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Wyniki wyszukiwania dla: secondary organic aerosol
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Organic and conventional kiwifruit myths versus reality: antioxidant, antiproliferative and health effects
PublikacjaComparison between organic and conventional kiwifruit cultivars ''Hayward'' and ''Bidan'', which was done by four redical scavenging assays, ESI-MS, and DSC measurements, showed significant differences between cultivars. Such results were not estimated in kiwifruit growing under organic and conventional conditions. The extraction of bioactive compounds was done by two different methods: sequential extraction with ethyl acetate...
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From ashes to porous hierarchical nanocarbon electrode: Upcycling secondary waste materials through self-catalytic chemical vapour deposition
PublikacjaMetal and metal oxide particles are abundant in various ash-based wastes. Utilizing these as catalyst sources for the fabrication of carbon nanomaterials could present a valuable approach to reduce our reliance on non-renewable and costly catalyst sources, thereby facilitating large-scale nanomaterial production. In this context, secondary waste materials (SWMs) are by-products resulting from the (complete or partial) combustion...
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Inkjet Printing of Lanthanide–Organic Frameworks for Anti-Counterfeiting Applications
PublikacjaPhotoluminescent lanthanide−organic frameworks (Ln-MOFs) were printed onto plastic and paper foils with a conventional inkjet printer. Ln-MOF inks were used to reproduce color images that can only be observed under UV light irradiation. This approach opens a new window for exploring Ln-MOF materials in technological applications, such as optical devices (e.g., lab-on-a-chip), as proof of authenticity for official documents.
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Application of Passive Samplers in Monitoring of Organic Constituents of Air
PublikacjaThe principles of passive dosimetry, which has been known for over 100 years, are finding an ever increasing use in analytical practice and are being used as a convenient technique for isolation and enrichment of analytes from various environmental media. Due to its simplicity, a variety of designs, as well as the possibility of using a number of different final determination techniques, passive dosimetry has been applied in...
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Assessment of organic coating degradation via local impedance imaging
PublikacjaThe paper presents a new approach to organic coating condition evaluation at micrometer scale using localized impedance measurements. It is based on atomic force microscopy (AFM) in contact mode. Impedance is measured between conductive AFM tip and metal substrate covered with organic coating. A single-frequency voltage perturbation signal is applied between the electrodes and current response signal is registered. As the tip is...
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Photophysical processes in the selected white organic light-emitting diodes
PublikacjaThe first part discusses history of organic emitters, the scope of the work, phenomena in molecular systems, types of architectures in OLEDs, types of OLEDs emitting white light with examples from the literaturę and a description of the parameters chcracterizing LEDs. The second part describes materials, production of the samples, the measurement systems and results. In chapter 8.1 the results for the OLEDs based on emission from...
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Fabrication and photoactivity of organic-inorganic systems based on titania nanotubes and PEDOT containing redox centres formed by different Prussian Blue analogues
PublikacjaHerein, the heterojunction composed of an inorganic substrate: ordered hydrogenated titania nanotubes (H-TiO2NTs) and a deposited organic film: poly(3,4-ethylenedioxythiophene) (PEDOT) is reported. The conducting polymer is modified with different transition metal haxacyanoferrates (Mehcf), wherein as metal: copper, iron, cobalt and nickel are introduced. The presence of various metal centres provides characteristic redox activity...
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Influence of nitrogen and organic matter fractions on wastewater treatment in treatment wetland
PublikacjaMunicipal wastewater contains both biodegradable and non-degradable pollutants. Moreover, they are present in dissolved, colloidal and particulate forms. These fractions are characterised by various decomposition rates, hence their bioavailability during microbial respiration. It was confirm that biological degradation rate in terms of COD reduction is influenced by particle size speciation. Therefore, the objective of the study...
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Water uptake in protective organic coatings and its reflection in measured coating impedance
PublikacjaWater uptake in commercially available epoxy coating on mild steel using impedance spectroscopy and gravimetry was studied. The water content in the coating was determined using the Brasher-Kingsbury equation and various methods of coating capacitance calculation used in the literature. The obtained results were compared with reference gravimetric data. An overestimation of values obtained from impedance data in relation to gravimetric...
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Phosphorus concentration and availability in raw organic waste and post fermentation products
PublikacjaThe aim of the study was to determine the mobility of phosphorus forms in raw organic waste and from the solid and liquid fractions of digestate. To achieve the purpose of this study, the components (including livestock manure, agricultural waste, food waste, sewage sludge) and their post fermentation products were considered. Subsequently, the effect of the fermentation process on the mobility of phosphorus forms in post-fermentation fractions...
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Mitigating metal-organic framework (MOF) toxicity for biomedical applications
PublikacjaMetal-organic frameworks (MOFs) are a novel class of crystalline porous materials, consisting of metal ions and organic linkers. These hybrid materials are highly porous and have a large specific surface area, making them of great interest for applications in gas separation, energy storage, biomedical imaging, and drug delivery. As MOFs are being explored for biomedical applications, it is essential to comprehensively assess their...
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Magnetic field effects in dye-sensitized and organic solar cells
PublikacjaThe charge recombination and exciton dissociation are generally recognized as the basic electronic processes limiting the efficiency of photovoltaic devices. The aim of this thesis is to understand the electronic processes limiting the operation of efficient solar cells with particular emphasis on the role of electronic states endowed with magnetic dipole moment. The research work is divided into two parts. The first part deals...
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Synthesis and structural characterization of new cyclic siloxane with functionalized organic substituents
PublikacjaOcta(2-pyridyloxy)cyclotetrasiloxane was isolated as the product of the reaction between silicon disulfide and 2-hydroxypyridine. The new compound has been characterised by single crystal X-ray analysis, revealing a planar eight-membered ring with functionalized organic substituents on the silicon atoms.
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Functionalized nanodiamonds as a perspective green carbo-catalyst for removal of emerging organic pollutants
PublikacjaRapid industrial and urban development jointly with rising global population strongly affect the large-scale issues with drinking, groundwater, and surface water pollution. Concerns are not limited to environmental issues but also human health impact becoming serious global aspect. Organic pollution becomes a primarily serious hazard, therefore, the novel sophisticated approaches to treat them are thoroughly investigated. Among...
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Family Tree for Aqueous Organic Redox Couples for Redox Flow Battery Electrolytes: A Conceptual Review
PublikacjaRedox flow batteries (RFBs) are an increasingly attractive option for renewable energy storage, thus providing flexibility for the supply of electrical energy. In recent years, research in this type of battery storage has been shifted from metal-ion based electrolytes to soluble organic redox-active compounds. Aqueous-based organic electrolytes are considered as more promising electrolytes to achieve “green”, safe, and low-cost...
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Injection of charge into the archetype organic hole transporting material TPD at the electrical contacts with ITO and Al
PublikacjaW pracy opisano mechanizm przewodnictwa ciemnego w układzie ITO/warstwa TPD/Al oraz Al/warstwa TPD/Al, gdzie TPD oznacza dwaminę powszechne stosowaną jako transporter dziur w organicznych diodach EL.
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Determination of Selected Organic Acids in Animal Farm Water Samples by Ion Chromatography
PublikacjaLow molecular mass carboxylic acids (LCAs) occur in many environmental compartments due to natural processes and human activity. They are an important group of organic pollutants of waste water that mainly includes, volatile fatty acids, and also dicarboxylic, aromatic, hydroxy- and ketoacids. LCAs are present in the environment at concentrations between 1 to 5000 ppm and different methods have been reported for their determination...
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Oxychlorination of organic compounds
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Organic syntheses greenness assessment with multicriteria decision analysis
PublikacjaGreen chemistry requires a metrics system that is comprehensive by the criteria included and simple in the application at the same time. We propose the application of multicriteria decision analysis for com- parative greenness assessment of organic synthesis procedures. The assessment is based on 9 criteria (the reagent, reaction efficiency, atom economy, temperature, pressure, synthesis time, solvent, catalyst and reactant) for...
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Human hair as a biomarker of human exposure to persistent organic pollutants (POPs)
PublikacjaThe main aim of this article is to investigate the possibility of using human hair as a biomarker with particular emphasis on persistent organic pollutants (POPs). We report previous results of studies of this topic. We critically review the available information on analytical procedures applied during analysis of human hair. Finally, we discuss future trends and possibilities arising from hair analysis.
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Four-body recombination in organic bulk heterojunction solar cells: an alternative interpretation
PublikacjaWe demonstrate a new interpretation of the previously reported quadrimolecular recombination in organic bulk heterojunction solar cells. It is suggested that the recently described (Szmytkowski 2012 Phys. Status Solidi RRL 6 300) interaction between exciton and electron–hole Langevin bound pair formed across the donor–acceptor interface is a four-particle process. This is in opposition to the treatment of this effect as a three-particle...
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Influence of excitons interaction with charge carriers on photovoltaic parameters in organic solar cells
PublikacjaWe report on theoretical analysis of excitons annihilation on charge carriers in organic solar cells. Numerical calculations based on transient one-dimensional drift-diffusion model have been carried out. An impact of three quantities (an annihilation rate constant, an exciton mobility and a recombination reduction factor) on current density and concentrations of charge carriers and excitons is investigated. Finally, we discuss...
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Application of dynamic headspace and gas chromatography coupled to mass spectrometry (DHS-GC-MS) for the determination of oxygenated volatile organic compounds in refinery effluents
PublikacjaThe paper presents a new procedure for the determination of oxygenated volatile organic compounds (O-VOCs) in postoxidative effluents from the production of petroleum asphalt using dynamic headspace coupled to gas chromatography-mass spectrometry in the selected ion monitoring (SIM) mode (DHSGC-MS). Among the GC capillary columns tested, a polar SLB-IL111 column with the ionic liquid stationary phase was found to be superior due...
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Precipitation and Transformation of Vaterite Calcium Carbonate in the Presence of Some Organic Solvents
PublikacjaIn this paper, the production of CaCO3 particles via the carbonation route in the reaction of CaCl2 and CO2, using NH3 as a promoter of CO2 absorption, was studied. The solvents used as the reaction media for CaCO3 precipitation were aqueous solutions of methanol, isopropanol and dimethyl sulfoxide (DMSO), in a concentration range of 0–20% (v/v). It was found that the presence of an organic additive influenced the precipitation...
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Enhanced photoelectrochemical performance of inorganic-organic hybrid consisting of BiVO4 and PEDOT:PSS
PublikacjaThe PEDOT:PSS (poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)) was electrodeposited on a thin layer of bismuth vanadate (BiVO 4 ) prepared using the pulsed laser deposition technique onto FTO. The inorganic-organic junction was characterized by Raman spectroscopy, UV-Vis spectroscopy and sc anning electron microscopy. Chronoamperometry curves, recorded under simulated solar light illumination,...
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Determination of the chemical structure of potencial organic impurities occuring in the drug substance opopramol
PublikacjaThe tricyclic antipsychotic and antidepressant drug opipramol was examined with regard to the chemical structure of its organic impurities. Impurities were isolated from the technical product by chromatographic methods and their chemical structures were estabilished by HMNR, MS and FTIR.
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Pendant Proton-Relays Systematically Tune the Rate and Selectivity of Electrocatalytic Ammonia Generation in a Fe-Porphyrin Based Metal-Organic Framework
PublikacjaElectrocatalytic nitrite reduction (eNO2RR) is a promising alternative route to produce ammonia (NH3). Until now, several molecular catalysts have shown capability to homogeneously reduce nitrite to NH3, while taking advantage of added secondary-sphere functionalities to direct catalytic performance. Yet, realizing such control over heterogeneous electrocatalytic surfaces remains a challenge. Herein, we demonstrate that heterogenization...
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Use of electrochemical methods to examine different surface preparation methods for organic coatings on steel
PublikacjaObróbka strumieniowo - ścierna jest jedną z powszechnie stosowanych metod przygotowania powierzchni. Wśród nowoczesnych metod coraz większe zainteresowanie wzbudza przygotowanie powierzchni wodą pod wysokim ciśnieniem (z ang. waterjetting). W porównaniu z konwencjonalnymi metodami ''waterjetting'' jest nowoczesną oraz przyjazną środowisku metodą. W literaturze brakuje informacji na temat skuteczności owej metody do zastosowań...
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Synthetic strategies in construction of organic low molecular-weight carrier-drug conjugates
PublikacjaInefficient transportation of polar metabolic inhibitors through cell membranes of eukaryotic and prokaryotic cells precludes their direct use as drug candidates in chemotherapy. One of the possible solutions to this problem is application of the ‘Trojan horse’ strategy, i.e. conjugation of an active substance with a molecular carrier of organic or inorganic nature, facilitating membrane penetration. In this work, the synthetic...
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Morphology control through the synthesis of metal-organic frameworks
PublikacjaDesignable morphology and predictable properties are the most challenging goals in material engineering. Features such as shape, size, porosity, agglomeration ratio significantly affect the final properties of metal- organic frameworks (MOFs) and can be regulated throughout synthesis parameters but require a deep under- standing of the mechanisms of MOFs formation. Herein, we systematically summarize the effects of the indi- vidual...
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The influence of the thickness, recombination and space charge on the loss of photocurrent in organic semiconductors: an analytical model
PublikacjaWe propose an analytical model of the photocurrent efficiency dependence on the light intensity in organic semiconductors. The influence of the thickness of sample, space charge effects and recombination of charge on the loss of photocurrent has been considered. We demonstrate that the presented model is the enhancement of an analytical model reported recently by Rappaport et al (2005 J. Appl. Phys. 98 033714). The method to identify...
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Recent Advances in Nanocomposite Membranes for Organic Compound Remediation from Potable Waters
PublikacjaWater treatment is one of the main approaches for producing drinking water from contaminated water sources which is challenging due to the presence of a variety of substances requiring removal. The fabrication of nanocomposite membranes relies either on filling nanomaterials into polymeric phases before membrane fabrication, or coating of nanomaterials on the fabricated membrane surface. The removal of organic compounds from potable...
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Analysis of higher recombination orders in organic bulk heterojunction solar cells
PublikacjaRecently, it has been experimentally demonstrated that an order of nongeminate recombination exceeds two in some types of organic bulk heterojunction donor-acceptor structures. This result is different than for the case of bimolecular recombination described by Langevin theory. Although several theoretical explanations of this effect have been presented, the origin of higher recombination orders is still questionable. In this work,...
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Effect of some organic solvent - water mixtures composion on precipitated calcium carbonate in carbonation process
PublikacjaPrecipitated calcium carbonate particles were obtained during carbonation of calcium hydroxide slurry with carbon dioxide. Aqueous solutions of isopropyl alcohol, n-butanol and glycerol were used as solvents. Concentration of organic additives in the reactive mixture was from 0 to 20 % (vol.). Precipitation process were performed in a stirred tank reactor equipped with gas distributor. Multimodal courses of particles size distribution...
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Dissolved and colloidal organic nitrogen removal from WWTP effluents and reject waters using physical-chemical processes
PublikacjaFour physical-chemical processes were compared in terms of the efficiencies of dissolved and colloidal organic nitrogen (DON and CON) removal from the secondary effluents (SE) and reject water from full-scale biological nutrient removal activated sludge systems. Adsorption on activated carbon was most efficient and allowed to remove from the SE up to 80% and 100% of DON and CON, respectively. High efficiencies of DON removal from...
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The CON−H…+NH2 Blue-Shifting H-Bond Stabilizing Effect on Z Secondary Amides and Cyclic System Conformational Rearrangement through an Alkylamine-Chain Migration Pathway
PublikacjaThe paper is focusing on the amide linkage exceptional properties and usage of chemistry (conformational rearrangement, geometrical stereoisomers, spectroscopic blue shift phenomenon, protonation and deprotonation reactions, synthetic scope, and mechanistic implications). Hydrogen-bond-stabilized acylation reactions of a diamine with thioamides or nitriles reveal how substituents influence both the outcome of stereoselectivity...
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Antibacterial and antioxidant activity of the secondary metabolites from in vitro cultures of alice sundew (drosera aliciae)
PublikacjaRośliny owadożerne (D. aliciae) produkują metabolity wtórne, farmakologicznie czynne substancje. Na wzrost akumulacji tychże substancji w tkankach roślin owadożernych ma wpływ dodatek elicytora. W pracy przedstawiono zarówno optymalizacje warunków hodowli roślin, jak również prawdopodobne mechanizmy działania bakteriobójczego. Końcowego oznaczenia zawartości metabolitów w ekstraktach roślinnych dokonano techniką chromatografii...
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Application of the 2-deoxyglucose scaffold as a new chiral probe for elucidation of the absolute configuration of secondary alcohols
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Self-assembly of secondary aryl amides in cocrystals with perfluoroaryl coformers: structural analysis and synthon preferences
PublikacjaCooperation of aryl⋯perfluoroaryl stacking interactions and hydrogen bonds was utilized in the construction of six novel cocrystals of aromatic cis-amides with pentafluorobenzoic acid (pfba) and pentafluorophenol (pfp). They were obtained by crystallization from solution and structurally characterized. In four instances, the components form heterotetrameric motifs, in which amide:amide homodimer interacts symmetrically on two sides...
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Supramolecular Synthesis Based on a Combination of Se···N Secondary Bonding Interactions with Hydrogen and Halogen Bonds
PublikacjaExamination of the solid state structures of 2,1,3-benzoselenadiazole complexes with hydrogen or halogen bond donors has demonstrated that the 2,1,3-benzoselenadiazole molecules preferably form centrosymmetric dimers with use of [Se–N]2 supramolecular synthon, whereas the two remaining nitrogen atoms not involved in the [Se–N]2 supramolecular interactions can act as acceptors of hydrogen or halogen bonds. Cocrystallization of selenadiazoles...
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COMPOSITION OF BIOACTIVE SECONDARY METABOLITES AND MUTAGENICITY OF SAMBUCUS NIGRA L. FRUIT AT DIFFERENT STAGES OF RIPENESS
PublikacjaThe relationship between the content of bioactive compounds and mutagenic activity of elderberry fruit at different stages of ripeness was investigated. Signifi cant differences in the antioxidant profi les (TLC, HPLC with post-column derivatization) and antioxidant activity (ABTS, DPPH, and FC tests) were observed for studied elderberry extracts. The more ripen the fruit at the time of harvest were, the higher the content of...
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High order of nongeminate recombination in organic bulk heterojunction solar cells
PublikacjaWe analyze high order of nongeminate recombination in organic donor–acceptor bulk heterojunction solar cells. The model of recombination where an exciton annihilates on an electron–hole Langevin bound pair near donor–acceptor interface has been applied in our studies. We obtained satisfactory agreement between experimental results and theoretical calculations for the concentration dependences of several parameters characterizing...
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Non-regulated organic compounds (NROC's) in the Odra River water samples.
PublikacjaW ramach badań opisanych w pracy podjęto próbę identyfikacji lotnych i średniolotnych związków z grupy Non-Regulated Organic Compounds obecnych w próbkach wody rzecznej. Analizie poddano 25 próbek wód pobranych z rzeki Odry w październiku 2000, w trakcie VIII kampanii zorganizowanej w ramach International Odra Project (IOP). W badaniach wykorzystano technikę PT-TD-GC-MS.Komputerowa analiza widm masowych wykazała obecność wielu...
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Friction-Induced Oscillations of a Non-Asbestos Organic Pin Sliding on a Steel Disc
PublikacjaFriction-induced oscillations result in deterioration of performance of disc brakes and are generally undesired. We conduct experimental study of friction-induced oscillations in a non-asbestos organic material / steel pair used in disc brakes of motor vehicles. The tests are done by use of a pin-on-disc machine which has the pin sample supported on a deformable beam. The adjustable friction parameters are the disc velocity, contact...
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Miniaturized Passive Emission Chambers for In Situ Measurement of Emissions of Volatile Organic Compounds
PublikacjaThe results of many different studies have demonstrated unequivocally that the quality of indoor air is often much worse than that of atmospheric air. The presence of dangerous chemical compounds in indoor air can have an adverse impact on human health and cause numerous diseases of the respiratory and circulatory systems. Such harmful chemicals get into indoor air as a result of their emission from building and indoor materials....
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Modification of current-voltage characteristics of planar organic systems by nm-thick interlayer
PublikacjaEffect of nm-thick interlayer of copper phthalocyanine (CuPc) or perylene dye (MePTCDI) on current-voltage characteristics of planar organic systems is discussed in the work. The MePTCDI layer strongly limits injection of holes from ITO into CuPc, while CuPc limits injection of electrons from ITO into MePTCDI. In the systems with CuPc/MePTCDI heterojunction an explicit photovoltaic effect occurs.
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Fluctuation-Enhanced Sensing of Organic Vapors by Ink-Printed MoS2 Devices under UV Irradiation
PublikacjaThis work presents the results of fluctuationenhanced sensing (FES) of selected organic gases by MoS2 sensor fabricated via a simple ink printing method. We demonstrate that low-frequency noise measured under UV irradiation (275 nm) is more sensitive to different gases than measured in the dark. The noise at 1 Hz under UV light increased 3.3, 3.5, 1.6, and 2.9 times for chloroform, tetrahydrofuran, acetonitrile, and acetone ambiances, respectively....
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PARTICLE SIZE ANALYSIS OF SUSPENSIONS IN REMOVING OF ORGANIC MATTER AND PHOSPHORUS FROM WASTEWATER AND SURFACE WATER
PublikacjaIn this paper the particle size of suspended solids in the removing of organic matter and phosphorus compounds from lake water and wastewater treated in the Ecological Treatment Systems (ETS) was analyzed. The invesigated materials were taken from two ETS located in Pomerania Region/Poland. Object in Swarzewo is 3rd stage of biological treatment of municipal wastewater, while object in Kartuzy has task to remove a phosphorus from...
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Monitoring and analytics of semivolatile organic compounds (SVOCs) in indoor air
PublikacjaThis paper reviews literature information on the behaviour of semivolatile organic compounds (SVOCs) in the indoor environment, as well as the most likely emission sources. The consecutive stages of analytical procedures used for monitoring SVOCs in indoor environments are described. The most common approaches used for collecting samples from the gas and particulate phases are mentioned. The paper discusses and compares various...
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Properties and Formation of Mineralized Veins in an Organic-Rich Shale Formation
PublikacjaAn earlier paper defined mineral and organic matter constituents in weak interfaces in shale formations (Ptaszynska, et. al., 2016). The formation studied in the earlier work and here is the Jurassic, early-Cretaceous Vaca Muerta formation in the Neuquen basin in Argentina. In this earlier work, mineralized "veins" were noted to be prevalent and complicated, sometimes being shear weak interfaces while in other cases they were not....