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Atmospheric and Surface Water Pollution Interpretation in the Gdańsk Beltway Impact Range by the Use of Multivariate Analysis
PublikacjaOpracowanie dotyczny zastosowania hierarchicznej analizy klastrów i testów nieparametrowych celem dokonania interpretacji wpływu Obwodnicy Trójmiejskiej. W większości przypadków wykryto obecność oddziaływań antropogenicznych (zastosowanie nawozów, transport, posypywanie dróg solą w okresie zimowych) jak i pół-środowiskowych (aerozole morskie, erozja materiałów budowlancyh). Nie wykrytu jednak ścisłej zależności okresowej dla zanieczyszczeń...
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Organic Rankine cycle turbogenerator cooling – Optimization of the generator water jacket heat exchange surface
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Photocatalytic decomposition of benzo-[a]-pyrene on the surface of acrylic, latex and mineral paints. Influence of paint composition
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Role of the Hydroxyl Groups Coordinated toTiO2 Surface on the Photocatalytic Decomposition of Ethylene at Different Ambient Conditions
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A measurement system for nonlinear surface spectroscopy with an atomic force microscope during corrosion process monitoring
PublikacjaIn addition to traditional imaging the surface, atomic force microscopy (AFM) enables wide variety of additional measurements. One of them is higher harmonic imaging. In tapping mode the nonlinear contact between tip and specimen results in higher frequency vibrations. More information available from the higher harmonics analysis proves to be helpful for more detailed imaging. Such visualization is espe-cially useful for heterogeneous...
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Partitioning of heavy metals in sub-surface flow treatment wetlands receiving high-strength wastewater
PublikacjaThe retention of heavy metals at two pilot-scale treatment wetlands (TWs), consisting of two vertical flow beds (VSSF) followed by a horizontal flow bed (HSSF) was studied. The TWs received highstrength wastewater: reject waters from sewage sludge centrifugation (RW) and landfill leachate (LL). The concentrations of metals: Fe, Mn, Zn, Al, Pb, Cu, Cd, Co, Ni were measured in treated wastewater, substrate of the beds and in plant...
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The importance of the shape of the protein–water interface of a kinesin motor domain for dynamics of the surface atoms of the protein
PublikacjaA single kinesin motor domain immersed in water has been investigated using molecular dynamics. It has been found that local properties of water in the solvation shell change along with the nature of the neighboring protein surface. However, a detailed analysis leads to the conclusion that the geometrical features of hydrogen bonds and overall structure of kinesin hydration water are not very different from bulk water. The local...
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Lanthanide co-doped TiO2: the effect of metal type and amount on surface properties and photocatalytic activity
PublikacjaPreparation of new rare earth metal-containing TiO2 nanocomposites (Nd3+/Er3+, Nd3+/Eu3+, Eu3+/Ho3+-TiO2) using sol–gel route and their photoactivity under visible and ultraviolet light is reported. The obtained photocatalysts were subsequently characterized by Brunauer–Emmett–Teller (BET) method, UV–Vis diffuse-reflectance spectroscopy (DRS), luminescence spectroscopy, X-ray photoelectron spectroscopy (XPS) and X-ray powder diffraction...
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Report vconcerning corrosion reasons of s/y Lunar hull surface and possible way of repair
PublikacjaDokonano oceny korozji kadłuba jednostki pływającej, przyczyn powstania korozji oraz zaproponowano sposoby naprawy miejsc skorodowanych.
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Germination improvement of fenugreek seeds with cold plasma: Exploring long-lasting effects of surface modification
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Surface Properties and Photocatalytic Activity of KTaO3, CdS, MoS2 Semiconductors and Their Binary and Ternary Semiconductor Composites
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Diamond surface modification following thermal etching of Si supported hydrogenated diamond films by DBr
PublikacjaZbadano, wykorzystując spektroskopię oscylacyjną (HREELS - High Resolution Electron Energy Loss Spectroscopy) modyfikacje chemiczne powierzchni wodorowanego diamentu, umieszczonego na podkładzie krzemowym i wystawionego na działanie DBr a następnie podgrzanego do temp. powyżej 600 st.K. Przedstawiona procedura powoduje tworzenie się węglika krzemu SiC na powierzchni warstwy diamentowej, co jest widoczne na widmie HREEL jako dwa...
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The importance of the shape of the protein-water interface of a kinesin motor domain for dynamics of the surface atoms of the protein
PublikacjaSingle kinesin motor domain immersed in water has been investigated using molecular dynamics. It has been found that local properties of water in solvation shell change along with the nature of neighboring protein surface. However, a detailed analysis leads to the conclusion that the geometrical features of hydrogen bonds and overall structure of kinesin hydration water is not very different from bulk water. The local values of...
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One-Step Synthesis of W/O and O/W Emulsifiers in the Presence of Surface Active Agents
PublikacjaThe main goal of this study was to describe the method of the synthesis of the dodecyl-, tetradecyl-, hexadecyl- and octadecyl-propylene glycol emulsifiers in the presence of selected anionic and nonionic surfactants. Acyl propylene glycol emulsifiers were produced by esterification of propane-1,2-diol (propylene glycol, PG) with C12:0-C18:0 fatty acids in the presence of anionic sodium dodecyl sulfate (SDS) and nonionic-poly(ethylene...
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Influence of the laser remelting parameters on the thickness of surface layers created on the stainless steel X5CrNi18-10
PublikacjaIn this work the surface of austenitic stainless steel type X5CrNi18-10 was treated by using laser. Laser remelting was done by means of laser MLT 2500 CO2 with different parameters of treatment: P - power beam (800 [W], 1000 [W], 1100 [W], 1200 [W]); v - scanning velocity (6 [mm/s], 7 [mm/s], 8 [mm/s]); diameter of laser beam (1.4 [mm], 1.6 [mm]). The influence of these parameters on the thickness and shape of layers in manufacturing...
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Surface properties and photocatalytic activity of KTaO3, CdS, MoS2 semiconductors and their binary and ternary semiconductor composites
PublikacjaSingle semiconductors such as KTaO3, CdS MoS2 or their precursor solutions were combined to form novel binary and ternary semiconductor nanocomposites by the calcination or by the hydro/solvothermal mixed solutions methods, respectively. The aim of this work was to study the influence of preparation method as well as type and amount of the composite components on the surface properties and photocatalytic activity of the new semiconducting...
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Assessment of copper surface coverage with corrosion inhibitor using AFM-based local electrical measurements
PublikacjaThe paper presents a new method of assessment of metal surface coverage with corrosion inhibitor and thus of inhibitor protective performance. It is based on the atomic force microscopy measurement performed in a contact mode. Apart from topography images the proposed approach allows acquisition of local DC maps and local electrical impedance spectra via application of DC bias voltage or AC perturbation signal between the conductive...
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Effect of the Post-Weld Surface Condition on the Corrosion Resistance of Austenitic Stainless Steel AISI 304
PublikacjaSurfaces of welded elements made of corrosion-resistant (stainless) steels develop temper colours. The removal of thickened oxide layers off steels exposed to temperatures below 300°C is necessary and entails the restoring of high corrosion resistance of the stainless steel. The article presents tests concerned with the effect of a method applied to remove post-weld temper on the corrosion resistance of austenitic stainless steel...
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The impact of drying and steaming processes on surface color changes of tension ad normal beech wood
PublikacjaThe aim of the article is to present the influence of high temperature to selected properties of beech wood (Fagus sylvatica L.). The properties such as moisture content, color changes and longitudinal warping were analyzed. The quality of beech wood is determined based on structure and properties of wood, frequency of defects in wood material. The tension wood is considered as an important wood defect causing negative alterations...
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Studies on Silver Ions Releasing Processes and Mechanical Properties of Surface-Modified Titanium Alloy Implants
PublikacjaDispersed silver nanoparticles (AgNPs) on the surface of titanium alloy (Ti6Al4V) and titanium alloy modified by titania nanotube layer (Ti6Al4V/TNT) substrates were produced by the chemical vapor deposition method (CVD) using a novel precursor of the formula [Ag5(O2CC2F5)5(H2O)3]. The structure and volatile properties of this compound were determined using single crystal X-ray diffractometry, variable temperature IR spectrophotometry...
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Evaluation of Three Peptide Immobilization Techniques on a QCM Surface Related to Acetaldehyde Responses in the Gas Phase
PublikacjaThe quartz-crystal microbalance is a sensitive and universal tool for measuring concentrations of various gases in the air. Biochemical functionalization of the QCM electrode allows a label-free detection of specific molecular interactions with high sensitivity and specificity. In addition, it enables a real-time determination of its kinetic rates and affinity constants. This makes QCM a versatile bioanalytical screening tool for...
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Influence of silver-core gold-shell nanoparticle parameters on the variation of surface-enhanced Raman spectra
PublikacjaThe detection of molecules by surface-enhanced Raman spectroscopy (SERS) is dependent on the nanomaterial used to induce the enhancement effect. This depends on a variety of parameters of the substrate such as the metal used for their creation, their shape, size and size distribution, concentration, as well as the parameters of the solution, such as packing of the nanoparticles, the complexity of the sample, the solvent, etc. It...
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A model of liquid film breakdown formed due to impingement of a two-phase jet on a horizontal surface
PublikacjaThe present work aims to provide an explanation to the phenomenon of breakdown of the thin liquid film created by impinging two-phase, liquid-gas jet. Existing in the literature models describe merely thebreakdown of single phase liquid films. The model presented here is based on examination of mass and energy equations under the applied criterion of the minimum of total energy. That allows to determinethe minimum thickness of...
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PARTICLE SIZE ANALYSIS OF SUSPENSIONS IN REMOVING OF ORGANIC MATTER AND PHOSPHORUS FROM WASTEWATER AND SURFACE WATER
PublikacjaIn this paper the particle size of suspended solids in the removing of organic matter and phosphorus compounds from lake water and wastewater treated in the Ecological Treatment Systems (ETS) was analyzed. The invesigated materials were taken from two ETS located in Pomerania Region/Poland. Object in Swarzewo is 3rd stage of biological treatment of municipal wastewater, while object in Kartuzy has task to remove a phosphorus from...
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Behaviour of orthotropic surgical implant in hernia repair due to the material orientation and abdomen surface deformation
Publikacjarelation to the different range of typical deformations observed in different directions and zones of abdomen surface due to the patients’ life activities, has a significant influence on the extreme junction forces in the mesh–tissue connections and hence the repair persistence. The finite element model of the orthotropic implant was developed, and the junction forces in the connections of tissue and mesh were studied. The kinematical...
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Surface and Corrosion Properties of AA6063-T5 Aluminium Alloy in Molybdate-containing Sodium Chloride Solutions
PublikacjaCorrosion properties of aluminium alloy AA6063-T5 were investigated in molybdate-containing NaCl solutions. Electrochemical, microscopic, and spectroscopic experiments were utilized to examine the mechanism of corrosion inhibition by molybdates. SEM-EDX, magnetic force, and intermodulation electrostatic force microscopy data suggested that the inhibition initiation preferentially occurred over Fe-rich cathodic IMPs. Spectroscopic...
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The Influence of the Depth of Cut in Single-Pass Grinding on the Microstructure and Properties of the C45 Steel Surface Layer
PublikacjaThe paper contains the results of a metallographic examination and nanoindentation test conducted for the medium carbon structural steel with low content of Mn, Si, Cu, Cr, and Ni after its grinding to a depth ranging from 2 μm to 20 μm, at constant cutting speed (peripheral speed) of vs = 25 ms−1 and constant feed rate of vft = 1 m/min. Applied grinding parameters did not cause the surface layer hardening, which could generate...
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Deformation and Surface Color Changes of Beech and Oak Wood Lamellas Resulting from the Drying Process
PublikacjaThe drying process was examined relative to parameters’ influence on the deformation and surface layer color changes of beech wood (Fagus sylvatica L.) and oak wood (Quercus robur L.). The goal was to analyze the impact of drying process conditions, wood and growth rings types, and load on the deformation and surface color changes of drying thin wooden elements. A further aim was to reduce the time of the lamella drying and minimize...
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Numerical Model of Surface and Quasi-Spherical Sea Noise and Its Application to Analysis of DIFAR Systems
PublikacjaVarious types of passive sonar systems are used to detect submarines. These activities are complex and demanding. Therefore, computer simulations are most often used at the design stage of these systems. For this reason, it is also necessary to simulate the acoustic ambient noise of the sea. The article proposes a new numerical model of surface and quasi-spherical sea noise and presents its statistical parameters. The results of...
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Strain sequence effect on fatigue life and fracture surface topography of 7075-T651 aluminium alloy
PublikacjaThe paper studies the effect of strain-loading sequence on fatigue lifetime and fracture surface topographies in 7075-T651 aluminum alloy specimens. Fatigue tests were performed in two ways: (i) constant-amplitude loading and (ii) two series of variable amplitude loading with non-zero mean strain values. The topography of the fatigue fractures was measured over their entire surfaces with the help of an optical confocal measurement...
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An isogeometric finite element formulation for boundary and shell viscoelasticity based on a multiplicative surface deformation split
PublikacjaThis work presents a numerical formulation to model isotropic viscoelastic material behavior for membranes and thin shells. The surface and the shell theory are formulated within a curvilinear coordinate system,which allows the representation of general surfaces and deformations. The kinematics follow from Kirchhoff–Love theory and the discretization makes use of isogeometric shape functions. A multiplicative split of the surface...
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Highly Occupied Surface States at Deuterium-Grown Boron-Doped Diamond Interfaces for Efficient Photoelectrochemistry
PublikacjaPolycrystalline boron-doped diamond is a promising material for high-power aqueous electrochemical applications in bioanalytics, catalysis, and energy storage. The chemical vapor deposition (CVD) process of diamond forma-tion and doping is totally diversified by using high kinetic energies of deu-terium substituting habitually applied hydrogen. The high concentration of deuterium in plasma induces atomic arrangements and steric...
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Betaine and L-carnitine ester bromides: Synthesis and comparative study of their thermal behaviour and surface activity
PublikacjaSix esters of both betaine and L-carnitine bromides, featuring alkyl groups ranging from C8 to C18 in length, have been synthesized. The thermal behaviour of these twelve bio-based salts has been analyzed and compared by thermal gravimetric analysis and differential scanning calorimetry. The L-carnitine alkyl ester bromides melted below 100 C and can hence be considered ionic liquids (ILs) with full rights. Conversely, the betaine...
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Studies on novel BiyXz-TiO2/SrTiO3 composites: Surface properties and visible light-driven photoactivity
PublikacjaA series of novel BiyXz-TiO2/SrTiO3 composites were prepared by multistep synthesis route. The asprepared photocatalysts were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), diffuse reflectance spectroscopy (DRS), Fourier transform infrared (FT-IR), Raman spectra and BET analysis. The photocatalytic activity test was performed in aqueous solution of phenol under...
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Visible light photocatalysis employing TiO2/SrTiO3-BiOI composites: Surface properties and photoexcitation mechanism
PublikacjaA series of binary TiO2/SrTiO3 and ternary TiO2/SrTiO3_BiOI composites have been synthesized using multistep preparation method. Characterization of the obtained photocatalysts covered complex analysis including morphology + y (SEM), BET specific surface area, porosity, optical properties (DRS), chemical composition of surface (XPS), crystal structure and crystal size (XRD). UV–vis and Vis ligh induced photocatalytic activity was...
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The Empirical Application of Automotive 3D Radar Sensor for Target Detection for an Autonomous Surface Vehicle’s Navigation
PublikacjaAvoiding collisions with other objects is one of the most basic safety tasks undertaken in the operation of floating vehicles. Addressing this challenge is essential, especially during unmanned vehicle navigation processes in autonomous missions. This paper provides an empirical analysis of the surface target detection possibilities in a water environment, which can be used for the future development of tracking and anti-collision...
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Degradable poly(ester-ether) urethanes of improved surface calcium deposition developed as novel biomaterials
PublikacjaBones, which are considered as hard tissues, work as scaffold for human body. They provide physical support for muscles and protect intestinal organs. Percentage of hard tissues in human body depends on age, weight, and gender. Human skeleton consists of 206 connected bones. Therefore, it is natural that the hard-tissue damage such as fractures, osteoporosis, and congenital lack of bone may appear. The innovative way of bone healing...
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Curing epoxy with ethylenediaminetetraacetic acid (EDTA) surface-functionalized Co Fe3-O4 magnetic nanoparticles
PublikacjaIn this work, the bulk and surface composition of Fe3O4 supermagnetic nanoparticles were modified for efficient epoxy curing. The bare, ethylenediaminetetraacetic acid (EDTA) capped, and cobalt (Co)-doped EDTA capped Fe3O4 nanoparticles were synthesized electrochemically. The crystalline structure and phase information, surface capping, morphology and magnetization behavior of nanoparticles were studied by X-Ray diffraction (XRD),...
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In-Out Surface Modification of Halloysite Nanotubes (HNTs) for Excellent Cure of Epoxy: Chemistry and Kinetics Modeling
PublikacjaIn-out surface modification of halloysite nanotubes (HNTs) has been successfully performed by taking advantage of 8-hydroxyquinolines in the lumen of HNTs and precisely synthesized aniline oligomers (AO) of different lengths (tri- and pentamer) anchored on the external surface of the HNTs. Several analyses, including FTIR, H-NMR, TGA, UV-visible spectroscopy, and SEM, were used to establish the nature of the HNTs’ surface engineering....
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Measurement of the Temporal and Spatial Temperature Distribution on the Surface of PVCP Tissue Phantom Illuminated by Laser Dataset
PublikacjaThe dataset entitled Measurement of the temporal and spatial temperature distribution on the surface of PVCP tissue phantom illuminated by laser was obtained with a laboratory set-up for characterisation of the thermal properties of optical tissue phantoms during laser irradiation. The dataset contains a single image file representing the spatial temperature distribution on the surface of a PVCP tissue phantom. This thermal image...
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Evaluation of the Cathodic Electrodeposition Effectiveness of the Hydroxyapatite Layer Used in Surface Modification of Ti6Al4V-Based Biomaterials
PublikacjaThe important issue associated with the design and the fabrication of the titanium and titanium alloy implants is the increase of their biointegration with bone tissue. In the presented paper, the research results concerning the conditions used in the cathodic deposition of hydroxyapatite on the surface Ti6Al4V substrates primarily modified by the production of TiO2 nanoporous coatings, TiO2 nanofibers, and titanate coatings, are...
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Blade Section Prpfile Array Lifting Surface Design Method for Marine Screw Propeller Blade
PublikacjaThe lifting surface model is widely used in screw propeller design and analysis applications. It serves as a reliable tool for determination of the propeller blade mean line and pitch distribution. The main idea of this application was to determine the blade shape that would satisfy the kinematic boundary condition on its surface with the prescribed bound circulation distribution over it. In this paper a simplified lifting surface...
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Determination of selected parameters/ analytes in surface water samples collected in the surroundings of the capital of Spitsbergen (Longyearbyen)
PublikacjaPolar regions are extremely sensitive to pollution such as harmful gases, particles or toxic substances which affect the Arctic climate and ecosystems. Spitsbergen, as well as all Arctic region, because of its geographically distant location and lack of industry sector, should be free of chemical pollution. Despite this, many pollutants could be found in the Polar environment, for example in freshwaters. Their occurrence is related...
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Laser-assisted modification of titanium dioxide nanotubes in a tilted mode as surface modification and patterning strategy
PublikacjaElectrochemical anodization is regarded as a facile and easily scalable fabrication method of titania nanotubes (TiO2NTs). However, due to the extended duration of calcination and further modifications, much faster alternatives are highly required. As a response to growing interest in laser modification of nanotube arrays, a comprehensive investigation of pulsed-laser irradiation and its effect onto TiO2NT properties has been carried out....
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Analiza wad powierzchni gorącowalcowanych wyrobów stalowych = Hot rolled sections surface defects analysis
PublikacjaZanalizowano hutnicze wady powierzchni dwuteowników walcowanych na gorąco, głebokość zdefektowanych obszarów i zmiany mikrostruktury w tych obszarach.
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Synergistic interactions and reaction mechanisms of biochar surface functionalities in antibiotics removal from industrial wastewater
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Patterned hydrophobic and hydrophilic surfaces of ultra-smooth nanocrystalline diamond layers
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Phonons of (100) and (110) iron surfaces from first-principles calculations
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Application of acoustic emission metod for measurement of joint gap and cartilage surfaces
PublikacjaW artykule przedstawiono zastosowanie emisji akustycznej do lokalizacji wczesnych uszkodzeń stawu biodrowego lub kolanowego człowieka. Ponadto metoda ta służy do pomiaru wysokości szczeliny stawu oraz struktury geometrycznej powierzchni chrząstki stawowej. Jest to metoda nieinwazyjna. Pomiary metodą emisji akustycznej stosujemy na ogół w materiałach, w których energia sprężysta zmienia się nagle. Takie zmiany energii mogą być...
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Cutting Forces and Vibrations During Ball End Milling of Inclined Surfaces
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