Wyniki wyszukiwania dla: INJECTABLE HYDROGEL
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Structural and electrical transport studies of reduced in hydrogen surfaceof bismuth germanate glass
PublikacjaOtrzymano nanostruktury krystalicznego bizmutu w matrycy szkła germanowegooraz warstwę nanostruktur krystalicznego bizmutu na powierzchni redukowanegow atmosferze wodoru szkła Bi0.33Ge0.67O1.83. Zaproponowano prosty model bu-dowy zredukowanych szkieł bizmutowo-germanowych potwierdzony wynikami badańAFM i XRD. Zbadano wpływ czasu i temperatury redukcji oraz topnienia bizmu-tu na własności elektryczne badanych szkieł. Przeanalizowano...
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Structure and morphology of hydrogen reduced surface of bismuth germanateand bismuth silicate glasses.
PublikacjaOtrzymano nanostruktury krystalicznego bizmutu w matrycy XO2(X=Si,Ge) oraz warstwę nanostruktur krystalicznego bizmutu na powierzchni redukowanych w atmosferze wodoru szkieł Bi0.33Ge0.67O1. i Bi0.57Si0.43O1.72. Zaproponowano prosty model budowy zredukowanych szkieł bizmutowo-germanowych potwierdzony wynikami badań AFM i XRD. Obserwowane zmiany przewodnictwa elektrycznego redukowanych szkieł wyjaśniono na podstawie modelu.
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Investigating BiMeVOx compounds as potential photoelectrochemical and electrochemical materials for renewable hydrogen production
PublikacjaIn this study, BiMeVOx compounds (where Me: Co, Mo, Ce, Zr) were synthesized and characterized as potential photoelectrochemical materials for solar water splitting, the hydrogen evolution reaction (HER), and oxygen evolution reaction (OER). The analysis confirmed the successful formation of phase BiMeVOx compounds with the desired crystal structure. Among the tested materials, BiCoVOx(800) showed the highest photocurrent density...
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State selective electron capture in the collision of S3+ ions in atomic hydrogen and helium.
PublikacjaZostało zaprezentowane teoretyczne podejście, uwzględniające obliczenia krytycznych adiabatycznych energii potencjalnych i dynamicznych sprzężeń pomiędzy nimi, do opisu procesu przechwytu elektronu przez jony siarki w zderzeniach z atomami wodoru i helu.
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The new analyzer based on single pellistor sensor for determination of hydrogen and methane in air
PublikacjaW artykule przedstawiono rezultaty niedawnych badań nad konstrukcją prostego i selektywnego analizatora do monitoringu stężenia gazów wybuchowych w powietrzu. Opisano konstrukcję takiego urządzenia i wyniki prób laboratoryjnych dla gazowych mieszanin wzorcowych.
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Strength deterioration of 26H2MF and 34HNM steels used in ship engines: hydrogen factor
PublikacjaBadano podatność stali 26H2MF i 34HNM poddanych różnej obróbce cieplnej na niszczenie wodorowe. Badania wykonano metodą powolnego rozciągania z szybkością 10-6 s-1. Określano wytrzymałość, wydłużenie, przewężenie i energię zniszczenia. Stwierdzono znaczna degradację w 0,01 M kwasie siarkowym z dodatkiem arszeniku. Wykazano istnienie korelacji między obróbką cieplną i stopniem degradacji. Efekty przypisano pułapkowaniu wodoru.
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Techno-economic assessment of cooperation of hybrid renewable energy sources with hydrogen storage
PublikacjaThe paper presents a technical and economic analysis of the power supply for a model industrial facility with the use of the most promising renewable energy sources (RES), supported by a hydrogen energy storage. This scenario was compared with the variants of supplying the facility directly from the grid and from RES without energy storage. A strategy was proposed for powering the plant aimed at maximising self-consumption of self-generated...
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Recent advances in hydrogen production from biomass waste with a focus on pyrolysis and gasification
PublikacjaThis paper presents the results research on the optimal fuel compositions and the control parameters of the spark ignition engine fueled with syngas-biogas-hydrogen for the purpose of setting up a flexible electronic control unit for the engine working in a solar-biomass hybrid renewable energy system. In syngas-biogas-hydrogen mixture, the optimal content of hydrogen and biogas is 20% and 30%, respectively. Exceeding these thresholds,...
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Bismuth-based nanomaterials-assisted photocatalytic water splitting for sustainable hydrogen production
PublikacjaThe rapidly increase in the world's population has resulted in a corresponding increase in the energy demand. This demand is largely being met by fossil fuels for power generation, industrial fuel and transportation. However, due to the limited availability of fossil fuels and their negative effects on the environment. The use of fossil fuels results in by-products such as carbon, nitrogen and sulfur oxides which have negative...
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Effect of plasma nitrided layers on low-alloy steel on its hydrogen degradation
PublikacjaPrzedstawiono badania wpływu warstw azotowanych jarzeniowo na stali 34CrAlNi7-10 na jej podatność na niszczenie wodorowe. Wytworzono warstwy azotowane w atmosferach technologicznych o różnym udziale wodoru. Próbki materiału rodzimego i z warstwami azotowanymi poddano próbie rozciągania z małą prędkością odkształcania w środowisku 0,01 N kwasu siarkowego przy polaryzcaji katodowej. Względny spadek plastyczności i charakter przełomu...
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Bismuth-based nanomaterials-assisted photocatalytic water splitting for sustainable hydrogen production
PublikacjaThe rapidly increase in the world's population has resulted in a corresponding increase in the energy demand. This demand is largely being met by fossil fuels for power generation, industrial fuel and transportation. However, due to the limited availability of fossil fuels and their negative effects on the environment. The use of fossil fuels results in by-products such as carbon, nitrogen and sulfur oxides which have negative...
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Bi-based halide perovskites: Stability and opportunities in the photocatalytic approach for hydrogen evolution
PublikacjaIn this study, we successfully prepared Bi-based single perovskites of the A3Bi2I9 type (A = Cs, Rb, MA, FA), and, for the first time, attempted to experimentally obtain double perovskites Cs2B’BiI6 type (B′ = Ag, Au, In, Cu). Despite the premises available in theoretical studies, our research has proven the impossibility of the existence of double perovskites of this type. Nevertheless, both types of obtained materials were subjected...
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Intermolecular Hydrogen Bonding Directed by Aryl–Perfluoroaryl π–π Stacking Interactions
PublikacjaThe crystal structures of five compounds capable of forming self-complementary hydrogen bonds but crystallizing as catemers or creating more complex crystal structures were compared with their complexes prepared by cocrystallization with perfluoroaryl compounds. The results of X-ray diffraction revealed that in all the cases the π–π stacking interactions caused reorganization of hydrogen bonds and induced creation of the expected...
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Hydrogen Embrittlement and Oxide Layer E ect in the Cathodically Charged Zircaloy-2
PublikacjaThe present paper is aimed at determining the less investigated effects of hydrogen uptake on the microstructure and the mechanical behavior of the oxidized Zircaloy-2 alloy. The specimens were oxidized and charged with hydrogen. The different oxidation temperatures and cathodic current densities were applied. The scanning electron microscopy, X-ray electron diffraction spectroscopy, hydrogen absorption assessment, tensile, and...
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DETERMINATION OF DIFFUSIBLE HYDROGEN CONTENT IN DEPOSITED METAL OF RUTILE ELECTRODES BY GLYCERIN METHOD
PublikacjaThe presence of diffusible hydrogen in welded joints is one of the causes of formation the welding imperfections. Improvement of weldability can be achieved by reducing the hydrogen amount in welded joints. This requires, among others, the finding of sources of hydrogen. For high hydrogen processes the commonly used method of determining the diffusible hydrogen amount is the glycerin method. This paper concerns issues related to...
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Shape-controllable synthesis of GdVO4 photocatalysts and their tunable properties in photocatalytic hydrogen generation
PublikacjaNovel visible light responsive materials for water splitting are essential for the efficient conversion of solar energy into hydrogen bond energy. Among other semiconductors, gadolinium orthovanadate has appropriate conduction and valence band edges positioned to split water molecules and a narrow band gap that allows the use of visible light for hydrogen generation. Thus, we present here that hydrogen evolution under visible light...
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Structure and thermoelectric properties of nickel-doped copper selenide synthesised in a hydrogen atmosphere
PublikacjaNickel-doped copper selenide—Cu2-xNixSe (x = 0; 0.01; 0.02; 0.03)—materials with high thermoelectric properties were synthesised through reduction of reagents in hydrogen. The impact of the nickel content on both the microstructure and thermoelectric properties was examined. The nickel-doped samples’ microstructure differed significantly from pristine copper selenide. Besides Cu2Se, copper precipitations were present in the materials....
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Bioconversion of waste materials to hydrogen via dark fermentation using Enterobacter aerogenes
PublikacjaHydrogen can be obtained via dark fermentation with the use of anaerobic Enterobacter aerogenes. The efficiency of hydrogen production by fermentation techniques is strongly dependent on the con-ditions used i.e. the pH range, temperature, composition of fermentation broths, oxygen content, or even the presence of substances with potentially inhibitory effects on the microbiological culture [1-4]. The paper describes the study...
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Neutral Dissociation of Pyridine Evoked by Irradiation of Ionized Atomic and Molecular Hydrogen Beams
PublikacjaThe interactions of ions with molecules and the determination of their dissociation patterns are challenging endeavors of fundamental importance for theoretical and experimental science. In particular, the investigations on bond-breaking and new bond-forming processes triggered by the ionic impact may shed light on the stellar wind interaction with interstellar media, ionic beam irradiations of the living cells, ion-track nanotechnology,...
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Hydrogel Delivery System Containing Calendulae flos Lyophilized Extract with Chitosan as a Supporting Strategy for Wound Healing Applications
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DEVELOPMENT OF HYDROGEL CAPSULES FOR USE IN DUAL-PHASE TOPICAL PREPARATIONS CONTAINING DIHYDROXYACETONE AND AMINO ACIDS – PRELIMINARY RESULTS
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In vivo evaluation of the antipsoriatic effect of hydrogel with lavandin essential oil and its main components after topical application
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Expermental investigation on adsorption of methylene blue dye from waste water using corncob cellulose-based hydrogel
PublikacjaHydrogel from corncob cellulose was synthesized in this investigation. The synthesized Hydrogel was characterized by SEM, XRD, and FTIR instruments. As the results indicate the synthesized hydrogel has required and important features, these suggest the suitability of hydrogel for the adsorption of methylene blue dye (MBD). Three important process variables (dosage, contact time, and initial concentration) with three levels were...
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Effect of Pd loading on hydrogen storage properties of disordered mesoporous hollow carbon spheres
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PANI/NaTaO3 composite photocatalyst for enhanced hydrogen generation under UV light irradiation
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Oxidized SWCNT and MWCNT as co-catalysts of polymeric carbon nitride for photocatalytic hydrogen evolution
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Enhancement of photocatalytic hydrogen evolution with catalysts based on carbonized MOF-5 and g-C3N4
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Aluminum-TiO2 NPs Composites as Non-precious Catalysts for Efficient Electrochemical Generation of Hydrogen
PublikacjaIn this paper, we demonstrated, for the first time, aluminum titania nanoparticle (Al-TiO2 NP) composites with variable amounts of TiO2 NPs as nonprecious active catalysts for the electrochemical generation of H2. These materials were synthesized by mixing desired amounts of hydrogen titanate nanotubes (TNTs), fabricated here by a cost-effective approach at moderate hydrothermal conditions, with aluminum powder (purity 99.7%; size...
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Diffusible hydrogen management in underwater wet self-shielded flux cored arc welding
PublikacjaThis article reports the effect of underwater wet welding parameters and conditions on the diffusible hydrogen content in deposited metal for welding with a self-shielded flux cored wire. The diffusible hydrogen content in deposited metal was determined using the glycerin method according to the Plackett-Burman design determining the significance of the effect of the stick out length, welding current, arc voltage, travel speed...
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Nanosize effect of clay mineral nanoparticles on the drug diffusion processes in polyurethane nanocomposite hydrogels
PublikacjaStudies of swelling and release of naproxen sodium (NAP) solution by polyurethane nanocomposite hydrogels containing Cloisite® 30B (organically modified montmorillonite (OMMT)) have been performed. Polyurethane nanocomposite hydrogels are hybrid, nontoxic biomaterials with unique swelling and release properties in comparison with unmodified hydrogels. These features enable to use nanocomposite hydrogels as a modern wound dressing....
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Mathematical modeling of hydrogen production performance in thermocatalytic reactor based on the intermetallic phase of Ni3Al
PublikacjaThe main goal of the following work is to adjust mathematical modelling for mass transfer, to specific conditions resulting from presence of chemical surface reactions in the flow of the mixture consisting of helium and methanol. The thermocatalytic devices used for decomposition of organic compounds incorporate microchannels coupled at the ends and heated to 500 oC at the walls regions. The results of the experiment were compared...
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Review of hydrogen production technologies for automotive sector – thermodynamic analysis of energy and exergy losses
PublikacjaFew recent years has shown that hydrogen technology has a good chance to replace petroleum technology in automotive sector. However, hydrogen in pure form practically does not occur on Earth. That is why H2 form is used only as an energy carrier and it must be produced using another source of energy form water or hydrocarbon fuels. In this paper short overview of hydrogen production technology has been presented, with energy and...
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The effect of pre-hydrogen charging on corrosion behaviour of superduplex stainless steel welded joints
PublikacjaThe paper presents results of research undertaken to determine the influence of hydrogen on passivity and corrosion resistance of 2507 super duplex stainless steel welded joints. Butt welded joints were made with low heat input using flux corded arc welding (FCAW) method. Coupons of 5.0 x 5.0 mm were cut from the welded joints containing weld metal (WM), heat affected zone (HAZ) and parent metal (PM). Hydrogen was introduced...
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Pd nanoparticles with tunable diameter deposited on carbon nanotubes with enhanced hydrogen storage capacity
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Crystal structure, hydrogen bonds, and lattice dynamics in kanemite from first-principles calculations
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In situ deposition of Pd nanoparticles with controllable diameters in hollow carbon spheres for hydrogen storage
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Pressure and temperature effect on hypergolic ignition delay of triglyme-based fuel with hydrogen peroxide
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Experimental determination of critical conditions for hydrogen-air detonation propagation in partially confined geometry
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Photocatalytic mineralisation of humic acids using TiO2 modified by tungsten dioxide/ hydrogen peroxide
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Effect of shielded electrode wet welding conditions on diffusible hydrogen content in deposited metal
PublikacjaWet welding is the most popular method of joining in water enviroment. During underwater welding, the weldability of steel is limited by the higher cooling rates and hydrogen content in weld metal. Article presents results of preliminary tests on the effects of wet welding conditions on diffusible hydrogen amount. Seven parameters were optimized using a Plackett-Burman plan to get the most relevant variables. These parameters were:...
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High temperature air/steam gasification of biomass in view of hydrogen rich gas production.
PublikacjaArtykuł przedstawia opis nowej i zaawansowanej metody konwersji termochemicznej biomasy i miejskich odpadów stałych w paliwo gazowe, bogate w wodór. W porównaniu z tradycyjnym procesem gazyfikacji, w metodzie tej wykorzystuje się powietrze/parę wodną przegrzane do wysokiej temperatury (powyżej 1300 st. C). Przegrzanie powietrza lub pary wodnej odbywa się z zastosowaniem ceramicznego przegrzewacza wysokotemperaturowego. W celu...
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Hydrogen-enhanced stress corrosion cracking and corrosion fatigue of HSLA steels in sea-water
PublikacjaPrzedstawiono ocenę podatności stali o wysokiej wytrzymałości na naprężeniowe pękanie korozyjne i zmęczenie korozyjne wspomagane przez wodór. Wykonano próby powolnego rozciągania i zmęczenia niskoczęstotliwościowego na stalach 17HMBVA i 14HNMBCu oraz ich złączach spawanych, w środowisku wody morskiej, przy polaryzacji katodowej. Zamieszczono wyniki badań elektrochemicznych oraz przełomów na skaningowym mikroskopie elektronowym.
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Hydrogen rich gas production from high temperature air/steam gasification of biomass
PublikacjaW pracy przedstawiono nowoczesną technikę konwersji biomasy oraz stałych odpadów komunalnych w celu produkcji paliwa gazowego bogatego w wodór. Opisany proces gazyfikacji przebiega w wysokiej temperaturze przy obniżonej koncentracji tlenu i udziale pary wodnej. Dzięki temu możliwa jest produkcja gazów palnych, w szczególności H2, który można wykorzystać do produkcji energii elektrycznej i cieplnej.
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Effect of wet Hydrogen Sulfide on Carbon Steels Degradation in Refinery Based on Case Study
PublikacjaMaterial degradation caused by wet hydrogen sulfide (Wet H2S) is one of the major issues in refineries. Carbon steel is the main construction material used in refineries and is subjected not only to thickness loss but the hydrogen is the major concern. H2S leads to high atomic hydrogen penetration in steel which causes degradation in the form of blistering and/or cracking (HIC/SOHIC) and stress cracking in the area of welds and...
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Influence of conductive carbon and MnCo2O4 on morphological and electrical properties of hydrogels for electrochemical energy conversion
PublikacjaIn this work, a strategy for one-stage synthesis of polymer composites based on PNIPAAm hydrogel was presented. Both conductive particles in the form of conductive carbon black (cCB) and MnCo2O4 (MCO) spinel particles were suspended in the three-dimensional structure of the hydrogel. The MCO particles in the resulting hydrogel composite acted as an electrocatalyst in the oxygen evolution reaction. Morphological studies confirmed...
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Niszczenie wodorowe stali o podwyższonej wytrzymałości = Hydrogen degradation of high-strength steels.
PublikacjaW artykule przedstawiono niszczenie wodorowe stali 18G2A i jej symulowanej strefy wpływu ciepła (SWC). Jako parametry niszczenia wodorowego wybrano względne wartości energii zniszczenia, czasu do pęknięcia, wydłużenia, przewężenia i wytrzymałości na rozciąganie. Parametry te wyznaczono w próbie odkształcania z małą prędkością na próbkach gładkich, okrągłych. Stwierdzono, że stal 18G2A w środowisku kwaśnym (0,1 N H2SO4) podczas...
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Preliminary investigations of effect of conditions of FCAW process on diffusible hydrogen content in deposited metal
PublikacjaOne of the types of hydrogen degradation of steel welded joints is cold cracking. The direct cause of the formation of cold cracks is simultaneous presence of hydrogen, residual stresses and brittle structure. The way of preventing the occurring of degradation is to eliminate at least one of these factors. Practice has shown that the best solution is to control the amount of hydrogen in deposited metal. In this paper the state...
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Bismuth-Doped Nano Zerovalent Iron: A Novel Catalyst for Chloramphenicol Degradation and Hydrogen Production
PublikacjaIn this study, we showed that doping bismuth (Bi) at the surface of Fe0 (Bi/Fe0, bimetallic iron system)—synthesized by a simple borohydride reduction method—can considerably accelerate the reductive degradation of chloramphenicol (CHP). At a reaction time of 12 min, 62, 68, 74, 95, and 82% degradation of CHP was achieved with Fe0, Bi/Fe0-1 [1% (w/w) of Bi], Bi/Fe0-3 [3% (w/w) of Bi], Bi/Fe0-5 [5% (w/w) of Bi], and Bi/Fe0-8 [8%...
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Conversion of Biomass and Municipal Wastes into Syngas and Hydrogen using Highly Preheated Agent (HTAG)
PublikacjaGasification is considered to be one of the most promising energy recovery technologies for the widespread utilization of biomass and wastes. During this process raw feedstock is converted into a combustible gas, which can then be burnt to produce thermal energy, or to run engines for mechanical or electrical power. The studies of biomass gasification demonstrate it as a friendly alternative to fossil fuels as one of renewable...
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Hydrogen Production from Energy Poplar Preceded by MEA Pre-Treatment and Enzymatic Hydrolysis
PublikacjaThe need to pre-treat lignocellulosic biomass prior to dark fermentation results primarily from the composition of lignocellulose because lignin hinders the processing of hard wood towards useful products. Hence, in this work a two-step approach for the pre-treatment of energy poplar, including alkaline pre-treatment and enzymatic saccharification followed by fermentation has been studied. Monoethanolamine (MEA) was used as the...