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Search results for: weak solutions
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The influence of external interference on AFM imaging, the use of a protective helmet
Open Research DataThis collection is of purely practical importance, showing how the presence of external disturbances can adversely affect the quality of imaging with an atomic force microscope. For this reason, it is also advisable to provide a link to a workshop-like study [1] as well as a huge number of commercial solutions available after entering the keyword "AFM...
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Towards Compact City – Gdańsk-Osowa district case study, proposal no 2, January 2021
Open Research DataThe data presents results of work within the participatory planning process: Towards Compact City – Gdańsk-Osowa district case study, proposal no 2, from January 2021. The goal of the process was to present the new, innovative design visions for the area located in Gdańsk-Osowa district in the context of “Compact city” and “Walkable city” ideas. The...
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Towards Compact City – Gdańsk-Osowa district case study, proposal no 3, January 2021
Open Research DataThe data presents results of work within the participatory planning process: Towards Compact City – Gdańsk-Osowa district case study, proposal no 3, from January 2021. The goal of the process was to present the new, innovative design visions for the area located in Gdańsk-Osowa district in the context of “Compact city” and “Walkable city” ideas. The...
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Towards Compact City – Gdańsk-Osowa district case study, proposal no 7, January 2021
Open Research DataThe data presents results of work within the participatory planning process: Towards Compact City – Gdańsk-Osowa district case study, proposal no 7, from January 2021. The goal of the process was to present the new, innovative design visions for the area located in Gdańsk-Osowa district in the context of “Compact city” and “Walkable city” ideas. The...
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Towards Compact City – Gdańsk-Osowa district case study, proposal no 6, January 2021
Open Research DataThe data presents results of work within the participatory planning process: Towards Compact City – Gdańsk-Osowa district case study, proposal no 6, from January 2021. The goal of the process was to present the new, innovative design visions for the area located in Gdańsk-Osowa district in the context of “Compact city” and “Walkable city” ideas. The...
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Towards Compact City – Gdańsk-Osowa district case study, proposal no 5, January 2021
Open Research DataThe data presents results of work within the participatory planning process: Towards Compact City – Gdańsk-Osowa district case study, proposal no 5, from January 2021. The goal of the process was to present the new, innovative design visions for the area located in Gdańsk-Osowa district in the context of “Compact city” and “Walkable city” ideas. The...
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Towards Compact City – Gdańsk-Osowa district case study, proposal no 1, January 2021
Open Research DataThe data presents results of work within the participatory planning process: Towards Compact City – Gdańsk-Osowa district case study, proposal no 1, from January 2021. The goal of the process was to present the new, innovative design visions for the area located in Gdańsk-Osowa district in the context of “Compact city” and “Walkable city” ideas. The...
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Towards Compact City – Gdańsk-Osowa district case study, proposal no 4, January 2021
Open Research DataThe data presents results of work within the participatory planning process: Towards Compact City – Gdańsk-Osowa district case study, proposal no 4, from January 2021. The goal of the process was to present the new, innovative design visions for the area located in Gdańsk-Osowa district in the context of “Compact city” and “Walkable city” ideas. The...
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Towards Compact City – Gdańsk-Matarnia district case study, proposal for Klukowo area, January 2021
Open Research DataThe data presents results of work within the participatory planning process: Towards Compact City – Gdańsk-Matarnia district case study, proposal for Klukowo area, from January 2021. The goal of the process was to present the new, innovative design visions for the area located in Gdańsk-Matarnia district in the context of “Compact city” and “Walkable...
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Towards Compact City – Gdańsk-Osowa district case study, proposal no 8, January 2021
Open Research DataThe data presents results of work within the participatory planning process: Towards Compact City – Gdańsk-Osowa district case study, proposal no 8, from January 2021. The goal of the process was to present the new, innovative design visions for the area located in Gdańsk-Osowa district in the context of “Compact city” and “Walkable city” ideas. The...
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Towards Compact City – Gdańsk-Osowa district case study, proposal no 9, January 2021
Open Research DataThe data presents results of work within the participatory planning process: Towards Compact City – Gdańsk-Osowa district case study, proposal no 9, from January 2021. The goal of the process was to present the new, innovative design visions for the area located in Gdańsk-Osowa district in the context of “Compact city” and “Walkable city” ideas. The...
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Preparation and X-ray structures of selected aminium thiosulfates
PublicationVarious types of aminium thiosulfates (1–6), including hydrates and mixed salts, have been obtained by the reaction of ammonium thiosulfate with amines. Tertbutylamine, cyclo-hexylamine and 1,6-diaminohexane gave crystals of (t-BuNH3)2S2O3·H2O (1), (c-C6H11NH3)2S2O3 (3) and {(NH4)2(H3NC6H12NH3)(S2O3)2} (6), respectively, which were investigated by X-ray structural analysis. Extensive hydrogen bonding of the N-H…O and N-H…S type...
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Comparison of the coordination geometries of Zn(II) and Cd(II) ions in complexes with water, methanol and bulky aryloxysilanethiolate ligands
PublicationZinc and cadmium complexes containing silanethiolate anions and methanol or water were synthesized and characterized by X-ray diffraction, FT-IR and NMR spectroscopy, and DFT calculations. Contrary to zinc, the cadmium ion utilizes very weak donors to complete its coordination sphere; it forms contacts to phenyl rings of the silanethiolate ligand. Two zinc analogs of the general formula [Zn{SSi(OAr)3}2(L)2] where L = CH3OH (2)...
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Detailed investigation of the phase transition inKxP4W8O32and experimental arguments for a charge density wave due to hidden nesting
PublicationDetailed structural and magnetotransport properties of monophosphate tungsten bronze Kx(PO2)4(WO3)8 single crystals are reported. Both galvanomagnetic and thermal properties are shown to be consistent with a charge density wave electronic transition due to hidden nesting of the quasi-1D portion of the Fermi surface. We also observe the enhancement of electronic anisotropy due to reconstruction of the Fermi surface at the Peierls...
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The Perception of an Entrepreneur’s Structural, Relational and Cognitive Social Capital among Young People in Poland - An Exploratory Study
PublicationThe goal of the current paper is to verify how an entrepreneur’s structural, relational and cognitive social capital levels are perceived by young people in Poland. The research involved a group of 374 undergraduate business students from a Polish university as participants. Participants completed a survey on entrepreneurial cognitions. It was found that participants assess the level of an entrepreneur’s social capital as relatively...
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INCREASING THE COUNTRY'S SECURITY AND PUBLIC TRANSPORT ACCESSIBILITY BY CREATING A NETWORK OF SMALL AIRPORTS
PublicationIt has been shown that by creating a network of small airports, it is possible to increase the communication accessibility of large population groups and the country's security, including safety at sea. The airports mentioned above may also be located on land considered to be weak from an engineering point of view. These include, for example, wetlands, swamps, flood embankments, poor coastal belt grounds, and reclaimed land. A...
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Dynamical description of quantum computing: generic nonlocality of quantumnoise
PublicationWe develop a dynamical non-Markovian description of quantum computing in the weak-coupling limit, in the lowest-order approximation. We show that the long-range memory of the quantum reservoir (such as the 1/t4 one exhibited by electromagnetic vacuum) produces a strong interrelation between the structure of noise and the quantum algorithm, implying nonlocal attacks of noise. This shows that the implicit assumption of quantum error...
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Photophysics of Soret-Excited Tin(IV) Porphyrins in Solution
PublicationThe photophysics of low-chlorin tin(IV) tetraphenylporphyrin dihydroxide, a core building block for axially substituted supramolecular tin porphyrin constructs, has been studied in a variety of hydrogen-bonding, nonpolar, and aprotic polar solvents using steady-state, nanosecond, and femtosecond time-resolved emission, and femtosecond time-resolved absorption methods. In hydrogen-bonding solvents the metalloporphyrin exists as...
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Anatomy of noise in quantitative biological Raman spectroscopy
PublicationRaman spectroscopy is a fundamental form of molecular spectroscopy that is widely used to investigate structures and properties of molecules using their vibrational transitions. It relies on inelastic scattering of monochromatic laser light irradiating the specimen. After appropriate filtering the scattered light is dispersed onto a detector to determine the shift from the excitation wavelength, which appears in the form of...
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Surface Plasmon-Coupled Emission of Rhodamine 110 Aggregates in a Silica Nanolayer
PublicationFirst analysis of strong directional surface plasmon-coupled emission(SPCE) of ground-state formed intermolecular aggregates of Rhodamine 110 (R110) insilica nanofilms deposited on silver nanolayers is reported. Until now, the processes ofenergy transport and its trapping due to aggregate formation have not been studied in the presence of SPCE. A new approach to multicomponent systems with weakly and strongly fluorescent centers...
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Synthesis and structure of Bi 5 FeTi 3 O 15 ceramics
PublicationAim of the present research was to fabricate and study crystal structure and phase composition of Bi5FeTi3O15 (BTFO) ceramics exhibiting Aurivillius - type structure. By means of simultaneous thermal analysis and X-ray diffraction analysis the process of synthesis of BTFO ceramics has been studied. Mixed oxide method followed by pressureless sintering was used for ceramics preparation. Three endothermic thermal effects have been...
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On Symmetry of Uniform and Preferential Attachment Graphs
PublicationMotivated by the problem of graph structure compression under realistic source models, we study the symmetry behavior of preferential and uniform attachment graphs. These are two dynamic models of network growth in which new nodes attach to a constant number m of existing ones according to some attachment scheme. We prove symmetry results for m=1 and 2 , and we conjecture that for m≥3 , both models yield asymmetry with high...
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The LaPdIn 4 indide and elementary properties of the LaTIn 4 ( T = Ni, Pd, Pt) materials family
PublicationThe indium-rich intermetallic compound LaPdIn4 is reported, prepared by arc-melting and annealing at 600 C. Single crystal X-ray diffraction found the material to be orthorhombic, space group Cmcm (No. 63), with lattice parameters a ¼ 4.5462(3) Å, b ¼ 16.9208(10) Å, and c ¼ 7.3100(5) Å. This previously unreported indide is isostructural with LaNiIn4 and LaPtIn4. It is demonstrated that all three compounds in the LaTIn4 (T ¼ Ni,...
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Superconductivity in a new intermetallic structure type based on endohedral Ta@Ir7Ge4 clusters
PublicationWe report the observation of superconductivity at a temperature near 3.5 K for the previously unreported compound TaIr2Ge2. In addition to being a superconductor, this material displays a new crystal structure type that contains endohedral clusters, as determined by single-crystal x-ray diffraction structure refinement; the structure is more complex than those of the commonly observed tetragonal 122 intermetallic phases. Despite...
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Novel sorptive extraction techniques in bioanalysis evaluated by Blue Applicability Grade Index: The paradigm of fabric phase sorptive extraction and capsule phase microextraction
PublicationFabric phase sorptive extraction (FPSE) and capsule phase microextraction (CPME) are two sol-gel derived microextraction techniques that emerged in the last decade towards the minimization of the environmental impact of conventional sample preparation approaches. Complementary to the well-established green metric tools, Blue Applicability Grade Index (BAGI) was recently proposed for the evaluation of method’s practicability. In...
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Static and dynamic concrete calculations: Breakable aggregates in DEM model
PublicationThe paper deals with the calculations of a 3-point bending beam under static and dynamic loads. The real microstructure was obtained from laboratory tests using micro-tomography images. The quasi-static results were compared directly with experimental data at both macro and micro levels. Subsequently, higher strain rates were applied to investigate dynamic effects. The study focused on the influence of dynamic loading on the macroscopic...
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Elucidating the impact of enzymatic modifications on the structure, properties, and applications of cellulose, chitosan, starch and their derivatives: a review
PublicationPolysaccharides, as one of the most prominent natural biopolymers, display numerous biological activities and industrial applications. Nevertheless, some polysaccharides lack biological properties or display weak biological activities. Besides, practical usages of polysaccharides still remain challenging because of their poor solubility and inappropriate hydrophilic/hydrophobic balance. Hence, enzymatic or chemical modifications...
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Modeling of Electrodynamic Phenomena in an Ultra-Rapid Inductive–Dynamic Actuator as Applied to Hybrid Short-Circuit Breakers - A Review Study
PublicationThis article is a study of the research development of electrodynamic phenomena occurring in ultra-fast electrodynamic drives. These types of linear drives are among the fastest, not only because of the huge accelerations achieved, but, above all, because of the extremely short reaction time. For this reason, electrodynamic drives are used in hybrid short-circuit breakers. The phenomena occurring in this type of drive are actually...
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MgPd2Sb : A Mg-based Heusler-type superconductor
PublicationWe report the synthesis and physical properties of a full Heusler compound, MgPd2Sb, which we found toshow superconductivity belowTc=2.2K. MgPd2Sb was obtained by a two-step solid-state reaction methodand its purity and cubic crystal structure [Fm-3m,a=6.4523(1) Å] were confirmed by powder x-ray diffrac-tion. Normal and superconducting states were studied by electrical resistivity, magnetic susceptibility, andheat...
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Chitin and derivative chitosan-based structures — Preparation strategies aided by deep eutectic solvents: A review
PublicationThe high molecular weight of chitin, as a biopolymer, challenges its extraction due to its insolubility in the solvents. Also, chitosan, as the N-deacetylated form of chitin, can be employed as a primary material for different industries. The low mechanical stability and poor plasticity of chitosan films, as a result of incompatible interaction between chitosan and the used solvent, have limited its industrialization. Deep eutectic...
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Electron scattering from tin tetrachloride (SnCl4) molecules
PublicationAbsolute grand-total cross section (TCS) for electron scattering from a tin tetrachloride, SnCl4, molecule was measured at electron-impact energies ranging from 0.6 to 300 eV, in the linear electron-transmission experiment. The measured TCS energy dependence shows two very pronounced enhancements peaking near 1.2 eV and around 9.5 eV, separated with a deep minimum centered close to 3 eV. The low energy structure is attributed to...
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Towards Compact City 2.0 – Gdańsk-Osowa district case study, proposal no 1, February 2022
Open Research DataThe data presents results of work within the participatory planning process: Towards Compact City – Gdańsk-Osowa district case study, proposal no 1, from February 2022. The result/ aim of the process was to present the new, innovative design visions for the area located in Gdańsk-Osowa district in the context of land use plan. The participatory methodology...
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Towards Compact City 2.0 – Gdańsk-Osowa district case study, proposal no 4, February 2022
Open Research DataThe data presents results of work within the participatory planning process: Towards Compact City – Gdańsk-Osowa district case study, proposal no 4, from February 2022. The result/ aim of the process was to present the new, innovative design visions for the area located in Gdańsk-Osowa district in the context of land use plan. The participatory methodology...
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Towards Compact City 2.0 – Gdańsk-Osowa district case study, proposal no 5, February 2022
Open Research DataThe data presents results of work within the participatory planning process: Towards Compact City – Gdańsk-Osowa district case study, proposal no 5, from February 2022. The result/ aim of the process was to present the new, innovative design visions for the area located in Gdańsk-Osowa district in the context of land use plan. The participatory methodology...
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Au nanoparticles identifiction with the use of AFM Volta potential mapping
Open Research DataThe specific physical, chemical and electrochemical electrical properties of gold nanoparticles have led to their extensive use as high-performance chemical and biochemical sensors. The described properties relate to surface plasmon resonance, fluorescence quenching or enhancement, high electrical conductivity and light scattering. The described nanoparticles...
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Rospuda - czy wszędzie budować mosty?
PublicationStreszczenie - SummaryThe article presents the problem of planning transport system in the areas of high natural and landscape values. Bridges and roads crossing valuable areas undergo Environmental Impact Assessment (EIA) Procedure. This procedure in Poland is often treated only as formal requirement, not as an instrument helping to solve conflicts and to minimise negative environmental and landscape effects. The potential of...
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Gelatin-Modified Polyurethanes for Soft Tissue Scaffold
PublicationRecently, in the field of biomaterials, which are being designed for soft tissue scaffolding, is growing the interest of their modification with natural polymers. Synthetic polymers are often hard, not easy to process and they do not possess fine biodegradable profile. From the other hand natural polymers are biocompatible, but weak when used alone. The combination of natural and synthetic polymers gives the suitable properties...
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Structural change in New Member States (1995-2005): shift-share analysis of productivity growth and its determinants
PublicationThe chapter focuses on the latest developments in ten New MemberStates (presented vis-à-vis EU-15countries), seen from the perspective of structural change and quality upgrading of their economic structures. In particular, recently released disaggregated labor statistics are used,allowing to analyse the process of labor reallocation and productivitychanges associated with inter-and intra-industrystructural change. Since the mid-1990s...
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Multi-mode vibronic interactions in the five lowest electronic states of the fluorobenzene radical cation
PublicationThe multi-mode vibronic interactions between the five lowest electronic states of the fluorobenzene radical cation are investigated theoretically, based on ab initio electronic structure data, and employing the linear vibronic coupling model. Low-energy conical intersections, and strong vibronic couplings are found to prevail within the set of X-A and B-C-D cationic states, while the interactions between these two sets of states...
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In-Situ Processing of Biocomposites via Reactive Extrusion
PublicationLaw regulations, economic and environmental factors are the main causes for the rapidly growing interests in biocomposites’ research, conducted currently in a number of academic and industrial scientific centers. However, weak polymer matrix/filler interactions, common in biocomposites, result in unsatisfactory mechanical properties, which limit their practical applications. From many attempts performed to solve this problem, in-situ...
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Optical and photoelectrochemical characterization of pulsed laser deposited Bi4V2O11, BICUVOX, and BIZNVOX
PublicationThin layers of three compounds from the BIMEVOX family (Bi4V2O11, Bi2V0.9Cu0.1O5.35, and Bi2V0.9Zn0.1O5.35) were prepared via pulsed laser deposition technique on quartz, silicon, and platinum foil and tested as photoanodes for water photooxidation. The film formation, as well as the crystallization upon heating, was characterized using X-ray diffraction and Raman spectroscopy. The optical properties were investigated using spectroscopic...
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Nexus between stock markets, economic strength, R&D and environmental deterioration: new evidence from EU-27 using PNARDL approach
PublicationThis research investigates the impact of stock market indices, economic strength, and research and development expenditures on environmental deterioration in the EU-27 countries for the period 2000–2020. This study utilized linear and non-linear panel ARDL to estimate the short- and long-run effect. According to the results, the stock market indices have negative effect on environmental deterioration in the symmetric form. However,...
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Weakly-Supervised Word-Level Pronunciation Error Detection in Non-Native English Speech
PublicationWe propose a weakly-supervised model for word-level mispronunciation detection in non-native (L2) English speech. To train this model, phonetically transcribed L2 speech is not required and we only need to mark mispronounced words. The lack of phonetic transcriptions for L2 speech means that the model has to learn only from a weak signal of word-level mispronunciations. Because of that and due to the limited amount of mispronounced...
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The luminescence study of SrAl11.88−xGaxO19:0.12Cr3+ coumpounds.
Open Research DataPortable near-infrared (NIR) light sources are in high demand for applications in spectroscopy, night vision, bioimaging, and many others. Typical phosphor designs feature isolated Cr3+ ion centers, and it is challenging to design broadband NIR phosphors based on Cr3+–Cr3+ pairs. Here, we explore the solid-solution series SrAl11.88–xGaxO19:0.12Cr3+...
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Results of the effect of mixtures of ketoprofen with three cations on the germination of Sorghum bicolor (sorghum) seeds
Open Research DataThe research data includes an attempt to verify whether the addition of cations (sodium, ammonium and potassium) at levels found in the environment would affect the toxicity of pharmaceuticals to Sorghum Bicolor grain. Ion concentrations were selected based on studies of water samples collected in water bodies receiving wastewater from wastewater treatment...
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Results of the effect of mixtures of ketoprofen with three anions on the germination of Sorghum bicolor (sorghum) seeds
Open Research DataThe research data includes an attempt to verify whether the addition of anions (bromide, chloride and fluoride) at levels found in the environment would affect the toxicity of pharmaceuticals to Sorghum Bicolor grain. Ion concentrations were selected based on studies of water samples collected in water bodies receiving wastewater from wastewater treatment...
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Effect of interlayer bonding quality of asphalt layers on pavement performance
PublicationThe quality of interlayer bonding at the interfaces between the asphalt layers in flexible pavements affects the overall pavement performance. Lack or partial lack of interlayer bonding between asphalt layers can cause pavement's premature failures such as rutting, slippage of the wearing course, cracking or simply a reduction in the calculated fatigue life of the pavement structure. This paper shows the case studies of investigation...
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Acoustic heating produced in resonators filled by a newtonian fluid
PublicationAcoustic heating in resonators is studied. The governing equation of acoustic heating is derived by means of the special linear combination of conservation equations in differential form, allowing the reduction of all acoustic terms in the linear part of the final equation, but preserving terms belonging to the thermal mode responsible for heating. This equation is instantaneous and includes nonlinear acoustic terms that form a...
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Enhancement of the Magnetic Coupling in Exfoliated CrCl 3 Crystals Observed by Low‐Temperature Magnetic Force Microscopy and X‐ray Magnetic Circular Dichroism
PublicationMagnetic crystals formed by 2D layers interacting by weak van der Waals forces are currently a hot research topic. When these crystals are thinned to nanometric size, they can manifest strikingly different magnetic behavior compared to the bulk form. This can be the result of, for example, quantum electronic confinement effects, the presence of defects, or pinning of the crystallographic structure in metastable phases induced by...
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A general theory for anisotropic Kirchhoff–Love shells with in-plane bending of embedded fibers
PublicationThis work presents a generalized Kirchhoff–Love shell theory that can explicitly capture fiber-induced anisotropy not only in stretching and out-of-plane bending, but also in in-plane bending. This setup is particularly suitable for heterogeneous and fibrous materials such as textiles, biomaterials, composites and pantographic structures. The presented theory is a direct extension of classical Kirchhoff–Love shell theory to incorporate...