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Size-dependent effects of ZnO nanoparticles on the photocatalytic degradation of phenol in a water solution
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Zinc oxide nanoparticles toxicity toDaphnia magna: size-dependent effects and dissolution
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Numerical Analyses of Fracture Mechanism of the Pelvic Ring during Side-Impact Load
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In situ optical studies of thermal stability of iodine-doped polyazomethine thin films
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Cadmium tri-tert-butoxysilanethiolates. Structural and spectroscopic models of metal sites in proteins.
PublicationW publikacji opisano syntezy i struktury dla dwóch heteroleptycznych kompleksów kadmu z rdzeniem CdS2NO2 i CdS2N2. Bis(tri-tert-butoksysilanotiolato)(1-metyloimidazol)kadmu(II) oraz bis(tri-tert-butoksysilanotiolato)bis(1-metyloimidazol)kadmu(II) współistnieją w roztworze chloroformu przy różnych stężeniach Bis(tri-tert-butoksysilanotiolanu) kadmu(II) i 1 metyloimidazolu. Rotzwór ten został scharakteryzowany za pomocą analizy spektralnej...
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PtCo cathode electrocatalyst behaviour viewed by in-situ XAFS fuel cell measurements
PublicationW pracy zostały przedstawione wstępne wyniki analizy XAS (X-ray absorption spectroscopy), TEM (transmission electron microscopy) i XRD (X-ray diffraction) nanostruktur PtCo 1:1 (20% fazy metalicznej osadzonej na węglu, Vulcan XC-72) używanych jako elektrokatalizatory w polimerowych ogniwach paliwowych (PEM FC). Pomiary realizowane były również w warunkach pracy ogniwa paliwowego za pomocą specjalnie zoptymalizowanej do pomiarów...
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Novel calix[4]resorcinarenes with side azobenzo-15-crown-5 residues
PublicationZsyntezowano nowe kaliks[4]rezorcareny z dwoma lub czteroma resztami azobenzo-15-korony-5 w dowolnym pierścieniu. Związki te otrzymano w reakcji kondensacji rezorcynolu z odpowiednimi aldehydami (acetalami).
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Miniaturized passive emission test chamber for in-situ measurement of emissions of organic compounds
PublicationThe results of many different studies have demonstrated unequivocally that the quality of indoor air is often much worse than that of atmospheric air (outdoor). One of the main groups of chemical compounds present in indoor air, with proven harmfulness to health,are volatile organic compounds (VOCs). VOCs present indoor comprise a wide variety of hydrocarbons and hydrocarbons derivatives including aliphatic, aromatics, alkylbenzens,...
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Miniaturized Passive Emission Chambers for In Situ Measurement of Emissions of Volatile Organic Compounds
PublicationThe results of many different studies have demonstrated unequivocally that the quality of indoor air is often much worse than that of atmospheric air. The presence of dangerous chemical compounds in indoor air can have an adverse impact on human health and cause numerous diseases of the respiratory and circulatory systems. Such harmful chemicals get into indoor air as a result of their emission from building and indoor materials....
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Insight into the Effect of ZIF‐8 Particle Size on the Performance in Nanocarbon‐Based Supercapacitors
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Effect of pyridine extraction on the pyrolysis of a perhydrous coal based on in-situ FTIR analysis
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Weighted-Sum Approach for Bi-objective Optimization of Fleet Size with Environmental Aspects
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Modified nanodiamond particle size studies by means of dynamic light scattering technique
PublicationThe Methods Utilizing the Phenomena of Light Scattering to Measure Particle Size distribution in different solvent, such as deionise water and alcohol and also to study the various structural formation when nanodiamond solution is placed on silicon surface. The purpose of this research project is divided into two parts to configure the measurement units for examining modified nanodiamond particles, examination...
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Modified nanodiamond particle size studies by means of dynamic light scattering technique
PublicationThe Methods Utilizing the Phenomena of Light Scattering to Measure Particle Size distribution in different solvent, such as deionise water and alcohol and also to study the various structural formation when nanodiamond solution is placed on silicon surface. The purpose of this research project is divided into two parts to configure the measurement units for examining modified nanodiamond particles, examination...
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SEM and TEM Studies on <i>In-Situ</i> Cast Al–TiC Composites
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Rare coexistence of unilateral erythema nodosum with erysipelas in the area of previous adder bite
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Comparative Analysis of CpG Sites and Islands Distributed in Mitochondrial DNA of Model Organisms
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Local atomic order in low Pt-content nanocatalysts investigated in situ by XAS
PublicationThe unique features of X-ray absorption spectroscopy allow investigations of nanosized catalysts for fuel cells under working conditions. We present the results of an experiment carried out on a low Pt content electrocatalyst supported by a mesoporous heteropolyacid salt and used at the cathode of a proton exchange membrane fuel cell (PEMFC). The analysis of the EXAFS signal at the Pt L3-edge indicates that upon operating the fuel...
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Zeta potential, effective diameter and multimodal size distribution in oil/water emulsion
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Advances in Pd Nanoparticle Size Decoration of Mesoporous Carbon Spheres for Energy Application
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Bulk quantity and physical properties of boron nitride nanocapsules with a narrow size distribution
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Pathological Changes in Early Medieval Horses from Different Archaeological Sites in Poland
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The effect of gold shape and size on the properties and visiblelight-induced photoactivity of Au-TiO2
PublicationtIn the present investigation, TiO2modified with a different geometry and size of gold particles, suchas nanospheres (NSPs), nanostars (NSTs) and nanorods (NRs), were prepared by the immobilizationmethod. The effect of the gold shape, size and TiO2matrix type (TiO2microspheres or rutile TIO-6 TiO2)were systematically investigated. The obtained photocatalysts were thoroughly characterized by UV–visdiffuse-reflectance spectroscopy...
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Analizy numeryczne i badania in situ innowacyjnego wiaduktu zespolonego VFT-WIB
PublicationDziedzina konstrukcji zespolonych w mostownictwie jest jedną z ciągle rozwijających się. Uwarunkowania wynikające z ciągle udoskonalanych i automatyzowanych procesów produkcji, technologii spawania oraz optymalizacji kosztów wymagają od projektantów nieustannych poszukiwań nowych rozwiązań konstrukcyjnych. Jednym z innowacyjnych obiektów wybudowanych w ostatnim czasie w Polsce jest wiadukt zespolony w ciągu drogi krajowej nr 22,...
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Badania in situ i analizy numeryczne mostu typu extradosed w Gdańsku
PublicationJednym z najnowszych typów konstrukcji wśród obiektów mostowych są mosty typu extradosed. Pierwsze konstrukcje tego typu powstały w latach 70-tych XX wieku. Stanowią one hybrydę pomiędzy sprężonym mostem belkowym, a mostem podwieszonym. W pracy przedstawiono analizy numeryczne oraz przeprowadzone badania in situ dla mostu typu extradoes w Gdańsku .Przedstawiono założenia, wyniki oraz wnioski z przeprowadzonych badań oraz analiz...
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Objective relaxation algorithm for reliable simulation-driven size reduction of antenna structure
PublicationThis letter investigates reliable size reduction of antennas through electromagnetic-driven optimization. It is demonstrated that conventional formulation of the design task by direct footprint miniaturization with imposing constraints on electrical performance parameters may not lead to optimum results. The reason is that—in a typical antenna structure—only a few geometry parameters explicitly determine the antenna footprint,...
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Composite Sandwich Footbridge – Numerical ESL FEM Calculations vs. In Situ Measurements
PublicationSelected results of the static analysis of composite sandwich footbridge with the corresponding in situ measured values are compared in the paper. The analysed bridge is a research object, which was built in 2015 and is currently located at the Gdańsk University of Technology campus. Since it is a novel structure, a proper definition of the bridge numerical model, allowing its safe design, is very important. Therefore, instead...
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Size-Reduction-Oriented Design of Compact CPW-Fed UWB Monopole Antenna
PublicationA structure and design optimization of compact CPW-fed UWB monopole antenna is presented. Explicit size reduction through constrained numerical optimization of all relevant geometry parameters of the structure leads to a very small footprint of only 321 mm2. At the same time, a very wide antenna bandwidth is achieved from 3.1 GHz to 17 GHz.
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The effect of nanoparticles size on photocatalytic and antimicrobial properties of Ag-Pt/TiO2 photocatalysts
PublicationAg-Pt-modified TiO2 nanocomposites were synthesized using the sol–gel method. Bimetallic modified TiO2 nanoparticles exhibited improved photocatalytic activity under visible-light irradiation, better than monometallic Ag/TiO2 and Pt/TiO2 nanoparticles (NPs). All modified powders showed localized surface plasmon resonance (LSPR) in visible region. The photocatalysts’ characteristics by X-ray diffractometry (XRD), scanning transmission...
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Underwater in situ local heat treatment by additional stitches for improving the weldability of steel
PublicationIn this paper the influence of in situ local heat treatment performed by additional stitches on the weldability of high-strength low-alloy (HSLA) S355J2C+N steel was tested. The investigated steel is characterized by high susceptibility to cold cracking. It is necessary to find a method to improve the quality of welded joints. The local heat treatment was applied as an eect of bead-on plate welding made on the face of a Tekken...
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Size Exclusion Coupled to Reversed Phase Liquid Chromatography for the Characterization of Cranberry Products
PublicationA combination of solvent extraction, size exclusion purification, and reversed-phase liquid chromatography with UV absorption and fluorescence detection was here used for the determination of flavan-3-ols and related oligomeric compounds in cranberry products. The method relied on robust, simple, and inexpensive instrumental equipment present in most of routine analytical laboratories. Sample extracts in methanol/water/hydrochloric...
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Effect of Particle Size of Fly Ash Microspheres (FAMs) on the Selected Properties of Concrete
PublicationThis paper presents the investigations of selected properties of concrete containing two fractions of fly ash microspheres (FAMs) with grain size up to 200 μm and up to 500 μm. Concrete mixtures with ordinary Portland cement and three substitution rates of cement by FAMs, 1.3%, 2.0%, and 2.6%, were investigated. For all concrete mixes, the constant water–binder ratio (w/b) equal to 0.50 was used. The research program included the...
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Influence of the fragment size on the recycling process of thin-film modules based on CdTe
PublicationFor several years, the production of second generation cells (the so-called thin film), produced from amorphous silicon, cadmium telluride (CdTe) or copper indium (gallium) diselenide (CI(G)S), has been increasing. The total number of end-of-life panels by 2050 is expected to reach 9.57 million tonnes. They contain heavy metals that can be leached into the environment at the land field. The EU directive on waste electrical and...
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Influence of the Shear Cap Size and Stiffness on the Distribution of Shear Forces in Flat Slabs
PublicationThe scope of this paper is to investigate analytically and numerically the influence of shear cap size and stiffness on the distribution of shear forces in flat slabs in a slab–column-connections-reinforced concrete structure. The effect of support (shear cap) stiffness on the calculation of the length of the shear control perimeter according to the available methods is presented. Based on the analysis, the authors indicate in...
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Permeability of sandy soils estimated from particle size distribution and field measurements
PublicationAccurate estimation of soil permeability is crucial in many geotechnical applications. Empirical and theoretical equations based on soil particle size distribution (PSD) offer a fast and cheap way for preliminary estimation of permeability in granular soils, however the results obtained from various formulas available in the literature often show significant discrepancies. While several comparative studies on this topic have been...
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Determination of p-y curves for offshore piles based on in-situ soil investigations
PublicationOffshore piles are subjected to complex loads with considerable lateral component. The pile-soil response to lateral loads can be described with the p-y method. For a given depth the load–deflection relationship is built to simulate the surrounding soil stiffness. This state-of-art paper presents a brief discussion of determination methods for the p-y curves using a standard approach based on the soil parameters derived from laboratory...
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Mutually polarizable QM/MM model with in situ optimized localized basis functions
PublicationWe extend our recently developed quantum-mechanical/molecular mechanics (QM/MM) approach [Dziedzic et al., J. Chem. Phys. 145, 124106 (2016)] to enable in situ optimization of the localized orbitals. The quantum subsystem is described with ONETEP linear-scaling density functional theory and the classical subsystem – with the AMOEBA polarizable force field. The two subsystems interact via multipolar electrostatics and are fully...
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Technical and Economic Analysis of an Intermediate Size Photovoltaic Power Plant. Case Study
PublicationThe article presents an analysis of the construction of a photovoltaic power plant with an installed capacity of about 30 kW. The principles of selecting the basic elements of the plant are shown. The impact of a high constant price on the profitability of the project is highlighted. The article also describes the existing mechanisms for subsidizing the investment.
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Receiver-side fingerprinting method for color images based on a series of quaternion rotations
PublicationThe proposed method is a new Joint Fingerprinting and Decryption (JFD) method that uses a cipher based on quaternion rotation to encrypt color images that are then sent to all users via multicast transmission. Individual encryption keys depend on the users’ fingerprints, so that a unique fingerprint is introduced into the image during decryption for each decryption key. A simulation-based research was conducted to examine the method’s...
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Application of polarisation-maintaining side-hole fibres do direct force measurement
PublicationW pracy przedstawiono zastosowanie utrzymujących polaryzację światłowodów typu Side Hole do bezpośredniego pomiaru siły. Dla wybranych struktur tych światłowodów wyznaczono, przy pomocy Metody Elementów Skończonych i metody modów sprzężonych, czułość na siłę działającą prostopadle do osi symetrii światłowodu. Określono zależność tej czułości od poszczególnych wymiarów struktur tych światłowodów. Następnie, biorąc pod...
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Wzmacnianie gruntu in situ metodą wgłębnego mieszania i wykorzystanie cemento gruntu
PublicationOpisano zasady wykonywania mieszania wgłębnego gruntu przy zastosowaniu suchych spoiw oraz zaczynu cementowego. Pierwszy sposób, określany jako metoda mieszania na sucho, zastosowano w Polsce m.in. do posadowienia nasypów drogowych w ramach budowy przeprawy mostowej przez Regalicę. Drugi sposób, określany jako mieszanie na mokro, zastosowano m.in. do wzmocnienia gruntów pod Trasą Zieloną w Lublinie oraz do wykonania uszczelnień...
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The synthesis of 1,4,7,10-tetraazacyclododecanes with acetylsalicylic side arm as potential cobalt(II) fluorophores.
PublicationMonoacylowe pochodne 1,4,7,10-tetraazacyklododekanu otrzymano w bezpośredniej reakcji cyklenu z chlorkiem kwasu salicylowego, jak również przy użyciu trichronionego cyklenu. Monoacylową pochodną wykorzystano następnie w reakcji z fosforynem etylu otrzymując difunkcyjny związek. Otrzymane ligandy zbadano spektrofotometrycznie. Obydwa ligandy oddziaływują selektywnie z jonami Co(II), tworząc kompleksy o stechiometrii 2:1 i 1:1 (ligand:metal).
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Zastosowanie dyskretnych łańcuchów Markowa do modelowania udziału w sile roboczej.
PublicationW pracy przedstawiono możliwości zastosowania dyskretnych łańcuchów Markowa do opisu przepływu strumieni siły roboczej w województwie Pomorskim. Dokonano estymacji macierzy prawdopodobieństw przejścia pomiędzy wyróżnionym stanami. Na podstawie ocen prawdopodobieństw przejścia obliczono indeks mobilności Bartholomew'a. Z przeprowadzonych badań wynika, iż procesy Markowa z czasem dyskretnym są bardziej adekwatnym opisu przepływu...
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The effect of plate size on the natural convective heat transfer intensity of horizontal surfaces
PublicationW pracy przedstawiono badania wpływu rozmiarów płyty prostokątnej poziomej na intensywność wymiany ciepła w warunkach konwekcji swobodnej. Zaproponowano dwa zakresy: dla płyt o wymiarze charakterystycznym mniejszym niż 0,1 m - 0,2 m intensywność konwekcyjnej wymiany ciepła jest odwrotnie proporcjonalna do szerokości płyty, dla płyt szerszych niż 0,2 m szerokość płyty nie wpływa znacząco na współczynnik konwekcyjnej wymiany ciepła....
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Dynamic control of the receiving beam horizontal cross-section in the side scan sonar
PublicationW skonstruowanych przed kilkunastu laty a obecnie modernizowanych sonarach bocznych jako jeden z zabiegów modernizacyjnych wprowadzono dynamiczną regulację kąta rozwarcia odbiorczej charakterystyki kierunkowej w przekroju horyzontalnym. Regulacja taka zapewnia quasi-stałą rozdzielczość liniową sonaru (zamiast stałej rozdzielczości kątowej) przy odbiorze sygnałów echa ze wzrastających odległości od wykrywanych celów. W efekcie tego...
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Modelling of size effects in concrete using elasto-plascity with non-local softening
PublicationArtykuł przedstawia numeryczne symulacje MES efektów skali w materiałach kruchych takich jak beton , wykonane w warunkach płaskiego stanu odkształceń. Materiał był modelowany w ramach sprężysto-plastyczności z izotropowym wzmocnieniem i osłabieniem. W obszarze ściskania przyjęto liniowe kryterium Druckera-Pragera z niestowarzyszonym prawem płynięcia a w obszarze rozciągania liniowe kryterium Rankina ze stowarzyszonym prawem płynięcia....
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Adolfo Poma
PeopleI am the group leader of the computational modelling of biomolecules divison at the institute of Fundamental Technological Research Polish Academy of Sciences in Poland. My group was hosted between 2021-2022 by International Centre for Research on Innovative Bio-based Materials (ICRI-BioM). In 2008, I got a Master degree in computational physics from the State University of Campinas, Brazil. Then I moved to Germany and under the...
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Reactive metabolites of acridinone antitumor agents, C-1311 and C-1305, are trapped within the active site of CYP1A2 and CYP3A4, causing irreversible enzymes inactivation
PublicationZwiązki C-1305 i C-1311, zsyntetyzowane w Katedrze Technologii Leków i Biochemii, wykazują najsilniejsze właściwości przeciwnowotworowe wśród pochodnych, odpowiednio, triazolo- i imidazoakrydonu. Obecnie prowadzone są badania mające na celu określenie biochemicznego mechanizmu działania, jak również potencjalnych szlaków biotransformacji C-1305 i C-1311.W bieżącym etapie podjęto próbę określenia mechanizmu obserwowanej inhibicji...
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Evidence for widespread occurrence of copper in Late Neolithic Poland? A deposit of Funnel Beaker Culture bone products at site 2 in Osłonki (Kuyavia, central Poland)
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Simple Physics-Based Analytical Formulas for the Potentials of Mean Force for the Interaction of Amino Acid Side Chains in Water. 3. Calculation and Parameterization of the Potentials of Mean Force of Pairs of Identical Hydrophobic Side Chains
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