską analizę strukturalną. Zaproponowano ścieżki reakcji prowadzące do konwersji poszczególnych związków w coraz stabilniejsze formy.
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Solid Phase Micro-Extraction, a Versatile and Handy Tool in Environmental Trace Organic Analysis, Gets a New Class of Coatings, Polymeric Ionic Liquids
PublicationSolid phase microextraction (SPME) fundamentals, characteristics and application are described. The special stress is put on characteristics of sorbents used as SPME fiber coatings. Description of commercially available fibers and the present-day trends in development of new sorbents for SPME are given. Discussion is focused on possibility of application of ionic liquids (IL) and polymeric ionic liquids (PIL) as SPME fiber coatings....
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Specjacja fizyczna analitów z grupy wielopierścieniowych węglowodorów aromatycznych w środowisku wodnym = Physical speciation of polycyclic organic hydrocarbons in water environment
PublicationW oparciu o literaturę opisano zagadnienia związane ze specjacją fizyczną wielopierścieniowych węglowodorów aromatycznych w środowisku wodnym. Przedstawiono podstawowe zagadnienia związane z losami środowiskowymi tych związków oraz z ich fizyczną analityką specjacyjną.
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The influence of global climate change on the environmental fate of anthropogenic pollution released from the permafrost
PublicationThis article presents a review of information related to the influence of potential permafrost degradation on the environmental fate of chemical species which are relased and stored, classified as potential influence in future Antarctic environment. Considering all data regarding climate change prediction, this topic may prove important issue for the future state of the Antarctic environment. A detailed survey on soil and permafrost...
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Low-energy interactions related to atmospheric and extreme conditions
PublicationThis Topical Issue, entitled “Low-Energy Interactions Related to Atmospheric and Extreme Conditions”, showcases a collection of eighteen articles that reported recent theoretical and experimental findings pertaining to the following topics: – low-energy interactions of charged particles (electrons [1–7], protons [8], positrons [9]), and photons [10] with atoms and molecules of biological [1–4,7,8], astrochemical [10], industrial,...
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Classification of submandibular salivary stones based on ultrastructural studies
PublicationIntroduction: Sialolithiasis remains a clinical problem with unclear etiopathogenesis, lack of prevention methods, and only surgical treatment. Materials and methods: An ultrastructure examination of submandibular sialoliths obtained from patients with chronic sialolithiasis was conducted using a scanning electron microscope and X-ray photoelectron...
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Controlling the size and morphology of precipitated calcite particles by the selection of solvent composition
PublicationCalcium carbonate particles were obtained in the reaction of calcium hydroxide with carbon dioxide at 65°C. Initial Ca(OH)2 suspensions were prepared in pure water and aqueous solutions of ethylene glycol or glycerol of the concentration range up to 20% (vol.). The course of reaction was monitored by conductivity measurements. Precipitated solids were analyzed by FTIR, XRD, SEM and the particles size distribution was determined...
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Botanical and geographical origin characterization of polish honeys by headspace SPME-GCxGC-TOFMS
PublicationVolatile organic compounds (VOCs) composition of Polish honeys obtained from various geographical regions was studied. Headspace solid phase microextraction (HS-SPME) using Divinylbenzene/Carboxen/Polydimethylsiloxane-coated fibers was used in combination with comprehensive two-dimensional gas chromatography-time-of-flight mass spectrometry (GC× GC-TOFMS) because of the complexity of the samples. Acacia, linden, rapeseed, buckwheat...
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Fast determination of bisphenol A in spiked juice and drinking water samples by pipette tip solid phase extraction using cobalt metal organic framework as sorbent
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Textural Characteristics of Resorcinol—Formaldehyde Resin and Temperature Behavior of Bound Water Affected by Co-Adsorbed Trifluoroacetic Acid or Pyridine in Weakly Polar Organic Media
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Skład moczu jako źródło informacji o narażeniu zawodowym na związki organiczne = Urine as a source of information on accupational exposure to organic compounds - A review
PublicationW publikacja przedstawiono przegląd informacji na temat wykorzystania próbek moczu ludzkiego do badań analitycznych, prowadzonych w celu uzyskania informacji o ekspozycji zawodowej na związki organiczne. Toksyczne działanie większości z tych związków stwarza nadal duże zagrożenie wystąpienia chorób zawodowych. Stąd też bardzo ważne jest wykorzystanie monitoringu biologicznego do ocena ryzyka zawodowego. W pracy przedstawiono również...
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Izolacja lotnych związków organicznych z próbek wody. Metody i aparatura. Analysis of volatile organic compounds (VOCs) in water samples. Methods and apparatus.
PublicationOmówiono techniki wykorzystywane do przygotowania próbek wody do oznaczeń analitów z grupy lotnych związków organicznych (VOCs) za pomocą chromatografii gazowej. Opisano wady i zalety takich technik jak: bezpośrednie dozowanie próbki wody do kolumny chromatograficznej, ekstrakcja rozpuszczalnikiem, ekstrakcja do fazy stałej lub stacjonarnej, ekstrakcja membranowa oraz analiza fazy nadpowierzchniowej. Omówiono także nowe rozwiązania...
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Modelling of migration and fate of selected persistent organic pollutans in the Gulf of Gdańsk and the Vistula catchment (Poland): selected results from the EU ELOISE EuroCat project
PublicationW publikacji przedstawiono wyniki pomiarów poziomu stężeń wybranych trwałych zanieczyszczeń organicznych w próbkach wody pobranych z Zatoki Gdańskiej i Wisły. Zamieszczono także opis modelu migracji zanieczyszczeń Co Z Mo - POP. Pokazano także migrację wybranych heksachlorobenzenów i polichlorowanych bifenyli w ekosystemie Zatoki Gdańskiej i Wisły.
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Studies on intercorrelation between selected persistent organic pollutants (POPs) and ions in sea water from the coastal zone of the Baltic Sea, Gdańsk Bay Region
PublicationMorze Bałtyckie jest zbiornikiem słonej wody a szacunkowy czas wymiany z innymi akwenami wynosi 25 lat. Woda morska jest zanieczyszczona wieloma nieorganicznymi oraz organicznymi substancjami. Opracowanie przedstawia wyniki badań monitoringowych oraz ocenę stanu zanieczyszczenia środowiska morskiego w południowej części Morza Bałtyckiego, w rejonie Zatoki Gdańskiej. W próbkach wody morskiej oznaczano: wielopierścieniowe węglowodory...
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Application of the Heavy-Atom Effect for (Sub)microsecond Thermally Activated Delayed Fluorescence and an All-Organic Light-Emitting Device with Low-Efficiency Roll-off
PublicationThefeatureof abundantandenvironmentallyfriendlyheavyatoms(HAs)like bromineto acceleratespin-forbiddentransitionsin organicmoleculeshas beenknownforyears.In combinationwiththe easinessof incorporation,brominederivativesof organicemittersshowingthermallyactivateddelayedfluorescence(TADF)emergeas a cheapand efficientsolutionforthe slowreverseintersystemcrossing(rISC)problemin suchemittersand strongefficiencyroll-offof all-organiclight-emittingdiodes(OLEDs).Here,we...
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Spin-Resolved Band Structure of Hoffman Clathrate [Fe(pz)2Pt(CN)4] as an Essential Tool to Predict Optical Spectra of Metal–Organic Frameworks
PublicationParamount spin-crossover properties of the 3D-Hoffman metalorganic framework (MOF) [Fe(pz)2Pt(CN)4] are generally described on the basis of the ligand field theory, which provides adequate insight into theoretical and simulation analysis of spintronic complexes. However, the ligand field approximation does not take into account the 3D periodicity of the actual complex lattice and surface effects and therefore cannot predict a full-scale...
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Electromodulation of monomer and excimer phosphorescence in vacuum-evaporated films of platinum (II) complexes of 1,3-di(2-pyridyl)benzenes
PublicationElectric field-modulated photoluminescence (EML) measurements are presented for vacuum-evaporated films of cyclometallated Pt (II) complexes of 1,3-di(2-pyridyl) benzenes used as triplet emitters in organic light-emitting diodes (OLEDs). The excimer phosphorescence is quenched by the external electric field of 2.5 MV/cm up to 25% but the same effect on monomer phosphorescence is one order of magnitude smaller. The higher quenching...
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Insight into Potassium Vanadates as Visible-Light-Driven Photocatalysts: Synthesis of V(IV)-Rich Nano/Microstructures for the Photodegradation of Methylene Blue
PublicationPhotocatalysis is regarded as a promising tool for wastewater remediation. In recent years, many studies have focused on investigating novel photocatalysts driven by visible light. In this study, K2V6O16·nH2O nanobelts and KV3O8 microplatelets were synthesized and investigated as photocatalysts. Samples were obtained via the facile method based on liquid-phase exfoliation with ion exchange. By changing the synthesis temperature...
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Light‐Driven Multi‐Charge Separation in a Push‐Pull Ruthenium‐Based Photosensitizer – Assessed by RASSCF and TDDFT Simulations
PublicationThe performance of photosensitizers in the field of, for example, solar energy conversion, relies on their light-harvesting efficiency in the visible region, population of long-lived charge separated intermediates, as well as their charge-accumulation capacity amongst other properties. In this computational study, we investigate the photophysical properties of a bis(bipyridyl)ruthenium(II)-based black dye (Ru) incorporating a chromophoric...
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Comparative effects of biochar-nanosheets and conventional organic-amendments on health risks abatement of potentially toxic elements via consumption of wheat grown on industrially contaminated-soil
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Solvothermal growth of {0 0 1} exposed anatase nanosheets and their ability to mineralize organic pollutants. The effect of alcohol type and content on the nucleation and growth of TiO2 nanostructures
PublicationHerein, the series of {0 0 1} exposed anatase nanosheets from HF-assisted solvothermal growth synthesis were obtained. The two-dimensional TiO2 were characterized, including both bulk (XRD, DR-UV–Vis, Mott-Schottky) and surface characteristics (N2 sorption, XPS, SEM) with experimental results compiled with Density Functional Theory (DFT) calculations. The effect of alcohol amount and type was studied, demonstrating the crucial...
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Application of deep eutectic solvents in analytical sample pretreatment (update 2017–2022). Part A: Liquid phase microextraction
PublicationSustainable development in all branches of human activity has become an unequivocal necessity in the last two decades, and green chemistry goes hand in hand with it. Various ways have been proposed in analytical chemistry to meet the current requirements of green chemistry. One such approach is the research of new reagents and solvents for analytical purposes. Deep eutectic solvents (DESs) began being investigated and used in analytical...
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Mateusz Daśko dr inż.
PeopleDr inż. Mateusz Daśko urodził się w 1990 roku w Kołobrzegu. Od 2009 roku związany jest z Politechniką Gdańską gdzie uzyskał stopień inżyniera (2013) oraz magistra (2014) na kierunku biotechnologia. W 2014 rozpoczął Studia Doktoranckie na Wydziale Chemicznym Politechniki Gdańskiej, gdzie zajmował się projektowaniem oraz syntezą chemiczną nowych inhibitorów sulfatazy steroidowej jako potencjalnych leków przeciwnowotworowych w grupie...
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Elżbieta Hallmann dr inż.
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Advanced Oxidation Processes for Degradation of Water Pollutants—Ambivalent Impact of Carbonate Species: A Review
PublicationAdvanced oxidation processes (AOPs) hold great promise in the removal of organic contaminants. Reactive oxygen species (ROS) produced in AOPs react with target pollutants to initially form several intermediate compounds that finally undergo complete mineralization. Such observations are reported, especially for laboratory-scale experiments performed in pure water. On the other hand, while considering real contaminated wastewater...
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The influence of polarization of titania nanotubes modified by a hybrid system made of a conducting polymer PEDOT and Prussian Blue redox network on the Raman spectroscopy response and photoelectrochemical properties
PublicationIn this work we show the impact of applied potential on network vibrations and photoelectrochemical properties of a composite material containing hydrogenated titania nanotubes and poly (3,4-ethylenedioxythiophene) with iron hexacyanoferrate (H-TiO2/pEDOT:Fehcf) acting as a redox centre. For this purpose, Raman spectroscopy measurements under the working electrode (WE) polarization were carried out, allowing investigation of changes...
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Teresa Olszewska dr hab. inż.
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Annual changes of basic parameters of bottom sediments from the Klodnica River Catchment
PublicationThe Klodnica River Catchment is heavily contaminated ecosystem located in area of the Upper Silesia Industrial Region. In this area various forms of human activity can be observed (e.g. mining coal underground, metallurgy, power/heat plants, wastewater discharged directly into the river). The impact of industrial and municipal wastes on this aquatic system causes to changes in the hydrographic network of river and the waters quality. In...
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The properties, functions and use of selenium compounds in living organisms
PublicationSelenium occurs in the environment in inorganic and organic compounds. For many years it was regarded as a toxic element, causing numerous illnesses and diseases. But research in the last 50 years has revealed a "bright side" to this element, especially as a component of selenoproteins, selenium makes a significant contribution to the health of humans and animals. The selenium content in an organism depends on its concentration...
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Diethyl carbonate as a green extraction solvent for chlorophenol determination with dispersive liquid–liquid microextraction
PublicationThe principles of green analytical chemistry indicate that the search for greener organic solvents for extraction applications is crucial. In this study diethyl carbonate (DEC) is proved to be a green solvent, as it is relatively nontoxic, obtainable from renewable resources and biodegradable. Here it is applied as an extraction solvent for chlorophenol determination in water samples with dispersive liquid–liquid microextraction....
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Effect of selected ammonia escape inhibitors on carbon dioxide capture and utilization via calcium carbonate precipitation
PublicationCarbon dioxide was used to precipitate CaCO3 with CaCl2 solution in the presence of NH3 as a CO2 absorption promoter. Compounds that were previously indicated as inhibitors of ammonia escape during CO2 absorption were also added to the reaction mixture. Inorganic salts, i.e. ZnCl2, CuCl2, CoCl2, and organic substances, i.e. glycerol, ethylene glycol and triethanolamine were tested inhibitors in this work. A model post-distillation...
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Correction to: Chromium‑based metal organic framework for pipette tip micro‑solid phase extraction: an effective approach for determination of methyl and propyl parabens in wastewater and shampoo samples
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PCN-222 metal–organic framework: a selective and highly efficient sorbent for the extraction of aspartame from gum, juice, and diet soft drink before its spectrophotometric determination
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Jakość powietrza wewnętrznego - lotne związki organiczne jako wskaźnik jakości powietrza wewnętrznego = Indoor air quality - volatile organic compounds as an indicator of the quality of indoor air
PublicationPomieszczenia zamknięte z jednej strony są barierą chroniącą przed negatywnymi czynnikami środowiska, zmiennymi warunkami pogodowymi - deszczem, wiatrem, niską lub wysoką temperaturą, z drugiej jednak strony - w zamkniętych wnętrzach nastepuje często kumulacja toksycznych związków organicznych i nieorganicznych, co nie pozostaje bez wpływu na ludzkie zdrowie.Głównym celem badań jest oszacowanie jakości powietrza wewnętrznego pod...
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Bovine Serum Albumin – Hydroxyapatite Nanoflowers as Potential Local Drug Delivery System of Ciprofloxacin
PublicationIntroduction: Hybrid nanoflowers are structures consisting of organic (enzymes, proteins, nucleic acids) and inorganic components (mostly metal phosphates) with a flower-like hierarchical structure. Novel hybrid nanoflowers based on bovine serum albumin (BSA) and hydroxyapatite (HA) were obtained and characterized. Study on BSA-HA nanoflowers as potential drug delivery system is reported for the first time. Methods: Embedding ciprofloxacin...
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Jacek Ryl dr hab. inż.
PeopleI have obtained my PhD in chemical technology in 2010. In the same year, I was employed at the Department of Electrochemistry, Corrosion and Materials Engineering at the Faculty of Chemistry. In 2018 I received habilitation at the Faculty of Chemistry GUT in technical sciences in the discipline of chemical technology. From 2021, he was employed at the Institute of Nanotechnology and Materials Science at the Faculty of Technical...
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Witold Przychodzeń dr hab. inż.
People