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Wyniki wyszukiwania dla: ANALYTICAL ECO-SCALE
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Selectivity of lithium electrodes: correlation with ion-ionophore complexstability constants and with interfacial exchange current densities
PublikacjaMembranowe elektrody selektywne na jony litu oparte na dwóch różnych dicyk-lohesyloamidowych jonoforach poddane zostały systematycznym badaniom. Potencjometrycznie wyznaczono wartości współczynników selektywności. Wartości stałych trwałości kompleksów z jonami litu, sodu i potasu wyznaczono metodą membran "sandwichowych". Transfer ładunków przez membranę oraz przez granicę faz membrana/roztwór badano metodą spektroskopii impedancyjnej....
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Silica-Based Ionogels: Nanoconfined Ionic Liquid-Rich Fibers for Headspace Solid-Phase Microextraction Coupled with Gas Chromatography–Barrier Discharge Ionization Detection
PublikacjaIn this work, hybrid silica-based materials with immobilized ionic liquids (ILs) were prepared by sol–gel technology and evaluated as solid-phase microextraction (SPME) fiber coatings. High loadings of the IL 1-methyl-3-butylimidazolium bis(trifluoromethylsulfonyl)imide ([C4MIM][TFSI]) were confined within the hybrid network. Coatings composition and morphology were evaluated using scanning electron microscopy and energy dispersive...
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Application of dynamic headspace and gas chromatography coupled to mass spectrometry (DHS-GC-MS) for the determination of oxygenated volatile organic compounds in refinery effluents
PublikacjaThe paper presents a new procedure for the determination of oxygenated volatile organic compounds (O-VOCs) in postoxidative effluents from the production of petroleum asphalt using dynamic headspace coupled to gas chromatography-mass spectrometry in the selected ion monitoring (SIM) mode (DHSGC-MS). Among the GC capillary columns tested, a polar SLB-IL111 column with the ionic liquid stationary phase was found to be superior due...
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Sources of errors associated with the determination of PAH and PCB analytes in water samples
PublikacjaW pracy przedstawiono problemy związane z oznaczaniem analitów z grupy WWA i PCB w próbkach wody. Zidentyfikowano źródła błędów. Szczególną uwagę zwrócono na:- proces adsorpcji analitów na ściankach szklanych naczyń używanych w trakcie obróbki i przechowywania próbek,- wpływ etapu odparowywania nadmiaru rozpuszczalnika z ekstraktów na odzysk analitów,- wpływ materiału, z którego jest wykonana kolumienka ekstrakcyjna (szkła, polietylenu)...
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Neutral point balancing technique for 3-level neutral point clamped converter with servo system
PublikacjaNeutral point voltage drift compensation technique in 3-level NPC multilevel converter and servo system is described in the paper. Analytical expressions are obtained for power subsystem elements parameters of servo drive system. Simulation of servo system, based on PMSM motor with 3-level NPC converter is considered.
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Design advantages and analysis of a novel five-phase doubly-fed induction generator
PublikacjaPurpose – The purpose of this paper is to provide an analysis of the performance of a new five-phase doubly fed induction generator (DFIG). Design/methodology/approach – This paper presents the results of a research work related to fivephase DFIG framing, including the development of an analytical model, FEM analysis as well as the results of laboratory tests of the prototype. The proposed behavioral level analytical model is based...
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A novel method of creating thermoplastic chitosan blends to produce cell scaffolds by FDM additive manufacturing
PublikacjaDue to its remarkable and promising biological and structural properties, chitosan has been widely studied in several potential applications in the biomedical sector. Attempts are being made to use this polymer and its properties in thermoplastics dedicated to 3D printing in FDM technology. However, chitosan can be processed only from acid solution, which limits its applications. The paper presents a new path for the production...
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Dynamics of Chains as a Tool to Study Thermomechanical Properties of Proteins.
PublikacjaPolymer dynamics can be formulated on different levels of detail. One approach eliminates microscopic degrees of freedom and a polymer molecule is represented by a simplified structure—a chain. In the simplest case monomers of ideal chain have fixed length, and their orientation is independent of the orientations and positions of neighbouring monomers. This is reason that two monomers can co-exist at the same place. Ideal chain...
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Thermal Buckling Analysis of Circular Bilayer Graphene sheets Resting on an Elastic Matrix Based on Nonlocal Continuum Mechanics
PublikacjaIn this article, the thermal buckling behavior of orthotropic circular bilayer graphene sheets embedded in the Winkler–Pasternak elastic medium is scrutinized. Using the nonlocal elasticity theory, the bilayer graphene sheets are modeled as a nonlocal double–layered plate that contains small scale effects and van der Waals (vdW) interaction forces. The vdW interaction forces between the layers are simulated as a set of linear springs...
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Practical issues for the implementation of survivability and recovery techniques in optical networks
PublikacjaFailures in optical networks are inevitable. They may occur during work being done for the maintenance of other infrastructures, or on a larger scale as the result of an attack or large-scale disaster. As a result, service availability, an important aspect of Quality of Service (QoS), is often degraded. Appropriate fault recovery techniques are thus crucial to meet the requirements set by the Service Level Agreements (SLAs) between...
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Territorial Aspects of Entrepreneurial Activity in Polish Suburban Zones
PublikacjaGlobalization has led to an increased correlation and integration of various fields in modern civilization, including those connected with allocation of entrepreneurial functions. Connection, on a global scale, has shown an increased significance of worldwide corporations. Territorial allocation of the entrepreneurial function has become the subject of translocation and revaluation. Translocation can be understood as the change...
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Responsible Court in the Global World - Managerism or Managerialism
PublikacjaOne can look at the improvement of the effectiveness and efficiency of the justice system from three perspectives: macro, mezo, and micro. After all, the general goal is to enhance the effectiveness and efficiency of the justice system as a whole (the macro perspective), the courts (the mezo scale), and court proceedings (the micro scale). The need to improve the effectiveness and efficiency of the justice system was noticed in...
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Two-dimensional simulations of concrete fracture at aggregate level with cohesive elements based on X-ray lCT images
PublikacjaThe paper presents results of two-dimensional meso-scale simulations of fracture in notched concrete beams subjected to three-point bending test. Concrete was assumed as a 4-phase material composed of aggregate grains placed in the cement matrix, interfacial transitional zones (ITZs) and macro-voids. The particle distribution was taken from real concrete beams on the basis of X-ray lCT images. Comprehensive numerical analyses were carried...
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Zastosowanie spowalniania wypowiedzi w celu poprawy rozumienia mowy przez dzieci w szkole
PublikacjaThis paper presents a time-scale modification algorithms that could be used for hearing impairment therapy supported by real-time speech stretching. In this paper the OLA based algorithms and Phase Vocoder were described. In the experimental part usability of those algorithms for real-time speech stretching was discussed
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Job-related emotions and job burnout among civil servants: examining the shape of the relationship in cross-sectional and longitudinal models
PublikacjaWstęp: Związek pozytywności, czyli proporcji między pozytywnymi a negatywnymi emocjami, z wypaleniem zawodowym może przybierać kształt krzywoliniowy. Ponadto z perspektywy teoretycznej jest to relacja przyczynowo - skutkowa, w której pozytywność jest proksymalnym, a wypalenie – dystalnym wymiarem dobrostanu zawodowego. Dotychczasowe badania były jednak prowadzone najczęściej w planie poprzecznym i testowały relacje prostoliniowe....
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Isoprostanes-Biomarkers of Lipid Peroxidation: Their Utility in Evaluating Oxidative Stress and Analysis
PublikacjaIsoprostanes (IsoPs) are key biomarkers for investigating the role of free radical generation in the pathogenesis of human disorders. To solve IsoPs-related problems with regard to isoprostanes, analytical tools are required. This paper reviews the problems and trends in this field focusing on the methodology for assaying biomarkers in exhaled breath condensate (EBC) samples. A large amount of work has been done in the qualitative...
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Rapid Multi-band Patch Antenna Yield Estimation Using Polynomial Chaos-Kriging
PublikacjaYield estimation of antenna systems is important to check their robustness with respect to the uncertain sources. Since the Monte Carlo sampling-based real physics simulation model evaluations are computationally intensive, this work proposes the polynomial chaos-Kriging (PC-Kriging) metamodeling technique for fast yield estimation. PC-Kriging integrates the polynomial chaos expansion (PCE) as the trend function of Kriging metamodel...
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Improving Output Performance of the Ultrasonic Multicell Piezoelectric Motor by Development the Multi-Rotor Structure
PublikacjaIn recent years, many researches have been carried out on piezoelectric multi-rotor structures. This paper describes the analysis, development and experimental process of an ultrasonic multi-cell piezoelectric motor using a multi-rotor structure. In this design, three independent cells have been integrated into a mechatronic system. Analytical model and finite element method are used for modal and dynamic analysis of the proposed...
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Highly efficient maximum power point tracking control technique for PV system under dynamic operating conditions
PublikacjaThe application of small-scale electrical systems is widespread and the integration of Maximum Power Point Tracking (MPPT) control for Photovoltaic systems with battery applications further enhances the techno-economic feasibility of renewable systems. For this purpose, a novel MPPT control system using Dynamic Group based cooperation optimization (DGBCO) algorithm is utilized for PV systems. The population in the DGBCO is divided...
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Guided waves for nondestructive diagnostics of embedded waveguides
PublikacjaThe thesis concentrates on comprehensive theoretical, numerical and experimental analysis of guided wave propagation in bars embedded in concrete or mortar. The investigations are focused on a particular type of objects representing a laboratory model of a ground anchor. Complex description of wave propagation phenomena in partially embedded bars is given and its application in...
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INWESTYCJE A ZATRUDNIENIE W POLSCE W PERSPEKTYWIE FINANSOWE 2007-2013
PublikacjaNakłady inwestycyjne przedsiębiorstw traktowane są jako jeden z głównych czynników wzrostu gospodarczego. Ich wielkość i dynamika mogą mieć wpływ na zmiany w poziomie zatrudnienia. Światowy kryzys finansowy przyczynił się do spowolnienia dynamiki wzrostu oraz gwałtownego spadku w 2009 roku PKB w większości gospodarek świata. We wspomnianym okresie w Polsce zaobserwowano spowolnienie gospodarcze, które miało wpływ na decyzje...
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Environmental aspects of coastal earth structures made of soil-ash composites
PublikacjaThis paper presents an innovative technology of building the coastal dams with the use of soil-ash composites. A natural- scale test stand and results of the performed environmental tests are presented ; they have been compared with standards for purity of soils and waters. Also, an analysis of the obtained results and discussion of trends and anomalies in the observations, are given.
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Capacity Transforming challenges into opportunities
PublikacjaThe Urban Initiative Laboratory (UIL) aims to upgrade the smart city concept in Gdańsk by introducing the Food-Water-Energy (FWE) nexus to the city. It was agreed in the CRUNCH international consortium that projects on different scales would be implemented in the individual countries to test the Integrated Decision Supportive system platform, which would, in principle, concern urban scale. The regular urban scale was to be researched...
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Anterior subcutaneous transposition and simple decompression of the ulnar nerve at the elbow – the postoperative improvement in DASH score, VAS score and sonographic findings
PublikacjaIntroduction. Although a lot of studies have described long- term outcomes after surgical treatment of cubital tunnel syndrome, and the usefulness of sonography in diagnosing of this disorder, few studies have evaluated patients self-reporting outcomes or sonographic findings after surgery. Aim. We assessed patients self-reporting instruments and sonographic findings in patients with the cubital tunnel syndrome before and after...
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Combining MUSHRA Test and Fuzzy Logic in the Evaluation of Benefits of Using Hearing Prostheses
PublikacjaAssessing the effectiveness of hearing aid fittings based on the benefits they provide is crucial but intricate. While objective metrics of hearing aids like gain, frequency response, and distortion are measurable, they do not directly indicate user benefits. Hearing aid performance assessment encompasses various aspects, such as compensating for hearing loss and user satisfaction. The authors suggest enhancing the widely used...
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A review of recent advances in the single- and multi-degree-of-freedom ultrasonic piezoelectric motors
PublikacjaIn this paper a comprehensive review of recent studies on the ultrasonic piezoelectric motors is presented. The analytical, numerical and experimental analysis. In further sections, classification methods of piezoelectric motors, survey criteria and three main groups of ultrasonic piezoelectric motors with examples have been presented and described. Finally, the conclusions and future research perspectives have been proposed.
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Modelling of blood flow: from macro to microscales
PublikacjaThe aim of this paper it to review various scale approaches to blood flow modelling. Blood motion may be described by three types of mathematical models according to the observed scales or resolutions, namely microscopic, mesoscopic and macroscopic description. The above approaches are discussed together with their advantages and disadvantages. Several results of mesoscopic simulations are presented.
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Electroelastic biaxial compression of nanoplates considering piezoelectric effects
PublikacjaIn the present theoretical work, it is assumed that a piezoelectric nanoplate is connected to the voltage meter which voltages have resulted from deformation of the plate due to in-plane compressive forces whether they are critical buckling loads or arbitrary forces. In order to derive governing equations, a simplified four-variable shear deformation plate theory has been employed using Hamilton’s principle and Von-Kármán...
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Numerical Simulations of Hydrodynamic Open-Water Characteristics of a Ship Propeller
PublikacjaThe paper presents the results of numerical simulations of ship propeller operation bearing the name of Propeller Open Water (POW) Tests. The object of tests was a sample ship propeller (PPTC1), the geometrical and kinematic data of which are available, along with the results of model tests, on the official page of the research centre involved in the measurements. The research aimed at verifying the correctness of results of numerical...
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Influence of Gd deposition on the oxidation behavior and electrical properties of a layered system consisting of Crofer 22 APU and MnCo2O4 spinel
PublikacjaIn the study, the surface of the Crofer 22APU ferritic steel was modified with gadolinium oxide nanoparticles and a protective-conducting layer consisting of the MnCo2O4 spinel. This system was studied in the context of application in IT-SOFC interconnects. Four types of samples were studied: unmodified steel, steel coated with a manganese-cobalt spinel layer, steel modified with gadolinium oxide nanoparticles, and a system consisting...
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ReFlexeNN - the Wearable EMG Interface with Neural Network Based Gesture Classification
PublikacjaThe electromyographic activity of muscles was measured using a wireless biofeedback device. The aim of the study was to examine the possibility of creating an automatic muscle tension classifier. Several measurement series were conducted and the participant performed simple physical exercises - forcing the muscle to increase its activity accordingly to the selected scale. A small wireless device was attached to the electrodes placed...
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PROPELLER INVESTIGATIONS BY MEANS OF NUMERICAL SIMULATION
PublikacjaThe analyses of hydroacoustics are of high interest at the moment due to strong impact of hydroacoustic phenomena on marine environment; the noises, generated e.g. by marine traffic, may be harmful for sea life. The analyses presented here are focused on one of main sources of noises generated by ships, i.e. cavitating propeller. The goal of the work is the assessment of the cavitation phenomenon, carried out with the standard...
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An advanced synergy of partial denitrification-anammox for optimizing nitrogen removal from wastewater: A review
PublikacjaAnammox is a widely adopted process for energy-efficient removal of nitrogen from wastewater, but challenges with NOB suppression and NO3− accumulation have led to a deeper investigation of this process. To address these issues, the synergy of partial denitrification and anammox (PD-anammox) has emerged as a promising solution for sustainable nitrogen removal in wastewater. This paper presents a comprehensive review of recent developments...
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Block-based Representation of Application Execution on Modern Parallel Systems
PublikacjaThe chapter presents how to model execution of a parallel computational application that is to be executed in a large-scale parallel or distributed environment with potentially thousands to millions of execution units. The representation uses pre- viously attributes and factors representative of modern high performance systems including multicore CPUs, GPUs, dedicated accelerators such as Intel Phi.
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Magnetic deep eutectic solvents – Fundamentals and applications
PublikacjaMagnetic deep eutectic solvents (MDES), a relatively new subclass of conventional deep eutectic solvents (DES) containing additional paramagnetic components in their structure. MDES exhibit a strong response toward external magnetic fields, thus they can improve many industrial and analytical applications. In addition, this new group of solvents present unique physicochemical properties that can be easily tuned by selecting the...
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Ion Chromatography with Pulsed Amperometric Detection for Determining Cyanide in Urine and Meconium Samples
PublikacjaThe parents’ addictions and eating habits have a significant influence on the child’s growth. The first stool of a newborn baby provides a large amount of information about xenobiotics transmitted by the mother’s body. The analytical technique used in the study is ion chromatography with pulsed amperometric detection (IC-PAD). The biological samples, which were obtained from women staying in a maternity ward and their partners,...
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Estimating the uncertainty of discharge coefficient predicted for oblique side weir using Monte Carlo method
PublikacjaSide weir is a hydraulic structure, which is used in irrigation systems to divert some water from main to side channel. It is installed at the entrance of the side channel to control and measure passing water into the side channel. Many studies provided side weir water surface profile and coefficient of discharge to measure water discharge diverted into the side channel. These studies dealt with different side weir shapes (rectangular,...
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Comparison of Impedance-Source Networks for Two and Multilevel Buck–Boost Inverter Applications
Publikacjampedance-source networks are an increasingly popular solution in power converter applications, especially in single-stage buck-boost power conversion to avoid additional front-end dc-dc power converters. In the survey papers published, no analytical comparisons of different topologies have been described, which makes it difficult to choose the best option. Thus, the aim of this paper is to present a comprehensive analytical comparison...
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Local buckling of composite channel columns
PublikacjaThe investigation concerns local buckling of compressed flanges of axially compressed composite channel columns. Cooperation of the member flange and web is taken into account here. The buckling mode of the member flange is defined by rotation angle a flange about the line of its connection with the web. The channel column under investigation is made of unidirectional fibre-reinforced laminate. Two approaches to member orthotropic...
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Development of potential candidate reference materials for drugs in bottom sediment, cod and herring tissues
PublikacjaRegular use of a reference material and participation in a proficiency testing program can improve the reliability of analytical data. This paper presents the preparation of candidate reference materials for the drugs metoprolol, propranolol, carbamazepine, naproxen, and acenocoumarol in freshwater bottom sediment and cod and herring tissues. These reference materials are not available commercially. Drugs (between 7 ng/g and 32...
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Ultrasound assisted extraction
PublikacjaThe use of green and sustainable extraction techniques is very popular topic in the multidisciplinary area of chemistry, biology and technology. There is no doubt that extraction constitutes a very important step of analytical procedures of separation, detection, identification and determination of wide spectrum analytes from samples characterized by complex and very often nonhomogeneous composition of matrix. Traditional techniques...
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‘Green’ multi - residue methods for the determination of high importance currently used pesticides in environmental samples
PublikacjaThe purpose of the research has been to develop and apply ‘green’ analytical methodologies to control and monitor the level of currently used pesticides from different chemical groups in aqueous samples. For extraction of analytes solid - phase microextraction (SPME) and dispersive liquid - liquid microextraction (DLLME) have been applied and compared. For SPME, commonly used materials for coating fibers include: polydimethylsiloxane...
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Calix[4]arenes appended with thioamide moieties as powerful tool for heavy metals recognition
PublikacjaSelectivity of new thioamide derivatives was assessed using those ligands as sensor materials in ion-selective membrane electrodes and tested towards Pb2+ - selectivity. The influence of the nature of the thioamide function (linear, branched or cyclic substituents) on their ionophoric properties was investigated. Electrodes based on cyclic thioamide moieties are promising analytical tools for monitoring Pb2+ concentration in natural...
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CRVG - a new model for wireless networks topology generation
PublikacjaThis paper presents a new model of wireless network topology generator. Its main advantage is the possibility of relatively sparse networks generation. Because no iteration is needed, the model can be used for massive generation of networks for testing. The topological properties of produced graphs place them in the class of scale free networks, resembling real ones.
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Polyethylene as a small vessel's building material
PublikacjaThe most common use of polyethylene we can notice nowadays are areas like water supply systems, gas industry (esp. gas piping), food industry, small-scale, light and consumer goods industries. That material has far more applications. One of them is shipbuilding - especially small inland or offshore vessels.
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Problemy planowania rozwoju systemu transportowego w obszarach metropolitalnych – przykład Obszaru Metropolitalnego G-G-S
PublikacjaProblemy rozwoju systemów transportowych w metropoliach wynikają ze specyfiki tych obszarów, ich skali i struktury przestrzennej. Obszary te charakteryzują się dużą wewnętrzną integracją funkcjonalną oraz dobrze rozwiniętą siecią transportową. Dynamicznie rozwijające się obszary metropolitalne mają odrębne systemy zarządzania finansami, rozwią- zania prawne oraz administrację, a także własne organy planowania i zarządzania, które...
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Wirówka geotechniczna - historia, modelowanie i współczynniki skali
PublikacjaRozwój modelowania zjawisk geotechnicznych w wirówce. Historia rozwoju urządzenia. Przyczyny wykorzystania wirówki geotechnicznej przez ośrodki naukowe i biura inżynieryjne. Obecny status urządzenia w edukacji i przemyśle. Podstawy teoretyczne badań modelowych w wirówce geotechnicznej. Lista wybranych zależności korelacyjnych. Przegląd i dyskusja wybranych współczynników skali.
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Elastic distortional buckling of thin-walled bars of closed quadratic cross-section
PublikacjaIn this study a thin-walled bar with closed quadratic cross-section is considered. The elastic stability of axially compressed bar related to the cross-section distortion is investigated. The governing differential equation is derived with aid of the principle of stationary total potential energy. The critical load for the simply supported bar is found in analytical form and it is compared with the FEM solution. Sufficient accuracy...
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Organic Compounds: Halogenated
PublikacjaThe entry focuses on halogenated organic compounds, mainly short-chain chlorinated aliphatic organic compounds. It describes their occurrence in the different compartments of the environment and their environmental fate, presents the basic toxicological mechanisms, and discusses the different approaches to remediation processes as applied to soil and water pollution. Finally, basic analytical solutions for the determination of...
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Elastic distortional buckling of thin-walled bars of closed quadratic cross-section
PublikacjaIn this study a tin-walled bar with closed quadratic cross-section is considered. The elastic stability of axially compressed bar related to the cross-section distortion is investigated. The governing differential equatio is derived with aid of the principle of stationary potential energy. The critical load for simply supported bar is found in an analytical form and it is copared with the FEM solution. Sufficient accuracy of the...