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Search results for: co2 fracturing
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Soil burial degradation of chemically compatibilized poly(butylene adipate-co-terephthalate)/thermoplastic starch/poly(ε-caprolactone)/cellulose biocomposites
PublicationDeveloping bio-blends and biocomposites has become a widespread strategy to combat plastic pollution in line with sustainability principles and decarbonization necessities. Although chemically modified ternary and quaternary biocomposites are developing rapidly because of their broader processing and performance windows than single matrix and binary counterparts, a few have been reported about their biodegradation. Herein, diisocyanates-based...
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Interspecific distribution and co-associations of chemical elements in the liver tissue of marine mammals from the Polish Economical Exclusive Zone, Baltic Sea
PublicationPrzeprowadzono analizy próbek wątroby ssaków morskich z Polskiej Strefy Ekonomicznej Morza Bałtyckiego w celu oznaczenia szerokiej gamy pierwiastków (mikro- i makroelementy) z wykorzystaniem takich technik analitycznych jak ICP-MS, ICP-AES oraz CV-AAS.Badano zależności pomiędzy zawartością poszczególnych pierwiastków a wiekiem, płcią, miejscem bytowania, sposobem odżywiania i gatunkiem ssaków.
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The electrochemical response to BDD electrode functionalization with CD147 receptor
Open Research DataThis dataset contains the results of the electrochemical impedance spectroscopy (EIS) measurements of the boron-doped diamond (BDD) electrode functionalization with CD147 receptor. The functionalized electrode was then used for the electrochemical detection of the SARS-CoV-2 virus S1 protein.
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The electrochemical response to BDD electrode functionalization with ACE2 receptor
Open Research DataThis dataset contains the results of the electrochemical impedance spectroscopy (EIS) measurements of the boron-doped diamond (BDD) electrode functionalization with ACE2 receptor. The functionalized electrode was then used for the electrochemical detection of the SARS-CoV-2 virus S1 protein.
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The electrochemical response to BDD electrode functionalization with IgG2B receptor
Open Research DataThis dataset contains the results of the electrochemical impedance spectroscopy (EIS) measurements of the boron-doped diamond (BDD) electrode functionalization with IgG2B receptor. The functionalized electrode was then used for the electrochemical detection of the SARS-CoV-2 virus S1 protein.
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Microscopy analysis of A549 and H460 cells' mitochondria after exposure to TXT2 and TXT4
Open Research DataThe data set contains live-cell imaging of A549 and H460 cells' mitochondria after exposure to TXT2 and TXT4. Cells were exposed for 6 h to the tested compounds at their IC90 concentration or to DMSO. Then, mitochondrial labelling was performed by incubating the cells with a MitoTracker Green FM probe (Thermo Fisher Scientific) and Hoechst 33342 (Thermo...
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Ion-selective electrodes based on p-tert-butyl-homooxacalixarene di(ethyl) amides
PublicationPochodne dietyloamidowe p-tert-butylodihomooksakaliks[4]arenu (1), p-tert-butyloheksahomotrioksakaliks[3]arenu (2) oraz p-tert-butylokaliks[4]arenu (3) były wykorzystane jako materiał aktywny w membranach elektrod jonoselektywnych w celu sprawdzenia detekcji kationów różnych rodzajów (Na+, K+, Cs+, Mg2+, Ca2+, Mn2+, Cu2+, Zn2+, Cd2+, Pb2+ oraz kation tetrametyloammoniowy). Wyznaczono charakterystyki elektrod oraz współczynniki...
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Frontispiece: Tuning of High Spin Ground State and Slow Magnetic Relaxation within Trimetallic Cyanide‐Bridged {Ni II x Co II 9− x [W V (CN) 8 ] 6 } and {Mn II x Co II 9− x [W V (CN) 8 ] 6 } Clusters
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New generation composite panels for military and civil applications: mechanical, thermal, fire, and acoustic properties
PublicationThe article presents selected results from a research programme on innovative composite panels featuring an insulating core and magnesium cement facings, optionally reinforced with additional steel facings. The scope of the research programme includes the assessment of the panels themselves, as well as the partitions constructed from them and entire buildings, including portable structures built in accordance with the requirements...
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The culture of excellence and its dimensions in higher education
PublicationPurpose To recognize the existing state of knowledge on a culture of excellence (CoE) in higher education institutions (HEIs) and to define the CoE in HEI and the dimensions that make up that culture. A subsidiary goal is to propose a qualitative tool to measure CoE maturity. Design/methodology/approach The study was based on the qualitative method, the preferred reporting system of systematic reviews and meta-analysis (PRISMA)....
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Unsaturated, biobased polyesters and their cross-linking via radical copolymerization
PublicationBiobased, unsaturated polyesters derived from isosorbide, maleic anhydride and succinic acid were synthesized and characterized. The presence of maleic anhydride units in the structure of the polyesters allowed converting them into cured coatings by radical copolymerization with cross-linking agents such as 2-hydroxyethyl methacrylate, N-vinyl-2-pyrrolidinone, acrylic acid or methacrylamide. The investigated polyesters were obtained...
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Waterborne polyesters partially based on renewable resources
PublicationA new experimental approach for preparing biobased, water-soluble polyesters via titanium(IV) n-butoxide-catalyzed bulk polycondensation is presented. In the described method polymers were obtained from isosorbide, maleic anhydride and poly(ethylene glycol). The chemical structure of the synthesized polyesters was confirmed using 2D NMR spectroscopy and by titration methods. Careful analysis of 2D NMR spectra viz. Correlation Spectra...
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Experimental and numerical investigation on shell and coil storage unit with biodegradable PCM for modular thermal battery applications
PublicationThermal energy storage (TES) in automotive applications is currently growing in importance. TES can visibly reduce primary energy consumptions, decrease CO2 emission, and improve thermal comfort in electric as well as hybrid vehicles. However, to meet the new ambitious target (15% reduction of CO2 emissions in the new cars until 2025) it is required to use plug-in electric vehicles. For this reason, this paper focuses on the optimization...
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Polyether-block-amide PEBA membranes for gas separation and pervaporation; current design and applications
PublicationPolyether-block-amide (PEBA) membranes have attracted considerable attention for their exceptional efficacy in gas separation and pervaporation processes. This comprehensive review delves into the precise definition, distinguishing characteristics, and diverse applications of PEBA membranes over the past five years. A primary research objective focuses on enhancing gas separation efficiency, primarily through augmenting membrane...
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Chapter 9. Sustainable development and heterogeneous photocatalysis
PublicationTlenek tytanu(IV) jest efektywnym fotokatalizatorem w procesach usuwania zanieczyszczeń z fazy wodnej i gazowej, fotokonwersji CO2 oraz generowania H2. TiO2 wykazuje wysoką stabilność i reaktywność pod wpływem promieniowania UV, którego energia jest wyższa od szerokości pasma wzbronionego anatazu (3,3 eV). W artykule omówiono mechanizm reakcji w obecności TiO2, obecne oraz potencjalne możliwości zastosowania.
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Green Geotechnics in practice and theory
PublicationW artykule przedstawiono analizę wykorzystania materiałów antropogenicznych (głównie ubocznych produktów spalania) w drogownictwie na przykładzie Polski. Główny nacisk położono na analizę technologii w aspekcie emisyjności CO2. Zdaniem autorów technologie niskoemisyjne powinny mieć priorytet ''stosowalności'' - zwłaszcza w świetle ustaleń tzw. Protokołu z Kioto 2005. Geotechnika przyjazna środowisku, czyli tzw. Zielona Geotechnika,...
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Study of the chemical state of Gd in a Ba-La-Gd-Co based ceramic
Open Research DataBarium, Lanthanum, Gadolinium and Cobaltium precursors were used for production of ceramic materials. Samples were produced by standard solid state reaction. Samples were annealed at 300 Celsius degree in wet and dry atmosphere. Annealing takes 72h or 2h. Results of annealing on a Gadolinum were observed by X-Ray photoemission spectroscopy (XPS), OmicronNanotechnology....
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Synergism of floated paperboard sludge cake /sewage sludge for maximizing biomethane yield and biochar recovery from digestate: A step towards circular economy
PublicationAnaerobic digestion of floated paperboard sludge (PS) cake suffers from volatile fatty acids (VFAs) accumulation, nutrient unbalanced condition, and generation of digestate with a risk of secondary pollution. To overcome these drawbacks, sewage sludge (SS) was added to PS cake for biogas recovery improvement under a co-digestion process followed by the thermal treatment of solid fraction of digestate for biochar production. Batch...
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Fractionation and origin of dissolved and colloidal organic nitrogen in BNR plant effluent
PublicationThe characteristics of effluent dissolved and colloidal organic nitrogen (DON and CON) as well as their origin, fate and biodegradability in wastewater treatment plants and receiving waters were identified as the major issues that limit the ability to achieve low total N in the effluent. This study presents the results of a comprehensive survey, which was conducted in eight biological nutrient removal (BNR) WWTPs in northern Poland....
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In vitro and in silico assessment of anti-inflammatory activity of cocoa powders
PublicationPlants are considered the major sources of biologically active compounds, which provide unlimited opportunities for their use either as medical treatments or as novel drug formulations. Cocoa powder is frequently used in nutrition and is known to have many benefits thanks to its wide range of biological activities. The presented study was focused on th evaluation of the anti-inflammatory potential of extracts obtained from cocoa...
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Nomos Verlagsgesellschaft mbH & Co. KG
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Elżbieta Hallmann dr inż.
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Different Routes of Proton Pumps Inhibitors Co-Administration have Significant Impact on Mycophenolate Acid (MPA) Serum Levels in Heart Transplant Recipients
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Effective perturbation signal and measurement of corrosion rate. Response to the commentary of Diard and co-workers concerning the paper in Corros. Sci. 37, 913 (1995)
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The effect of oxidized cholesterol on barrier functions and IL-10 mRNA expression in human intestinal epithelium co-cultured with dendritic cells in the transwell system
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Co-Existence of Iron Oxide Nanoparticles and Manganese Oxide Nanorods as Decoration of Hollow Carbon Spheres for Boosting Electrochemical Performance of Li-Ion Battery
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Staphylococcus aureus Co-Infection in COVID-19 Patients: Virulence Genes and Their Influence on Respiratory Epithelial Cells in Light of Risk of Severe Secondary Infection
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Enhanced mid-infrared 2.7 μm luminescence in low hydroxide bismuth-germanate glass and optical fiber co-doped with Er3+/Yb3+ ions
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Investigation of upconversion luminescence in antimony–germanate double-clad two cores optical fiber co-doped with Yb /Tm3+ and Yb3+/Ho3+ ions
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Nanoemulsion Structural Design in Co-Encapsulation of Hybrid Multifunctional Agents: Influence of the Smart PLGA Polymers on the Nanosystem-Enhanced Delivery and Electro-Photodynamic Treatment
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High-performance anode-supported solid oxide fuel cells with co-fired Sm0.2Ce0.8O2-δ/La0.8Sr0.2Ga0.8Mg0.2O3−δ/Sm0.2Ce0.8O2-δ sandwiched electrolyte
PublicationIn this study, intermediate-temperature solid oxide fuel cells (IT-SOFCs) with a nine-layer structure are constructed via a simple method based on the cost-effective tape casting-screen printing-co-firing process with the structure composed of a NiO-based four-layer anode, a Sm0.2Ce0·8O2-δ(SDC)/La0·8Sr0.2Ga0.8Mg0·2O3−δ (LSGM)/SDC tri-layer electrolyte, and an La0·6Sr0·4Co0·2Fe0·8O3-δ (LSCF)-based bi-layer cathode. The resultant...
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Relationship between Telomere Length, TERT Genetic Variability and TERT, TP53, SP1, MYC Gene Co-Expression in the Clinicopathological Profile of Breast Cancer
PublicationThe molecular mechanisms of telomerase reverse transcriptase (TERT) upregulation in breast cancer (BC) are complex. We compared genetic variability within TERT and telomere length with the clinical data of patients with BC. Additionally, we assessed the expression of the TERT, MYC, TP53 and SP1 genes in BC patients and in BC organoids (3D cell cultures obtained from breast cancer tissues). We observed the same correlation in the...
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3D mesoporous α-Co(OH)2 nanosheets electrodeposited on nickel foam: A new generation of macroscopic cobalt-based hybrid for peroxymonosulfate activation
PublicationCobalt-based catalysts with high stability and facile recovery for heterogeneous peroxymonosulfate (PMS) activation are still rather sparse and therefore highly desirable. Herein, 3D mesoporous α-Co(OH)2 nanosheets was created on robust nickel foam (NF) via facile electrodeposition approach at 6 mA/cm2 for only 400 s. Almost complete removal of phenol can be achieved within 7 min with a degradation rate of 0.39 min−1, 2 times higher...
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Synthesis of eosin modified TiO2 film with co-exposed {001} and {101} facets for photocatalytic degradation of para-aminobenzoic acid and solar H2 production
PublicationOwing to the increasing photosensitivity and DNA damage properties of para-aminobenzoic acid (PABA), concerns have been raised over the exposure of humans to PABA. Solar light-driven photocatalysis (SPC) provides a promising solution for the effective removal of organic pollutants especially when directed towards sulfate radical (SO4−) production. Herein, we have developed a sulfite-enhanced SPC using Eosin-Y sensitized TiO2/Ti...
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Mn-Co spinel coatings on Crofer 22 APU by electrophoretic deposition: Up scaling, performance in SOFC stack at 850 °C and compositional modifications
PublicationCeramic coatings for metallic interconnects play a key role in limiting corrosion and chromium evaporation in solid oxide cells. This study presents the upscaling of the electrophoretic deposition (EPD) technique to process Mn-Co spinels on real-dimension Crofer 22 APU interconnects and the test in a SOFC stack. Area specific resistance of long-term test conducted for 5000 h at 850 °C demonstrated that two-steps sintering has a...
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Evolution of the nanostructure of Pt and Pt–Co polymer electrolyte membrane fuel cell electrocatalysts at successive degradation stages probed by X-ray photoemission
PublicationWe present a set of XPS (X-ray photoemission spectroscopy) measurements and detailed data-analysis of electrodes for polymer electrolyte membrane fuel cell (PEMFC) based on carbon supported catalysts (Pt and Pt–Co) subjected to a step-like potential cycling (accelerated degradation test). The results of the measurements complete and corroborate parallel TEM (transmission electron microscopy), XRD (X-ray diffraction) and XAS (X-ray...
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The influence of screw configuration and screw speed of co-rotating twin screw extruder on the properties of products obtained by thermomechanical reclaiming of ground tire rubber
PublicationThe results of our investigations on the process of continuous thermomechanical reclaiming of ground tire rubber (GTR) carried out using a twin screw extruder are presented.We used a co-rotating twin screw extruder with a special configuration of plasticizing unit, enabling generation of considerable shear forces. The influence of screw configuration and screw speed on breaking of chemical crosslink bonds contained in ground tire...
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Mechanistic insights and atmospheric implications of the degradation reaction of 3-methoxy-1-propanol by reaction with hydroxyl radicals and identification of the end products in the presence of O2/NO
PublicationThe study investigated the degradation of 3-methoxy-1-propanol (3M1P) by OH using the M06-2X/6-311++G(d,p) level, with CCSD(T) single-point corrections. We focused on hydrogen atom abstraction from various alkyl groups within the molecule. The rate coefficient for 3M1P degradation was calculated from the sum of the rate coefficients corresponding to the removal of H-atoms from primary (-CH3), secondary (-CH2-), tertiary (-CH<),...
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The influence of the size of a one-faced metallic head in Janus nanoparticles as a co-catalyst on the photocatalytic efficiency of hydrogen evolution under vis light irradiation
PublicationJanus nanoparticles (NPs) consisting of MoOxSy nanospheres and silver (Ag) head, successfully developed by a simple, controlled method were in the first time they were applied as a co-catalysts in photocatalytic hydrogen generation reaction under vis light irradiation (λ > 420 nm). The MoOxSy-Ag as a co-catalysts were deposited on the obtained ZnIn2S4 microspheres (ZIS) using physical absorption method. The influence of the size...
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Electrical and noise responses of the ink-printed WS2-based gas sensor for sensing mixtures of NO2 and NH3 under UV light (275 nm)
Open Research DataThe data set consists of results collected for the resistive gas sensor composed of 2D flakes of tungsten disulfide (WS2) printed on the ceramic substrate: 1) time-resolved DC resistance measurements and 2) low-frequency noise measurements realized in the dark and under UV light assistance (275 nm) for selected gas atmospheres (NO2 and NH3 as target...
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Distribution of Relaxation Times analysis results of impedance of porous Sr0.86Ti0.65Fe0.35O3 oxygen electrode (sintered at 1000 °C) as a function of measuring temperature at 0.1% pO2
Open Research DataThis dataset contains results of Distribution of Relaxation Times analysis (DRT) of impedance of porous Sr0.86Ti0.65Fe0.35O3 oxygen electrode as a function of measuring temperature at 0.1% pO2. Electrode was sintered at 1000 °C and measured at different temperatures (800 °C, 750 °C, 700 °C).
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Electrical and noise responses of the ink-printed MoS2-based gas sensor for sensing of NO2, NH3 and C3H6O under UV light (275 nm)
Open Research DataThis data set consists of DC data, low-frequency noise spectra data and UV-vis spectroscopy data collected for ink-printed MoS2-based resistive sensors (2D MoS2 overlapping flakes creating a continuous layer on the ceramic substrate). The sensors were investigated toward three target gases - nitrogen dioxide (1-10 ppm), ammonia (2-12 ppm) and acetone...
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Superconductivity in Bismuth Pyrochlore Lattice Compounds RbBi2 and CsBi2: The Role of Relativistic Effects
PublicationSuperconducting properties of two bismuthide intermetallic compounds, RbBi2 and CsBi2, were studied by means of experimental measurements and ab initio calculations. We show that in both compounds, the superconductivity emerges from the pyrochlore Bi lattice and its formation is heavily influenced by relativistic effects. Based on our analysis of the effect of spin–orbit coupling on the electron–phonon coupling, we suggest a possible...
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Technological capability dynamics through cluster organizations
PublicationPurpose – The purpose of the paper is to portrait how members of cluster organizations (COs) perceive the role of COs in enabling them to accumulate technological capability (TC) significant for their innovation. Design/methodology/approach – The authors report the findings from their qualitative study based on an analysis of four COs. The organizational inertia and absorptive capacity (AC) theories are the theoretical underpinning...
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A. Computational analysis by molecular docking of thirty alkaloid compounds from medicinal plants as potent inhibitors of SARS-CoV-2 main protease(2020). Focused on analysis of the Medicinal plants that have potential therapeutic ability against COVID-19.
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Singlet oxygen in the removal of organic pollutants: An updated review on the degradation pathways based on mass spectrometry and DFT calculations
PublicationThe degradation of pollutants by a non-radical pathway involving singlet oxygen (1O2) is highly relevant in advanced oxidation processes. Photosensitizers, modified photocatalysts, and activated persulfates can generate highly selective 1O2 in the medium. The selective reaction of 1O2 with organic pollutants results in the evolution of different intermediate products. While these products can be identified using mass spectrometry...
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The Emission and Combustion Characteristics of Marine Diesel Engine with Extreme Throttled of Air or Exhaust Ducts
PublicationPresented paper shows the results of the laboratory tests on the relationship between the extreme throttling of both air intake duct and exhaust gas duct and gaseous emission from the marine engine. The object of research is a laboratory, 4-stroke, DI diesel engine, operated at loads from 50 kW to 250 kW at a constant speed equal to 750 rpm. During the laboratory tests the thermodynamic and exhaust gas emission characteristics...
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Modelowanie polskiego podsystemu wytwarzania energii elektrycznej w programie MARKAL ze szczególnym uwzględnieniem Europejskiego Systemu Handlu Emisjami
PublicationArtykuł dotyczy problematyki emisji gazów cieplarnianych w Unii Europejskiej oraz działań mających na celu ich redukcję, w szczególności Europejskiego Systemu Handlu Emisjami (EU ETS). Model polskiego podsystemu wytwarzania energii elektrycznej, uwzględniający mechanizmy EU ETS, został opracowany za pomocą pakietu optymalizacyjnego MARKAL. Do modelu wprowadzono dane zebrane na podstawie dostępnych projektów, rozporządzeń i danych...
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Exergetic Analysis of the nCO2PP Cycle with Particular Reference to the Exergy Destruction of Sewage Sludge Due to Gasification
PublicationAn exergy analysis is carried out on the negative CO2 emission gas power plant (nCO2PP), which integrates the process sections of fuel preparation, power generation and carbon capture. Processes of exergy destruction are studied with particular focus on the process in the gasification unit of the fuel preparation section, where a large amount of exergy is destroyed in various chemical reactions from sewage sludge to producer gas...
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The role of particulate and colloidal substrate in biological nutrient removal activated sludge systems
PublicationThe authors investigated COD fractionation according to the physical state (soluble/colloidal/particulate) in four wastewater treatment plants (WWTPs) in northern Poland. It was found that particulate and colloidal organic compounds constituted up to 70% of total COD. On the other hand, according to literature data, municipal wastewater contains readily and slowly biodegradable substrates in the amount of approximately 10-30% and...