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Wyniki wyszukiwania dla: Ti-based alloys
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Ti-Fe2O3/In2O3 as photoactive material: The role of the substrate in photoelectrochemical water oxidation
PublikacjaThe layers of Ti-Fe2O3/In2O3 were prepared on the different substrates using hydrothermal method: Ti/TiO2 nanotubes, Ti foil, FTO and FTO/TiO2. Materials were characterized using scanning electron microscopy, XRD, Raman, UV-Vis, and X-ray photoelectron spectroscopy and tested as photoanodes for water oxidation under illumination. The formation of heterojunction on the TiO2 nanotubes increases photocurrent of water oxidation at...
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Nanoindentation tests titanium alloy Ti-6Al-4V after interference laser treatment
PublikacjaThe study aimed was to assess selected mechanical properties of surface layers obtained after interference laser treatment – DLIL of titanium alloy Ti-6Al-4V used for implants. The samples were melted in still air at room temperature, for this purpose Nd:YAG laser was used, the number of laser shots was variable. Next, nanoindentation tests were performed, based on which Young’s modulus and nanohardness in the obtained surface...
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Superconductivity of Ta-Hf and Ta-Zr alloys: Potential alloys for use in superconducting devices
PublikacjaThe electronic properties relevant to superconductivity are reported for bulk Ta-Hf and Ta-Zr body centered cubic alloys, in a large part to determine whether their properties are suitable for potential use in superconducting qbits. The body centered cubic unit cell sizes increase with increasing alloying. The results of magnetic susceptibility, electrical resistivity, and heat capacity characterization are reported. While elemental...
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Hydrogen-enhanced degradation and oxide effects in zirconium alloys for nuclear applications
PublikacjaThe zirconium alloys used in nuclear industry include mainly ZreSn and ZreNb alloys ofdifferent chemical composition, microstructure and susceptibility to both hydrogendegradation and oxidation. The hypothetic nuclear accidents can create a real danger tothe Zr alloys and stability of parts made of these alloys, and especially such as loss ofcoolant accident (LOCA) and reactivity initiated accidents (RIA). The hydrogen degradationcan...
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An approach for evaluating trust in it infrastructures
PublikacjaW artykule zademonstrowano metodę oceny poziomu zaufania do systemu TI w oparciu o podejście funkcji przekonania.
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Application and mechanical properties of aluminium alloys
PublikacjaThe paper presents a short survey of the application and mechanical properties of aluminium alloys. This area of scientific research is still developing, the authors restricted it to about 30 papers. Numerical simulations of the aluminium bracket are also investigated. The authors propose a solution to increase the load capacity of aluminium brackets with application of the additional cover plates. This study is proposed as an...
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Multicomponent layers for aluminium alloys surface consolidation
PublikacjaThe main reason of the surface modification of the components such as pistons and cylinder blocks made of cast aluminium alloys is to obtain high hardness, wear and corrosion resistance of the working surface for larger lifetime of the motor-car and aircraft engines. In that aspect, the new conception of development - by hybrid method - of surface layers containing manganese, nitrogen, sulphur (Mn-N-S) and manganese, nitrogen,...
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Structure and thermoelectric properties of Bi–Te alloys obtained by novel method of oxide substrates reduction
PublikacjaA novel method of thermoelectric materials fabrication has been developed. Oxide reagents have been melted at high temperature in air, quenched, milled to powder and reduced in hydrogen to form Bi–Te alloys. Structural and thermoelectric properties of samples have been investigated depending on initial composition and temperature of reduction process. Sample 25Bi2O3–75TeO2 reduced at 340 °C for 10 h has been found to be a p-type...
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Dynamical properties of ordered Fe–Pt alloys
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Electrical and mechanical characterization of two-phase alloys by means of scanning probe microscopy in dynamic impedance spectroscopy mode
PublikacjaDynamic impedance spectroscopy, evaluated for measuring non-stationary systems, was used in combination with scanning probe microscope. Using this approach, localized impedance measurements in the AFM contact mode could be carried out. Additionally, impedance–force curves were made at each phase of investigated materials to illustrate the relation between impedance and the force applied to a probe. Therefore, correlation of electrical...
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Influence of Laser Modification on the Surface Character of Biomaterials: Titanium and Its Alloys—A Review
PublikacjaLaser surface modification is a widely available and simple technique that can be applied to different types of materials. It has been shown that by using a laser heat source, reproducible surfaces can be obtained, which is particularly important when developing materials for medical applications. The laser modification of titanium and its alloys is advantageous due to the possibility of controlling selected parameters and properties...
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Influence of Laser Modification on the Surface Character of Biomaterials: Titanium and Its Alloys—A Review
PublikacjaLaser surface modification is a widely available and simple technique that can be applied to different types of materials. It has been shown that by using a laser heat source, reproducible surfaces can be obtained, which is particularly important when developing materials for medical applications. The laser modification of titanium and its alloys is advantageous due to the possibility of controlling selected parameters and properties...
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Hydrogen degradation of pre-oxidized zirconium alloys
PublikacjaThe presence of the oxide layers on Zr alloys may retard or enhance the hydrogen entry and material degradation, depending on the layer features. This research has been aimed to determine the effects of pre-oxidation of the Zircaloy-2 alloy at a different temperature on hydrogen degradation. The specimens were oxidised in laboratory air at 350°C, 700°C, and 900°C. After, some samples were tensed at 10-5 strain rate and simultaneously...
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Review on friction stir welding of dissimilar magnesium and aluminum alloys: Scientometric analysis and strategies for achieving high-quality joints
PublikacjaMagnesium and aluminum alloys continually attract interest as lightweight structural materials for transport applications. However, joining these dissimilar alloys is very challenging. The main obstacle that hinders progress in dissimilar Mg-Al joining is the formation of brittle intermetallic compounds (IMCs). As a solid-state joining technique, FSW is an excellent candidate to attenuate the deleterious IMC effects in dissimilar...
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Identification of Bodner-Partom Viscoplastic Model Parameters for Some Aluminum Alloys at Elevated Temperature
PublikacjaThe paper presents the identification process of inelastic (viscoplastic) properties for two aluminum alloys at a temperature of 120°C. The material parameters are calculated on the basis of uniaxial tension tests. Twelve tests at elevated temperature for each alloy have been performed—three tests for four different strain rates. The main purpose of the paper is to identify the Bodner-Partom viscoplastic model parameters for two...
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Selective Laser Melting of Ti Alloy for Manufacturing The Prosthetic Elements
PublikacjaThe selective laser melting (SLM) is the additive manufacturing method of custom-designed parts. The used materials and the applications are various, including medicine. The titanium and its alloys are materials for which the dimensional quality, surface smoothness and no or extremely low porosity are difficult to reach. In this paper, the successful attempt to obtain by SLM the individually designed prosthetic bridges is described....
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High temperature corrosion and corrosion protection of porous Ni22Cr alloys
PublikacjaIn this work corrosion kinetics of the porous IN625 alloy is studied in the temperature range of 700 °C – 800 °C in air and humidified hydrogen for up to 1000 hours. Moreover, an effective and simple method of reducing corrosion rates of porous alloys by the infiltration of the rare earths elements is shown. Modification by the yttrium containing precursor reduces the corrosion rate by a factor of 50 in air at 700 °C so that the...
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Nanostructuring of thin Au films deposited on ordered Ti templates for applications in SERS
PublikacjaIn this work the results on thermal nanostructuring of the Au films on Ti templates as well as morphology and optical properties of the obtained structures are reported. The bimetal nanostructures are fabricated in a multi-step process. First, the titania nanotubes are produced on the surface of Ti foil by anodization in an ethylene glycol-water solution containing fluoride ions. This is followed by chemical etching in oxalic acid...
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Nanotubular Ti Oxide Layers for Enhancement of Bone-Implant Bonding and Bioactivity
PublikacjaAbstrakt artykułu pt. ''Nanotubular Ti Oxide Layers for Enhancement of Bone-Implant Bonding and Bioactivity''. The paper describes techniques to improve the bioactivity of titanium and ehnahnce the bone-implant bonding ability by the electrochemical anodization to fabricate titania nanotubular oxide layer.
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Cyclic behaviour modelling of additively manufactured Ti-6Al-4V lattice structures
PublikacjaThe present work is concerned with the numerical modelling of the cyclic behaviour of Ti-6Al-4V lattice structures. In the study, diamond structures of titanium alloy produced by the additive laser powder bed fusion (LPBF) method with different degrees of relative density were used. Realistic geometric models of the studied mesostructures were generated using computed microtomography, taking into account the imperfections of the...
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Influence of Surface Laser Treatment on Mechanical Properties and Residual Stresses of Titanium and its Alloys
PublikacjaSurface modification of the titanium and its alloys used in implantology with a long-pulse laser can change the surface topography, but it also leads to changes in the stress sign and magnitude in the resulting subsurface layer. The presented research was aimed at evaluating the state of stress after laser remelting with the Nd:YAG laser of pre-etched titanium alloys Ti6Al4V and Ti13Nb13Zr and pure titanium. The obtained surface...
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Investigation of corrosion behavior of 6060 and 6082 aluminum alloys under simulated acid rain conditions
PublikacjaInstantaneous impedance changes of 6060 and 6082 type aluminum alloys in pure water, and simulated acid rain poured into the pure water was investigated by dynamic electrochemical impedance spectroscopy (DEIS). In this way, the influence of aluminum content on the corrosion behavior of 6060 and 6082 type aluminum alloys immersed in simulated acid rain was determined. The corrosion rate of the alloy decreased with increasing Al...
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X-ray Photoelectron Spectroscopy of Carboxylic Acids as Corrosion Inhibitors of Aluminium Alloys
PublikacjaThe datasets, titled X-ray Photoelectron Spectroscopy studies of citric acid adsorption on aluminium alloy 5754 in alkaline media and X-ray Photoelectron Spectroscopy studies of various carboxylic acids adsorption on aluminium alloys in alkaline media, contain XPS studies of the corrosion inhibitory action of selected dicarboxylic acids towards commercially available aluminium alloy 5754 in alkaline media at pH=11. These datasets...
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Application of Shape Memory Alloys in Pipeline Couplings for Shipbuilding
PublikacjaThe aim of the study is to analyse shape memory alloy (SMA) pipeline joints in limited space applications for all kinds of ships. Generally, the space available in various areas on ships is strictly limited and service works usually meet many obstacles. If we consider a pipeline, the flange joints always require a larger free space around the pipe than the pipe alone. A simultaneous problem can occur with the propeller shaft line...
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Prosthetic Elements Made of the Ti-13Zr-13Nb Alloy by Selective Laser Melting
PublikacjaThe fabrication of the prosthetic foundations and bridges from the Ti-13Zr-13Nb alloy is described. The process was started from CAD/CAM design of 3D models of the foundations based on scanning of patient`s mouth. Next, 3D models were transformed into *.stl files for the manufacturing stage and then the manufacturing process by means of the selective laser melting with the SLM Realizer 100 equipment was made. The intrinsic structure...
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Structure and properties of liquid Al–Cu alloys: Empirical potentials compared
PublikacjaWe report on the structure and mass transport properties of liquid Al–Cu alloys predicted by two recently-developed empirical many-body potentials: MEAM (Jelinek et al., 2012) and EAM-ADP (Apostol and Mishin, 2011), and by the well-known Gupta potential. Total and partial pair correlation functions, angular distribution functions, densities, coordination numbers and self-diffusion coefficients are compared with published experimental...
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Fabrication, Microstructure and High Temperature Corrosion Resistance of Porous Alloys for Solid Oxide Fuel Cells
PublikacjaPorous alloys find use in modern Solid Oxide Fuel Cells as the supporting structures. As they are exposed to high temperatures (> 500°C) an oxide scale forms on their surface due to high temperature corrosion phenomena. Since the ratio between the surface area and volume is much higher than for planar samples, formation of the oxide can lead to a breakaway oxidation after relatively short times. Therefore corrosion properties of...
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Experimental and theoretical investigation of the reactivity of [(BDI*)Ti(Cl){η2-P(SiMe3)-PiPr2}] towards selected ketones
PublikacjaIn this work, we report a new type of reactivity of [(BDI*)Ti(Cl){η2-P(SiMe3)-PiPr2}] (1) towards ketones (BDI* = 2,6-diisopropylphenyl-β-methyldiketiminate ligand). In the reaction of 1 with acetone, cyclopentanone or cyclohexanone, a ketone moiety is inserted into Ti–Pphosphanyl or Ti–Pphosphido bonds to form complexes with a new C–P–P moiety, providing [(BDI*)Ti(Cl){η2-P(SiMe3)-PiPr2-C(Me)2O}] (2a), [(BDI*)Ti(Cl){η2-OC(Me)2P(SiMe3)-PiPr2}]...
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Influence of microstructure on properties of 18Cr-10Ni-Ti stainless steel products.
PublikacjaBadano wpływ mikrostruktury na właściwości mechaniczne i odporność korozyjną wyrobów ze stali austenitycznej 18Cr-10Ni-Ti po przesycaniu z temperatury 1050 C. Wykazano, że węgliki TiC w ziarnach i na granicach ziaren/bliźniaków powodują znaczne obniżenie wydłużenia stali. Węgliki TiC na granicach ziaren/bliźniaków obniżają odporność na korozję międzykrystaliczną i sprzyjają powstawaniu uszkodzeń korozyjnych podczas hutniczej operacji...
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Electrophoretically deposited titanium and its alloys in biomedical engineering: Recent progress and remaining challenges
PublikacjaOver the past decade, titanium implants have gained popularity as the number of performed implantation operations has significantly increased. There are a number of methods for modifying the surface of biomaterials, which are aimed at extending the life of titanium implants. The developments in this field in recent years have required a comprehensive discussion of all the properties of electrophoretically deposited coatings on...
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Ti/TiO2 nanotubes sensitized PbS quantum dots as photoelectrodes applied for decomposition of anticancer drugs under simulated solar energy
PublikacjaOne of the challenges in research into photoelectrocatalytic (PEC) degradation of pollutants is finding the appropriate photoanode material, which has a significant impact on the process efficiency. Among all others, photoelectrodes based on an ordered TiO2 nanotube arrays are a promising material due to well-developed surface area and efficient charge separation. To increase the PEC activity of this material, the SILAR method was...
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Wpływ nadtapiania laserowego w warunkach kriogenicznych na strukturę warstwy wierzchniej stopu Ti-6Al-4V = Effect of laser melting at cryogenic conditions on structure of the surface layer of the Ti-6Al-4V alloy
PublikacjaWykonano nadtapianie laserowe stopu Ti-6Al-4V zanurzonego w środowisku ciekłego azotu. Badania mikroskopowe wykazały znaczący wpływ parametrów nadtapiania na grubość, mikrostrukturę i mikrotwardośc warstwy wierzchniej.
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Efficient method for octahedral NH2-MIL-125 (Ti) synthesis: Fast and mild conditions
PublikacjaA new hot injection method for preparing octahedral NH2-MIL-125 (Ti) was developed. This method is six times faster and conducted under milder conditions, i.e., at 120°C in a flask, and exhibits higher crystal formation efficiency than the commonly used solvothermal method while maintaining comparable structural, optical, and photocatalytic properties.
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Cavitation erosion of some laser-produced iron-base corrosion-resistance alloys
PublikacjaW pracy przedstawiono badania kawitacyjne stali C45, X20Cr13 oraz X5CrNi18-10 po laserowym stopowaniu ich warstwy wierzchniej proszkami Mn, Cr, Ni, Si, Ti, Co, Al, Mo, B. Badania kawitacyjne prowadzono na stanowisku z wirującą tarczą. Zniszczenia powierzchni w okresie inkubacji oceniano metodą optyczną. Przedstawiono związek pomiędzy uzyskaną mikrostrukturą obrabianej warstwy i jej odpornością kawitacyjną.
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Pre-oxidation of porous ferritic Fe22Cr alloys for lifespan extension at high-temperature
PublikacjaPre-oxidation of porous ferritic Fe22Cr alloys was extensively studied in this paper. Weight gain measurements and SEM analysis revealed that pre-oxidation performed at 900◦C for 40 min increased the lifespan of the alloy. A Cr evaporation study did not disclose any significant influence of the pre-oxidation process on the Cr content in the alloy. For a more detailed assessment, TEM imaging and X-ray tomography measurements of...
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Effect of native air-formed oxidation on the corrosion behavior of AA7075 aluminum alloys
PublikacjaThe microstructure of aluminum alloys plays a key role in their corrosion resistance. In particular, the presence of intermetallic precipitates differing in the potential from the alloy matrix induces local corrosion. The study presents the effect of native air-formed oxidation on the corrosion behavior of AA 7075 aluminum alloy. Various microscopic and spectroscopic techniques were used to examine the changes occurring in the...
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Nanotubular oxide layers and hydroxyapatite coatings on ‘Ti–13Zr–13Nb’ alloy
PublikacjaThe presented research was aimed to determine the mechanical properties of the nanotubular oxide layer covered with hydroxyapatite coating. The Ti–13Zr–13Nb alloy was oxidised in 1M phosphoric acid with an addition of 0?5% HF for HF solution at 20 V voltage. The electrochemically assisted deposition of hydroxyapatite was performed at cyclic polarisation in NH4H2PO4 and CaCl2 solution at 80uC. The mechanical properties were determined...
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Influence of High Temperature Oxidation on Hydrogen Absorption and Degradation of Zircaloy-2 and Zr 700 Alloys
PublikacjaThe present research was aimed at determining the effects of the oxide layers on hydrogen absorption, microstructure and mechanical properties of the Zircaloy- 2 and Zr 702 alloys. The oxidation was made at 350 °C, 700 °C and 900 °C for 10 to 30 min in laboratory air, followed by hydrogen cathodic charging for 72 h and annealing at 400 °C for 4 h. The slow strain rate tests were carried out on oxidized, charged and annealed specimens. The...
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Korozyjne pękanie naprężeniowe stali 18Cr-10Ni-Ti w systemie chłodzenia za wodorowym reaktorem.
PublikacjaPrzedstawiono mechanizm korozyjnego pękania napręzeniowego stali austenitycznej 18Cr-10Ni-Ti w systemie chłodzenia za reaktorem instalacji hydrorafinacji olejów przepracowanych.
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Solvent Impact on the Diversity of Products in the Reaction of Lithium Diphenylphosphide and a Ti(III) Complex Supported by a tBu2P–P(SiMe3) Ligand
PublikacjaWe present two important trends in the reactivity ofthe titanium complex [MeNacNacTi(Cl){η2-P(SiMe3)-PtBu2}](MeNacNac− = [Ar]NC(Me)CHC(Me)N[Ar]; Ar = 2,6-iPr2Ph)with nucleophilic reagents RLi (R = Ph2P,tBuO, (Me3Si)2N, andtBu2N) depending on the reaction medium. Reaction in nonpolarsolvent (toluene) leads to three main products: via an autoredoxprocess and nucleophilic substitution at the Ti-atom to afford theTi(IV) complex [MeNacNacTi(R){η2-P-PtBu2}]...
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Nickel alloys in hydroprocessing units
PublikacjaPrzedstawiono uszkodzenia stopu niklu typu 825 w wyniku eksploatacji w chłodnicy powietrznej za reaktorem wodorowym w rafineryjnej instalacji przepracowanych olejów napędowych. Wyjaśnono korozyjno-erozyjny mechanizm niszczenia, zwracając uwagę na kruchość materiału w obecności wodoru i udarowego działania strumieni procesowych.
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A continual model of a damaged medium used for analyzing fatigue life of polycrystalline structural alloys under thermal–mechanical loading
PublikacjaThe main physical laws of thermal–plastic deformation and fatigue damage accumulation processes in polycrystalline structural alloys under various regimes of cyclic thermal–mechanical loading are considered. Within the framework of mechanics of damaged media, a mathematical model is developed that describes thermal–plastic deformation and fatigue damage accumulation processes under low-cycle loading. The model consists of three...
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Influence of laser remelting at cryogenic conditions on corrosion resistance of non-ferrous alloys
PublikacjaCelem nadtapiania laserowego elementów wytwarzanych z stopów aluminium, miedzi i tytanu jest uzyskanie wysokiej twadrości i odporności na korozję dla wydłużenia okresu ich eksploatacji w rezultacie ich szybkiej krystalizacji. Końcowa mikrostruktura, skład fazowy i właściwości wymienionych stopów zależą od parametrów obróbki laserowej oraz budowy wykresów równowagi fazowej. W artykule przedstawiono wpływ laserowego nadtapiania...
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Application and modelling of Shape-Memory Alloys for structural vibration control: State-of-the-art review
PublikacjaOne of the most essential components of structural design for civil engineers is to build a system that is resistant to environmental conditions such as harsh chemical environments, and catastrophic disasters like earthquakes and hurricanes. Under these circumstances and disturbances, conventional building materials such as steel and concrete may demonstrate inadequate performance in the form of corrosion, deterioration, oxidizing,...
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Thermoelectric properties of bismuth-antimony-telluride alloys obtained by reduction of oxide reagents
PublikacjaThe BieSbeTe alloys with different Bi/Sb/Te ratio were fabricated by an innovative method. For that purpose the oxide reagents were melted at high temperature, then quenched to form pellets, milled to a powder and finally reduced in hydrogen at various temperatures. Complex structures consisting of connected thin layers forming a continuous path between nano- and micrometer size grains have been obtained. The electrical conductivity,...
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Effect of double thermal and electrochemical oxidation on titanium alloys for medical applications
PublikacjaThe research focuses on the development and characterization of innovative thin hybrid oxide coatings obtained in subsequent processes of thermal (TO) and electrochemical (EO) oxidation. Four different surface modifications were investigated and the microstructure was determined, the mechanical, chemical and biological properties of the Ti-13Nb-13Zr alloy were assessed using scanning electron microscopy, X-ray dispersion analysis,...
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Synthesis and properties of HoT2Al20 (T = Ti, V, Cr) intermetallic cage compounds
PublikacjaPolycrystalline samples of HoT2Al20 (T = Ti, V, Cr) intermetallics were synthesized using a step-wise arc-melting technique. All three compounds adopt the CeCr2Al20-type crystal structure with Ho atoms positioned inside oversized icosahedral cages formed by Al atoms. The structure of HoV2Al20 compound is reported. The materials properties were studied by means of electrical resistivity, magnetic susceptibility, and specific heat...
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Effect of copper and silver modification of NH2-MIL-125(Ti) on the photoreduction of carbon dioxide to formic acid over this framework under visible-light irradiation
PublikacjaCu and Ag enhance the photocatalytic activities of metal–organic frameworks (MOFs) toward CO2 conversion because of their CO2 adsorption capacities and effects on the lowest unoccupied molecular orbital (LUMO) overpotentials of MOFs. However, to date, targeted introduction of metals into MOFs to achieve visible (Vis)- light-active photocatalysts for CO2 photoconversion has not been realized. Herein, a series of aminefunctionalized...
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Fluorine ions in photocatalysts’ synthesis: an obstacle or an ally? The investigation of photocatalysts in Ti-O-F system
PublikacjaTitanium(IV) oxide (TiO2) is one of the most promising photocatalysts, which is expected to be applied in the photocatalytic degradation of xenobiotics. For sustainable development and green chemistry approach recently, much effort has been paid to enhance TiO2 photocatalytic activity in UV-vis light by modifying its structure. The photocatalytic process’s complexity cannot be simply described as electron-hole pairs generations...
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Investigation of the Effects of Tool Positioning Factors on Peak Temperature in Dissimilar Friction Stir Welding of AA6061-T6 and AA7075-T6 Aluminum Alloys
PublikacjaAmong the emerging new welding techniques, friction stir welding (FSW) is used frequently for welding high-strength aluminum alloys that are difficult to weld by conventional fusion-welding techniques. This paper investigated the effects of tool-positioning factors on the maximum temperature generated in the dissimilar FSW joint of AA6061-T6 and AA7075-T6 aluminum alloys. Three factors of plunge depth, tool offset, and tilt angle...