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Wyniki wyszukiwania dla: chemical hydrogen storage
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Hydrogen degradation of high-strength weldable steels in seawater
PublikacjaOceniono podatność na niszczenie wodorowe stali spawalnych o wysokiej wytrzymałości przy obciążeniach monotonicznie rosnących. Badano dwa gatunki stali ulepszonych cieplnie i ich złącza spawane. Przeprowadzono próby rozciągania z małą prędkością odkształcania w wodzie morskiej przy polaryzacji katodowej. Wykonano próby przenikania wodoru metodą Devanathana-Stachurskiego.
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Hydrogen delayed cracking of high-strength weldable steels
PublikacjaOceniano podatność na niszczenie wodorowe stali 14HNMBCu o wysokiej wytrzymałości i jej połączeń spawanych przy obciążeniu stałym w wodzie morskiej. Badania przeprowadzono w powietrzu, oraz w środowisku wody morskiej przy potencjale korozyjnym i przy polaryzacji katodowej. Obecność lub brak opóźnionych pęknięć próbek z karbem przyjęto za miarę odporności na niszczenie wodorowe przy stałym obciążeniu.
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Hydrogen degradation of high strength low alloyed steels.
PublikacjaBadano wpływ polaryzacji katodowej na własności stali węglowej, stali o podwyższonej i wysokiej wytrzymałości metodą stałego powolnego odkształcania.Stwierdzono, że stopień kruchości wodorowej każdej z badanych stali zależał od stężenia wodoru dyfuzyjnego.
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Influence of Storage Time and Temperature on the Toxicity, Endocrine Potential, and Migration of Epoxy Resin Precursors in Extracts of Food Packaging Materials
PublikacjaThe aim of the present study was to establish a standard methodology for the extraction of epoxy resin precursors from several types of food packages (cans, multi-layered composite material, and cups) with selected simulation media (distilled water, 5% ethanol, 3% dimethyl sulfoxide, 5% acetic acid, artificial saliva) at different extraction times and temperatures (factors). Biological analyses were conducted to determine the acute...
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Raman Spectra Measurements for Chemical Identifications - Aspect of Uncertainty Sources and Reduction of Their Effects
PublikacjaRaman spectrometers enable fast and non-contact identification of examined chemicals. These devices measure Raman spectra and compare with the spectra database to identify unknown and often illicit chemicals (e.g. drugs, explosives) usually without any sample preparation. Raman spectra measurements are a challenge due to noise and interferences present outside the laboratories (field applications). The design of a portable Raman...
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Full CI ground state potential energy curves and one-electron relativistic corrections for hydrogen molecule in various basis sets
Dane BadawczeThis dataset consists of Full CI ground state Born-Oppenheimer potential energy curves and one-electron relativistic corrections for hydrogen dimer. Nonrelativistic energies, as well as one electron relativistic corrections (treated perturbatively with help of the Cowan-Griffin Hamiltonian) are presented for internuclear distances between 0.8 and 10...
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Determination of Chemical Oxygen Demand (COD) at Boron-doped Diamond (BDD) Sensor by Means of Amperometric Technique
PublikacjaA boron-doped diamond (BDD) sensor was proposed for effective detection of chemical oxygen demand (COD) by means of amperometric technique. Thin boron doped diamond active sensor layer was deposited on Si wafer and glassy carbon substrate by Microwave Plasma Enhanced Chemical Vapor Deposition (MW PE CVD). The structure of BDD was confirmed by Raman spectra analysis. Broad Raman bands centered at 482 cm-1 and 1219 cm-1 are typical...
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Determination of chemical oxygen demand (cod) at boron-doped diamond (bdd) sensor by means of amperometric technique
PublikacjaA boron-doped diamond (BDD) sensor was proposed for effective detection of chemical oxygen demand (COD) by means of amperometric technique. Thin boron doped diamond active sensor layer was deposited on Si wafer and glassy carbon substrate by Microwave Plasma Enhanced Chemical Vapor Deposition (MW PE CVD). The structure of BDD was confirmed by Raman spectra analysis. Broad Raman bands centered at 482 cm-1 and 1219 cm-1 are typical...
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Interaction of Acoustic and Thermal Modes in the Gas with Nonequilibrium Chemical Reactions: Possibilities of Acoustic Cooling
PublikacjaNonlinear generation of thermal mode during propagation of dominative sound in a chemically reacting gas is considered. The dynamic equation of excess temperature associated with the thermal mode is derived. It is instantaneous and includes quadratic nonlinear acoustic source reflecting the nonlinear character of interaction between acoustic and non-acoustic types of gas motion. Both periodic and aperiodic sound may be considered...
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Experimental investigation of thermal energy storage in shell-and-multi-tube unit with nano-enhanced phase change material
PublikacjaThis paper deals with thermal energy storage with use of nanoparticle enhanced phase change material in shell-and-multitube unit. The experiments are conducted under atmospheric pressure. Paraffin wax and two different fatty acids are used as base phase change material. Graphite and multi-walled carbon nanotubes serve as nanoparticles. Graphite nanoparticles are tested at the concentrations of 0.1%, 1% and 5% by weight, while multi-walled...
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Chemical surface etching methods for ground tire rubber as sustainable approach for environmentally-friendly composites development– a review
PublikacjaGround tire rubber (GTR) has been used as a sustainable low-cost modifier in various composites. However, due to the hydrophobic nature of GTR, it is in compatible with most matrices and results in deterioration in both mechanical and physical properties of composites. This necessitates pre-modification of the powdered rubber to improve the interfacial bonding at the rubber-matric interface. The most common GTR modification research...
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Properties of Oxygen Vacancy and Hydrogen Interstitial Defects in Strontium Titanate: DFT + Ud,p Calculations
PublikacjaThis work presents extensive theoretical studies focused on the mixed ion-electron transport in cubic strontium titanate (STO). A new approach to the description of this difficult system was developed within the framework of linear-scaling Kohn–Sham density functional theory, as realized in the ONETEP program. The description we present is free of any empirical parameters and relies on the Hubbard U and Hund’s J corrections applied...
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Application of Thermo-chemical Technologies for Conversion of Associated Gas in Diesel-Gas Turbine Installations for Oil and Gas Floating Units
PublikacjaThe paper considers the issue of thermo-chemical recovery of engine’s waste heat and its further use for steam conversion of the associated gas for oil and gas floating units. The characteristics of the associated gas are presented, and problems of its application in dual-fuel medium-speed internal combustion engines are discussed. Various variants of combined diesel-gas turbine power plant with thermo-chemical heat recovery are...
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Computational analysis of substituent effects on proton affinity and gas-phase basicity of TEMPO derivatives and their hydrogen bonding interactions with water molecules
PublikacjaThe study investigates the molecular structure of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) and its derivatives in the gas phase using B3LYP and M06-2X functional methods. Intermolecular interactions are analyzed using natural bond orbital (NBO) and atoms in molecules (AIM) techniques. NO2-substituted TEMPO displays high reactivity, less stability, and softer properties. The study reveals that the stability of TEMPO derivatives...
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Selected aspects of performance of organic Rankine cycles incorporated into bioenergy with carbon capture and storage using gasification of sewage sludge
PublikacjaThe study aims to investigate the application of the Organic Rankine Cycle (ORC) in the bioenergy with carbon capture and storage (BECCS) using gasification of sewage sludge. The tool used in the investigation is the Aspen Plus software with REFPROP property methods for calculating fluid properties. The reason for this study is that a detailed analysis of the proposed BECCS process flow diagram indicates that a certain amount of...
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Influence of storage time on the useful properties of silicone pressure-sensitive adhesives
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Evaluation of BaY1−Pr Mn2O5+δ oxides for oxygen storage technology
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An Insight into the Stages of Ion Leakage during Red Blood Cell Storage
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Carbon dioxide ocean and ground storage as a method of climate change mitigation
PublikacjaW pracy dokonano krytycznego przeglądu negatywnego wpływu globalnego ocieplenia na środowisko i przedstawiono dwie nowatorskie metody zmniejszenia stężenia atmosferycznego ditlenku węgla. Obie metody: magazynowanie antropogenicznego ditlenku węgla, pochodzącego z dużych źródeł emisji, w oceanach i w glebie są technologicznie możliwe do przeprowadzenia, co potwierdzają przykłady z różnych regionów świata. W pracy przedyskutowano...
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Impedance spectroscopy by means of a digital storage oscilloscope based measurement system.
PublikacjaW pracy przedstawiono system pomiarowy służący do badań spektroskopowych. Został on zbudowany w oparciu o szerokopasmowy oscyloskop cyfrowy. Przeprowadzono analizę dokładności pomiarów oraz przedstawiono wyniki badań kalibracyjnych i przykładowych pomiarów parametrów materiałów biologicznych.
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The influence of storage time on the performance of polypropylene membranes applied for membrane distillation
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Effect of Storage Conditions on Storability and Antioxidant Potential of Pears cv. ‘Conference’
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The molecular mechanism of genistein action in lysosomal storage diseases: A transcriptomic approach
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Red Algae – An Alternative Source of Carbon Material for Energy Storage Application
PublikacjaNew electrode material obtained by pyrolysis of aquatic biomass macro (red algae) soaked with glucose solution has been characterized by SEM, EDX and Raman spectroscopy. Graphitized carbon was identified by Raman spectroscopy. Galvanostatic cyclic polarization of the materials in contact with 1M LiPF6 electrolyte in EC:DMC (1:1 v/v) and Li as a counter electrode was performed. Specific capacity of the novel material was enhanced...
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The generalized Banach match-box problem: Application in disc storage management
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Victor Eremeev prof. dr hab.
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The impact of sediment, fresh and marine water on the concentration of chemical elements in water of the ice-covered lagoon
PublikacjaThe common use of chemical elements by man has been contributing to their extraction for centuries. As a consequence, they have been directly or indirectly introduced into the biogeochemical cycle. In the framework of many conventions, mining and processing of elements are currently subject to many restrictions. However, their large load that has already been deposited in the soil and bottom sediments can be remobilised and...
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Formaldehyde detection with chemical gas sensors based on WO3 nanowires decorated with metal nanoparticles under dark conditions and UV light irradiation
PublikacjaWe report results of formaldehyde gas (CH2O) detection under dark conditions and UV light irradiation with pristine tungsten trioxide nanowires (WO3 NWs) and metal nanoparticles decorated WO3 NWs gas sensing layers. The resistive layers were deposited by one step aerosol assisted chemical vapor deposition (AACVD) on commercial alumina substrates with 10-pair interdigitated platinum electrodes. The elaborated gas sensors, based...
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Application of nonlinearity measures to chemical sensor signals
PublikacjaSzumy rezystancji sensorów gazu zawierają istotną informację, która może być przedstawiona nie tylko przez ich gęstość widmową mocy. Analiza tych szumów za pomocą różnych miar nieliniowości może prowadzić do znacznego wzrostu selektywności i czułości czujników gazu. Stwierdzono, że dla dostępnych na rynku czujników gazu zastosowanie funkcji bispektrum dostarcza dodatkowej informacji, potrzebnej do detekcji różnych gazów. Analizując...
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POULTRY MANURE AS A SUBSTRATE FOR AGRICULTURE AND THE CHEMICAL INDUSTRY
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Chemical fingerprint ofPotentillaspecies by using HPTLC method
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Fluorescence Measurements for chemical optical sensor of cobalt
PublikacjaW pracy zaproponowano i opisano optoelektroniczny fluorescencyjny sensor do pomiaru stężenia kobaltu w wodzie.
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Chemical, biological and functional aspects of food lipids
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Review of ionic liquids applications in chemical processes
PublikacjaCiecze jonowe stały się obiektem zainteresowania naukowców. Składają się one z dużego organicznego kationu i małego anionu. Modyfikacje kationu i anionu pozwalają na dostosowanie ich właściwości do aktualnych potrzeb. Rozpuszczają one szerokie spektrum związków organicznych i nieorganicznych związków. Mogą zatem z powodzeniem zastąpić dotychczas stosowane tradycyjne rozpuszczalniki. Znajdują zastosowanie jako medium reakcyjne,...
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On the joint time-frequency characteristics of chemical oscillations
PublikacjaZaprezentowano rezultaty analizy czasowo-częstotliwościowej rejestrów potencjałowych oscylacyjnej reakcji Biełousowa-Żabotyńskiego (BŻ). Wybraną reprezentację czasowo-częstotliwościową w postaci algorytmu STFT zastosowano do analizy typowych przebiegów reakcji BŻ, prowadzonej w układzie zamkniętym. Zaprezentowano spektrogramy STFT ukazujące czasowo-częstotliwościową strukturę oscylacji regularnych, mieszanych i chaotycznych. Na...
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Synthesis of carbon nanotubes via chemical vapor deposition by using rareearth metals as catalysts
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Consequences of New Approach of Chemical Stability Tests of Active Pharmaceutical Ingredients (APIs)
PublikacjaThere is a great need of broaden look on stability tests of active pharmaceuticalingredients (APIs) in comparison with current requirements contained in pharmacopeia.By usage of many modern analytical methods the conception of monitoring the changesof APIs during initial stage of their exposure to harmful factors has been developed. Newknowledge must be acquired in terms of identification of each degradation...
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The influence of dynamic load changes on temporary impedance in hydrogen fuel cells, selection and validation of the electrical equivalent circuit
PublikacjaTo achieve optimal performance of a fuel cell, a reliable monitoring and diagnostic method is required. The currently utilized methods give limited information or they are impossible to use under dynamic working conditions. To obtain comprehensive information about the fuel cell operation we utilized novel dynamic electrochemical impedance spectroscopy. Impedance measurements in dynamic mode were performed on a hydrogen fuel cell,...
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Two-step Conversion of Crude Glycerol Generated by Biodiesel Production into Biopolyols: Synthesis, Structural and Physical Chemical Characterization
PublikacjaIn this work biopolyols were synthesized via two-step process from crude glycerol and castor oil. For better evaluation of analyzed process, the impact of its time and temperature on the structure and properties of biopolyols was determined. Obtained results fully justified conducting of synthesis in two steps. Prepared materials were characterized by hydroxyl value and water content comparable to polyols industrially applied in...
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Synergistic effects of low-/medium-vacuum carbonization on physico-chemical properties and stability characteristics of biochars
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Temesgen Amibo PhD student
OsobyMy name is Temesgen Abeto Amibo, I'm PhD. student at Gdansk University of Technology under the faculity of Chemistry and Depertment of Process Engineering and Chemical Technology. I was Graduted BSc. and MSc. in Chemical Engineering from Jimma University, since 2017 and 2020GC. I have been there serving as acadamic Lecturere from 2020 to september 2022.
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Green thermoplastic poly(ether-urethane)s – synthesis, chemical structure and selected properties investigation
PublikacjaThis work aimed to characterize the effect of the monomers chemical structure on the selected properties of the green thermoplastic poly(ether-urethane)s. During synthesis two types of polyether biopolyols, 4,4′-diphenylmethane diisocyanate and bio-based 1,3-propanediol were employed. Materials were synthesized with the use of two step method and two different prepolymers, which were mixed together in equimolar quantities. Obtained...
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Chemical and structural studies of screen-printed carbon electrodes (SPCE) with boron-doped diamond foils
Dane BadawczeThis dataset contains chemical analyses and structural studies by XPS and Raman spectroscopy, carried out for SPCE containing boron-doped diamond BDD foils done with scanning electron microscope. Different points for XPS analysis mark different electrode spots: A) working electrode, B) reference electrode, C) counter electrode, D) pads.
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Thermo-Chemical Decomposition Study of Polyurethane Elastomer Through Glycerolysis Route with Using Crude and Refined Glycerine as a Transesterification Agent
PublikacjaDue to the increasing amount of polyurethane waste, chemical recycling of these materials is a topic of growing interest for many researchers. The primary pur- pose of polyurethane feedstock recycling is to recover the starting polyol. In this study glycerolysis using glycerine from two sources and two purity grades is proposed as a method of chemical recycling. The main effort of this paper focuses on the employment of commercial...
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Physical and chemical basis of energy generation - GT 2021-2022 laboratory
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Anna Zielińska-Jurek prof. dr hab. inż.
OsobyResearch work on photocatalysis by Prof. Anna Zielinska-Jurek started in 2006 at Gdansk University of Technology (Poland), including 3-month research stay at Hokkaido University, Training School “Environmental Applications of TiO2 Photocatalysis” at the University of Oulu in Finland granted by COST Program and Training School “NanoBiophotonics” at the Beckmann Institute, Urbana-Champaign in the USA granted by University of Illinois....
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Rheological characteristics of oligomeric semiproducts gained via chemical degradation of polyurethane foam using crude glycerin in the presence of different catalysts
PublikacjaPolyurethane (PU) recycling is a topic of growing interest due to the increasing amount of polyurethane waste. The main purpose of polyurethane chemical recycling is to recover the starting polyol. In this study, a method of polyurethane thermochemical recycling, glycerolysis by means of crude glycerin, is proposed. This work presents a comparative study of commercial catalysts used in order to accelerate the decomposition process,...
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Hydrogen degradation of 26H2MF and 34HNM steels used in ship engines.
PublikacjaPrzedstawiono wyniki badań podatności stali 26H2MF i 34HNM na niszczenie wodorowe, uzyskane po badaniach w roztworze kwasu siarkowego przy równoczesnej polaryzacji katodowej. Wykazano, że skład i obróbka cieplna stali mają wpływ na ich podatność. Efejkt ten przypisano różnej zdolności pułapkowania wodoru przez stale.
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Hydrogen degradation of high-strength weldable steels in sea-water.
PublikacjaW pracy przedstawiono ocenę degradacji wodorowej dwóch gatunków stali spawalnych o wysokiej wytrzymałości 17HMBVA i 14HNMBCu. Badania wykonano na materiałach rodzimych i złączach spawanych stali w oparciu o próbę rozciągania z małą prędkością. Próby wykonano w powietrzu oraz środowisku wody morskiej przy polaryzacji katodowej. Dodatkowo wykonano elektrochemiczne badania przenikania wodoru i wyznaczono zależności stężenia wodoru...
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Hydrogen delayed cracking of high-strength 14hnmbcu steel in seawater
PublikacjaOceniano podatność na niszczenie wodorowe stali o wysokiej wytrzymałości i jej połączeń spawanych przy stałym obciążeniu w wodzie morskiej. Badania przeprowadzono na próbkach okrągłych z karbem w środowisku wody morskiej przy potencjale korozyjnym oraz przy polaryzacji katodowej. Badano stal gatunku 14HNMBCu o minimalnej granicy plastyczności 690 MPa oraz jej połączenia spawane automatycznie łukiem krytym i ręcznie łukowo elektrodą...