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Metrological characteristics of the flat voltammetric electrode in time domain with a reversible electrochemical reaction running on the surface
PublicationW artykule przedstawiono właściwości metrologiczne płaskich elektrod woltamperometrycznych. Omówiono wpływ napięcia polaryzującego na wartości parametrów charakteryzujących te elektrody.
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Spectacular Oxygen Evolution Reaction Enhancement through Laser Processing of the Nickel‐Decorated Titania Nanotubes
PublicationThe selective, laser‐induced modification of the nickel‐decorated titania nanotubes provides remarkable enhancement toward oxygen evolution reaction. Particularly, the irradiation of the laterally spaced crystalline TiO2 nanotubes, results in the formation of the tight closure over irradiated end, preserving their hollow interior. The shape of the absorbance spectra is modulated along with applied energy, and the new absorption...
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Optimization of the Relative Humidity of Reactant Gases in Hydrogen Fuel Cells Using Dynamic Impedance Measurements
PublicationWater management is a key factor affecting the efficiency of proton exchange membrane fuel cells (PEMFCs). The currently used monitoring methods of PEMFCs provide limited information about which processes or components that humidity has a significant impact upon. Herein, we propose the use of a novel approach of impedance measurements using a multi-sinusoidal perturbation signal, which enables impedance measurements under dynamic...
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Fabrication of ILs-Assisted AgTaO3 Nanoparticles for the Water Splitting Reaction: The Effect of ILs on Morphology and Photoactivity
PublicationThe design of an active, stable and ecient photocatalyst that is able to be used for hydrogen production is of great interest nowadays. Therefore, four methods of AgTaO3 perovskite synthesis, such as hydrothermal, solvothermal, sol-gel and solid state reactions, were proposed in this study to identify the one with the highest hydrogen generation eciency by the water splitting reaction. The comprehensive results clearly show that...
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New reaction of dithiophosphoric acids with O-thioacylhydroxylamines. Nucleophilic substitution or single electron transfer process?
PublicationUdowodniono, że dipodstawione lub sterycznie przeszkodzone hydroksyloaminy reagują z przestrzennie rozbudowanymi S-tioacyloditiofosforanami dając odpowiednie O-tioacylohydroksyloaminy. Dalsza reakcja O-tioacylohydroksyloaminy z kwasem ditiofosforowym prowadzi do powstania disiarczku acylowo tiofosfo-rylowego oraz soli amoniowej kwasu ditiofosforowego. Wpływ pułapek rodnikowych na wydajność tej reakcji świadczy dobitnie, że w procesie...
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Effect of Manual Therapy Compared to Ibuprofen on Primary Dysmenorrhea in Young Women—Concentration Assessment of C-Reactive Protein, Vascular Endothelial Growth Factor, Prostaglandins and Sex Hormones
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Mechanistic insights into the reactive radicals-assisted degradation of sulfamethoxazole via calcium peroxide activation by manganese-incorporated iron oxide–graphene nanocomposite: Formation of radicals and degradation pathway
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Immunization with an anti-idiotypic antibody against the broadly lipopolysaccharide-reactive antibody WN1 222-5 induces Escherichia coli R3-core-type specific antibodies in rabbits
PublicationThe mouse monoclonal antibody (mAb) WN1 222-5 recognizes a carbohydrate epitope in the inner core region of LPS that is shared by all strains of Escherichia coli and Salmonella enterica and is able to neutralize their endotoxic activity in vitro and in vivo. Immunization of mice with mAb WN1 222-5 yielded several anti-idiotypic mAbs one of which (mAb S81-19) competitively inhibited binding of mAb WN1 222-5 to E. coli and Salmonella...
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VSC converters control for offshore wind farms HVDC grid connection
PublicationThe paper proposes a voltage sourced converter (VSC) new control method. A well-known in the electric power systems correlation between voltage angle and active power and correlation between voltage and reactive power is used instead of feedforward control. This allows for a fast and almost independent control of active and reactive power flow.
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Phosphorus modified hollow, porous Nickel-Cobalt oxides nanocubes with heterostructure for oxygen evolution reaction in alkaline
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Toward an Understanding of the Chemiluminescence Accompanying the Reaction of 9-Carboxy-10-methylacridinium Phenyl Ester with Hydrogen Peroxide
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Proton transfer reaction from some C–H acids to N-bases in polar aprotic solvents
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The effect of a polyharmonic structure of the perturbation signal on the results of harmonic analysis of the current of a first-order electrode reaction
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The fixed state in impedance measurements of a two-step electrode reaction proceeding with accompanying adsorption of an intermediate product
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Chemical-vapor generation of transition metals through the reaction with tetrahydroborate in recent achievements in analytical atomic spectrometry
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Effect of the Relative Position of the Face Milling Tool towards the Workpiece on Machined Surface Roughness and Milling Dynamics
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Effect of preparation conditions and promoters on the structure and activity of the ammonia decomposition reaction catalyst based on nanocrystalline cobalt
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The role of aluminium in metal–organic frameworks derived carbon doped with cobalt in electrocatalytic oxygen evolution reaction
PublicationWater electrolysis is one of the most crucial processes in the development of new energy sources, where ultra-clean fuel is produced - hydrogen. Oxygen evolution reaction (OER) is the sluggish process of overall water splitting. Therefore, this study presents the design, characterization and electrochemical study of cobalt-based electrocatalysts embedded into porous carbons derived from an Al-metal–organic...
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The effect of the iron oxidation degree on distribution of promotors in the fused catalyst precursors and their activity in the ammonia synthesis reaction
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Generation of vorticity motion by sound in a chemically reacting gas and inversion of acoustic streaming in the non-equilibrium regime
PublicationBadanie dotyczy nieliniowych pobudzeń modu wirowego wywoływanych przez straty momentu pędu w gazie, w którym zachodzą reakcje chemiczne. Zostało wyprowadzone chwilowe dynamiczne równanie dla modu wirowego. Zawiera ono nieliniową siłę akustyczną co pokazuje, że powodem interakcji między modami akustycznym i wirowym jest nieliniowość. Równanie pozwala jako przyczynę ruchu wirowego rozważać zarówno dźwięk okresowy, jak i aperiodyczny....
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Determination of the refractive index and wavelength‐dependent optical properties of few‐layer CrCl3 within the Fresnel formalism
PublicationBased on previous reports on the optical microscopy contrast of mechanically exfoliated few layer CrCl3 transferred on 285 nmand 270 nmSiO2 on Si(100), we focus on the experimental determination of an effective mean complex refractive index via a fitting analysis based on the Fresnel equations formalism. Accordingly, the layer and wavelength-dependent absorbance and reflectance are calculated. Layer and wavelength-dependent optical...
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Glutathione-mediated conjugation of anticancer drugs: an overview of reaction mechanisms and biological significance for drug detoxification and bioactivation.
PublicationThe effectiveness of many anticancer drugs depends on the creation of specific metabolites that may alter their therapeutic or toxic properties. One significant route of biotransformation is a conjugation of electrophilic compounds with reduced glutathione, which can be non-enzymatic and/or catalyzed by glutathione-dependent enzymes. Glutathione usually combines with anticancer drugs and/or their metabolites to form more polar...
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Tailoring a low-energy ball milled MnCo2O4 spinel catalyst to boost oxygen evolution reaction performance
PublicationThe development of cost-efficient oxygen evolution reaction (OER) catalysts is one of the most important tasks facing modern techniques for hydrogen production. In this work, for the first time, a low-energy ball milling process of MnCo2O4 (MCO) spinel powders, with a mechanical modification time exceeding 1 day was used. After 6 days of ball-milling, the obtained overpotential of the electrocatalyst reached the value of 375 mV...
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Fiber optic microsphere with a ZnO thin film for potential application in a refractive index sensor – theoretical study
PublicationOptical fiber sensors of refractive index play an important role in analysis of biological and chemical samples. This work presents a theoretical investigation of spectral response of a fiber optic microsphere with a zinc oxide (ZnO) thin film deposited on the surface and evaluates the prospect of using such a structure for refractive index sensing. A microsphere is fabricated by an optical fiber tapering method on the base of...
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Impact of Tetrazolium Ionic Liquid Thermal Decomposition in Solvothermal Reaction on the Remarkable Photocatalytic Properties of TiO2 Particles
PublicationIonic liquids (ILs) could serve as a structuring agent, a solvent, or a source of dopant during solvothermal synthesis of semiconductors particles. To understand the role of IL during formation of TiO2 particles, it is necessary to study the stability of this IL in solvothermal synthesis conditions, as well as studying the surface properties of formed TiO2 particles. In view of this, the effect of the 2,3,5-triphenyltetrazolium...
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Short-term Price Reaction to Involuntary Bankruptcies Filed in Bad Faith: Empirical Evidence from Poland
PublicationPurpose: Assessing the reaction of the prices of shares of companies listed in the Warsaw Stock Exchange to the public disclosure of information about the filing a bankruptcy petition in bad faith by creditors. Design/Methodology/Approach: Event study analysis. Findings: It can therefore be assumed that the filing of an unfounded bankruptcy petition does not, in the short term, have a statistically significant negative impact on...
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A measurement method for lossy capacitive relative humidity sensors based on a direct sensor-to-microcontroller interface circuit
PublicationA new time-domain measurement method for determining the capacitance and resistance values of lossy relative humidity capacitive sensors is presented. The method is based on a direct sensor-to-microcontroller interface for microcontrollers with internal analog comparators and timers. The interface circuit consists only of four reference resistors (two reference resistors if a microcontroller includes a voltage reference source),...
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Real-Time Monnitoring of Vegetable Oils' Thermal Degradation Using Proton Transfer Reaction Mass Spectrometry
PublicationThe volatile aldehydes, which are generated during frying, can be harmful to human health, therefore the concentration of these compounds in frying fumes should be monitored. In addition, aldehydes are markers of oils’ quality, and so it is possible to determine shelf-life or suitability for frying of these oils. Commonly, in order to determine aldehydes concentration gas chromatography is performed, however it does not allow for...
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Convenient Synthesis of Functionalized Unsymmetrical Vinyl Disulfides and Their Inverse Electron-Demand Hetero-Diels-Alder Reaction
PublicationThe simple, convenient, and efficient methods for the preparation of unsymmetrical vinyl disulfides with additional functional groups under mild conditions with moderate to high yields were designed. The developed methods include the reaction of S-vinyl phosphorodithioate with thiotosylates or S-vinyl thiotosylate with thiols. The designed methods allow for the synthesis of unsymmetrical vinyl disulfides with additional functionalities...
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Morphology, Thermo-Mechanical Properties and Biodegradibility of PCL/PLA Blends Reactively Compatibilized by Different Organic Peroxides
PublicationReactive blending is a promising approach for the sustainable development of bio-based polymer blends and composites, which currently is gaining more and more attention. In this paper, biodegradable blends based on poly(ε-caprolactone) (PCL) and poly(lactic acid) (PLA) were prepared via reactive blending performed in an internal mixer. The PCL and PLA content varied in a ratio of 70/30 and 55/45. Reactive modification of PCL/PLA...
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Raman investigation of minor component reaction during polymer synthesisprocess. IV Workshop on Atomic and Molecular Physics.
PublicationWykonano badania ramanowskie reakcji zachodzących podczas procesu wytwarzania polimerów hybrydowych w ich części organicznej. Optyczne monitorowanie przebiegu reakcji w czasie rzeczywistym umożliwiło zbadanie ich efektywności oraz czasu trwania. Wyjaśniono też rolę katalizatorów.
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Role of Herbal Bioactive Compounds as a Potential Bioavailability Enhancer for Active Pharmaceutical Ingredients
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Consequences of New Approach of Chemical Stability Tests of Active Pharmaceutical Ingredients (APIs)
PublicationThere is a great need of broaden look on stability tests of active pharmaceuticalingredients (APIs) in comparison with current requirements contained in pharmacopeia.By usage of many modern analytical methods the conception of monitoring the changesof APIs during initial stage of their exposure to harmful factors has been developed. Newknowledge must be acquired in terms of identification of each degradation...
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Quantitative active dynamic thermal ir-imaging and thermal tomography in medical diagnostics
PublicationPraca dotyczy nowych technik obrazowania w diagnostyce medycznej, wykorzystując przetwarzanie obrazów termicznych rejestrowanych w podczerwieni. Opisano właściwości termiczne tkanek biologicznych, omówiono medele termiczne i zdefiniowano zastępcze parametry syntetyczne, metody pomiarów i stosowane urządzenia. Omówiono procedury akwizycji danych i ich przetwarzania. Wprowadzono pojęcie tomografii termicznej. Opisano przeprowadzone...
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Modelling of temperature field of flat boiling section with active single nucleation site
PublicationZaprezentowano główne założenia wybranych modeli wrzenia dla pojedynczego centrum nukleacji. Przedstawiony model numeryczny dotyczy zagadnienia dwuwymiarowego, osiowo-symetrycznego, nieizotropowego przewodzenia ciepła dla warunków brzegowych pierwszego, drugiego i trzeciego rodzaju. Warunek brzegowy drugiego rodzaju reprezentuje gęstość strumienia ciepła połączoną z generacją pęcherzy z pojedynczego centrum nukleacji.
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Reconfigurable Dual Active Bridge (DAB) Converter Topology for Aircraft Application System
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Effective mode volume of a natural mode of an open dielectric resonator with an active region
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Biologically Active Preparations from the Leaves of Wild Plant Species of the Genus Rubus
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Micellar liquid chromatography for lipophilicity determination of new biologically active 1,3‐purinodiones
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Kombucha as a Potential Active Ingredient in Cosmetics—An Ex Vivo Skin Permeation Study
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Self-assembly of zinc and cobalt complexes mimicking active site of alcohol dehydrogenase
PublicationPo raz pierwszy zsyntetyzowano obojętne kompleksy cynku i kobaltu naśladujące strukturę centrum aktywnego dehydrogenazy alkoholowej z wodą jako dodatkowym ligandem. Jakość otrzymanych kryształów pozwoliła na szczegółową analizę wewnątrzcząsteczkowych wiązań wodorowych w kryształach tych związków. Wnioski potwierdzono za pomocą spektroskopii FT-IR w ciele stałym.
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Enhanced switched parasitic antenna with switched active monopoles for indoor positioning systems
PublicationThis paper presents the concept of enhanced reduced-size steerable antenna array with two rows of switched active and passive elements. Designed array is similar to ESPAR antenna but it has a set of switched monopoles instead of central one. It is intended for 2.4 GHz ISM applications with emphasis on indoor positioning systems (IPS). Proposed antenna provides improved radiation parameters and reduced dimensions in comparison to...
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Quantitative active dynamic thermal Ir-Imaging and thermal tomography in medical diagnostics
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Generation of chirality in 4,4'-azopyridine by co-crystallization with optically active dicarboxylic acids
PublicationOtrzymano kokryształy anti-4,4'-azopirydyny z optycznie czynnymi kwasai: 9,10-dihydro-9,10-etanoantraceno-11,12-dikarboksylowym i trans-1,2-cykloheksnodikarboksylowym. Następnie pomierzono dichroizm kołowy otrzymanych kryształów. Dodatni znak efektu Cottona, odpowiadający niskoenergetycznemu wzbudzeniu elektronowemu n-pi*, został skorelowany z M helikalnością skręconego chromoforu Ar-N=N. Absolutna konfiguracja skręconej cząsteczki...
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Solid electrolyte gas sensors based on cyclic voltammetry with one active electrode
PublicationW artykule przedstawiono wyniki badań elektrokatalitycznego czujnika gazów toksycznych z jedną elektrodą aktywną.
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Smart MV/LV distribution transformer for Smart Grid with active prosumer participation
PublicationWraz z rozwojem sieci dystrybucyjnych i ich stopniowym przekształcaniem w inteligentne sieci typu Smart Grid będzie rosłoznaczenie i udział sterowanych układów przekształtnikowych mocy stosowanych jako interfejsy pomiędzy źródłami energii a sieciąoraz pomiędzy siecią a odbiorcami. W artykule rozwinięto koncepcję wymiany konwencjonalnych transformatorów dystrybucyjnych50 Hz na inteligentne transformatory dystrybucyjne. Zaproponowano...
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Quantitative Active Dynamic Thermal IR-Imaging and Thermal Tomography in Medical Diagnostics
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Performance of Passive and Active Balancing Systems of Lithium Batteries in Onerous Mine Environment
PublicationTo use lithium-iron-phosphate battery packs in the supply systems of any electric mining equipment and/or machines, the required conditions of work safety must be met. This applies in particular to coal mines endangered by fire and/or explosion. To meet the spark-safety conditions, the cells (together with the battery management system—BMS) must be isolated from the influence of the environment, and therefore placed in special...
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Active Control of Highly Autocorrelated Machinery Noise in Multivariate Nonminimum Phase Systems
PublicationIn this paper, a novel multivariate active noise control scheme, designed to attenuate disturbances with high autocorrelation characteristics and preserve background signals, is proposed. The algorithm belongs to the class of feedback controllers and, unlike the popular feedforward FX-LMS approach, does not require availability of a reference signal. The proposed approach draws its inspiration from the iterative learning control...
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Transformation of bimetallic Ag–Cu thin films into plasmonically active composite nanostructures
PublicationFormation of plasmonically active silver, copper and composite silver-copper nanostructures were studied in this paper. Metallic nanostructures were fabricated by thermal disintegration, so called dewetting, of the thin films in an argon atmosphere. The formation process of the nanostructures was in-situ observed by a novel method, based on resistance measurements. The influence of the material and thickness of the initial thin...