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Effect of transglutaminase and EDC on biodegradation of fish gelatin and gelatin-chitosan films
PublicationCelem pracy było zbadanie podatności usieciowanych folii opakowaniowych z naturalnych polimerów na enzymatyczną hydrolizę. Niemodyfikowane folie żelatynowe były całkowicie hydrolizowane przez pepsynę i proteinazę N oraz w 60% przez pepsynę. Sieciowania przy użyciu transglutaminazy lub EDC zmiejszyło podatność folii na hydrolizę tylko przez pepsynę. Obecność chitozanu w dwuskładnikowych foliach modyfkownych EDC zmniejszyła stopień...
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Temperature Impact of Nitrogen Transformation in Technological System: Vertical Flow Constructed Wetland and Polishing Pond
PublicationThe article describes the results of the research, purpose of which was to evaluate influence of the temperature on the effectiveness of nitrification and denitrification in the sewage treatment system consisting of vertical flow constructed wetland and polishing pond. During the analysed period, the efficiency of removing total nitrogen was low and amounted to 12.7%. In the polishing pond in the summer period, content of total...
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New thiourea organocatalysts and their application for the synthesis of 5-(1H-indol-3-yl)methyl-2,2-dimethyl-1,3-dioxane-4,6-diones a source of chiral 3-indoylmethyl ketenes
PublicationThe stereoselective properties of modified thiourea organocatalysts were tested in the Friedel–Crafts alkylation of indole with 5-arylidene-2,2-dimethyl-1,3-dioxane-4,6-diones, which produces chiral 5-((1H-indol-3-yl)(aryl)methyl)-2,2-dimethyl-1,3-dioxane-4,6-diones. Based on a tentative reaction mechanism for ((S)-N-benzyl-2-(3-(3,5-bis (trifluoromethyl)phenyl)thioureido)-N,3,3-trimethylbutanamide organocatalysts, modifications...
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Multicomponent layers for aluminium alloys surface consolidation
PublicationThe main reason of the surface modification of the components such as pistons and cylinder blocks made of cast aluminium alloys is to obtain high hardness, wear and corrosion resistance of the working surface for larger lifetime of the motor-car and aircraft engines. In that aspect, the new conception of development - by hybrid method - of surface layers containing manganese, nitrogen, sulphur (Mn-N-S) and manganese, nitrogen,...
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Synthesis, Structure, and Spectroscopic Properties of Calcium Thiophenecarboxylate Polymers. Structural Comparison with Analogous Lead Complexes
PublicationThree novel calcium coordination polymers [Ca(2tpCOO)2(2mpa)(H2O)]n (1), [Ca(3tpCOO)2(2mpa)(H2O)]n (2), and {[Ca(3tpacCOO)2(H2O)2]⋅⋅⋅H2O}n (3) (2tpCOO− or 3tpCOO− – thiophene-2- or thiophene-3-carboxylate, 3tpacCOO− – thiophene-3-acetate, 2mpa – 2-methylpropanal), were synthesised using a self-assembly method. The obtained polymers were characterised using SC-XRD, FTIR, UV-Vis DRS, thermogravimetric and luminescence analyses. The...
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Cooperativity of Halogen- and Chalcogen-Bonding Interactions in the Self-Assembly of 4‑Iodoethynyl- and 4,7-Bis(iodoethynyl)benzo-2,1,3-chalcogenadiazoles: Crystal Structures, Hirshfeld Surface Analyses, and Crystal Lattice Energy Calculations
PublicationSeveral new 4-iodoethynyl- and 4,7-bis- (iodoethynyl)benzo-2,1,3-chalcogenadiazoles were prepared, and a comprehensive analysis of the most prominent secondary bonding interactions responsible for the crystal self-assembly was performed using X-ray diffraction. The presence of both the iodoethynyl and chalcogenadiazole moieties allows an evaluation of the preference of these molecules to aggregate through either chalcogen- or halogen-bonding...
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Implication of the disulfide bridge in trypsin inhibitor SFTI-1 in its interaction with serine proteinases
PublicationFourteen monocyclic analogues of trypsin inhibitor SFTI-1 isolated from sunflower seeds were synthesized by the solid-phase method. The purpose of this work was to establish the role of a disulfide bridge present in inhibitor's side chains of Cys3 and Cys11 in association with serine proteinases. This cyclic fragment was replaced by the disulfide bridges formed by L-pencillamine (Pen), homo-L-cysteine (Hcy), N-sulfanylethylglycine...
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The effect of high pressure on formation of volatile amines in minced meat of cod (Gadus morhua)
PublicationThe effects of high pressure at subzero temperature (193 MPa, at −20 °C) on inactivation of natural microflora of cod meat and degradation of trimethylamine oxide (TMAO) to trimethylamine (TMA) during refrigerated storage and to dimethylamine (DMA) and formaldehyde (FA) during frozen storage were investigated. The content of TMA, DMA and FA in cod meat did not change immediately after pressure treatment. During 40 days of frozen...
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A novel (Ti/Ce)UiO-X MOFs@TiO2 heterojunction for enhanced photocatalytic performance: Boosting via Ce4+/Ce3+ and Ti4+/Ti3+ redox mediators
PublicationTitanium-substituted cerium-oxo-based UiO MOFs with terephthalate linkers modified by various groups (–Br, –NH2, –NO2) or their derivatives (N-heterocyclic or biphenyl groups) were combined with titanium dioxide in a multistep route to obtain a core-shell-like architecture. DFT simulations showed that Ce- and bimetallic Ti/Ce- MOFs exhibited different charge compensation. Extended characterization revealed the formation of heterojunctions between...
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Restrained differential of a graph
PublicationGiven a graph $G=(V(G), E(G))$ and a vertex $v\in V(G)$, the {open neighbourhood} of $v$ is defined to be $N(v)=\{u\in V(G) :\, uv\in E(G)\}$. The {external neighbourhood} of a set $S\subseteq V(G)$ is defined as $S_e=\left(\cup_{v\in S}N(v)\right)\setminus S$, while the \emph{restrained external neighbourhood} of $S$ is defined as $S_r=\{v\in S_e : N(v)\cap S_e\neq \varnothing\}$. The restrained differential of a graph $G$ is...
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Inhibition effect of free ammonia on deammonification process under different intermittent aeration strategies in sequencing batch reactor
PublicationThe deammonification process involves two steps. The first step is the partial nitrification of ammonia (NH4-N) by ammonia oxidizing bacteria (AOB) to produce nitrite (NO2-N) and the second step is the anammox process to “anaerobically” oxidize ammonia to nitrogen gas with nitrite as an electron acceptor (Lackner et al., 2014). Free ammonia (FA) plays a significant role in the stable, long-term deammonification system operation....
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Density, sound velocity, viscosity, and refractive index of new morpholinium ionic liquids with amino acid-based anions: Effect of temperature, alkyl chain length, and anion
PublicationIn this work, room temperature synthesis of twenty new ionic liquids (ILs) based on the N-alkyl-N-methylmorpholinium ([Mor1,R], R = 2, 3, 4, 6, 8) cation and N-acetyl-L-amino acid anions (L-alaninate, L-valinate, L-leucinate, L-isoleucinate) was described. The synthesized ILs were characterized by various spectroscopic techniques and high-resolution mass spectrometry. Furthermore, density (ρ), sound velocity (v), viscosity (η)...
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2,2,6,6-Tetramethylpiperidinium pentachlorobenzenethiolate
PublicationMetodą rentgenowskiej analizy strukturalnej wyznaczono strukturę krystaliczną i cząsteczkową tytułowego związku. Charakterystycznym motywem struktury determinowanej przez wiązania wodorowe N-H...S, jest izolowany dimer (silanotiol-amina)2.
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Low-dimensional bound entanglement with one-way distillable cryptographic key
PublicationIn this paper, we provide a class of bound entangled states that have positive distillable secure key rate. The smallest state of this kind is 4 circle times 4, which shows that peculiar security contained in bound entangled states does not need high-dimensional systems. We show that for these states a positive key rate can be obtained by one-way Devetak-Winter (DW) protocol. Subsequently, the volume of bound entangled key-distillable...
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Power equalization of AES FPGA implementation
PublicationThis paper briefly introduces side channel attacks on cryptographic hardware with special emphasis on differential power analysis(DPA). Based on existing countermeasures against DPA, design method combining power equalization for synchronous and combinatorialcircuits has been proposed. AES algorithm has been implemented in Xilinx Spartan II-E field programmable gate array (FPGA) deviceusing the standard and power-equalized methods....
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Fabrication of toughened plastic using styrene butadiene rubber-poly (methyl methacrylate) interpenetrating polymer networks
PublicationA standard set of interpenetrating polymeric networks (IPNs) has been contrived using an elastomerstyrene butadiene rubber and a thermoplastic poly (methyl methacrylate) through sequential polymerization protocol. This low-cost material can be hopefully engaged as a toughened plastic with cocontinuous morphology. Different morphological protocols including Raman imaging are effectively utilized to envisage the effect of blend ratio...
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Increase in wear resistance of nickel plasma coatings under traditional and combined treatment conditions
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Kinematic analysis of crank -cam mechanism of process equipment
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Efficiency of hybrid equipment combining operations of surface hardening by high frequency currents and abrasive grinding
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Research into properties of wear resistant ceramic metal plasma coatings
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High Q-factor Microwave Fabry-Perot Resonator With Distributed Bragg Reflectors
PublicationZrealizowany został rezonator Fabry-Perot pracujący na częstotliwości 39 GHz i wykorzystujący dwie pary ćwierćfalowych kwarcowych reflektorów Bragga. Dla fali o długości 98.26 mm otrzymano dobroć ok. 560,000, co oznacza 4.3-krotny wzrost w porównaniu z identycznym rezonatorem bez reflektorów Bragga. Analizę problemu wykonano przy pomocy metody różnic skończonych w dziedzinie częstotliwości (FDFD) i porównano z uproszczonym rozwiązaniem...
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Bis(2-methylquinolinium) tetrachloroferrate(III) chloride
PublicationW krysztale współkrystalizują tetrachlorożelazian i chlorek 2-metylochinoliny. Anion tetrachlorożelazianowy wykazuje nieuporządkowanie. W strukturze występują wiązania wodorowe N-H...Cl oraz oddziaływania Fe-Cl...π oraz π...π.
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Quantification of Radiation-Induced Single-Strand Breaks in Plasmid DNA using a TUNEL/ELISA-Based Assay
PublicationWprowadzono nową metodę służącą do oznaczania in vitro pojedynczych pęknięć nici DNA powstałych pod wpływem naświetlań. Porównano wyniki otrzymane z nowej metody z modelem teoretycznym. Porównano wyniki z szeroko używaną metodą elektroforezy żelowej. Pokazano, że poziom pojedynczych pęknięć powstających w niciach DNA pod wpływem promieniowania VUV jest wyższy niż zakładany na podstawie wyników otrzymywanych metodami standardowymi.
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Rendezvous of Heterogeneous Mobile Agents in Edge-Weighted Networks
PublicationWe introduce a variant of the deterministic rendezvous problem for a pair of heterogeneous agents operating in an undirected graph, which differ in the time they require to traverse particular edges of the graph. Each agent knows the complete topology of the graph and the initial positions of both agents. The agent also knows its own traversal times for all of the edges of the graph, but is unaware of the corresponding traversal...
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Lipopeptides - synthesis and their properties
PublicationPrzedstawiono syntezę nowych peptydów zawierających Hyp, Met, Gly podstawionych w miejscu histydyny tripeptydu o sekwencji Gly-His-Lys oraz ich odpowiednie modyfikacje na N- i C-końcach. Syntezę zaprojektowanych analogów prowadzono na fazie stałej z zastosowaniem procedury Fmoc. Po otrzymaniu zaplanowanego łańcucha peptydowego metodą karbodiimidową (z zastosowaniem DIC oraz HOBt), przystąpiono do wprowadzania na N-koniec glicyny...
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Enhancing nitrogen removal in the partial denitrification/anammox processes for SO4− - Rich wastewater treatment: Insights into autotrophic and mixotrophic strategies
PublicationThe investigation of partial denitrification/anammox (PD/anammox) processes was conducted under autotrophic (N–S cycle) and mixotrophic (N–S–C cycle) conditions over 180 days. Key findings revealed the remarkable capability of SO42--dependent systems to produce NO2− effectively, supporting anaerobic NH4+ oxidation. Additionally, SO42− served as an additional electron acceptor in sulfate reduction ammonium oxidation (SRAO). Increasing...
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Optimization of Chemical Functionalities of Indole-2-carboxamides To Improve Allosteric Parameters for the Cannabinoid Receptor 1 (CB1)
Publication5-Chloro-3-ethyl-N-(4-(piperidin-1-yl)phenethyl)-1H-indole-2-carboxamide (1; ORG27569) is a prototypical allosteric modulator for the cannabinoid type 1 receptor (CB1). Here, we reveal key structural requirements of indole-2-carboxamides for allosteric modulation of CB1: a critical chain length at the C3-position, an electron withdrawing group at the C5-position, the length of the linker between the amide bond and the phenyl ring...
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The effects of different aeration modes on ammonia removal from sludge digester liquors in the nitritation–anammox proces
PublicationThe aim of this study was to determine the impact of continuous and intermittent aeration on the rate of ammonia removal in the combined nitritation–anammox process. This process was run in two parallel sequencing batch reactors (SBRs), with a working volume V = 10 L, treating sludge digester liquors from the Gdansk (Poland) wastewater treatment plant (WWTP). The ammonia oxidizing bacteria were cultivated from activated sludge...
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Rendezvous of heterogeneous mobile agents in edge-weighted networks
PublicationWe introduce a variant of the deterministic rendezvous problem for a pair of heterogeneous agents operating in an undirected graph, which differ in the time they require to traverse particular edges of the graph. Each agent knows the complete topology of the graph and the initial positions of both agents. The agent also knows its own traversal times for all of the edges of the graph, but is unaware of the corresponding traversal...
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Super Dominating Sets in Graphs
PublicationIn this paper some results on the super domination number are obtained. We prove that if T is a tree with at least three vertices, then n2≤γsp(T)≤n−s, where s is the number of support vertices in T and we characterize the extremal trees.
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XPS analysis of the GO based materials
Open Research DataGraphene oxides samples were measured by XPS method. The X-ray photoemission spectroscopy measurements were carried out with Omicron NanoTechnology UHV equipment. The hemispherical spectrophotometer was equipped with a 128-channel collector. The XPS measurements were performed at room temperature at a pressure below 1.1 × 10−8 mBar. The photoelectrons...
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Place attachment, place identity and aesthetic appraisal of urban landscape
PublicationAs the aesthetic of the Polish cities became a topic of wider discussions, it is important to detect the potentialrole of human-place relations. Two studies (N = 185 & N = 196) were conducted to explore the relationship betweenplace attachment, place identity and appraisal of urban landscape. Satisfaction with urban aesthetic was predicted by twodimensions of place attachment (place inherited and place...
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Effect of temperature and ionic strength on volumetric and acoustic properties of solutions of urea alkil derivatives in aqueous NaCl
PublicationThe present work was undertaken to study volumetric and acoustic properties for diluted solutions of tetramethylurea in pure water and for urea, n-propylurea, n-butylurea and tetramethylurea in 0.5 or 1 moldm3 aqueous solutions of sodium chloride. This paper presents measured values of densities and sound velocities at T = (288.15, 298.15 and 308.15) K. From these data the apparent molar volumes, , adiabatic compressibilities,...
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Analogues of trypsin inhibitor SFTI-1 modified in the conserved P1′ position by synthetic or non-proteinogenic amino acids retain their inhibitory activity
PublicationA series of linear and monocyclic (with a disulfide bridge only) analogues of trypsin inhibitor SFTI-1 modified in the P-1 and/or P-1' positions were synthesized by the solid-phase method. In the substrate specificity P-1 position, Phe or N-benzylglycine (Nphe) were introduced, whereas the conserved Ser6 in Bownam-Birk (BBI) inhibitors was replaced by Hse (L-homoserine), Nhse [N-(2-hydroxyethyl)glycine], Sar, and Ala. Kinetic studies...
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Binuclear Co(II), Zn(II) and Cd(II) tri-tert-butoxysilanethiolates. Synthesis, crystal structure and spectroscopic studies.
PublicationA series of Co(II), Zn(II) and Cd(II) complexes have been synthesized in reaction of respective metal tri-tert-butoxysilanethiolates with pyrazine 1 and 2 and 1,2-bis(2-pyridyl)ethylene 3–5. All compounds have been characterized by single-crystal X-ray structure determination, elemental analysis, FT-IR and thermogravimetry. Obtained complexes are bimetallic with the formula of [M{SSi(OtBu)3}2(μ-L)]2 and metal ions bridged by N,N′-spacer....
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A more colorful hat problem
PublicationThe topic is the hat problem in which each of n players is randomly fitted with a blue or red hat. Then everybody can try to guess simultaneously his own hat color by looking at the hat colors of the other players. The team wins if at least one player guesses his hat color correctly, and no one guesses his hat color wrong; otherwise the team loses. The aim is to maximize the probability of winning. We consider a generalized hat...
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ortho-Fluorobenzanilides and ortho-fluorothiobenzanilides: Molecular conformations and crystal packing
PublicationSeries of 2-fluoro and 2,6-difluorobenzanilides and their thiobenzanilide analogs have been synthesized to investigate the influence of the fluorine atom on their crystal structures and self-assembly in the crystal lattice. The X-ray analysis of the single crystal revealed that the synthesized molecules adopt a geometry being deflected from planarity. The deflection was investigated by analysis of dihedral angles between mean planes...
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Układy cyfrowe zbudowane w oparciu o bramki prądowe: stan obecny i zastosowania.
PublicationW pracy omówiono stan obecny oraz perspektywy rozwoju i zastosowania bramek cyfrowych pracujących w trybie prądowym, a także różnego rodzaju układów cyfrowych zbudowanych z bramek prądowych. Praca podsumowuje kilkuletnie badania autorów nad koncepcją bramki prądowej i jej realizacją, podstawami algebry bramek prądowych oraz sposobów projektowania i weryfikacji cyfrowych układów prądowych działających w standardowej logice binarnej...
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Dynamic Perfect hashing with finite-state automata
PublicationMinimalna doskonała funkcja mieszająca dostarcza odwzorowania zbioru n niepowtarzalnych słów w zwarty zakres n liczb całkowitych. Gdy jest realizowane za pomocą automatów skończonych, odwzorowanie wynika z porządku słów (zwykle alfabetycznego) w zbiorze. Dodanie nowych słów zmieniłoby porządek słów rozpoznawanych przez automat, zmieniając całe odwzorowanie i czyniąc je bezużytecznym w wielu dziedzinach. Dlatego nazywamy je statycznym....
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1,1,2,2-Tetrakis(diisopropylamino)diphosphane
PublicationTytułowy związek otrzymano w trakcie badań raktywności (i-Pr2N)2P-P(SiMe3)Li z Cp2ZrCl2 (Cp-cyklopentadienyl). Strukturę C24H56N4P2 wyznaczono metodą rentgenowskiej analizy strukturalnej. Wiązanie P-P należy do najdłuższych wśród tego typu wiązań wyznaczonych dla niekoordynowanych difosfanów. W sieci krystalicznej obserwuje się nieuporządkowanie...
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Porównanie heurystyk dla problemu szeregowania zadań czasowo-zależnych o wspólnym podstawowym czasie wykonywania
PublicationW pracy rozważany jest następujący, jednoprocesorowy problem szeregowania zadań czasowo-zależnych. danych jest n+1 zadań o czasach wykonywania postaci pi = a + bisi, gdzie si oznacza czas rozpoczęcia wykonywania i-tego zadania, a > 0, bi > 0, i = 0, 1, ..., n. wszystkie zadania są niepodzielne i dostępne w chwili t0 = 0. należy znaleźć harmonogram minimalizujący łączny czas zakończenia. w pracy przedstawiono algorytm, który, o...
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Characterization of fatty acids composition in the European beaver (Castor fiber L.).
PublicationW pracy przedstawiono zawartość lipidów , klas lipidów i skład kwasów tłuszczowych lipidów ogólnych uzyskanych z różnych tkanek bobra europejskiego (tkanka okołojelitowa, tkanka okołonerkowa, miesień uda, mięsień kreskowy, podskórna tkanka tłuszczowa, ogon). Wykazano różnice w zawartości lipidów i składzie KT w tkankach samic (n=7) i samców (n=3). Wykazano wysokie zawartości nienasyconych KT w tkankach bobrów w porównaniu z tkankami...
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Nitrogen conversion during treatment of various type of wastewater in multistage treatment wetlands
PublicationThe objective of this investigation was to recognize nitrogen speciation during wastewater treatment in three multistage TWs (MTWs), which are assuming more a most effective in nitrogen removal than single stage TWs. Carried out investigations and analysis enable for determination of conditions, relationships and processes responsible for nitrogen conversions in subsequent stages of MTWs. In treated wastewater and reject water...
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Photoconduction and magnetic field effect on photoconduction in hole-transporting star-burst amine (m-MTDATA) films
PublicationPhotoconduction and magnetic field effect on photoconduction have been investigated as a function of electric field strength, excitation light intensity and wavelength in vacuum evaporated films of m-MTDATA (4,4′,4″-tris(N-(3-methylphenyl)-N-phenylylamino) triphenylamine), the starburst amine commonly used as hole-transporting material in organic light-emitting diodes. The photocurrent is found to be generated by the singlet exciton...
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Palladium versus Platinum: The Metal in the Catalytic Center of a Molecular Photocatalyst Determines the Mechanism of the Hydrogen Production with Visible Light
PublicationTo develop highly efficient molecular photocatalysts for visible light-driven hydrogen production, a thorough understanding of the photophysical and chemical processes in the photocatalyst is of vital importance. In this context, in situ X-ray absorption spectroscopic (XAS) investigations show that the nature of the catalytically active metal center in a (N^N)MCl2 (M=Pd or Pt) coordination sphere has a significant impact on the...
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A note on total reinforcement in graphs
PublicationIn this note we prove a conjecture and inprove some results presendet in a recent paper of N. Sridharan, M.D. Elias, V.S.A. Subramanian, Total reinforcement number of a graph, AKCE Int. J. Graphs Comb. 4 (2) (2007) 197-202.
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Przetwarzanie sygnałów i obrazów, WIMiO, II st., Mechatronika sem.02 - 22/23 (PG_00057031)
e-Learning CoursesCelem przedmiotu jest nabycie wiedzy w zakresie zaawansowanych metod przetwarzania i analizy sygnałów i obrazów cyfrowych. Zakres obejmuje zagadnienia dotyczące filtracji cyfrowej sygnałów i obrazów (w tym próbkowanie nierównomierne), analiza widmowa i estymacja gęstości widmowej mocy, widma wyższych rzędów, filtr Wienera i Kalmana, liniowa i nieliniowa filtracja adaptacyjne, analiza czasowo-częstotliwościowa (STFT, falkowa), metody...
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Przetwarzanie sygnałów i obrazów, WIMiO, II st., Mechatronika sem.02 - 23/24 (PG_00057031)
e-Learning CoursesCelem przedmiotu jest nabycie wiedzy w zakresie zaawansowanych metod przetwarzania i analizy sygnałów i obrazów cyfrowych. Zakres obejmuje zagadnienia dotyczące filtracji cyfrowej sygnałów i obrazów (w tym próbkowanie nierównomierne), analiza widmowa i estymacja gęstości widmowej mocy, widma wyższych rzędów, filtr Wienera i Kalmana, liniowa i nieliniowa filtracja adaptacyjne, analiza czasowo-częstotliwościowa (STFT, falkowa), metody...
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The 2:1 cocrystal of benzamide and pentafluororbenzoic acid
PublicationKrystaliczna struktura centrosymetrycznej supermolekuły składa się z czterech cząsteczek benzamidu oraz dwóch kwasu karboksylowego, które powiązane są ze sobą za pomocą wiązań wodorowych typu O-H...O oraz N-H...O.
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Scheduling on Uniform and Unrelated Machines with Bipartite Incompatibility Graphs
PublicationThe problem of scheduling jobs on parallel machines under an incompatibility relation is considered in this paper. In this model, a binary relation between jobs is given and no two jobs that are in the relation can be scheduled on the same machine. We consider job scheduling under the incompatibility relation modeled by a bipartite graph, under the makespan optimality criterion, on uniform and unrelated machines. Unrelated machines...